CN1537909A - 用于滑动部件中的涂料组合物 - Google Patents
用于滑动部件中的涂料组合物 Download PDFInfo
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- CN1537909A CN1537909A CNA2004100329725A CN200410032972A CN1537909A CN 1537909 A CN1537909 A CN 1537909A CN A2004100329725 A CNA2004100329725 A CN A2004100329725A CN 200410032972 A CN200410032972 A CN 200410032972A CN 1537909 A CN1537909 A CN 1537909A
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- coating composition
- coupling agent
- mass percent
- slip film
- adhesive resin
- Prior art date
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- 238000000576 coating method Methods 0.000 title description 6
- 239000011248 coating agent Substances 0.000 title description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 86
- 239000000843 powder Substances 0.000 claims abstract description 61
- 239000008199 coating composition Substances 0.000 claims abstract description 43
- 239000000314 lubricant Substances 0.000 claims abstract description 39
- 239000007787 solid Substances 0.000 claims abstract description 39
- 229920002312 polyamide-imide Polymers 0.000 claims abstract description 33
- 239000004962 Polyamide-imide Substances 0.000 claims abstract description 32
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 28
- 239000004840 adhesive resin Substances 0.000 claims description 37
- 229920006223 adhesive resin Polymers 0.000 claims description 37
- 239000004408 titanium dioxide Substances 0.000 claims description 37
- 239000007822 coupling agent Substances 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 5
- 125000000524 functional group Chemical group 0.000 claims description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 3
- 125000003700 epoxy group Chemical group 0.000 claims 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 description 29
- 239000011347 resin Substances 0.000 description 29
- -1 polytetrafluoroethylene Polymers 0.000 description 24
- 239000000758 substrate Substances 0.000 description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- 239000010954 inorganic particle Substances 0.000 description 14
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 10
- 239000000377 silicon dioxide Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 8
- 239000004810 polytetrafluoroethylene Substances 0.000 description 8
- 229910002804 graphite Inorganic materials 0.000 description 6
- 239000010439 graphite Substances 0.000 description 6
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 6
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 6
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 6
- PRKPGWQEKNEVEU-UHFFFAOYSA-N 4-methyl-n-(3-triethoxysilylpropyl)pentan-2-imine Chemical compound CCO[Si](OCC)(OCC)CCCN=C(C)CC(C)C PRKPGWQEKNEVEU-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- KBJFYLLAMSZSOG-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)aniline Chemical compound CO[Si](OC)(OC)CCCNC1=CC=CC=C1 KBJFYLLAMSZSOG-UHFFFAOYSA-N 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- LTQBNYCMVZQRSD-UHFFFAOYSA-N (4-ethenylphenyl)-trimethoxysilane Chemical compound CO[Si](OC)(OC)C1=CC=C(C=C)C=C1 LTQBNYCMVZQRSD-UHFFFAOYSA-N 0.000 description 1
