CN1307608A - 阻燃聚碳酸酯/abs模塑组合物 - Google Patents
阻燃聚碳酸酯/abs模塑组合物 Download PDFInfo
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- CN1307608A CN1307608A CN99807924A CN99807924A CN1307608A CN 1307608 A CN1307608 A CN 1307608A CN 99807924 A CN99807924 A CN 99807924A CN 99807924 A CN99807924 A CN 99807924A CN 1307608 A CN1307608 A CN 1307608A
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- preferred
- moulding compound
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- alkyl
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- 239000004417 polycarbonate Substances 0.000 title claims abstract description 21
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 21
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title description 5
- 239000012778 molding material Substances 0.000 title 1
- 238000010137 moulding (plastic) Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 31
- 238000000034 method Methods 0.000 claims abstract description 19
- 238000012662 bulk polymerization Methods 0.000 claims abstract description 8
- 238000010557 suspension polymerization reaction Methods 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims description 32
- 239000000206 moulding compound Substances 0.000 claims description 28
- 125000003118 aryl group Chemical group 0.000 claims description 24
- -1 polysiloxane Polymers 0.000 claims description 23
- 229920001971 elastomer Polymers 0.000 claims description 19
- 239000005060 rubber Substances 0.000 claims description 19
- 239000000178 monomer Substances 0.000 claims description 17
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 16
- 229920001283 Polyalkylene terephthalate Polymers 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 11
- 229920001169 thermoplastic Polymers 0.000 claims description 11
- ZSTLPJLUQNQBDQ-UHFFFAOYSA-N azanylidyne(dihydroxy)-$l^{5}-phosphane Chemical class OP(O)#N ZSTLPJLUQNQBDQ-UHFFFAOYSA-N 0.000 claims description 10
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 8
- 239000004416 thermosoftening plastic Substances 0.000 claims description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
- 239000005977 Ethylene Substances 0.000 claims description 7
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims description 7
- 229920000098 polyolefin Polymers 0.000 claims description 7
- 229920002554 vinyl polymer Polymers 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000003063 flame retardant Substances 0.000 claims description 6
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 150000002825 nitriles Chemical class 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 230000007704 transition Effects 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- 125000005907 alkyl ester group Chemical group 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 230000003068 static effect Effects 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 claims description 2
- 125000001624 naphthyl group Chemical group 0.000 claims description 2
- 125000005186 naphthyloxy group Chemical group C1(=CC=CC2=CC=CC=C12)O* 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 125000001475 halogen functional group Chemical group 0.000 claims 1
- 229920000578 graft copolymer Polymers 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 3
- 238000000465 moulding Methods 0.000 abstract description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 24
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 16
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 14
- 239000000839 emulsion Substances 0.000 description 13
- 229920000573 polyethylene Polymers 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 11
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 10
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 9
- 239000001294 propane Substances 0.000 description 8
- 239000002245 particle Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 6
- 239000002585 base Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000006085 branching agent Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 150000008065 acid anhydrides Chemical class 0.000 description 4
