CN1218913C - 流化床芳烃烷基化 - Google Patents

流化床芳烃烷基化 Download PDF

Info

Publication number
CN1218913C
CN1218913C CNB998131873A CN99813187A CN1218913C CN 1218913 C CN1218913 C CN 1218913C CN B998131873 A CNB998131873 A CN B998131873A CN 99813187 A CN99813187 A CN 99813187A CN 1218913 C CN1218913 C CN 1218913C
Authority
CN
China
Prior art keywords
fluidized bed
reaction zone
toluene
reactor
aromatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CNB998131873A
Other languages
English (en)
Chinese (zh)
Other versions
CN1326430A (zh
Inventor
D·L·约翰森
R·G·廷格
R·A·韦尔
S·约查克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
ExxonMobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp, ExxonMobil Oil Corp filed Critical Mobil Oil Corp
Publication of CN1326430A publication Critical patent/CN1326430A/zh
Application granted granted Critical
Publication of CN1218913C publication Critical patent/CN1218913C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CNB998131873A 1998-10-05 1999-09-27 流化床芳烃烷基化 Expired - Lifetime CN1218913C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/166,188 US6642426B1 (en) 1998-10-05 1998-10-05 Fluid-bed aromatics alkylation with staged injection of alkylating agents
US09/166,188 1998-10-05

Publications (2)

Publication Number Publication Date
CN1326430A CN1326430A (zh) 2001-12-12
CN1218913C true CN1218913C (zh) 2005-09-14

Family

ID=22602174

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB998131873A Expired - Lifetime CN1218913C (zh) 1998-10-05 1999-09-27 流化床芳烃烷基化

Country Status (14)

Country Link
US (1) US6642426B1 (enExample)
EP (1) EP1119532B1 (enExample)
JP (1) JP4607326B2 (enExample)
KR (1) KR100637964B1 (enExample)
CN (1) CN1218913C (enExample)
AT (1) ATE247613T1 (enExample)
AU (1) AU6165499A (enExample)
BR (1) BR9915913B1 (enExample)
CA (1) CA2346431C (enExample)
DE (1) DE69910598T2 (enExample)
ES (1) ES2205882T3 (enExample)
ID (1) ID29191A (enExample)
TW (1) TW505620B (enExample)
WO (1) WO2000020360A1 (enExample)

