CN1285622C - 被载体支持的膦亚胺聚合催化剂 - Google Patents

被载体支持的膦亚胺聚合催化剂 Download PDF

Info

Publication number
CN1285622C
CN1285622C CNB028182243A CN02818224A CN1285622C CN 1285622 C CN1285622 C CN 1285622C CN B028182243 A CNB028182243 A CN B028182243A CN 02818224 A CN02818224 A CN 02818224A CN 1285622 C CN1285622 C CN 1285622C
Authority
CN
China
Prior art keywords
catalyst
ligand
catalyst system
polymerization
aluminoxane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB028182243A
Other languages
English (en)
Chinese (zh)
Other versions
CN1561349A (zh
Inventor
高效良
P·S·奇泽姆
R·D·唐纳森
I·麦凯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NOWAWIH CHEMICAL-PRODUCTS Co Ltd
Original Assignee
NOWAWIH CHEMICAL-PRODUCTS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NOWAWIH CHEMICAL-PRODUCTS Co Ltd filed Critical NOWAWIH CHEMICAL-PRODUCTS Co Ltd
Publication of CN1561349A publication Critical patent/CN1561349A/zh
Application granted granted Critical
Publication of CN1285622C publication Critical patent/CN1285622C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNB028182243A 2001-09-17 2002-09-16 被载体支持的膦亚胺聚合催化剂 Expired - Fee Related CN1285622C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA2357385A CA2357385C (en) 2001-09-17 2001-09-17 Supported phosphinimine polymerization catalyst
CA2,357,385 2001-09-17

Publications (2)

Publication Number Publication Date
CN1561349A CN1561349A (zh) 2005-01-05
CN1285622C true CN1285622C (zh) 2006-11-22

Family

ID=4169992

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB028182243A Expired - Fee Related CN1285622C (zh) 2001-09-17 2002-09-16 被载体支持的膦亚胺聚合催化剂

Country Status (9)

Country Link
US (1) US6710143B2 (https=)
EP (1) EP1427761A2 (https=)
JP (1) JP2005502777A (https=)
KR (1) KR20040035793A (https=)
CN (1) CN1285622C (https=)
AU (1) AU2002325742A1 (https=)
BR (1) BR0212565A (https=)
CA (1) CA2357385C (https=)
WO (1) WO2003025027A2 (https=)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7534842B2 (en) * 2005-11-16 2009-05-19 Chevron Phillips Chemical Company, Lp Catalysts for olefin polymerization
CN102770467B (zh) * 2010-02-22 2015-07-22 尤尼威蒂恩技术有限责任公司 催化剂体系和使用该催化剂体系制备聚烯烃产物的方法
WO2013028283A1 (en) * 2011-08-19 2013-02-28 Univation Technologies, Llc Catalyst systems and methods for using same to produce polyolefin products
KR102329527B1 (ko) * 2013-10-25 2021-11-22 디에스엠 아이피 어셋츠 비.브이. 초고분자량 폴리에틸렌의 제조
JP6576336B2 (ja) * 2013-10-25 2019-09-18 ディーエスエム アイピー アセッツ ビー．ブイ．Ｄｓｍ Ｉｐ Ａｓｓｅｔｓ Ｂ．Ｖ． 超高分子量エチレンコポリマーの調製
US9441063B2 (en) 2014-10-09 2016-09-13 Chevron Phillips Chemical Company Lp Titanium phosphinimide and titanium iminoimidazolidide catalyst systems with activator-supports
US9796795B2 (en) 2015-01-14 2017-10-24 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
CN114685703A (zh) 2015-04-20 2022-07-01 埃克森美孚化学专利公司 包含氟化物化的载体的催化剂组合物及其使用方法
EP3274381B1 (en) 2015-04-20 2019-05-15 ExxonMobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
CN107636029B (zh) 2015-04-20 2020-05-22 埃克森美孚化学专利公司 包含氟化载体的催化剂组合物及其使用方法
WO2017192226A1 (en) 2016-05-03 2017-11-09 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
US9803037B1 (en) 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
KR20190061032A (ko) * 2016-09-28 2019-06-04 니폰 제온 가부시키가이샤 포장 구조의 제조 방법
US10703838B2 (en) 2017-10-31 2020-07-07 Exxonmobil Chemical Patents Inc. Mixed catalyst systems with four metallocenes on a single support
US10894841B2 (en) 2018-03-19 2021-01-19 Exxonmobil Chemical Patents Inc. Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems
WO2019194958A1 (en) 2018-04-06 2019-10-10 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates and compositions therefrom
US11420196B2 (en) * 2018-09-27 2022-08-23 Chevron Phillips Chemical Company Lp Processes for producing fluorided solid oxides and uses thereof in metallocene-based catalyst systems
US20220267649A1 (en) 2019-07-17 2022-08-25 Exxonmobil Chemical Patents Inc. Pressure Sensitive Adhesives Comprising Propylene-Ethylene(-Diene) Copolymers
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
WO2022155026A1 (en) 2021-01-12 2022-07-21 Exxonmobil Chemical Patents Inc. Asymmetric constrained geometry catalysts