- 150000001721 carbon Chemical group 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000010559 graft polymerization reaction Methods 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 3
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 125000005587 carbonate group Chemical group 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229940051250 hexylene glycol Drugs 0.000 description 3
- 150000003949 imides Chemical class 0.000 description 3
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000002989 phenols Chemical group 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 3
- 238000002411 thermogravimetry Methods 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 2
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical class [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical group OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical compound OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 229920002313 fluoropolymer Polymers 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical class O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- WVAFEFUPWRPQSY-UHFFFAOYSA-N 1,2,3-tris(ethenyl)benzene Chemical compound C=CC1=CC=CC(C=C)=C1C=C WVAFEFUPWRPQSY-UHFFFAOYSA-N 0.000 description 1
- ODNRTOSCFYDTKF-UHFFFAOYSA-N 1,3,5-Trimethyl-cyclohexan Natural products CC1CC(C)CC(C)C1 ODNRTOSCFYDTKF-UHFFFAOYSA-N 0.000 description 1
- LQWSBXWILISUST-UHFFFAOYSA-N 1,3,5-trimethylcyclohexane Chemical compound CC1[CH]C(C)CC(C)C1 LQWSBXWILISUST-UHFFFAOYSA-N 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- IVORCBKUUYGUOL-UHFFFAOYSA-N 1-ethynyl-2,4-dimethoxybenzene Chemical class COC1=CC=C(C#C)C(OC)=C1 IVORCBKUUYGUOL-UHFFFAOYSA-N 0.000 description 1
- YIYBRXKMQFDHSM-UHFFFAOYSA-N 2,2'-Dihydroxybenzophenone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1O YIYBRXKMQFDHSM-UHFFFAOYSA-N 0.000 description 1
- CMQUQOHNANGDOR-UHFFFAOYSA-N 2,3-dibromo-4-(2,4-dibromo-5-hydroxyphenyl)phenol Chemical compound BrC1=C(Br)C(O)=CC=C1C1=CC(O)=C(Br)C=C1Br CMQUQOHNANGDOR-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- XSXWOBXNYNULJG-UHFFFAOYSA-N 2-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=CC=C1O XSXWOBXNYNULJG-UHFFFAOYSA-N 0.000 description 1
- VXHYVVAUHMGCEX-UHFFFAOYSA-N 2-(2-hydroxyphenoxy)phenol Chemical compound OC1=CC=CC=C1OC1=CC=CC=C1O VXHYVVAUHMGCEX-UHFFFAOYSA-N 0.000 description 1
- XSVZEASGNTZBRQ-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfinylphenol Chemical compound OC1=CC=CC=C1S(=O)C1=CC=CC=C1O XSVZEASGNTZBRQ-UHFFFAOYSA-N 0.000 description 1
- QUWAJPZDCZDTJS-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfonylphenol Chemical compound OC1=CC=CC=C1S(=O)(=O)C1=CC=CC=C1O QUWAJPZDCZDTJS-UHFFFAOYSA-N 0.000 description 1
- KAIRTVANLJFYQS-UHFFFAOYSA-N 2-(3,5-dimethylheptyl)phenol Chemical compound CCC(C)CC(C)CCC1=CC=CC=C1O KAIRTVANLJFYQS-UHFFFAOYSA-N 0.000 description 1
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 1
- KYGLCUAXJICESS-UHFFFAOYSA-N 2-[2,3-di(propan-2-yl)phenyl]phenol Chemical compound CC(C)C1=CC=CC(C=2C(=CC=CC=2)O)=C1C(C)C KYGLCUAXJICESS-UHFFFAOYSA-N 0.000 description 1
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- UITKHKNFVCYWNG-UHFFFAOYSA-N 4-(3,4-dicarboxybenzoyl)phthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1C(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 UITKHKNFVCYWNG-UHFFFAOYSA-N 0.000 description 1
- CUAUDSWILJWDOD-UHFFFAOYSA-N 4-(3,5-dimethylheptyl)phenol Chemical compound CCC(C)CC(C)CCC1=CC=C(O)C=C1 CUAUDSWILJWDOD-UHFFFAOYSA-N 0.000 description 1
- HJSPWKGEPDZNLK-UHFFFAOYSA-N 4-benzylphenol Chemical compound C1=CC(O)=CC=C1CC1=CC=CC=C1 HJSPWKGEPDZNLK-UHFFFAOYSA-N 0.000 description 1
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 1
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 1
- PBTXWTNXVCYRJA-UHFFFAOYSA-N 4-hept-2-enylphenol Chemical compound CCCCC=CCC1=CC=C(O)C=C1 PBTXWTNXVCYRJA-UHFFFAOYSA-N 0.000 description 1