- DOYKFSOCSXVQAN-UHFFFAOYSA-N 3-[diethoxy(methyl)silyl]propyl 2-methylprop-2-enoate Chemical compound CCO[Si](C)(OCC)CCCOC(=O)C(C)=C DOYKFSOCSXVQAN-UHFFFAOYSA-N 0.000 description 1
- LZMNXXQIQIHFGC-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propyl 2-methylprop-2-enoate Chemical compound CO[Si](C)(OC)CCCOC(=O)C(C)=C LZMNXXQIQIHFGC-UHFFFAOYSA-N 0.000 description 1
- URDOJQUSEUXVRP-UHFFFAOYSA-N 3-triethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C(C)=C URDOJQUSEUXVRP-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229910000639 Spring steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 210000000038 chest Anatomy 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- PKTOVQRKCNPVKY-UHFFFAOYSA-N dimethoxy(methyl)silicon Chemical compound CO[Si](C)OC PKTOVQRKCNPVKY-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002118 epoxides Chemical group 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 229910052961 molybdenite Inorganic materials 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- INJVFBCDVXYHGQ-UHFFFAOYSA-N n'-(3-triethoxysilylpropyl)ethane-1,2-diamine Chemical compound CCO[Si](OCC)(OCC)CCCNCCN INJVFBCDVXYHGQ-UHFFFAOYSA-N 0.000 description 1
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 1
- MQWFLKHKWJMCEN-UHFFFAOYSA-N n'-[3-[dimethoxy(methyl)silyl]propyl]ethane-1,2-diamine Chemical compound CO[Si](C)(OC)CCCNCCN MQWFLKHKWJMCEN-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- NESLVXDUKMNMOG-UHFFFAOYSA-N triethoxy-(propyltetrasulfanyl)silane Chemical compound CCCSSSS[Si](OCC)(OCC)OCC NESLVXDUKMNMOG-UHFFFAOYSA-N 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D179/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
- C09D179/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C09D179/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/065—Sulfides; Selenides; Tellurides
- C10M2201/066—Molybdenum sulfide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/06—Perfluoro polymers
- C10M2213/062—Polytetrafluoroethylene [PTFE]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/044—Polyamides
- C10M2217/0443—Polyamides used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/055—Particles related characteristics
- C10N2020/06—Particles of special shape or size
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/015—Dispersions of solid lubricants
- C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16N—LUBRICATING
- F16N15/00—Lubrication with substances other than oil or grease; Lubrication characterised by the use of particular lubricants in particular apparatus or conditions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Lubricants (AREA)
- Paints Or Removers (AREA)
- Compressors, Vaccum Pumps And Other Relevant Systems (AREA)
- Compressor (AREA)
