CN1232557C - 聚氨酯弹性体、其制备方法及其应用 - Google Patents
聚氨酯弹性体、其制备方法及其应用 Download PDFInfo
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- CN1232557C CN1232557C CNB028168518A CN02816851A CN1232557C CN 1232557 C CN1232557 C CN 1232557C CN B028168518 A CNB028168518 A CN B028168518A CN 02816851 A CN02816851 A CN 02816851A CN 1232557 C CN1232557 C CN 1232557C
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
- C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
Description
%重量 | A组分 |
余量加到100 | 聚醚二醇b)(重量比PO∶EO 70∶30;分子量4000g/mol) |
10 | 聚醚三醇c)(重量比PO∶EO 78∶22;分子量6000g/mol) |
10 | 丁二醇e) |
0.2 | TELA e) |
0.5 | DABCO f) |
Y | 催化剂及其用量(参见表4) |
0.10 | DC-190k) |
0.35 | 水j) |
%重量 | B组分 |
66 | 4,4’-MDI a) |
5 | 聚合物MDI(29.8wt%NCO,官能度2.1)a) |
29 | 三丙二醇和PO聚醚的混合物;数均分子量690g/mol;官能度~2b) |
商品名或缩写 | 化学名称 |
TyzorAA 95来自DuPont | 双(二乙酰丙酮合)钛(IV)丁醇化物.异丙醇化物在丁醇中 |
TyzorAA 105来自DuPont | 双(二乙酰丙酮合)钛(IV)乙醇化物.异丙醇化物 |
Li2 Hex-Cem来自OMG(OntokumpuMooney Group) | 2-乙基己酸锂在2-(2-乙氧基乙氧基)乙醇中 |
Li Ten-Cemwater sol.来自OMG | 新癸酸锂水溶液 |
DBTL | 二月桂酸二丁基锡 |
Coscat83来自D.H.Erbslh | 新癸酸铋(III) |
TELA | 三乙醇胺 |
DABCO | 二氨基双环辛烷 |
DC-190来自Air Products | 定泡剂 |
实验 | 锡催化剂 | 乳白期[sec] | 纤维期[sec] | 邵尔-A硬度,脱模后x min测定 | 邵尔-A硬度,脱模后24h | 刺穿膨胀,mm,b=60,000次弯折后 | ||||
名称 | 用量wt.% | 0min后 | 2min后 | 10min后 | 60min后 | |||||
1 | DBTL | 0.02 | 11 | 22 | 37 | 42 | 47 | 51 | 54 | 35000*/30000*35000*/30000* |
2 | DBTL | 0.03 | 10 | 15 | 34 | 38 | 44 | 48 | 52 | 6.7/60000* |
实验 | 锂组分 | 钛组分 | 铋组分 | [nTi∶nLi] | nBi∶(nTi+nLi) | 乳白期[sec] | 纤维期[sec] | 邵尔-A硬度,脱模后x分测度 | 邵尔-A硬度,脱模后24h | 刺穿膨胀,mm,b=60,000次弯折后 | ||||||
名称 | 用量wt.% | 名称 | 用量wt.% | 名称 | 用量wt.% | 0min后 | 2min后 | 10min后 | 60min后 | |||||||
3 | TyzorAA105 | 0.15 | 11 | 17 | 30 | 35 | 45 | 54 | 56 | 4.1/3.2 | ||||||
4 | Li-2-HexCem | 0.06 | TyzorAA105 | 0.09 | 1.38 | 11 | 24 | 33 | 38 | 46 | 52 | 54 | 2.9/2.2 | |||
5 | Li TenCem | 0.15 | 11 | 33 | 25 | 30 | 39 | 43 | 48 | 4.3/6.2 | ||||||
6 | Li TenCem | 0.1 | TyzorAA95 | 0.1 | 0.25 | 11 | 20 | 38 | 42 | 49 | 52 | 54 | 1.8/3.6 | |||
7 | OctaSoligenLithium | 0.1 | TyzorAA95 | 0.1 | 0.85 | 12 | 27 | 45 | 40 | 48 | 52 | 52 | 1.8/2.9 | |||
8 | 硬脂酸锂 | 0.03 | TyzorAA95 | 0.04 | Coscat 83 | 0.02 | 1.83 | 0.7 | 9 | 22 | 31 | 35 | 45 | 50 | 54 | 2.4/1.2 |
9 | 苯甲酸锂 | 0.0014 | TyzorAA95 | 0.04 | Coscat 83 | 0.02 | 1.83 | 0.7 | 9 | 24 | 32 | 36 | 46 | 51 | 53 | 60000*/55000* |
10 | Li-2-HexCem | 0.04 | TyzorAA95 | 0.04 | 72%双-2-乙基己酸盐在容剂油中的溶液 | 0.014 | 0.92 | 0.07 | 11 | 26 | 33 | 39 | 47 | 51 | 53 | 2.1/1.8 |
11 | Li-2-HexCem | 0.04 | TyzorAA95 | 0.04 | 72%双-2-乙基己酸盐在二甲苯中的溶液 | 0.014 | 0.92 | 0.07 | 11 | 22 | 33 | 41 | 46 | 50 | 53 | 3.3/1.9 |
实验 | 锂组分 | 钛组分 | [nTi∶nLi] | 乳白期[sec] | 纤维期[sec] | 邵尔-A硬度,脱模后x分测度 | 邵尔-A硬度,脱模后24h | 刺穿膨胀,mm,b=60,000次弯折后 | |||||
名称 | 用量wt.% | 名称 | 用量wt.% | 0min后 | 2min后 | 10min后 | 60min后 | ||||||