- KNDDEFBFJLKPFE-UHFFFAOYSA-N 4-n-Heptylphenol Chemical compound CCCCCCCC1=CC=C(O)C=C1 KNDDEFBFJLKPFE-UHFFFAOYSA-N 0.000 description 1
- YVPZFPKENDZQEJ-UHFFFAOYSA-N 4-propylcyclohexan-1-ol Chemical compound CCCC1CCC(O)CC1 YVPZFPKENDZQEJ-UHFFFAOYSA-N 0.000 description 1
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 1
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- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
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- 229910052738 indium Inorganic materials 0.000 description 1
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- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
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- 235000019341 magnesium sulphate Nutrition 0.000 description 1
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- 230000008018 melting Effects 0.000 description 1
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 1
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- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical class CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
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- AKIDPNOWIHDLBQ-UHFFFAOYSA-N naphthalene-1,4,5,8-tetracarbonyl chloride Chemical compound C1=CC(C(Cl)=O)=C2C(C(=O)Cl)=CC=C(C(Cl)=O)C2=C1C(Cl)=O AKIDPNOWIHDLBQ-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical class C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 150000002896 organic halogen compounds Chemical class 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical class [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
- 229940090668 parachlorophenol Drugs 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-N peroxydisulfuric acid Chemical group OS(=O)(=O)OOS(O)(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-N 0.000 description 1
- 230000005501 phase interface Effects 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000377 silicon dioxide Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- DVQHRBFGRZHMSR-UHFFFAOYSA-N sodium methyl 2,2-dimethyl-4,6-dioxo-5-(N-prop-2-enoxy-C-propylcarbonimidoyl)cyclohexane-1-carboxylate Chemical compound [Na+].C=CCON=C(CCC)[C-]1C(=O)CC(C)(C)C(C(=O)OC)C1=O DVQHRBFGRZHMSR-UHFFFAOYSA-N 0.000 description 1
- JMHCCAYJTTWMCX-QWPJCUCISA-M sodium;(2s)-2-amino-3-[4-(4-hydroxy-3,5-diiodophenoxy)-3,5-diiodophenyl]propanoate;pentahydrate Chemical compound O.O.O.O.O.[Na+].IC1=CC(C[C@H](N)C([O-])=O)=CC(I)=C1OC1=CC(I)=C(O)C(I)=C1 JMHCCAYJTTWMCX-QWPJCUCISA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000000454 talc Chemical class 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- WYXIGTJNYDDFFH-UHFFFAOYSA-Q triazanium;borate Chemical class [NH4+].[NH4+].[NH4+].[O-]B([O-])[O-] WYXIGTJNYDDFFH-UHFFFAOYSA-Q 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical class [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/5399—Phosphorus bound to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/22—Thermoplastic resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
Abstract
本发明涉及含有磷腈类的聚碳酸酯/ABS模塑材料,其表现出极好的阻燃性和非常好的加工特性,其中接枝聚合物是通过用一种本体聚合、溶液聚合或本体/悬浮聚合方法制备的。
Description
本发明涉及含有磷腈类的聚碳酸酯/ABS模塑组合物,其表现出极好的阻燃性和非常好的加工特性,其中接枝聚合物是通过本体聚合、溶液聚合或本体/悬浮聚合方法制备的。
DE-A19616968描述了可聚合的磷腈衍生物、其制备方法和其作为可固化粘合剂用于漆、涂料、填料、表面处理组合物、粘合剂、模制品或薄膜的用途。
WO97/40092描述了由热塑性聚合物和未取代磷腈类(PNn-xH1-y型)制备的阻燃模塑组合物。
EP-A728811描述了一种由芳族聚碳酸酯、接枝共聚物、共聚物和磷腈组成的热塑性共混物,其表现出良好的阻燃性、冲击强度和耐热性。
本发明的目的是提供聚碳酸酯/ABS模塑组合物,其具有极好的阻燃性和极好的加工性能,诸如良好的流动特性和在加工期间较少在模上形成沉积物。对于诸如用于监视器、打印机、复印机等的壳体的数字加工中的应用特别需要该特性范围。
现已发现含有磷腈和通过本体聚合、溶液聚合或本体/悬浮聚合方法制备的基于二烯橡胶的接枝聚合物的PC/ABS模塑组合物表现出所希望的性质。
因此本发明提供热塑性模塑组合物,它含有:
A)40-99、优选60-98.5重量份的芳族聚碳酸酯和/或聚酯碳酸酯;
B)0.5-60、优选1-40、特别是2-25重量份接枝聚合物,其制备方法是用本体聚合、溶液聚合或本体/悬浮聚合方法将
B.1)50-99、优选65-98%重量的一种或多种乙烯基单体聚合到
B.2)50-1、优选35-2%重量的一种或多种玻璃化转变温度<10℃、优选<0℃、特别优选<-10℃的接枝骨架上;
C)0-45、优选0-30、特别优选2-25重量份的至少一种选自乙烯基(共)聚合物和聚对苯二甲酸亚烷基酯的热塑性聚合物;
D)0.1-50,优选2-35、特别是5-25重量份的至少一种选自下式的磷腈类的组分:
其中
R在每种情况下相同或不同,表示氨基;在每种情况下任选地被卤素取代、优选被氟卤代的C1-C6烷基或C1-C8烷氧基;C5-C6环烷基,C6-C20芳基(优选苯基或萘基),C6-C20芳氧基(优选苯氧基、萘氧基),或C7-C12芳烷基(优选苯基C1-C4烷基),在每种情况下可任选被烷基,优选被C1-C4烷基和/或卤素,优选氯、溴,取代。
k表示0或1-15的数,优选1-10的数;
