KR100637964B1 - 유동상 방향족 알킬화 - Google Patents

유동상 방향족 알킬화 Download PDF

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Publication number
KR100637964B1
KR100637964B1 KR1020017004337A KR20017004337A KR100637964B1 KR 100637964 B1 KR100637964 B1 KR 100637964B1 KR 1020017004337 A KR1020017004337 A KR 1020017004337A KR 20017004337 A KR20017004337 A KR 20017004337A KR 100637964 B1 KR100637964 B1 KR 100637964B1
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South Korea
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fluidized bed
methanol
toluene
aromatic
alkylation
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Korean (ko)
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KR20010083889A (ko
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존슨데이빗리
팅거로버트제라드
웨어로버트아담스
유첵세르게이
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엑손모빌 오일 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020017004337A 1998-10-05 1999-09-27 유동상 방향족 알킬화 Expired - Lifetime KR100637964B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/166,188 US6642426B1 (en) 1998-10-05 1998-10-05 Fluid-bed aromatics alkylation with staged injection of alkylating agents
US09/166,188 1998-10-05

Publications (2)

Publication Number Publication Date
KR20010083889A KR20010083889A (ko) 2001-09-03
KR100637964B1 true KR100637964B1 (ko) 2006-10-23

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KR1020017004337A Expired - Lifetime KR100637964B1 (ko) 1998-10-05 1999-09-27 유동상 방향족 알킬화

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US (1) US6642426B1 (enExample)
EP (1) EP1119532B1 (enExample)
JP (1) JP4607326B2 (enExample)
KR (1) KR100637964B1 (enExample)
CN (1) CN1218913C (enExample)
AT (1) ATE247613T1 (enExample)
AU (1) AU6165499A (enExample)
BR (1) BR9915913B1 (enExample)
CA (1) CA2346431C (enExample)
DE (1) DE69910598T2 (enExample)
ES (1) ES2205882T3 (enExample)
ID (1) ID29191A (enExample)
TW (1) TW505620B (enExample)
WO (1) WO2000020360A1 (enExample)