Abstract
Description
(质量%) | C1 | C2 | C3 | C4 | C5 | C6 | C7 | C8 | C9 | C10 | |
PAI树脂(作为活性成分) | 65 | 65 | 65 | 65 | 65 | 65 | 65 | 65 | 65 | 65 | |
固体润滑剂 | PTFE粉末 | 35 | 30 | 25 | 15 | 34 | 33 | 32 | 28 | 23 | 13 |
二硫化钼 | - | - | - | - | - | - | - | - | - | - | |
石墨 | - | - | - | - | - | - | - | - | - | - | |
每100%质量百分比的PAI树脂的固体润滑剂的质量% | 53.8 | 46.2 | 38.5 | 23.1 | 52.3 | 50.1 | 49.2 | 43.1 | 35.4 | 20.0 | |
无机颗粒 | 氧化钛粉末 | - | 5 | 10 | 20 | - | - | - | 5 | 10 | 20 |
碳化硅粉末 | - | - | - | - | - | - | - | - | - | - | |
硅石粉末 | - | - | - | - | - | - | - | - | - | - | |
每100%质量百分比的PAI树脂的无机颗粒的质量% | 0 | 7.7 | 15.4 | 30.8 | 0 | 0 | 0 | 7.7 | 15.4 | 30.8 | |
硅烷偶联剂 | 2-(3,4-环氧环己基)乙基三甲氧基硅烷 | - | - | - | - | 1 | 2 | 3 | 2 | 2 | 2 |
3-三乙氧基甲硅烷基-N-(1,3-二甲基-亚丁基)丙胺 | - | - | - | - | - | - | - | - | - | - |
N-苯基-3-氨丙基三甲氧基硅烷 | - | - | - | - | - | - | - | - | - | - | |
3-脲基丙基三乙氧基硅烷 | - | - | - | - | - | - | - | - | - | - | |
3-异氰酰丙基三乙氧基硅烷 | - | - | - | - | - | - | - | - | - | - | |
每100%质量百分比的PAI树脂的硅烷偶联剂的质量% | 0 | 0 | 0 | 0 | 1.5 | 3.1 | 4.6 | 3.1 | 3.1 | 3.1 |
(质量%) | C11 | C12 | C13 | C14 | C15 | C16 | C17 | C18 | C19 | C20 | |
PAI树脂(作为活性成分) | 65 | 65 | 65 | 58 | 50 | 65 | 65 | 65 | 65 | 65 | |
固体润滑剂 | PTFE粉末 | 24 | 23 | 22 | 30 | 38 | 23 | 23 | 23 | 23 | - |
二硫化钼 | - | - | - | - | - | - | - | - | - | 25 | |
石墨 | - | - | - | - | - | - | - | - | - | 10 | |
每100%质量百分比的PAI树脂的固体润滑剂的质量% | 36.9 | 35.4 | 33.8 | 51.7 | 76.0 | 35.4 | 35.4 | 35.4 | 35.4 | 53.8 | |
无机颗粒 | 氧化钛粉末 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | - |
碳化硅粉末 | - | - | - | - | - | - | - | - | - | - | |
硅石粉末 | - | - | - | - | - | - | - | - | - | - | |
每100%质量百分比的PAI树脂的无机颗粒的质量% | 15.4 | 15.4 | 15.4 | 17.2 | 20.0 | 15.4 | 15.4 | 15.4 | 15.4 | 0 | |
硅烷偶联剂 | 2-(3,4-环氧环己基)乙基三甲氧基硅烷 | 1 | 2 | 3 | 2 | 2 | - | - | - | - | - |
3-三乙氧基甲硅烷基-N-(1,3-二甲基-亚丁基)丙胺 | - | - | - | - | - | 2 | - | - | - | - |
N-苯基-3-氨丙基三甲氧基硅烷 | - | - | - | - | - | - | 2 | - | - | - | |
3-脲基丙基三乙氧基硅烷 | - | - | - | - | - | - | - | 2 | - | - | |
3-异氰酰丙基三乙氧基硅烷 | - | - | - | - | - | - | - | - | 2 | - | |
每100%质量百分比的PAI树脂的硅烷偶联剂的质量% | 1.5 | 3.1 | 4.6 | 3.4 | 4.0 | 3.1 | 3.1 | 3.1 | 3.1 | 0 |
(质量%) | C21 | C22 | C23 | C24 | C25 | C26 | C27 | C28 | C29 | C30 | |
PAI树脂(作为活性成分) | 95 | 90 | 80 | 70 | 50 | 80 | 80 | 70 | 70 | 75 | |
固体润滑剂 | PTFE粉末 | - | - | - | - | - | - | - | - | 20 | 20 |
二硫化钼 | - | - | - | - | - | - | - | 20 | - | - | |
石墨 | - | - | - | - | - | - | - | 10 | - | - | |
每100%质量百分比的PAI树脂的固体润滑剂的质量% | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 42.9 | 28.9 | 26.7 | |
无机颗粒 | 氧化钛粉末 | 5 | 10 | 20 | 30 | 50 | - | - | - | 10 | - |
碳化硅粉末 | - | - | - | - | - | 20 | - | - | - | - | |
硅石粉末 | - | - | - | - | - | - | 20 | - | - | - | |
每100%质量百分比的PAI树脂的无机颗粒的质量% | 5.3 | 11.1 | 25.0 | 42.9 | 100.0 | 25.0 | 25.0 | 0 | 14.3 | 0 | |
硅烷偶联剂 | 2-(3,4-环氧环己基)乙基三甲氧基硅烷 | - | - | - | - | - | - | - | - | - | 5 |
每100%质量百分比的PAI树脂的硅烷偶联剂的质量% | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 6.7 |