E)0-5,优选0.1-1,特别优选0.1-0.5重量份的氟化聚烯烃。组分A
根据本发明适用的成分A芳族聚碳酸酯和/或芳族聚酯碳酸酯可从文献中获知,或可用来自文献的已知方法制备(参见与芳族聚碳酸酯制备相关的文献,例如Schnell,Chemistry & Physics ofPolycarbonates,Interscience Publishers,1964年和DE-AS 1 495626、DE-OS 2 232 877、DE-OS 2 703 376、DE-OS 2 714 544、DE-OS3 000 610、DE-OS 3 832 396;与芳族聚酯碳酸酯的制备相关的文献,例如DE-OS 3 077 934)。
例如,将二元酚与优选光气的碳酸卤化物和/或与优选苯二羧酸二卤化物的芳族二羧酸二卤化物通过相界面过程进行反应,任选地使用例如一元酚的链终止剂,和任选地使用例如三元酚或四元酚的三官能度或多于三官能度的支化剂,制备芳族聚碳酸酯。
其中
A是单键、C1-C5亚烷基、C2-C5烷叉基、C5-C6环烷叉基、-O-、-SO-、-CO-、-S-、-SO2-、可稠合其它任选含有杂原子的芳环的C6-C12亚芳基,
B每种情况下表示C1-C12烷基,优选甲基,卤素,优选氯和/或溴,
x在每种情况下相互独立地为0、1或2,
p是1或0和
R7和R8分别独立于每个X1选择,表示氢或C1-C6烷基,优选氢、甲基和乙基,
X1是碳,和
m表示整数4-7,优选4或5,前提条件是R7和R8同时为在至少一个原子X1上的烷基。
优选的二元酚是氢醌、间苯二酚、二羟基二元酚、双(羟基苯基)-C1-C5烷烃、双(羟基苯基)-C5-C6环烷烃、双(羟基苯基)醚、双(羟基苯基)亚砜、双(羟基苯基)酮、双(羟基苯基)砜和α,α-双(羟基苯基)二异丙基苯及其环被溴化的和/或环被氯化的衍生物。
特别优选的二元酚是4,4’-二羟基联苯、双酚A、2,4-双(4-羟基苯基)-2-甲基丁烷、1,1-双(4-羟基苯基)环己烷1,1-双(4-羟基苯基)-3,3,5-三甲基环己烷、4,4’-二羟基二苯基硫、4,4’-二羟基二苯基砜及其二和四溴代或氯代的衍生物,诸如例如2,2-双(3-氯-4-羟基苯基)丙烷、2,2-双(3,5-二氯-4-羟基苯基)丙烷或2,2-双(3,5-二溴-4-羟基苯基)丙烷。
特别优选的是2,2-双(4-羟基苯基)丙烷(双酚A)。
二元酚可单独使用或作为任何需要的混合物使用。
二元酚可从文献获知,或用从文献获知的方法制备。
适用于制备热塑性芳族聚碳酸酯的链终止剂是例如苯酚、对氯苯酚、对叔丁基苯酚或2,4,6-三溴苯酚,以及长链的烷基酚,诸如根据DE-OS 2 842 005的4-(1,3-四甲基丁基)苯酚或烷基取代基中共有8-20个原子的单烷基苯酚或二烷基苯酚,诸如3,5-二叔丁基苯酚、对异辛基苯酚、对叔辛基苯酚、对十二烷基苯酚和2-(3,5-二甲基庚基)苯酚和4-(3,5-二甲基庚基)苯酚。在每种情况下,链终止剂的用量一般为所用二元酚的总摩尔数的0.5-10%摩尔。
热塑性芳族聚碳酸酯的重均分子量(Mw,用例如超离心法或光散射法测定)为10000-200000,优选20000-80000。
可用已知方法将热塑性芳族碳酸酯支化,优选加入相对于二元酚总用量的0.05-2.0%摩尔的三官能度或大于三官能度的化合物,例如那些有三个或多于三个酚基的化合物。
均聚碳酸酯和共聚碳酸酯都适用。本发明的组分A共聚碳酸酯,也可用1-25%重量、优选2.5-25%重量(相对于二元酚的总用量)含有羟基-芳氧基端基的聚二有机硅氧烷制备。这些是已知的(参见例如美国专利3 419 634)或可用从文献获知的方法制备。在例如DE-OS 3 334782中描述了含有聚二有机硅氧烷的共聚碳酸酯的制备。
除了双酚A均聚碳酸酯以外,优选的聚碳酸酯是双酚A和相对于二元酚的总摩尔数至多15%摩尔的其它优选或特别优选的二元酚、尤其是2,2-双(3,5-二溴-4-羟基苯基)丙烷的共聚碳酸酯。
用于制备芳族聚酯碳酸酯的芳族二羧酸二卤化物优选为间苯二甲酸、对苯二甲酸、二苯基醚4,4’-二羧酸和2,6-萘二羧酸的二酸二卤化物。
特别优选的是间苯二甲酸和对苯二甲酸的二酸二氯化物按1∶20-20∶1比例的混合物。
在聚酯碳酸酯的制备中,还可使用一种碳酸卤化物,优选光气,作为双官能度酸衍生物。
除了上述一元酚外,在芳族聚酯碳酸酯的制备中可考虑使用的链终止剂还有其氯化碳酸酯和可任选被C1-C22烷基或卤素原子取代的芳族一元羧酸的酸氯化物,以及脂族C2-C22一元羧酸氯化物。
在每种情况下链终止剂的用量为0.1-10%摩尔,使用酚类链终止剂时,其相对于二元酚的摩尔数,使用单羧酸氯化物链终止剂时,其相对于二元羧酸二氯化物的摩尔数。
芳族聚酯碳酸酯还可含有加入的芳族羟基羧酸。
在已知的方法中,芳族聚酯碳酸酯可以是线型的或支化的(在这方面也可见DE-OS 2 940 024和DE-OS 3 007 934)。
可使用的支化剂是例如三官能度或多官能度的羧酸氯化物,诸如1,3,5-苯三酸三氯化物、三聚氰酸三氯化物、3,3’,4,4’-二苯酮四羧酸四氯化物、1,4,5,8-萘四羧酸四氯化物或均苯四酸四氯化物,用量为0.01-1.0%摩尔(相对于所用的二羧酸二氯化物);或三或多官能度酚类,诸如间苯三酚、4,6-二甲基-2,4,6-三(4-羟基苯基)-2-庚烯、4,4-二甲基-2,4,6-三(4-羟基苯基)庚烷、1,3,5-三(4-羟基苯基)苯、1,1,1-三(4-羟基苯基)乙烷、三(4-羟基苯基)苯基甲烷、2,2-双(4,4-双(4-羟基苯基)环己基]丙烷、2,4-双(4-羟基苯基异丙基)苯酚、四(4-羟基苯基)甲烷、2,6-双(2-羟基-5-甲基苄基)-4-甲基苯酚、2-(4-羟基苯基)-2-(2,4-二羟基苯基)丙烷、四(4-[4-羟基苯基异丙基]苯氧基)甲烷、1,4-双[4,4’-二羟基三苯基)甲基]苯其用量相对于使用的二元酚,为0.01-1.0%摩尔。酚类支化剂可在开始与二元酚一起引入,酸氯化物支化剂可与酸二氯化物一起引入。
在热塑性芳族聚酯碳酸酯中碳酸酯结构单元的比例可以任意变化。相对于酯基和碳酸酯基的总量,碳酸酯基的比例优选至多为100%摩尔,特别是至多80%摩尔,尤其优选至多50%摩尔。芳族聚酯碳酸酯的酯和碳酸酯部分可在缩聚产物中以嵌段或无规分布的形式存在。
芳族聚碳酸酯和聚酯碳酸酯的相对溶液粘度(ηrel)在1.18-1.4范围内,优选1.22-1.3(在25℃,用0.5g聚碳酸酯或聚酯碳酸酯在100ml二氯甲烷中的溶液测定)。
热塑性芳族聚碳酸酯和聚酯碳酸酯可单独使用或作为任意需要的彼此的混合物使用。组分B
橡胶改性的接枝聚合物B包括单体B.1.1和B.1.2的无规(共)聚合物和被B.1.1和B.1.2的无规(共)聚合物接枝的橡胶B.2,其中B用已知的方法使用本体聚合或溶液聚合或本体/悬浮聚合方法制备,如US 3 243 481,US 3 509 237,US 3 660 535,4 221 833和US4 239 863所述。
单体B.1.1的例子是苯乙烯,α-甲基苯乙烯,卤代或烷基环取代的苯乙烯,诸如对甲基苯乙烯、对氯苯乙烯,(甲基)丙烯酸C1-C8烷基酯,诸如甲基丙烯酸甲酯、丙烯酸正丁酯和丙烯酸叔丁酯。单体B.1.2的例子是不饱和腈类,诸如丙烯腈、甲基丙烯腈;(甲基)丙烯酸C1-C8烷基酯,诸如甲基丙烯酸甲酯、丙烯酸正丁酯和丙烯酸叔丁酯;不饱和羧酸的衍生物(诸如酸酐和酰亚胺),诸如马来酸酐和N-苯基马来酰亚胺或其混合物。
优选的B.1.1单体是苯乙烯、α-甲基苯乙烯和/或甲基丙烯酸甲酯,优选的B.1.2单体是丙烯腈、马来酸酐和/或甲基丙烯酸甲酯。
特别优选的单体是B.1.1苯乙烯和B.1.2丙烯腈。
适用于橡胶改性的接枝聚合物B的橡胶B.2是例如二烯橡胶、EP(D)M橡胶,即那些基于乙烯/丙烯和任选的二烯橡胶、丙烯酸酯、聚氨酯、聚硅氧烷、氯丁二烯和乙烯/乙酸乙烯酯橡胶。
优选的橡胶B.2是二烯橡胶(例如基于丁二烯、异戊二烯等)或二烯橡胶的混合物或二烯橡胶的共聚物或其与其它可共聚单体(例如根据B.1.1和B.1.2的)的混合物,前提条件是组分B.2的玻璃化转变温度<10℃,优选<-10℃。特别优选的是纯聚丁二烯橡胶。
如果需要或如果组分B.2的橡胶性能最终不受到削弱,则组分B还可含有少量的、通常相对于B.2,小于5%重量、优选小于2%重量的有交联作用的烯键式不饱和单体。这类具有交联作用的单体的例子是二(甲基)丙烯酸亚烷基二醇酯、聚酯二(甲基)丙烯酸酯、二乙烯基苯、三乙烯基苯、三聚氰酸三烯丙酯、(甲基)丙烯酸烯丙酯、马来酸二烯丙酯和富马酸二烯丙酯。
通过在1-50、优选2-35、更优选2-15、特别是2-13重量份的橡胶成分B.2存在下,接枝聚合50-99、优选65-98、特别优选75-97重量份的50-99、优选60-95重量份单体B.1.1和1-50、优选5-40重量份的单体B.1.2的混合物,得到橡胶改性的接枝聚合物B,其中接枝聚合通过本体聚合或溶液聚合或本体/悬浮聚合方法进行。
当制备橡胶改性的接枝聚合物B时,接枝聚合前,橡胶成分B.2以溶解在单体B.1.1和B.1.2的混合物中的形式存在是必要的。因此,橡胶成分B.2即不能被强交联到使其不能溶于B.1.1和B.1.2,B.2也不能在接枝共聚开始时就已经是分散的颗粒形式,对于B产品的性能很重要的B.2的颗粒形态和提高的交联度仅在接枝聚合期间形成(在该方面,参见例如Ullmann,Encyclopedie der technischenChemie,19卷,p284 et seq.,第4版,1980).