Families Citing this family (74)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7232936B1 (en) 2000-02-22 2007-06-19 Exxonmobil Chemical Patents Inc. Conversion of oxygenate to olefins with staged injection of oxygenate
US7226771B2 (en) 2002-04-19 2007-06-05 Diversa Corporation Phospholipases, nucleic acids encoding them and methods for making and using them
EP1523535A1 (en) * 2002-06-19 2005-04-20 Exxonmobil Chemical Patents Inc. Manufacture of xylenes from reformate
CN1886362B (zh) 2003-07-24 2010-10-13 皇后医学中心 烷基化剂的制备和用途
US7084318B2 (en) 2003-08-01 2006-08-01 Saudi Basic Industries Corporation Toluene methylation process
US7060864B2 (en) 2003-09-30 2006-06-13 Saudi Basic Industries Corporation Toluene methylation process
US7060644B2 (en) 2004-01-08 2006-06-13 Saudi Basic Industries Corporation Aromatic alkylation catalyst and method
US6943131B1 (en) 2004-03-02 2005-09-13 Saudi Basic Industries Corporation Selective zeolite catalyst modification
US7285511B2 (en) 2004-04-23 2007-10-23 Saudi Basic Industries Corporation Method of modifying zeolite catalyst
US7399727B2 (en) 2004-04-23 2008-07-15 Saudi Basic Industries Corporation Zeolite catalyst and method
US7304198B2 (en) * 2004-05-14 2007-12-04 Battelle Memorial Institute Staged alkylation in microchannels
WO2005123251A1 (en) 2004-06-09 2005-12-29 Saudi Basic Industries Corporation Fluoride-modified zeolite catalyst and method
DE102004041011A1 (de) 2004-08-24 2006-03-02 Martin Schleske Resonanzplatte in Faserverbund-Bauweise für akustische Musikinstrumente
US7304194B2 (en) 2005-05-05 2007-12-04 Saudi Basic Industries Corporation Hydrothermal treatment of phosphorus-modified zeolite catalysts
KR100598988B1 (ko) * 2005-05-18 2006-07-12 주식회사 하이닉스반도체 오버레이 버니어 및 이를 이용한 반도체소자의 제조방법
US7368410B2 (en) 2005-08-03 2008-05-06 Saudi Basic Industries Corporation Zeolite catalyst and method of preparing and use of zeolite catalyst
WO2009143397A2 (en) 2008-05-23 2009-11-26 E. I. Du Pont De Nemours And Company Novel dgat genes for increased seed storage lipid production and altered fatty acid profiles in oilseed plants
US8846559B2 (en) 2008-11-03 2014-09-30 Saudi Basic Industries Corporation Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing
US8252967B2 (en) * 2009-04-14 2012-08-28 Exxonmobil Chemical Patents Inc. Process for the purification of paraxylene
US8558046B2 (en) * 2009-05-28 2013-10-15 Saudi Basic Industries Corporation Aromatic alkylation process
US8062987B2 (en) 2009-10-05 2011-11-22 Saudi Basic Industries Corporation Phosphorus-containing zeolite catalysts and their method of preparation
US8344197B2 (en) * 2009-10-21 2013-01-01 Exxonmobil Chemical Patents Inc. Production of para-xylene by the methylation of benzene and/or toluene
US8399727B2 (en) * 2009-10-21 2013-03-19 Exxonmobil Chemical Patents Inc. Production of para-xylene by the methylation of benzene and/or toluene
CN102372582A (zh) * 2010-08-23 2012-03-14 中国石油化工股份有限公司 甲苯甲基化的流化催化方法
CN102372587A (zh) * 2010-08-23 2012-03-14 中国石油化工股份有限公司 芳烃甲基化的流化床方法
CN102372585B (zh) * 2010-08-23 2015-12-09 中国石油化工股份有限公司 芳烃烷基化制对二甲苯的流化床方法
CN102464559A (zh) * 2010-11-17 2012-05-23 中国石油化工股份有限公司 用于生产烷基化芳烃的方法
CN102464557B (zh) * 2010-11-17 2014-03-26 中国石油化工股份有限公司 由含氧化合物和甲苯制备二甲苯的方法
WO2012170336A2 (en) * 2011-06-10 2012-12-13 Exxonmobil Chemical Patents Inc. Production of para-xylene
CN103619786B (zh) * 2011-07-11 2016-06-01 埃克森美孚化学专利公司 苯和/或甲苯与甲醇的烷基化
TWI495511B (zh) 2011-07-27 2015-08-11 Exxonmobil Chem Patents Inc 具有分階擋板的流體床反應器
KR102049289B1 (ko) * 2011-12-08 2019-11-27 쥐티씨 테크놀로지 유에스,엘엘씨 방향족 화합물의 메틸화 반응에 의한 자일렌 생산
US9278342B2 (en) 2012-07-02 2016-03-08 Saudi Basic Industries Corporation Method of modifying a phosphorus-containing zeolite catalyst
CN103664485B (zh) * 2012-09-05 2016-05-18 中国石油化工股份有限公司 甲苯、甲醇侧链烷基化生产乙苯、苯乙烯的方法
US9802876B2 (en) 2012-07-12 2017-10-31 China Petroleum & Chemical Corporation Alkylating process for alkyl benzenes
CN103772129A (zh) * 2012-10-25 2014-05-07 中国石油化工股份有限公司 甲苯甲基化生产混合二甲苯的方法
US9353024B2 (en) 2013-02-06 2016-05-31 Exxonmobil Chemical Patents Inc. Selective hydrogenation of styrene to ethylbenzene
