JP4607326B2 - 流動床芳香族物質アルキル化 - Google Patents

流動床芳香族物質アルキル化 Download PDF

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Publication number
JP4607326B2
JP4607326B2 JP2000574481A JP2000574481A JP4607326B2 JP 4607326 B2 JP4607326 B2 JP 4607326B2 JP 2000574481 A JP2000574481 A JP 2000574481A JP 2000574481 A JP2000574481 A JP 2000574481A JP 4607326 B2 JP4607326 B2 JP 4607326B2
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Prior art keywords
fluidized bed
alkylating agent
reaction zone
reactor
methanol
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Japanese (ja)
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JP2002526513A (ja
JP2002526513A5 (enExample
Inventor
ジョンソン、デビッド・リー
ティンガー、ロバート・ジェラード
ウェア、ロバート・アダムス
ユーチャック、サージェイ
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ExxonMobil Oil Corp
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Mobil Oil AS
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64Addition to a carbon atom of a six-membered aromatic ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP2000574481A 1998-10-05 1999-09-27 流動床芳香族物質アルキル化 Expired - Lifetime JP4607326B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/166,188 US6642426B1 (en) 1998-10-05 1998-10-05 Fluid-bed aromatics alkylation with staged injection of alkylating agents
US09/166,188 1998-10-05
PCT/US1999/022414 WO2000020360A1 (en) 1998-10-05 1999-09-27 Fluid-bed aromatics alkylation

Publications (3)

Publication Number Publication Date
JP2002526513A JP2002526513A (ja) 2002-08-20
JP2002526513A5 JP2002526513A5 (enExample) 2006-11-16
JP4607326B2 true JP4607326B2 (ja) 2011-01-05

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JP2000574481A Expired - Lifetime JP4607326B2 (ja) 1998-10-05 1999-09-27 流動床芳香族物質アルキル化

Country Status (14)

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US (1) US6642426B1 (enExample)
EP (1) EP1119532B1 (enExample)
JP (1) JP4607326B2 (enExample)
KR (1) KR100637964B1 (enExample)
CN (1) CN1218913C (enExample)
AT (1) ATE247613T1 (enExample)
AU (1) AU6165499A (enExample)
BR (1) BR9915913B1 (enExample)
CA (1) CA2346431C (enExample)
DE (1) DE69910598T2 (enExample)
ES (1) ES2205882T3 (enExample)
ID (1) ID29191A (enExample)
TW (1) TW505620B (enExample)
WO (1) WO2000020360A1 (enExample)