B.1.1和B.1.2的无规共聚物部分通常以接枝在橡胶B.2上或B.2中的形式存在于聚合物B中,其中该接枝共聚物在聚合物B中形成分散的颗粒。这样接枝的B.1.1和B.1.2共聚物相对于整个B.1.1和B.1.2共聚物的比例,即,接枝产率(=实际接枝的接枝单体与使用的总接枝单体的重量比×100,以%表示)应为2-40%,优选3-30%,特别优选4-20%。
生成的接枝橡胶颗粒的平均颗粒直径(用电子显微照片计算测定)在0.5-5μm范围内,优选0.8-2.5μm。组分C
组分C包含一种或多种热塑性乙烯基(共)聚合物C.1和/或聚对苯二甲酸亚烷基酯C.2。
适合的(共)聚合物C.1是至少一种选自乙烯基芳族化合物、乙烯基氰化物(不饱和腈类)、(甲基)丙烯酸(C1-C8)烷基酯、不饱和羧酸和不饱和羧酸的衍生物(诸如酸酐和酰亚胺)的单体。特别适合的(共)聚合物是由下列物质制备的:
C.1.1 50-99、优选60-80重量份乙烯基芳族和/或环取代的乙烯基芳族化合物(例如苯乙烯、α-甲基苯乙烯、对甲基苯乙烯、对氯苯乙烯)和/或甲基丙烯酸(C1-C8)烷基酯(例如甲基丙烯酸甲酯、甲基丙烯酸乙酯)和
C.1.2 1-50、优选20-40重量份乙烯基氰化物(不饱和的腈类),诸如丙烯腈和甲基丙烯腈,和/或甲基丙烯酸(C1-C8)烷基酯(例如甲基丙烯酸甲酯、丙烯酸正丁酯、丙烯酸叔丁酯)和/或不饱和羧酸(如马来酸)和/或不饱和羧酸的衍生物(如酸酐和酰亚胺)(例如马来酸酐和N-苯基马来酰亚胺)。
(共)聚合物C.1是树脂状、热塑性和无橡胶的。
特别优选C.1.1苯乙烯和C.1.2丙烯腈的共聚物。
(共)聚合物C.1是已知的,并且可通过自由基聚合、特别是乳液聚合、悬浮聚合、溶液聚合或本体聚合制备。(共)聚合物优选具有15000-200000的分子量Mw(重均分子量,用光散射法或沉降法测定)。
组分C.2聚对苯二甲酸亚烷基酯是芳族二羧酸或诸如其二甲酯或酸酐的反应性的衍生物与脂族、环脂族或芳脂族二醇的反应产物以及这些反应产物的混合物。
优选的聚对苯二甲酸亚烷基酯含有相对于二羧酸成分的至少80%重量、优选至少90%重量的对苯二甲酸残基和相对于二醇成分的至少80%重量、优选至少90%摩尔的乙二醇和/或1,4-丁二醇残基。
除了对苯二甲酸残基,优选的聚对苯二甲酸亚烷基酯可含有至多20%摩尔、优选至多10%摩尔的其它含有8-14个碳原子的芳族或环脂族二羧酸残基或含有4-12个碳原子的脂族二羧酸残基,例如邻苯二甲酸、间苯二甲酸、2,6-萘二羧酸、4,4’-联苯二羧酸、丁二酸、己二酸、癸二酸、壬二酸、环己烷二乙酸的残基。
除了乙二醇或1,4-丁二醇残基外,优选的聚对苯二甲酸亚烷基酯可含有至多20%摩尔、优选至多10%摩尔的其它含有3-12个碳原子的脂族二醇或含有6-21个碳原子的环脂族二醇,例如1,3-丙二醇、2-乙基-1,3-丙二醇、新戊二醇、1,5-戊二醇、1,6-己二醇、1,4-环己烷二甲醇、3-乙基-2,4-戊二醇、2-甲基-2,4-戊二醇、2,2,4-三甲基-1,3-戊二醇、2-乙基-1,3-己二醇、2,2-二乙基-1,3-丙二醇、2,5-己二醇、1,4-二(β-羟基乙氧基)苯、2,2-双(4-羟基环己基)丙烷、2,4-二羟基-1,1,3,3-四甲基环丁烷、2,2-双(4-β-羟基乙氧基苯基)丙烷和2,2-双(4-羟基丙氧基苯基)丙烷的残基(DE-OS 2 407 674、2 407776、2 715 932)。
通过加入较少量的三元或四元醇或三元或四元羧酸可使聚对苯二甲酸亚烷基酯支化,例如根据DE-OS 1 900 270和US-PS 3 692 744。更优选的支化剂的例子是1,3,5-苯三酸、1,2,4-苯三酸、三甲醇乙烷和三甲醇丙烷和季戊四醇。
特别优选的聚对苯二甲酸亚烷基酯是那些仅由对苯二甲酸和其反应性衍生物(例如其二烷基酯)与乙二醇和/或1,4-丁二醇制备的产物和这些聚对苯二甲酸亚烷基酯的混合物。
聚对苯二甲酸亚烷基酯的混合物含有1-50%重量、优选1-30%重量聚对苯二甲酸乙二酯和50-99%重量、优选70-99%重量聚对苯二甲酸丁二酯。
优选使用的聚对苯二甲酸亚烷基酯通常具有0.4-1.5dl/g、优选0.5-1.2dl/g的特性粘度,系在25℃用Ubbelohde粘度计,以其在苯酚/邻二氯苯(1∶1重量份)中的溶液测量。
聚对苯二甲酸亚烷基酯可用已知方法制备(参见例如Kunststoff-Handbuch,卷III、695页及之后,Carl Hanser Verlag,Munich 1973)。组分D
其中
R和k定义如上。
下列成分可能在举例中提到
丙氧基磷腈、苯氧基磷腈、甲基苯氧基磷腈、氨基磷腈和氟代烷基磷腈。
优选苯氧基磷腈。
磷腈可单独使用或作为混合物使用。残基R可总是相同的,或在式(Ia)和(Ib)中两个或多个残基可以不同。
在例如EP-A 728 811、DE-A 1 961 668和WO97/40092中描述了磷腈及其制备方法。组分E
氟化的聚烯烃E是高分子量的,其玻璃化转变温度高于-30℃,通常高于100℃,氟含量优选为65-76%重量,特别是70-76%重量,平均颗粒直径d50为0.05-1000μm,优选0.08-20μm。氟化的聚烯烃E的密度优选为1.2-2.3g/cm3。优选的氟化聚烯烃E是聚四氟乙烯、聚偏氟乙烯、四氟乙烯/六氟丙烯和乙烯/四氟乙烯共聚物。氟化聚烯烃是已知的(参见Vinyl & Related Polymers,Schildknecht,JohnWiley & Sons Inc.,New York,1962,p484-494;氟代聚合物Fluoropolymers,Wall,Wiley-Interscience,John Wiley & SonsInc.,New York,卷13,1970,p 623-654;现代塑料大全ModernPlastics Encyclopedia,1970-1971,卷47,no.10 A,1970年10月,McGraw-Hill Inc.,New York,134和774页;现代塑料大全Modern Plastics Encyclopedia,1975-1976,1975年10月,卷52,no.10A,McGraw-Hill Inc.,New York,27、28和472页以及US-PS3 671 487、3 723 373和3 838 092)。
它们可用已知方法制备,因此,例如通过,在有例如过二硫酸的钠、钾或铵盐等自由基形成催化剂的含水介质中,在7-71kg/cm2压力和0-200℃、优选20-100℃的温度下将四氟乙烯聚合(更多细节参见例如US专利2 393 967)。根据它们使用的状态,这些原料的密度可以是1.2-2.3g/cm3,平均颗粒尺寸为0.5-1000μm。
根据本发明优选的聚烯烃E是四氟乙烯聚合物,其平均颗粒直径为0.05-20μm,优选0.08-10μm,密度为1.2-1.9g/cm3,优选以四氟乙烯聚合物E的乳液和接枝聚合物的乳液的凝固混合物的形式使用。
适合以粉末形式使用的聚合物E是平均颗粒直径为100-1000μm和密度为2.0-2.3g/cm3的四氟乙烯聚合物。
接枝聚合物B和组分E的凝固的混合物制备如下:首先将接枝聚合物B的含水乳液(胶乳)与四氟乙烯聚合物E的细分散乳液混合;适合的四氟乙烯聚合物乳液中固体含量通常为30-70%重量,特别是50-60%重量,优选30-35%重量。