(质量%) | C31 | C32 | C33 | C34 | C35 | C36 | C37 | |
PAI树脂(作为活性成分) | 65 | 65 | 65 | 65 | 65 | 65 | 80 | |
固体润滑剂 | PTFE粉末 | 20 | 24.9 | 21 | 23 | 23 | 23 | 20 |
二硫化钼 | - | - | - | - | - | - | - | |
石墨 | - | - | - | - | - | - | - | |
每100%质量百分比的PAI树脂的固体润滑剂的质量% | 30.1 | 38.3 | 32.3 | 35.4 | 35.4 | 35.4 | 25.0 | |
无机颗粒 | 氧化钛粉末 | 10 | 10 | 10 | 10 | 10 | 10 | - |
碳化硅粉末 | - | - | - | - | - | - | - | |
硅石粉末 | - | - | - | - | - | - | - | |
每100%质量百分比的PAI树脂的无机颗粒的质量% | 15.4 | 15.4 | 15.4 | 15.4 | 15.4 | 15.4 | 0 | |
硅烷偶联剂 | 2-(3,4-环氧环己基)乙基三甲氧基硅烷 | 5 | 0.1 | 4 | - | - | - | - |
3-环氧丙氧丙基三甲氧基硅烷 | - | - | - | 2 | - | - | - | |
3-环氧丙氧丙基甲基二乙氧基硅烷 | - | - | - | - | 2 | - | - | |
3-环氧丙氧丙基三乙氧基硅烷 | - | - | - | - | - | 2 | - | |
每100%质量百分比的PAI树脂的硅烷偶联剂的质量% | 7.7 | 0.2 | 6.2 | 3.1 | 3.1 | 3.1 | 0 |
C1 | C2 | C3 | C4 | C5 | C6 | C7 | C8 | C9 | C10 | |
磨损深度(μm) | 24.0 | 22.1 | 16.5 | 15.5 | 21.8 | 14.6 | 15.2 | 9.5 | 6.8 | 7.7 |
卡住接触压力(MPa) | 10 | 12 | 16 | 13 | 13 | 14 | 16 | 23 | 25或者更多 | 25或者更多 |
C11 | C12 | C13 | C14 | C15 | C16 | C17 | C18 | C19 | C20 | |
磨损深度(μm) | 7.8 | 5.9 | 6.5 | 5.8 | 6.2 | 7.2 | 6.9 | 8.1 | 7.2 | 基底暴露 |
卡住接触压力(MPa) | 24 | 25或者更多 | 25或者更多 | 22 | 24 | 24 | 25或者更多 | 22 | 24 | 25或者更多 |
C21 | C22 | C23 | C24 | C25 | C26 | C27 | C28 | C29 | C30 | ||
表面粗糙度(Rz) | 0.21 | 0.19 | 0.20 | 0.20 | 0.31 | 0.32 | 0.36 | 1.98 | - | - | |
动摩擦系数 | 开始测试以后立即 | 0.024 | 0.023 | 0.021 | 0.023 | 0.027 | 0.031 | 0.038 | 0.052 | - | - |
开始测试以后100小时 | 0.021 | 0.018 | 0.017 | 0.020 | 0.025 | 0.027 | 0.032 | 0.048 | - | - | |
磨损深度(μm) | 4.0 | 3.1 | 2.8 | 2.6 | 5.2 | 5.1 | 6.3 | 19.0 | 4.5 | 4.3 | |
卡住接触压力(MPa) | 21 | 22 | 25或者更多 | 22 | 18 | 20 | 18 | 25或者更多 | 25或者更多 | 22 |
C31 | C32 | C33 | C34 | C35 | C36 | C37 | ||
表面粗糙度(Rz) | - | - | - | - | - | - | - | |
动摩擦系数 | 开始测试以后立即 | - | - | - | - | - | - | - |
开始测试以后100小时 | - | - | - | - | - | - | - | |
磨损深度(μm) | 2.1 | 7.5 | 6.6 | 5.7 | 6.2 | 6.3 | 10.3 | |
卡住接触压力(MPa) | 25或者更多 | 23 | 24 | 25或者更多 | 24 | 24 | 20 |
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JP2003109597A JP4359066B2 (ja) | 2003-04-14 | 2003-04-14 | 摺動部用塗料組成物 |
JP109597/2003 | 2003-04-14 |
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EP (1) | EP1469050B1 (zh) |
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- 2004-04-13 US US10/823,199 patent/US8097569B2/en active Active
- 2004-04-13 EP EP04008760A patent/EP1469050B1/en not_active Expired - Lifetime
- 2004-04-13 BR BR0401329-8A patent/BRPI0401329A/pt not_active IP Right Cessation
- 2004-04-14 CN CNB2004100329725A patent/CN1330722C/zh not_active Expired - Lifetime
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US20040224856A1 (en) | 2004-11-11 |
EP1469050A1 (en) | 2004-10-20 |
BRPI0401329A (pt) | 2005-06-28 |
US8097569B2 (en) | 2012-01-17 |
JP4359066B2 (ja) | 2009-11-04 |
KR20040089492A (ko) | 2004-10-21 |
JP2004315618A (ja) | 2004-11-11 |
KR100583220B1 (ko) | 2006-05-25 |
EP1469050B1 (en) | 2012-12-26 |
CN1330722C (zh) | 2007-08-08 |
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