KR20040035793A - 지지된 포스핀이민 중합반응 촉매 - Google Patents

지지된 포스핀이민 중합반응 촉매 Download PDF

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Publication number
KR20040035793A
KR20040035793A KR10-2004-7003824A KR20047003824A KR20040035793A KR 20040035793 A KR20040035793 A KR 20040035793A KR 20047003824 A KR20047003824 A KR 20047003824A KR 20040035793 A KR20040035793 A KR 20040035793A
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KR
South Korea
Prior art keywords
group
catalyst
polymerization
ligand
ligands
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KR10-2004-7003824A
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English (en)
Korean (ko)
Inventor
가오지아올리앙
치숄름피.스코트
도널드슨로버트디.
맥케이이안
Original Assignee
노바 케미컬즈 (인터내셔널) 소시에테 아노님
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Publication of KR20040035793A publication Critical patent/KR20040035793A/ko
Ceased legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR10-2004-7003824A 2001-09-17 2002-09-16 지지된 포스핀이민 중합반응 촉매 Ceased KR20040035793A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CA2357385A CA2357385C (en) 2001-09-17 2001-09-17 Supported phosphinimine polymerization catalyst
CA2,357,385 2001-09-17
PCT/CA2002/001401 WO2003025027A2 (en) 2001-09-17 2002-09-16 Supported phosphinimine polymerization catalyst

Publications (1)

Publication Number Publication Date
KR20040035793A true KR20040035793A (ko) 2004-04-29

Family

ID=4169992

Family Applications (1)

Application Number Title Priority Date Filing Date
KR10-2004-7003824A Ceased KR20040035793A (ko) 2001-09-17 2002-09-16 지지된 포스핀이민 중합반응 촉매

Country Status (9)

Country Link
US (1) US6710143B2 (https=)
EP (1) EP1427761A2 (https=)
JP (1) JP2005502777A (https=)
KR (1) KR20040035793A (https=)
CN (1) CN1285622C (https=)
AU (1) AU2002325742A1 (https=)
BR (1) BR0212565A (https=)
CA (1) CA2357385C (https=)
WO (1) WO2003025027A2 (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160078394A (ko) * 2013-10-25 2016-07-04 디에스엠 아이피 어셋츠 비.브이. 초고분자량 폴리에틸렌의 제조
KR20160078395A (ko) * 2013-10-25 2016-07-04 디에스엠 아이피 어셋츠 비.브이. 초고분자량 에틸렌 공중합체의 제조

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7534842B2 (en) * 2005-11-16 2009-05-19 Chevron Phillips Chemical Company, Lp Catalysts for olefin polymerization
CN102770467B (zh) * 2010-02-22 2015-07-22 尤尼威蒂恩技术有限责任公司 催化剂体系和使用该催化剂体系制备聚烯烃产物的方法
WO2013028283A1 (en) * 2011-08-19 2013-02-28 Univation Technologies, Llc Catalyst systems and methods for using same to produce polyolefin products
US9441063B2 (en) 2014-10-09 2016-09-13 Chevron Phillips Chemical Company Lp Titanium phosphinimide and titanium iminoimidazolidide catalyst systems with activator-supports
US9796795B2 (en) 2015-01-14 2017-10-24 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
CN114685703A (zh) 2015-04-20 2022-07-01 埃克森美孚化学专利公司 包含氟化物化的载体的催化剂组合物及其使用方法
EP3274381B1 (en) 2015-04-20 2019-05-15 ExxonMobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
CN107636029B (zh) 2015-04-20 2020-05-22 埃克森美孚化学专利公司 包含氟化载体的催化剂组合物及其使用方法
WO2017192226A1 (en) 2016-05-03 2017-11-09 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
US9803037B1 (en) 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
KR20190061032A (ko) * 2016-09-28 2019-06-04 니폰 제온 가부시키가이샤 포장 구조의 제조 방법
US10703838B2 (en) 2017-10-31 2020-07-07 Exxonmobil Chemical Patents Inc. Mixed catalyst systems with four metallocenes on a single support
US10894841B2 (en) 2018-03-19 2021-01-19 Exxonmobil Chemical Patents Inc. Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems
WO2019194958A1 (en) 2018-04-06 2019-10-10 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates and compositions therefrom
US11420196B2 (en) * 2018-09-27 2022-08-23 Chevron Phillips Chemical Company Lp Processes for producing fluorided solid oxides and uses thereof in metallocene-based catalyst systems
US20220267649A1 (en) 2019-07-17 2022-08-25 Exxonmobil Chemical Patents Inc. Pressure Sensitive Adhesives Comprising Propylene-Ethylene(-Diene) Copolymers
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
WO2022155026A1 (en) 2021-01-12 2022-07-21 Exxonmobil Chemical Patents Inc. Asymmetric constrained geometry catalysts

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4077904A (en) * 1976-06-29 1978-03-07 Union Carbide Corporation Olefin polymerization process and catalyst therefor
FR2546522B1 (fr) 1983-05-25 1985-07-26 Ato Chimie Procede de preparation d'une composante de metal de transition pour un systeme catalytique de polymerisation d'olefines
US5221655A (en) 1991-01-02 1993-06-22 Phillips Petroleum Company Florided aluminas, catalysts, and polymerization processes
US5219962A (en) 1991-01-02 1993-06-15 Phillips Petroleum Company Fluorided aluminas, catalysts, and polymerization processes
US5221720A (en) 1991-01-02 1993-06-22 Phillips Petroleum Company Fluorided aluminas, catalysts, and polymerization processes
US5219817A (en) 1991-01-02 1993-06-15 Phillips Petroleum Company Fluorided aluminas, catalysts, and polymerization processes
US5221654A (en) 1991-01-02 1993-06-22 Phillips Petroleum Company Fluorided aluminas, catalysts, and polymerization processes
CA2210131C (en) * 1997-07-09 2005-08-02 Douglas W. Stephan Supported phosphinimine-cp catalysts
FR2769245B1 (fr) 1997-10-02 1999-10-29 Atochem Elf Sa Support solide activateur des catalyseurs metallocenes en polymerisation des olefines, son procede de preparation, systeme catalytique et procede de polymerisation correspondants
ES2197649T3 (es) * 1998-08-26 2004-01-01 Exxonmobil Chemical Patents Inc. Composiciones cataliticas soportadas altamente activas.

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160078394A (ko) * 2013-10-25 2016-07-04 디에스엠 아이피 어셋츠 비.브이. 초고분자량 폴리에틸렌의 제조
KR20160078395A (ko) * 2013-10-25 2016-07-04 디에스엠 아이피 어셋츠 비.브이. 초고분자량 에틸렌 공중합체의 제조

Also Published As

Publication number Publication date
JP2005502777A (ja) 2005-01-27
US6710143B2 (en) 2004-03-23
CN1561349A (zh) 2005-01-05
BR0212565A (pt) 2004-10-13
CN1285622C (zh) 2006-11-22
CA2357385A1 (en) 2003-03-17
EP1427761A2 (en) 2004-06-16
AU2002325742A1 (en) 2003-04-01
WO2003025027A3 (en) 2003-05-30
WO2003025027A2 (en) 2003-03-27
US20030119661A1 (en) 2003-06-26
CA2357385C (en) 2010-06-15

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