在乳液混合物中,接枝聚合物与四氟乙烯聚合物E的平衡重量比为95∶5-60∶40。然后用已知方法将乳液混合物凝固,例如用喷雾干燥、冷冻干燥,或通过加入无机或有机盐、酸、碱或有机水溶性溶剂如醇、酮,优选在20-150℃、特别是50-100℃发生凝固。如果需要,可在50-200℃、优选70-100℃进行干燥。
适合的四氟乙烯聚合物乳液通常是商品,并由例如DuPont公司以Teflon30N出售。
本发明的模塑组合物可含有至少一种常规添加剂,诸如润滑剂和脱模剂、成核剂、抗静电剂、稳定剂以及染料和颜料。
本发明的模塑组合物可含有相对于整个模塑组合物至多35%重量的其它任选的协同作用的阻燃剂。可述及的其它阻燃剂的例子是有机卤化合物,诸如十溴二苯醚、四溴双酚;无机卤化合物,如溴化铵;氮化合物,诸如三聚氰胺、三聚氰胺/甲醛树脂;无机氢氧化物,诸如Mg、Al氢氧化物;无机化合物,诸如氧化锑、偏硼酸钡、羟锑酸盐、氧化锆、氢氧化锆、氧化钼、钼酸铵、硼酸锌、硼酸铵、偏硼酸钡、滑石、硅酸盐、二氧化硅和氧化锡以及硅氧烷化合物。
根据本发明含有组分A-E和任选的其它已知添加剂如稳定剂,染料、颜料、润滑剂和脱模剂、成核剂以及抗静电剂的模塑组合物可制备如下:用已知的方法将特定的组分混合并在诸如密闭式捏合机、挤压机和双螺杆挤出机等常规设备中于200-300℃进行熔融混合和熔融挤出,其中组分E优选以上述凝固混合物的形式使用。
各组分可用已知的方法连续地或同时地在约20℃(室温)和更高的温度下进行混合。
因此本发明还提供一种制备模塑组合物的方法。
由于本发明的热塑性模塑组合物具有极好的阻燃性和良好的力学性能,其适用于制备各类模塑制品,特别是那些在加工性能方面有严格要求的模塑制品。
这类应用包括有两个或多个注入点的复杂结构和壁厚<2mm、优选<1.5mm的薄壁壳体元件的成分。
本发明的模塑组合物可用于制备任何类型的模塑制品。模塑制品特别可以通过注塑法制备。可制备的模塑制品的例子是各种壳体,例如用于家用电器如榨汁机、咖啡机、食物搅拌机;用于办公设备,诸如监视器、打印机、复印机的壳体;或用于建筑部件和汽车元件的包覆层。它们还可用于电工用途,因为它们有非常好的电气性能。
另一种加工方法是通过热成型预先制备的片材或薄膜来制备模塑制品。
因此本发明还提供本发明的模塑组合物用于制备各种模制品的用途,优选上述的那些,以及由本发明的模塑组合物制备的模制品。
本发明的模塑组合物还可用来生产下列模塑制品或成型制品:
用于轨道车辆(FR)的内装修
毂盖
用于有小变压器的电气设备的外壳
用于信息传播和传输设备的外壳
医用外壳和包覆层
信息设备及其外壳
儿童玩具车辆
片状墙体部分
安全设备的外壳
舱口扰流片
绝热运输容器
放置或照料小动物的装置
用于卫生间和浴室设备的模塑制品
用于通风口的保护格栅
用于夏季房屋和车棚的模塑制品
庭院用具的外壳
实施例
组分A
相对溶液粘度为1.26的线性双酚A基聚碳酸酯,其粘度在以CH2Cl2作为溶剂,于25℃和0.5g/100ml浓度下测定。组分B
B.1本体ABS聚合物,来自DOW化学公司Midland,Michigan,USA(商品名Magnum 3504)
丙烯腈∶丁二烯∶苯乙烯=22.0∶10.2∶67.8B.2对比
40重量份苯乙烯和丙烯腈按73∶27比例的共聚物和60重量份交联微粒聚丁二烯橡胶(平均颗粒直径d50=0.28μm)以乳液聚合法制备的接枝聚合物。组分C
苯乙烯/丙烯腈共聚物,其中苯乙烯/丙烯腈重量比为72∶28,特性粘度为0.55dl/g(系在20℃在二甲基甲酰胺中测定)。组分D
下式的苯氧基磷腈,是日本Nippon Soda公司的商品P-3800。
用四硬脂酸季戊四醇酯作脱模剂组分E
四氟乙烯聚合物作为一种由在水中的SAN接枝聚合物乳液(40重量份苯乙烯和丙烯腈按73∶27比例的共聚物接枝在60重量份颗粒状交联聚丁二烯橡胶上,由乳液聚合法制备,平均颗粒直径d50=0.28μm)和在水中的四氟乙烯聚合物乳液制备的凝固混合物。混合物中接枝聚合物B和四氟乙烯聚合物E的重量比为90%重量∶10%重量。四氟乙烯聚合物中固体含量为60%重量,平均颗粒直径为0.05-0.5μm。SAN接枝聚合物乳液中的固体含量为34%重量,平均乳胶颗粒直径d50=0.28μm。E的制备
将四氟乙烯聚合物的乳液(Dupont公司的Teflon 30N)与SAN接枝聚合物B的乳液进行混合,用相对于聚合物固体1.8%重量的酚类抗氧化剂稳定化。在85-95℃,让该混合物在pH4-5,用MgSO4(泻盐)和乙酸的水溶液凝固,过滤,洗涤,直至实际上已没有电解质,然后离心除去大部分水,在100℃干燥该材料,得到粉末。该粉末可与其它组分在所述的装置中混合。本发明的模塑组合物的制备和测试
各组分在3升的密闭式捏合机中混合。在Arburg 270E型注塑机上于260℃生产模塑制品。
用尺寸为80×10×4mm的试棒按照DIN 53 460(ISO 306)测定Vicat B的软化点。
用尺寸为80×10×4mm的试棒在260℃的处理温度下测试应力开裂行为(ESC行为)。使用的测试介质是60%体积甲苯和40%体积异丙醇的混合物。将试片在一个园弧形模板上预压(起始伸长率%)并浸入室温下的测试介质中。应力开裂行为根据在试验介质中开裂或失效随起始伸长率的变化进行评价。
热重分析(TGA)用来衡量在模具上沉积物的形成。为此,在惰性气体N2中、在0-400℃的温度范围内以10K/分钟的升温速率测定混合物的质量损失。用对应于常规加工温度280℃的质量损失进行评价。该数值越高,则在加工期间形成沉积物的趋势越大。低数值表示形成沉积物的趋势小。
表:模塑组合物及其性能(以重量份表示)
1 | 2 | 3 | 4 | 5(对比) | |
组分 | |||||
A | 66.7 | 66.7 | 60.7 | 75.0 | 66.7 |
B1 | 16.7 | 14.2 | 16.7 | 10.4 | - |
B2 | - | - | - | - | 7.3 |
C | - | 2.0 | - | - | 9.4 |
D | 12.0 | 12.0 | 18.0 | 10.0 | 12.0 |
E | 4.2 | 4.2 | 4.2 | 4.2 | 4.2 |
脱模剂 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 |
性能ak(ISO 180/1A)[kJ/m2] | 55 | 54 | 53 | 58 | 54 |
Vicat B 120[℃] | 108 | 108 | 99 | 105 | 107 |
UL 94 V,1.6mm | V-0 | V-0 | V-0 | V-0 | V-0 |
ESC性质,在εx失效(%) | 2.4 | 2.4 | 2.0 | 2.4 | 2.2 |
MVR(240/5),ISO1133(cm3/10分钟) | 13.6 | 15.3 | 26.6 | 10.3 | 8.4 |
在280℃TGA质量损失(%) | 0.56 | 0.55 | 0.57 | 0.51 | 0.75 |
本发明的模塑组合物以兼具良好的阻燃性和力学性能而著称。另外,令人惊奇地发现,含有本体ABS的模塑组合物还表现出在加工方面的优点。流动性(MVR)和可以看作为在加工条件下形成沉积物的评价指标的质量损失比含有乳液ABS的模塑组合物明显地好得多(约20%)。