WO2015094696A1 (en) 2013-12-20 2015-06-25 Exxonmobil Chemical Patents Inc. Process for converting oxygenates to aromatic hydrocarbons
WO2016003613A2 (en) 2014-06-30 2016-01-07 Exxonmobil Chemical Patents Inc. Process for the production of xylenes
WO2016003612A1 (en) 2014-06-30 2016-01-07 Exxonmobil Chemical Patents Inc. Processes for the production of para-xylene
JP6389284B2 (ja) 2014-06-30 2018-09-12 エクソンモービル・ケミカル・パテンツ・インク パラキシレンの製造方法
US9469579B2 (en) 2014-06-30 2016-10-18 Exxonmobil Chemical Patents Inc. Process for the production of xylenes
US9802877B2 (en) 2014-08-29 2017-10-31 Exxonmobil Chemical Patents Inc. Process of producing para-xylene by alkylation of benzene and/or toluene including treatment of an alkylating agent to remove metal salts
CN106433761B (zh) * 2015-08-06 2018-07-13 中国石油天然气股份有限公司 异丁烷与丁烯烷基化合成烷基化油的多级沸腾床催化工艺
US10071938B2 (en) 2015-09-25 2018-09-11 Exxonmobil Chemical Patents Inc. Hydrocarbon dehydrocyclization
US9815749B2 (en) 2015-09-25 2017-11-14 Exxonmobil Chemical Patents Inc. Hydrocarbon dehydrocyclization
US10906851B2 (en) 2016-02-26 2021-02-02 Exxonmobil Chemical Patents Inc. Process for recovering para-xylene
CN108779043B (zh) 2016-03-25 2021-09-24 埃克森美孚化学专利公司 用于生产对二甲苯的催化剂和方法
WO2018057125A2 (en) 2016-09-22 2018-03-29 Exxonmobil Chemical Patents Inc. Use of light gas by-products in the production of paraxylene by the methylation of toluene and/or benzene
CN109906213B (zh) * 2016-09-22 2022-03-25 埃克森美孚化学专利公司 轻质气体副产物在通过甲苯和/或苯的甲基化制备对二甲苯中的用途
KR20210088742A (ko) 2016-10-06 2021-07-14 엑손모빌 케미칼 패턴츠 인코포레이티드 벤젠 및/또는 톨루엔의 메틸화에 의한 파라크실렌의 제조 방법
JP6982068B2 (ja) 2016-10-06 2021-12-17 エクソンモービル・ケミカル・パテンツ・インク ベンゼンおよび／またはトルエンのメチル化によるパラキシレン製造用の触媒に選択性付与するプロセス
BR112019006899A2 (pt) 2016-10-06 2019-07-02 Exxonmobil Chemical Patents Inc processo para metilar hidrocarbonetos aromáticos
US11208365B2 (en) 2016-12-20 2021-12-28 Uop Llc Processes and apparatuses for methylation of aromatics in an aromatics complex
US11673849B2 (en) 2016-12-21 2023-06-13 Exxonmobil Chemical Patents Inc. Process for selectivating catalyst for producing paraxylene by methylation of benzene and/or toluene
CN108786670B (zh) 2017-04-27 2021-01-26 中国科学院大连化学物理研究所 甲醇和/或二甲醚与甲苯制对二甲苯联产低碳烯烃的方法
CN108786672B (zh) * 2017-04-27 2021-01-26 中国科学院大连化学物理研究所 甲醇和/或二甲醚与苯制对二甲苯联产低碳烯烃的方法
CN108794294B (zh) * 2017-04-27 2020-12-11 中国科学院大连化学物理研究所 流化床气体分布器、应用其的反应器及生产对二甲苯联产低碳烯烃的方法
CN108786669B (zh) * 2017-04-27 2021-01-12 中国科学院大连化学物理研究所 流化床气体分布器、应用其的反应器及生产对二甲苯联产低碳烯烃的方法
CN108786671B (zh) * 2017-04-27 2021-04-23 中国科学院大连化学物理研究所 甲醇和/或二甲醚与苯制对二甲苯联产低碳烯烃的流化床装置及方法
CN108794291B (zh) * 2017-04-27 2020-11-27 中国科学院大连化学物理研究所 甲醇和/或二甲醚与甲苯制对二甲苯联产低碳烯烃的流化床装置及方法
US10604458B2 (en) 2017-11-30 2020-03-31 Exxonmobil Chemical Patents Inc. Systems and methods for aromatic alkylation
US11130719B2 (en) * 2017-12-05 2021-09-28 Uop Llc Processes and apparatuses for methylation of aromatics in an aromatics complex
CN111448178B (zh) 2017-12-05 2023-01-06 埃克森美孚化学专利公司 二甲苯生产方法和系统
US10556214B2 (en) 2017-12-20 2020-02-11 Uop Llc Apparatuses for mixing of staged methanol injection
EP3728170A1 (en) 2017-12-22 2020-10-28 ExxonMobil Chemical Patents Inc. Catalysts for producing paraxylene by methylation of benzene and/or toluene
CN108441257B (zh) * 2018-03-20 2020-10-13 中国石油大学(华东) 一种重油裂解轻质石油烃原位烷基化的方法
US11130720B2 (en) 2018-03-23 2021-09-28 Uop Llc Processes for methylation of aromatics in an aromatics complex
US11078133B2 (en) * 2019-12-06 2021-08-03 Uop Llc Aromatic alkylation process
US12358857B2 (en) 2020-07-31 2025-07-15 Exxonmobil Chemicals Patents Inc. Processes for producing high-octane-number fuel component
WO2023044278A1 (en) 2021-09-16 2023-03-23 Exxonmobil Chemical Patents Inc. Xylene isomer separation processes
WO2023204947A1 (en) 2022-04-19 2023-10-26 Exxonmobil Chemical Patents Inc. Processes for oxidizing p-xylene or p-xylene-containing mixtures
US20250353800A1 (en) 2022-06-14 2025-11-20 Exxonmobil Chemical Patents Inc. Production of P-Xylene by Liquid-Phase Isomerization and Separation Thereof
WO2023244389A1 (en) 2022-06-14 2023-12-21 Exxonmobil Chemical Patents Inc. Production of p-xylene by liquid-phase isomerization in the presence of c9+ aromatic hydrocarbons and separation thereof