12 | Li-2-HexCem | 0.15 | 15 | 44 | 29 | 34 | 43 | 51 | 52 | 45000*/4.3 | |||
13 | Li-2-HexCem | 0.12 | Tyzor AA 95 | 0.03 | 0.23 | 12 | 32 | 35 | 39 | 48 | 53 | 54 | 2.5/7.6 |
14 | Li-2-HexCem | 0.09 | Tyzor AA 95 | 0.06 | 0.61 | 12 | 23 | 38 | 41 | 50 | 55 | 55 | 2.8/4.5 |
15 | Li-2-HexCem | 0.075 | Tyzor AA 95 | 0.075 | 0.92 | 11 | 23 | 38 | 42 | 51 | 55 | 56 | 4.1/4.2 |
16 | Li-2-HexCem | 0.06 | Tyzor AA 95 | 0.09 | 1.38 | 11 | 21 | 36 | 41 | 50 | 54 | 55 | 3.5/4 |
17 | Li-2-HexCem | 0.03 | Tyzor AA 95 | 0.12 | 3.67 | 10 | 20 | 35 | 41 | 50 | 53 | 55 | 4.1/4.5 |
18 | Tyzor AA 95 | 0.15 | 11 | 18 | 34 | 39 | 49 | 53 | 56 | 12.6/6.7 |
实验 | 锂组分 | 钛组分 | 铋组分 | [nTi∶nLi] | nBi∶(nTi+nLi) | 乳白期[sec] | 纤维期[sec] | 邵尔-A硬度,脱模后x分测度 | 邵尔-A硬度,脱模后24h | 刺穿膨胀,mm,b=60,000次弯折后 | ||||||
名称 | 用量wt.% | 名称 | 用量wt.% | 名称 | 用量wt.% | 0min后 | 2min后 | 10min后 | 60min后 | |||||||
19 | Li-2-HexCem | 0 | TyzorAA 95 | 0.1 | Coscat 83 | 0.02 | 0.27 | 11 | 20 | 30 | 35 | 42 | 48 | 53 | 60000*/11.9 | |
20 | Li-2-HexCem | 0.02 | TyzorAA 95 | 0.06 | Coscat 83 | 0.02 | 2.75 | 0.27 | 9 | 20 | 35 | 40 | 47 | 52 | 55 | 60000*/1.31 |
21 | Li-2-HexCem | 0.04 | TyzorAA 95 | 0.04 | Coscat 83 | 0.02 | 0.92 | 0.26 | 10 | 24 | 35 | 40 | 46 | 50 | 53 | 7.7/6.2 |
22 | Li-2-HexCem | 0.06 | TyzorAA 95 | 0.02 | Coscat 83 | 0.02 | 0.31 | 0.26 | 11 | 26 | 34 | 39 | 45 | 47 | 52 | 60000*/6.2 |
23 | Li-2-HexCem | 0.08 | TyzorAA 95 | 0 | Coscat 83 | 0.02 | 0.25 | 11 | 39 | 31 | 36 | 46 | 51 | 52 | 4.5/4.0 |
实验 | 锂组分 | 钛组分 | 铋组分 | [nTi∶nLi] | nBi∶(nTi+nLi) | 乳白期[sec] | 纤维期[sec] | 邵尔-A硬度,脱模后x分测度 | 邵尔-A硬度,脱模后24h | 刺穿膨胀,mm,b=60,000次弯折后 | ||||||
名称 | 用量wt.% | 名称 | 用量wt.% | 名称 | 用量wt.% | 0min后 | 2min后 | 10min后 | 60min后 | |||||||
24# | Coscat 83 | 0.1 | 0 | 10 | 35 | 28 | 35 | 47 | 50 | 55 | 1.6/1.7 | |||||
25 | Li-2-HexCem | 0.04 | TyzorAA 95 | 0.04 | Coscat 83 | 0.02 | 0.92 | 0.07 | 10 | 24 | 35 | 40 | 46 | 50 | 53 | 7.7/6.2 |
26# | Li-2-HexCem | 0.026 | TyzorAA 95 | 0.026 | Coscat 83 | 0.046 | 0.92 | 0.25 | 8 | 23 | 37 | 43 | 50 | 53 | 57 | 3.3/4.4 |
27 | Li-2-HexCem | 0.036 | TyzorAA 95 | 0.036 | Coscat 83 | 0.028 | 0.92 | 0.11 | 8 | 22 | 37 | 42 | 50 | 54 | 56 | 4.6/3.2 |
28 | Li-2-HexCem | 0.042 | TyzorAA 95 | 0.042 | Coscat 83 | 0.015 | 0.92 | 0.05 | 10 | 28 | 34 | 39 | 46 | 50 | 56 | 9.2/4.0 |
29 | Li-2-HexCem | 0.046 | TyzorAA 95 | 0.046 | Coscat 83 | 0.008 | 0.92 | 0.03 | 9 | 25 | 35 | 40 | 49 | 51 | 57 | 60000*/13.6 |
30 | Li-2-HexCem | 0.05 | TyzorAA 95 | 0.05 | 0.92 | 10 | 22 | 33 | 38 | 47 | 50 | 53 | 3.4/3.6 |
Claims (13)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10142296A DE10142296C1 (de) | 2001-08-29 | 2001-08-29 | Polyurethanelastomere, Verfahren zu ihrer Herstellung und ihre Verwendung |