Claims (11)
1.热塑性模塑组合物,其含有:
A)40-99重量份的芳族聚碳酸酯和/或聚酯碳酸酯;
B)0.5-60重量份的接枝聚合物,其制备方法是用本体聚合、溶液聚合或本体/悬浮聚合方法将
B.1)50-99%重量的一种或多种乙烯基单体聚合到
B.2)50-1%重量的一种或多种玻璃化转变温度<10℃的接枝骨架上;
C)0-45重量份的至少一种选自包含乙烯基(共)聚合物和聚对苯二甲酸亚烷基酯的热塑性聚合物;
其中
R在每种情况下相同或不同,表示氨基;在每种情况下任选地被卤素取代,优选被氟卤代的C1-C6烷基或C1-C8烷氧基;C5-C6环烷基,C6-C20芳基、优选苯基或萘基,C6-C20芳氧基、优选苯氧基、萘氧基,或C7-C12芳烷基、优选苯基C1-C4烷基,在每种情况下可任选地被烷基,优选C1-C4烷基和/或卤素、优选氯、溴,取代;
k表示0或1-15的数,优选1-10的数;
E)0-5重量份的氟化聚烯烃。
2.根据权利要求1的模塑组合物,含有
60-98.5重量份的A
1~40重量份的B
0~30重量份的C
2~35重量份的D和
0.1~1重量份的E。
3.根据权利要求1和2的模塑组合物,含有2~25重量份的C。
4.根据权利要求1-3的模塑组合物,含有5~25重量份的D。
5.根据前述权利要求的模塑组合物,其中乙烯基单体B.1是由下述物质制备的混合物:
B.1.1苯乙烯,α-甲基苯乙烯,卤代或烷基环取代的苯乙烯和/或(甲基)丙烯酸C1-C8烷基酯;和
B.1.2不饱和腈,(甲基)丙烯酸C1-C8烷基酯和/或不饱和羧酸的衍生物。
6.根据前述权利要求的模塑组合物,其中接枝骨架选自至少一种选自二烯橡胶、EP(D)M橡胶、丙烯酸酯、聚氨酯、聚硅氧烷、氯丁二烯和乙烯/乙酸乙烯酯橡胶的橡胶。
7.根据前述权利要求的模塑组合物,含有至少一种选自润滑剂和脱模剂、成核剂、抗静电剂、稳定剂以及染料和颜料的添加剂。
8.根据前述权利要求的模塑组合物,还含有不同于组分D的阻燃剂。
9.制备根据权利要求1的模塑组合物的方法,其中将组分A-E和任选的其它添加剂混合并熔融配混。
10.根据权利要求1的模塑组合物用于制备模塑制品的用途。
11.由根据权利要求1-8的模塑组合物制备的模塑制品。
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DE19828541A DE19828541A1 (de) | 1998-06-26 | 1998-06-26 | Flammwidrige Polycarbonat-ABS-Formmassen |
DE19828541.8 | 1998-06-26 |
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CN1325562C (zh) * | 2002-07-09 | 2007-07-11 | 拜尔材料科学有限责任公司 | 高韧性热塑性聚碳酸酯组合物 |
CN101263199B (zh) * | 2005-09-14 | 2011-12-14 | 拜尔材料科学股份公司 | 热塑性模塑组合物及其热成形制品 |
CN101305414B (zh) * | 2005-11-11 | 2012-04-18 | 夏普株式会社 | 液晶显示装置 |
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DE19851676A1 (de) * | 1998-11-10 | 2000-05-11 | Bayer Ag | Thermoplastische Formmassen mit verbesserten mechanischen Eigenschaften |
KR100426723B1 (ko) * | 2000-06-01 | 2004-04-08 | 주식회사 엘지화학 | 포스파겐계 난연 열가소성 수지 조성물 |
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BR112015012709A2 (pt) * | 2012-12-07 | 2017-07-11 | Bayer Materialscience Ag | massas de moldagem ii de policarbonato a prova de fogo iii |
MX2015006981A (es) | 2012-12-07 | 2016-01-08 | Bayer Materialscience Ag | Composiciones de moldeo de policarbonato retardantes de llama v. |
EP2928953B1 (de) * | 2012-12-07 | 2018-01-31 | Covestro Deutschland AG | Flammgeschützte polycarbonatformmassen vi |
MX2015006943A (es) * | 2012-12-07 | 2015-09-08 | Bayer Materialscience Ag | Composiciones de moldeo de policarbonato retardantes de llama iv. |
CN104822754A (zh) * | 2012-12-07 | 2015-08-05 | 拜耳材料科技股份有限公司 | 防火的聚碳酸酯模塑料i |
MX2016003734A (es) | 2013-09-27 | 2016-08-04 | Basf Se | Composiciones de poliolefina para materiales de construccion. |
TWI685524B (zh) | 2013-12-17 | 2020-02-21 | 美商畢克美國股份有限公司 | 預先脫層之層狀材料 |
US20190010308A1 (en) | 2015-07-20 | 2019-01-10 | Basf Se | Flame Retardant Polyolefin Articles |
JP2020502300A (ja) | 2016-12-22 | 2020-01-23 | ディーエスエム アイピー アセッツ ビー.ブイ.Dsm Ip Assets B.V. | 改善された耐熱性かつ電気抵抗性の熱可塑性樹脂組成物 |
EP3828236B1 (de) | 2019-11-27 | 2022-06-01 | Covestro Intellectual Property GmbH & Co. KG | Flammgeschützter polycarbonat-polyester blend |
MX2022014287A (es) | 2020-05-13 | 2022-12-07 | Covestro Deutschland Ag | Composicion de policarbonato retardante de llama. |
JP2023549936A (ja) | 2020-11-19 | 2023-11-29 | ビーエーエスエフ ソシエタス・ヨーロピア | 難燃性粉体組成物及びこの組成物から得られた3d印刷物体 |