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4077904A (en) * 1976-06-29 1978-03-07 Union Carbide Corporation Olefin polymerization process and catalyst therefor
FR2546522B1 (fr) 1983-05-25 1985-07-26 Ato Chimie Procede de preparation d'une composante de metal de transition pour un systeme catalytique de polymerisation d'olefines
US5221655A (en) 1991-01-02 1993-06-22 Phillips Petroleum Company Florided aluminas, catalysts, and polymerization processes
US5219962A (en) 1991-01-02 1993-06-15 Phillips Petroleum Company Fluorided aluminas, catalysts, and polymerization processes
US5221720A (en) 1991-01-02 1993-06-22 Phillips Petroleum Company Fluorided aluminas, catalysts, and polymerization processes
US5219817A (en) 1991-01-02 1993-06-15 Phillips Petroleum Company Fluorided aluminas, catalysts, and polymerization processes
US5221654A (en) 1991-01-02 1993-06-22 Phillips Petroleum Company Fluorided aluminas, catalysts, and polymerization processes
CA2210131C (en) * 1997-07-09 2005-08-02 Douglas W. Stephan Supported phosphinimine-cp catalysts
FR2769245B1 (fr) 1997-10-02 1999-10-29 Atochem Elf Sa Support solide activateur des catalyseurs metallocenes en polymerisation des olefines, son procede de preparation, systeme catalytique et procede de polymerisation correspondants
ES2197649T3 (es) * 1998-08-26 2004-01-01 Exxonmobil Chemical Patents Inc. Composiciones cataliticas soportadas altamente activas.

Also Published As

Publication number Publication date
JP2005502777A (ja) 2005-01-27
US6710143B2 (en) 2004-03-23
CN1561349A (zh) 2005-01-05
KR20040035793A (ko) 2004-04-29
BR0212565A (pt) 2004-10-13
CA2357385A1 (en) 2003-03-17
EP1427761A2 (en) 2004-06-16
AU2002325742A1 (en) 2003-04-01
WO2003025027A3 (en) 2003-05-30
WO2003025027A2 (en) 2003-03-27
US20030119661A1 (en) 2003-06-26
CA2357385C (en) 2010-06-15

Similar Documents

Publication Publication Date Title
CN1285622C (zh) 被载体支持的膦亚胺聚合催化剂
CN1139604C (zh) 有载体的烯烃聚合催化剂
CN100453562C (zh) 由取代二铝氧烷配合物获得的活化催化剂体系
CN1092669C (zh) 用于烯烃聚合的组分及催化剂
CN1301271C (zh) 双位烯烃聚合催化剂组合物
US6767975B1 (en) Olefin polymerization with pyridine moiety-containing singe-site catalysts
CN1275988C (zh) 烯烃聚合催化剂
CN1764676A (zh) 茂金属催化剂及用其制备聚烯烃的方法
CN1173186A (zh) 氮杂金属茂聚合催化剂
CN1414880A (zh) 有机金属化合物催化剂
CN1307594A (zh) 负载型烯烃聚合催化剂组合物
CN1426326A (zh) 有机金属催化剂组合物
CN1019579B (zh) 制备烯烃聚合催化剂的方法
CN1414978A (zh) 有机金属催化剂组合物
CN1910207A (zh) 载体茂金属催化剂、制备该催化剂的方法以及使用该催化剂制备聚烯烃的方法
CN1692129A (zh) 催化剂体系和其在聚合方法中的应用
CN1151178C (zh) 聚合催化剂
CN1137905C (zh) 茂金属化合物及其在烯烃聚合中的应用
CN1930193A (zh) 金属茂类和生产聚乙烯的方法
CN1849346A (zh) 用于高分子量聚烯烃生产的氢硅烷添加剂
CN1271366A (zh) 均质填充聚合物复合材料
CN1575295A (zh) 连接金属茂配合物,催化剂体系和使用该催化剂体系的烯烃聚合方法
CN1820035A (zh) 烯烃聚合法
CN1708517A (zh) 双金属茚并吲哚基催化剂
CN1612900A (zh) 用于烯烃聚合的固态助催化剂成分及其催化剂体系

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20061122

Termination date: 20170916