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4924921B1 (enExample) * 1970-06-27 1974-06-26
US3751504A (en) 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
US4049738A (en) * 1976-07-12 1977-09-20 Mobil Oil Corporation Selective production of para-xylene
JPS5726627A (en) 1980-07-25 1982-02-12 Teijin Yuka Kk Preparation of p-xylene
JPS5835128A (ja) * 1981-08-27 1983-03-01 Teijin Yuka Kk ｐ−キシレンの改良製造法
US4761513A (en) 1987-07-01 1988-08-02 Uop Inc. Temperature control for aromatic alkylation process
EP0308097B1 (en) * 1987-09-02 1992-01-29 Mobil Oil Corporation Transalkylation of polyalkylaromatic hydrocarbons
US5198595A (en) * 1987-11-23 1993-03-30 The Dow Chemical Company Alkylation of aromatic compounds
US4891458A (en) * 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
US4992607A (en) * 1989-03-20 1991-02-12 Mobil Oil Corporation Petroleum refinery process and apparatus for the production of alkyl aromatic hydrocarbons from fuel gas and catalytic reformate
US5120890A (en) 1990-12-31 1992-06-09 Uop Process for reducing benzene content in gasoline
CA2111101A1 (en) * 1991-06-21 1993-01-07 Guo S. J. Lee Alkylation of aromatic compounds
BR9507649A (pt) * 1994-05-16 1997-09-09 Hoechst Celanese Corp Fibra resistente a corte fio composto processo de fabricaçao de tecido resistente a corte e respectivo tecido fio e luva de segurancça resistente a corte
CN1043036C (zh) * 1994-05-24 1999-04-21 中国石油化工总公司 芳烃烷基化方法及其所用液固循环流化床设备
US5600048A (en) * 1994-12-27 1997-02-04 Mobil Oil Corporation Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation
US5660048A (en) * 1996-02-16 1997-08-26 Laroche Industries, Inc. Air conditioning system for cooling warm moisture-laden air
JPH10298117A (ja) * 1997-04-23 1998-11-10 Mitsubishi Heavy Ind Ltd 芳香族炭化水素の選択的アルキル化法