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DE19507749A1 (de) * | 1995-03-06 | 1996-09-12 | Bayer Ag | Thermoplastische Formmassen vom ABS-Typ |
DE19615230A1 (de) * | 1996-04-18 | 1997-10-23 | Basf Ag | Flammgeschützte thermoplastische Formmassen |
DE19616968A1 (de) | 1996-04-27 | 1997-11-06 | Daimler Benz Ag | Polymerisierbares Phosphazenderivat, Verfahren zu dessen Herstellung und dessen Verwendung |
JPH1067922A (ja) * | 1996-06-13 | 1998-03-10 | Toray Ind Inc | 熱可塑性樹脂組成物 |
JPH11181429A (ja) * | 1997-02-14 | 1999-07-06 | Otsuka Chem Co Ltd | 難燃剤、難燃性樹脂組成物及び難燃性樹脂成形体 |
WO1999019383A1 (fr) * | 1997-10-15 | 1999-04-22 | Otsuka Chemical Co., Ltd. | Composes phenoxyphosphazene reticules, agent ignifugeant, compositions de resine ignifugeante et moulages a base de resines ignifugeante |
-
1998
- 1998-06-26 DE DE19828541A patent/DE19828541A1/de not_active Withdrawn
-
1999
- 1999-06-12 DE DE59912270T patent/DE59912270D1/de not_active Expired - Lifetime
- 1999-06-12 JP JP2000557300A patent/JP4383665B2/ja not_active Expired - Fee Related
- 1999-06-12 WO PCT/EP1999/004060 patent/WO2000000542A1/de active IP Right Grant
- 1999-06-12 US US09/720,274 patent/US6740695B1/en not_active Expired - Lifetime
- 1999-06-12 KR KR1020007014732A patent/KR100584071B1/ko not_active IP Right Cessation
- 1999-06-12 EP EP99929191A patent/EP1095097B1/de not_active Expired - Lifetime
- 1999-06-12 AU AU46090/99A patent/AU4609099A/en not_active Abandoned
- 1999-06-12 BR BR9911478-0A patent/BR9911478A/pt not_active IP Right Cessation
- 1999-06-12 CN CNB998079243A patent/CN1207331C/zh not_active Expired - Lifetime
- 1999-06-12 CA CA002335965A patent/CA2335965A1/en not_active Abandoned
- 1999-06-25 AR ARP990103071A patent/AR016996A1/es not_active Application Discontinuation
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2002
- 2002-02-01 HK HK02100803.5A patent/HK1039346A1/zh unknown
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1325562C (zh) * | 2002-07-09 | 2007-07-11 | 拜尔材料科学有限责任公司 | 高韧性热塑性聚碳酸酯组合物 |
CN101263199B (zh) * | 2005-09-14 | 2011-12-14 | 拜尔材料科学股份公司 | 热塑性模塑组合物及其热成形制品 |
CN101305414B (zh) * | 2005-11-11 | 2012-04-18 | 夏普株式会社 | 液晶显示装置 |
CN104321382A (zh) * | 2012-05-24 | 2015-01-28 | 沙特基础创新塑料Ip私人有限责任公司 | 阻燃剂热塑性组合物、其制造方法和包含其的制品 |
CN104822753A (zh) * | 2012-12-07 | 2015-08-05 | 拜耳材料科技股份有限公司 | 防火的聚碳酸酯模塑料ii |
CN105452316A (zh) * | 2013-08-05 | 2016-03-30 | 株式会社钟化 | 含有磷腈的橡胶接枝共聚物及其热塑性树脂组合物 |
CN114230999A (zh) * | 2021-11-23 | 2022-03-25 | 金旸(厦门)新材料科技有限公司 | 一种无卤阻燃抗静电聚碳酸酯树脂组合物及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
DE19828541A1 (de) | 1999-12-30 |
EP1095097A1 (de) | 2001-05-02 |
KR100584071B1 (ko) | 2006-05-29 |
JP2002519462A (ja) | 2002-07-02 |
HK1039346A1 (zh) | 2002-04-19 |
US6740695B1 (en) | 2004-05-25 |
EP1095097B1 (de) | 2005-07-13 |
AR016996A1 (es) | 2001-08-01 |
CN1207331C (zh) | 2005-06-22 |
JP4383665B2 (ja) | 2009-12-16 |
DE59912270D1 (de) | 2005-08-18 |
BR9911478A (pt) | 2001-03-20 |
WO2000000542A1 (de) | 2000-01-06 |
AU4609099A (en) | 2000-01-17 |
CA2335965A1 (en) | 2000-01-06 |
KR20010053159A (ko) | 2001-06-25 |
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