Families Citing this family (74)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7232936B1 (en) 2000-02-22 2007-06-19 Exxonmobil Chemical Patents Inc. Conversion of oxygenate to olefins with staged injection of oxygenate
US7226771B2 (en) 2002-04-19 2007-06-05 Diversa Corporation Phospholipases, nucleic acids encoding them and methods for making and using them
WO2004000974A1 (en) * 2002-06-19 2003-12-31 Exxonmobil Chemical Patents Inc. Manufacture of xylenes from reformate
CA2538520C (en) 2003-07-24 2015-02-10 The Queen's Medical Center Preparation and use of alkylating agents
US7084318B2 (en) 2003-08-01 2006-08-01 Saudi Basic Industries Corporation Toluene methylation process
US7060864B2 (en) 2003-09-30 2006-06-13 Saudi Basic Industries Corporation Toluene methylation process
US7060644B2 (en) 2004-01-08 2006-06-13 Saudi Basic Industries Corporation Aromatic alkylation catalyst and method
US6943131B1 (en) 2004-03-02 2005-09-13 Saudi Basic Industries Corporation Selective zeolite catalyst modification
US7285511B2 (en) 2004-04-23 2007-10-23 Saudi Basic Industries Corporation Method of modifying zeolite catalyst
US7399727B2 (en) 2004-04-23 2008-07-15 Saudi Basic Industries Corporation Zeolite catalyst and method
US7304198B2 (en) * 2004-05-14 2007-12-04 Battelle Memorial Institute Staged alkylation in microchannels
US7105713B2 (en) 2004-06-09 2006-09-12 Saudi Basic Industries Corporation Preparation of alkyl-aromatic products
DE102004041011A1 (de) 2004-08-24 2006-03-02 Martin Schleske Resonanzplatte in Faserverbund-Bauweise für akustische Musikinstrumente
US7304194B2 (en) 2005-05-05 2007-12-04 Saudi Basic Industries Corporation Hydrothermal treatment of phosphorus-modified zeolite catalysts
KR100598988B1 (ko) * 2005-05-18 2006-07-12 주식회사 하이닉스반도체 오버레이 버니어 및 이를 이용한 반도체소자의 제조방법
US7368410B2 (en) 2005-08-03 2008-05-06 Saudi Basic Industries Corporation Zeolite catalyst and method of preparing and use of zeolite catalyst
EP2297310A2 (en) 2008-05-23 2011-03-23 E. I. du Pont de Nemours and Company Novel dgat genes for increased seed storage lipid production and altered fatty acid profiles in oilseed plants
US8846559B2 (en) 2008-11-03 2014-09-30 Saudi Basic Industries Corporation Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing
US8252967B2 (en) * 2009-04-14 2012-08-28 Exxonmobil Chemical Patents Inc. Process for the purification of paraxylene
US8558046B2 (en) * 2009-05-28 2013-10-15 Saudi Basic Industries Corporation Aromatic alkylation process
US8062987B2 (en) 2009-10-05 2011-11-22 Saudi Basic Industries Corporation Phosphorus-containing zeolite catalysts and their method of preparation
US8399727B2 (en) * 2009-10-21 2013-03-19 Exxonmobil Chemical Patents Inc. Production of para-xylene by the methylation of benzene and/or toluene
US8344197B2 (en) * 2009-10-21 2013-01-01 Exxonmobil Chemical Patents Inc. Production of para-xylene by the methylation of benzene and/or toluene
CN102372582A (zh) * 2010-08-23 2012-03-14 中国石油化工股份有限公司 甲苯甲基化的流化催化方法
CN102372587A (zh) * 2010-08-23 2012-03-14 中国石油化工股份有限公司 芳烃甲基化的流化床方法
CN102372585B (zh) * 2010-08-23 2015-12-09 中国石油化工股份有限公司 芳烃烷基化制对二甲苯的流化床方法
CN102464559A (zh) * 2010-11-17 2012-05-23 中国石油化工股份有限公司 用于生产烷基化芳烃的方法
CN102464557B (zh) * 2010-11-17 2014-03-26 中国石油化工股份有限公司 由含氧化合物和甲苯制备二甲苯的方法
CN103596907B (zh) * 2011-06-10 2016-04-27 埃克森美孚化学专利公司 对二甲苯的生产
CN103619786B (zh) * 2011-07-11 2016-06-01 埃克森美孚化学专利公司 苯和/或甲苯与甲醇的烷基化
TWI495511B (zh) * 2011-07-27 2015-08-11 Exxonmobil Chem Patents Inc 具有分階擋板的流體床反應器
TWI623511B (zh) * 2011-12-08 2018-05-11 Gtc科技美國有限責任公司 藉由將芳香族化合物甲基化以製造二甲苯的方法
US9278342B2 (en) 2012-07-02 2016-03-08 Saudi Basic Industries Corporation Method of modifying a phosphorus-containing zeolite catalyst
US9802876B2 (en) 2012-07-12 2017-10-31 China Petroleum & Chemical Corporation Alkylating process for alkyl benzenes
CN103664485B (zh) * 2012-09-05 2016-05-18 中国石油化工股份有限公司 甲苯、甲醇侧链烷基化生产乙苯、苯乙烯的方法
CN103772129A (zh) * 2012-10-25 2014-05-07 中国石油化工股份有限公司 甲苯甲基化生产混合二甲苯的方法
US9353024B2 (en) 2013-02-06 2016-05-31 Exxonmobil Chemical Patents Inc. Selective hydrogenation of styrene to ethylbenzene