DE10142296.2 | 2001-08-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1549835A CN1549835A (zh) | 2004-11-24 |
CN1232557C true CN1232557C (zh) | 2005-12-21 |
Family
ID=7696977
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB028168518A Expired - Fee Related CN1232557C (zh) | 2001-08-29 | 2002-08-19 | 聚氨酯弹性体、其制备方法及其应用 |
Country Status (14)
Country | Link |
---|---|
US (1) | US6590057B1 (zh) |
EP (1) | EP1432749B1 (zh) |
JP (1) | JP4167176B2 (zh) |
CN (1) | CN1232557C (zh) |
AT (1) | ATE380211T1 (zh) |
DE (2) | DE10142296C1 (zh) |
ES (1) | ES2295447T3 (zh) |
HK (1) | HK1069839A1 (zh) |
HR (1) | HRP20040296A2 (zh) |
HU (1) | HUP0401279A3 (zh) |
MX (1) | MXPA04001910A (zh) |
PL (1) | PL207298B1 (zh) |
TW (1) | TW593395B (zh) |
WO (1) | WO2003020783A1 (zh) |
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-
2001
- 2001-08-29 DE DE10142296A patent/DE10142296C1/de not_active Expired - Lifetime
-
2002
- 2002-08-19 WO PCT/EP2002/009244 patent/WO2003020783A1/de active IP Right Grant
- 2002-08-19 CN CNB028168518A patent/CN1232557C/zh not_active Expired - Fee Related
- 2002-08-19 PL PL367705A patent/PL207298B1/pl not_active IP Right Cessation
- 2002-08-19 JP JP2003525050A patent/JP4167176B2/ja not_active Expired - Fee Related
- 2002-08-19 MX MXPA04001910A patent/MXPA04001910A/es active IP Right Grant
- 2002-08-19 AT AT02797592T patent/ATE380211T1/de not_active IP Right Cessation
- 2002-08-19 ES ES02797592T patent/ES2295447T3/es not_active Expired - Lifetime
- 2002-08-19 HU HU0401279A patent/HUP0401279A3/hu unknown
- 2002-08-19 DE DE50211324T patent/DE50211324D1/de not_active Expired - Lifetime
- 2002-08-19 EP EP02797592A patent/EP1432749B1/de not_active Expired - Lifetime
- 2002-08-27 US US10/228,535 patent/US6590057B1/en not_active Expired - Fee Related
- 2002-08-28 TW TW091119474A patent/TW593395B/zh not_active IP Right Cessation
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2004
- 2004-03-26 HR HR20040296A patent/HRP20040296A2/hr not_active Application Discontinuation
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Also Published As
Publication number | Publication date |
---|---|
PL207298B1 (pl) | 2010-11-30 |
JP2005501940A (ja) | 2005-01-20 |
CN1549835A (zh) | 2004-11-24 |
HUP0401279A2 (hu) | 2004-09-28 |
HK1069839A1 (en) | 2005-06-03 |
JP4167176B2 (ja) | 2008-10-15 |
ATE380211T1 (de) | 2007-12-15 |
WO2003020783A1 (de) | 2003-03-13 |
MXPA04001910A (es) | 2005-03-07 |
HRP20040296A2 (en) | 2005-02-28 |
EP1432749B1 (de) | 2007-12-05 |
HUP0401279A3 (en) | 2005-11-28 |
TW593395B (en) | 2004-06-21 |
DE10142296C1 (de) | 2003-02-13 |
DE50211324D1 (de) | 2008-01-17 |
PL367705A1 (en) | 2005-03-07 |
US6590057B1 (en) | 2003-07-08 |
EP1432749A1 (de) | 2004-06-30 |
ES2295447T3 (es) | 2008-04-16 |
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