Also Published As

Publication number Publication date
TW505620B (en) 2002-10-11
AU6165499A (en) 2000-04-26
JP2002526513A (ja) 2002-08-20
ID29191A (id) 2001-08-09
US6642426B1 (en) 2003-11-04
EP1119532B1 (en) 2003-08-20
BR9915913B1 (pt) 2011-01-25
DE69910598T2 (de) 2004-06-24
ATE247613T1 (de) 2003-09-15
KR100637964B1 (ko) 2006-10-23
CA2346431C (en) 2009-02-03
EP1119532A4 (en) 2002-08-14
KR20010083889A (ko) 2001-09-03
BR9915913A (pt) 2001-10-16
WO2000020360A1 (en) 2000-04-13
ES2205882T3 (es) 2004-05-01
CN1326430A (zh) 2001-12-12
DE69910598D1 (de) 2003-09-25
JP4607326B2 (ja) 2011-01-05
EP1119532A1 (en) 2001-08-01
CA2346431A1 (en) 2000-04-13

Similar Documents

Publication Publication Date Title
CN1218913C (zh) 流化床芳烃烷基化
CN1190395C (zh) 分段注入含氧化合物用于含氧化合物转化成烯烃
AU2007308575B2 (en) A process for producing light olefins from methanol or dimethyl ether
JP2017125059A (ja) 多段式バッフルを備えた流動床反応器
US20200179891A1 (en) Device and method for preparing para-xylene and co-producing light olefins from methanol and/or dimethyl ether and toluene
RU2743989C1 (ru) Устройство с кипящим слоем и способ получения пара-ксилола и совместного получения низших олефинов из метанола и/или диметилового эфира и толуола
US11084765B2 (en) Device and method for preparing para-xylene and co-producing light olefins from methanol and/or dimethyl ether and benzene
CN107428879A (zh) 生物质衍生的化学中间体
CN102464532B (zh) 低碳烯烃的制备方法
CN106854128A (zh) 一种甲苯与甲醇制取对二甲苯的方法
CN1263715C (zh) 制备烷基和烯基取代的芳族化合物的综合工艺
EP3616782A1 (en) Fluidized bed device and method for preparing p-xylene and co-producing low-carbon olefins from methanol and/or dimethyl ether and benzene
CN104109065B (zh) 一种由苯和甲醇烷基化制二甲苯的方法
CN1163460C (zh) 由苯/甲苯与稀丙烯催化蒸馏烷基化的方法和设备
MXPA01003450A (es) Alquilacion de aromaticos en lecho fluido
CN211190110U (zh) 甲基化反应器
CN1986502B (zh) 一种乙烯与甲苯催化分离制备甲基乙苯的方法
CN1939882B (zh) 一种催化干气中乙烯与苯变相催化分离制备乙苯的方法
CN120187685A (zh) 用于利用多个催化剂入口使烃脱氢的方法
CA3246184A1 (en) PROCESSES FOR FORMING LIGHT OLEFINS USING HEAT EXCHANGER SYSTEMS
CN1299796A (zh) 一种烯烃与芳烃反应制取烷基芳烃的方法

Legal Events

Date Code Title Description
C06 Publication
C10 Entry into substantive examination
PB01 Publication
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20050914