WO2015094698A1 (en) 2013-12-20 2015-06-25 Exxonmobil Chemical Patents Inc. Process for converting oxygenates to aromatic hydrocarbons
US9469579B2 (en) 2014-06-30 2016-10-18 Exxonmobil Chemical Patents Inc. Process for the production of xylenes
WO2016003613A2 (en) 2014-06-30 2016-01-07 Exxonmobil Chemical Patents Inc. Process for the production of xylenes
CN106458788B (zh) 2014-06-30 2019-11-26 埃克森美孚化学专利公司 制备二甲苯的方法
WO2016003612A1 (en) 2014-06-30 2016-01-07 Exxonmobil Chemical Patents Inc. Processes for the production of para-xylene
US9802877B2 (en) 2014-08-29 2017-10-31 Exxonmobil Chemical Patents Inc. Process of producing para-xylene by alkylation of benzene and/or toluene including treatment of an alkylating agent to remove metal salts
CN106433761B (zh) * 2015-08-06 2018-07-13 中国石油天然气股份有限公司 异丁烷与丁烯烷基化合成烷基化油的多级沸腾床催化工艺
WO2017052860A1 (en) 2015-09-25 2017-03-30 Exxonmobil Chemical Patents Inc. Hydrocarbon dehydrocyclization
US10071938B2 (en) 2015-09-25 2018-09-11 Exxonmobil Chemical Patents Inc. Hydrocarbon dehydrocyclization
WO2017146914A1 (en) 2016-02-26 2017-08-31 Exxonmobil Chemical Patents Inc. Process for recovering para-xylene
KR102231925B1 (ko) 2016-03-25 2021-03-25 엑손모빌 케미칼 패턴츠 인코포레이티드 파라-크실렌의 제조 방법 및 촉매
WO2018057125A2 (en) 2016-09-22 2018-03-29 Exxonmobil Chemical Patents Inc. Use of light gas by-products in the production of paraxylene by the methylation of toluene and/or benzene
US10961168B2 (en) * 2016-09-22 2021-03-30 Exxonmobil Chemical Patents Inc. Use of light gas by-products in the production of paraxylene by the methylation of toluene and or benzene
KR102235872B1 (ko) 2016-10-06 2021-04-06 엑손모빌 케미칼 패턴츠 인코포레이티드 방향족 탄화수소의 메틸화 방법
KR102235874B1 (ko) 2016-10-06 2021-04-06 엑손모빌 케미칼 패턴츠 인코포레이티드 벤젠 및/또는 톨루엔의 메틸화에 의해 파라크실렌을 생성시키기 위한 촉매의 선택화 방법
KR20190040081A (ko) 2016-10-06 2019-04-16 엑손모빌 케미칼 패턴츠 인코포레이티드 벤젠 및/또는 톨루엔의 메틸화에 의한 파라크실렌의 제조 방법
US11208365B2 (en) 2016-12-20 2021-12-28 Uop Llc Processes and apparatuses for methylation of aromatics in an aromatics complex
US11673849B2 (en) 2016-12-21 2023-06-13 Exxonmobil Chemical Patents Inc. Process for selectivating catalyst for producing paraxylene by methylation of benzene and/or toluene
CN108786672B (zh) * 2017-04-27 2021-01-26 中国科学院大连化学物理研究所 甲醇和/或二甲醚与苯制对二甲苯联产低碳烯烃的方法
CN108794291B (zh) * 2017-04-27 2020-11-27 中国科学院大连化学物理研究所 甲醇和/或二甲醚与甲苯制对二甲苯联产低碳烯烃的流化床装置及方法
CN108786671B (zh) 2017-04-27 2021-04-23 中国科学院大连化学物理研究所 甲醇和/或二甲醚与苯制对二甲苯联产低碳烯烃的流化床装置及方法
CN108794294B (zh) * 2017-04-27 2020-12-11 中国科学院大连化学物理研究所 流化床气体分布器、应用其的反应器及生产对二甲苯联产低碳烯烃的方法
CN108786670B (zh) * 2017-04-27 2021-01-26 中国科学院大连化学物理研究所 甲醇和/或二甲醚与甲苯制对二甲苯联产低碳烯烃的方法
CN108786669B (zh) * 2017-04-27 2021-01-12 中国科学院大连化学物理研究所 流化床气体分布器、应用其的反应器及生产对二甲苯联产低碳烯烃的方法
WO2019108361A1 (en) 2017-11-30 2019-06-06 Exxonmobil Chemical Patents Inc Systems and methods for aromatic alkylation
US11377399B2 (en) 2017-12-05 2022-07-05 Exxonmobil Chemical Patents Inc. Xylene production processes and systems
US11130719B2 (en) * 2017-12-05 2021-09-28 Uop Llc Processes and apparatuses for methylation of aromatics in an aromatics complex
US10556214B2 (en) 2017-12-20 2020-02-11 Uop Llc Apparatuses for mixing of staged methanol injection
CN111511705A (zh) 2017-12-22 2020-08-07 埃克森美孚化学专利公司 通过苯和/或甲苯的甲基化制备对二甲苯的催化剂
CN108441257B (zh) * 2018-03-20 2020-10-13 中国石油大学(华东) 一种重油裂解轻质石油烃原位烷基化的方法
US11130720B2 (en) 2018-03-23 2021-09-28 Uop Llc Processes for methylation of aromatics in an aromatics complex
US11078133B2 (en) * 2019-12-06 2021-08-03 Uop Llc Aromatic alkylation process
CA3184956A1 (en) 2020-07-31 2022-02-03 Robert G. Tinger Processes for producing high-octane-number fuel component
WO2023044278A1 (en) 2021-09-16 2023-03-23 Exxonmobil Chemical Patents Inc. Xylene isomer separation processes
WO2023204947A1 (en) 2022-04-19 2023-10-26 Exxonmobil Chemical Patents Inc. Processes for oxidizing p-xylene or p-xylene-containing mixtures
WO2023244394A1 (en) 2022-06-14 2023-12-21 Exxonmobil Chemical Patents Inc. Production of p-xylene by liquid-phase isomerization and separation thereof
WO2023244389A1 (en) 2022-06-14 2023-12-21 Exxonmobil Chemical Patents Inc. Production of p-xylene by liquid-phase isomerization in the presence of c9+ aromatic hydrocarbons and separation thereof