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US7105713B2 (en) 2004-06-09 2006-09-12 Saudi Basic Industries Corporation Preparation of alkyl-aromatic products
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US8846559B2 (en) 2008-11-03 2014-09-30 Saudi Basic Industries Corporation Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing
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US8399727B2 (en) * 2009-10-21 2013-03-19 Exxonmobil Chemical Patents Inc. Production of para-xylene by the methylation of benzene and/or toluene
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CN102372582A (zh) * 2010-08-23 2012-03-14 中国石油化工股份有限公司 甲苯甲基化的流化催化方法
CN102372587A (zh) * 2010-08-23 2012-03-14 中国石油化工股份有限公司 芳烃甲基化的流化床方法
CN102372585B (zh) * 2010-08-23 2015-12-09 中国石油化工股份有限公司 芳烃烷基化制对二甲苯的流化床方法
CN102464559A (zh) * 2010-11-17 2012-05-23 中国石油化工股份有限公司 用于生产烷基化芳烃的方法
CN102464557B (zh) * 2010-11-17 2014-03-26 中国石油化工股份有限公司 由含氧化合物和甲苯制备二甲苯的方法
CN103596907B (zh) * 2011-06-10 2016-04-27 埃克森美孚化学专利公司 对二甲苯的生产
CN103619786B (zh) * 2011-07-11 2016-06-01 埃克森美孚化学专利公司 苯和/或甲苯与甲醇的烷基化
TWI495511B (zh) * 2011-07-27 2015-08-11 Exxonmobil Chem Patents Inc 具有分階擋板的流體床反應器
TWI623511B (zh) * 2011-12-08 2018-05-11 Ｇｔｃ科技美國有限責任公司 藉由將芳香族化合物甲基化以製造二甲苯的方法
US9278342B2 (en) 2012-07-02 2016-03-08 Saudi Basic Industries Corporation Method of modifying a phosphorus-containing zeolite catalyst
US9802876B2 (en) 2012-07-12 2017-10-31 China Petroleum & Chemical Corporation Alkylating process for alkyl benzenes
CN103664485B (zh) * 2012-09-05 2016-05-18 中国石油化工股份有限公司 甲苯、甲醇侧链烷基化生产乙苯、苯乙烯的方法
CN103772129A (zh) * 2012-10-25 2014-05-07 中国石油化工股份有限公司 甲苯甲基化生产混合二甲苯的方法
US9353024B2 (en) 2013-02-06 2016-05-31 Exxonmobil Chemical Patents Inc. Selective hydrogenation of styrene to ethylbenzene
WO2015094698A1 (en) 2013-12-20 2015-06-25 Exxonmobil Chemical Patents Inc. Process for converting oxygenates to aromatic hydrocarbons
US9469579B2 (en) 2014-06-30 2016-10-18 Exxonmobil Chemical Patents Inc. Process for the production of xylenes
WO2016003613A2 (en) 2014-06-30 2016-01-07 Exxonmobil Chemical Patents Inc. Process for the production of xylenes
CN106458788B (zh) 2014-06-30 2019-11-26 埃克森美孚化学专利公司 制备二甲苯的方法
WO2016003612A1 (en) 2014-06-30 2016-01-07 Exxonmobil Chemical Patents Inc. Processes for the production of para-xylene
US9802877B2 (en) 2014-08-29 2017-10-31 Exxonmobil Chemical Patents Inc. Process of producing para-xylene by alkylation of benzene and/or toluene including treatment of an alkylating agent to remove metal salts
CN106433761B (zh) * 2015-08-06 2018-07-13 中国石油天然气股份有限公司 异丁烷与丁烯烷基化合成烷基化油的多级沸腾床催化工艺
WO2017052860A1 (en) 2015-09-25 2017-03-30 Exxonmobil Chemical Patents Inc. Hydrocarbon dehydrocyclization
US10071938B2 (en) 2015-09-25 2018-09-11 Exxonmobil Chemical Patents Inc. Hydrocarbon dehydrocyclization
WO2017146914A1 (en) 2016-02-26 2017-08-31 Exxonmobil Chemical Patents Inc. Process for recovering para-xylene
KR102231925B1 (ko) 2016-03-25 2021-03-25 엑손모빌 케미칼 패턴츠 인코포레이티드 파라-크실렌의 제조 방법 및 촉매
WO2018057125A2 (en) 2016-09-22 2018-03-29 Exxonmobil Chemical Patents Inc. Use of light gas by-products in the production of paraxylene by the methylation of toluene and/or benzene
US10961168B2 (en) * 2016-09-22 2021-03-30 Exxonmobil Chemical Patents Inc. Use of light gas by-products in the production of paraxylene by the methylation of toluene and or benzene
KR102235872B1 (ko) 2016-10-06 2021-04-06 엑손모빌 케미칼 패턴츠 인코포레이티드 방향족 탄화수소의 메틸화 방법
KR102235874B1 (ko) 2016-10-06 2021-04-06 엑손모빌 케미칼 패턴츠 인코포레이티드 벤젠 및/또는 톨루엔의 메틸화에 의해 파라크실렌을 생성시키기 위한 촉매의 선택화 방법
KR20190040081A (ko) 2016-10-06 2019-04-16 엑손모빌 케미칼 패턴츠 인코포레이티드 벤젠 및/또는 톨루엔의 메틸화에 의한 파라크실렌의 제조 방법
US11208365B2 (en) 2016-12-20 2021-12-28 Uop Llc Processes and apparatuses for methylation of aromatics in an aromatics complex
US11673849B2 (en) 2016-12-21 2023-06-13 Exxonmobil Chemical Patents Inc. Process for selectivating catalyst for producing paraxylene by methylation of benzene and/or toluene
CN108786672B (zh) * 2017-04-27 2021-01-26 中国科学院大连化学物理研究所 甲醇和/或二甲醚与苯制对二甲苯联产低碳烯烃的方法
CN108794291B (zh) * 2017-04-27 2020-11-27 中国科学院大连化学物理研究所 甲醇和/或二甲醚与甲苯制对二甲苯联产低碳烯烃的流化床装置及方法
CN108786671B (zh) 2017-04-27 2021-04-23 中国科学院大连化学物理研究所 甲醇和/或二甲醚与苯制对二甲苯联产低碳烯烃的流化床装置及方法
CN108794294B (zh) * 2017-04-27 2020-12-11 中国科学院大连化学物理研究所 流化床气体分布器、应用其的反应器及生产对二甲苯联产低碳烯烃的方法
CN108786670B (zh) * 2017-04-27 2021-01-26 中国科学院大连化学物理研究所 甲醇和/或二甲醚与甲苯制对二甲苯联产低碳烯烃的方法
CN108786669B (zh) * 2017-04-27 2021-01-12 中国科学院大连化学物理研究所 流化床气体分布器、应用其的反应器及生产对二甲苯联产低碳烯烃的方法
WO2019108361A1 (en) 2017-11-30 2019-06-06 Exxonmobil Chemical Patents Inc Systems and methods for aromatic alkylation
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US11130719B2 (en) * 2017-12-05 2021-09-28 Uop Llc Processes and apparatuses for methylation of aromatics in an aromatics complex
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CN108441257B (zh) * 2018-03-20 2020-10-13 中国石油大学(华东) 一种重油裂解轻质石油烃原位烷基化的方法
US11130720B2 (en) 2018-03-23 2021-09-28 Uop Llc Processes for methylation of aromatics in an aromatics complex
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WO2023244389A1 (en) 2022-06-14 2023-12-21 Exxonmobil Chemical Patents Inc. Production of p-xylene by liquid-phase isomerization in the presence of c9+ aromatic hydrocarbons and separation thereof

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Also Published As

Publication number Publication date
BR9915913A (pt) 2001-10-16
KR20010083889A (ko) 2001-09-03
ATE247613T1 (de) 2003-09-15
US6642426B1 (en) 2003-11-04
EP1119532A4 (en) 2002-08-14
CN1326430A (zh) 2001-12-12
EP1119532A1 (en) 2001-08-01
EP1119532B1 (en) 2003-08-20
DE69910598D1 (de) 2003-09-25
JP2002526513A (ja) 2002-08-20
CN1218913C (zh) 2005-09-14
ES2205882T3 (es) 2004-05-01
JP4607326B2 (ja) 2011-01-05
DE69910598T2 (de) 2004-06-24
CA2346431A1 (en) 2000-04-13
BR9915913B1 (pt) 2011-01-25
TW505620B (en) 2002-10-11
AU6165499A (en) 2000-04-26
CA2346431C (en) 2009-02-03
WO2000020360A1 (en) 2000-04-13
ID29191A (id) 2001-08-09

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