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4924921B1 (enExample) * 1970-06-27 1974-06-26
US3751504A (en) 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
US4049738A (en) * 1976-07-12 1977-09-20 Mobil Oil Corporation Selective production of para-xylene
JPS5726627A (en) 1980-07-25 1982-02-12 Teijin Yuka Kk Preparation of p-xylene
JPS5835128A (ja) * 1981-08-27 1983-03-01 Teijin Yuka Kk p−キシレンの改良製造法
US4761513A (en) 1987-07-01 1988-08-02 Uop Inc. Temperature control for aromatic alkylation process
DE3868194D1 (de) * 1987-09-02 1992-03-12 Mobil Oil Corp Verfahren zur transalkylierung von (polyalkyl)aromatischen kohlenwasserstoffen.
US5198595A (en) * 1987-11-23 1993-03-30 The Dow Chemical Company Alkylation of aromatic compounds
US4891458A (en) * 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
US4992607A (en) * 1989-03-20 1991-02-12 Mobil Oil Corporation Petroleum refinery process and apparatus for the production of alkyl aromatic hydrocarbons from fuel gas and catalytic reformate
US5120890A (en) 1990-12-31 1992-06-09 Uop Process for reducing benzene content in gasoline
DE69115056T2 (de) * 1991-06-21 1996-04-18 Dow Benelux Verfahren zur Alkylierung von aromatischen Verbindungen.
EP0760025B1 (en) * 1994-05-16 2002-08-28 Honeywell International, Inc. Filled cut-resistant fiber
CN1043036C (zh) * 1994-05-24 1999-04-21 中国石油化工总公司 芳烃烷基化方法及其所用液固循环流化床设备
US5600048A (en) * 1994-12-27 1997-02-04 Mobil Oil Corporation Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation
US5660048A (en) * 1996-02-16 1997-08-26 Laroche Industries, Inc. Air conditioning system for cooling warm moisture-laden air
JPH10298117A (ja) * 1997-04-23 1998-11-10 Mitsubishi Heavy Ind Ltd 芳香族炭化水素の選択的アルキル化法

Also Published As

Publication number Publication date
BR9915913A (pt) 2001-10-16
KR20010083889A (ko) 2001-09-03
ATE247613T1 (de) 2003-09-15
US6642426B1 (en) 2003-11-04
KR100637964B1 (ko) 2006-10-23
EP1119532A4 (en) 2002-08-14
CN1326430A (zh) 2001-12-12
EP1119532A1 (en) 2001-08-01
EP1119532B1 (en) 2003-08-20
DE69910598D1 (de) 2003-09-25
JP2002526513A (ja) 2002-08-20
CN1218913C (zh) 2005-09-14
ES2205882T3 (es) 2004-05-01
DE69910598T2 (de) 2004-06-24
CA2346431A1 (en) 2000-04-13
BR9915913B1 (pt) 2011-01-25
TW505620B (en) 2002-10-11
AU6165499A (en) 2000-04-26
CA2346431C (en) 2009-02-03
WO2000020360A1 (en) 2000-04-13
ID29191A (id) 2001-08-09

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