CN118938597A - 化学增幅正型抗蚀剂组成物及抗蚀剂图案形成方法 - Google Patents

化学增幅正型抗蚀剂组成物及抗蚀剂图案形成方法 Download PDF

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Publication number
CN118938597A
CN118938597A CN202410560301.3A CN202410560301A CN118938597A CN 118938597 A CN118938597 A CN 118938597A CN 202410560301 A CN202410560301 A CN 202410560301A CN 118938597 A CN118938597 A CN 118938597A
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Chinese (zh)
Inventor
增永惠一
渡边聪
福岛将大
小竹正晃
松泽雄太
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Shin Etsu Chemical Co Ltd
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Shin Etsu Chemical Co Ltd
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/0045Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/20Exposure; Apparatus therefor
    • G03F7/2002Exposure; Apparatus therefor with visible light or UV light, through an original having an opaque pattern on a transparent support, e.g. film printing, projection printing; by reflection of visible or UV light from an original such as a printed image
    • G03F7/2004Exposure; Apparatus therefor with visible light or UV light, through an original having an opaque pattern on a transparent support, e.g. film printing, projection printing; by reflection of visible or UV light from an original such as a printed image characterised by the use of a particular light source, e.g. fluorescent lamps or deep UV light
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
    • G03F1/66Containers specially adapted for masks, mask blanks or pellicles; Preparation thereof
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/0046Photosensitive materials with perfluoro compounds, e.g. for dry lithography
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/039Macromolecular compounds which are photodegradable, e.g. positive electron resists
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/039Macromolecular compounds which are photodegradable, e.g. positive electron resists
    • G03F7/0392Macromolecular compounds which are photodegradable, e.g. positive electron resists the macromolecular compound being present in a chemically amplified positive photoresist composition
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/039Macromolecular compounds which are photodegradable, e.g. positive electron resists
    • G03F7/0392Macromolecular compounds which are photodegradable, e.g. positive electron resists the macromolecular compound being present in a chemically amplified positive photoresist composition
    • G03F7/0395Macromolecular compounds which are photodegradable, e.g. positive electron resists the macromolecular compound being present in a chemically amplified positive photoresist composition the macromolecular compound having a backbone with alicyclic moieties
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/039Macromolecular compounds which are photodegradable, e.g. positive electron resists
    • G03F7/0392Macromolecular compounds which are photodegradable, e.g. positive electron resists the macromolecular compound being present in a chemically amplified positive photoresist composition
    • G03F7/0397Macromolecular compounds which are photodegradable, e.g. positive electron resists the macromolecular compound being present in a chemically amplified positive photoresist composition the macromolecular compound having an alicyclic moiety in a side chain
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/20Exposure; Apparatus therefor
    • G03F7/2051Exposure without an original mask, e.g. using a programmed deflection of a point source, by scanning, by drawing with a light beam, using an addressed light or corpuscular source
    • G03F7/2059Exposure without an original mask, e.g. using a programmed deflection of a point source, by scanning, by drawing with a light beam, using an addressed light or corpuscular source using a scanning corpuscular radiation beam, e.g. an electron beam
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26Processing photosensitive materials; Apparatus therefor
    • G03F7/30Imagewise removal using liquid means
    • G03F7/32Liquid compositions therefor, e.g. developers
    • G03F7/322Aqueous alkaline compositions

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Materials For Photolithography (AREA)
  • Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN202410560301.3A 2023-05-10 2024-05-08 化学增幅正型抗蚀剂组成物及抗蚀剂图案形成方法 Pending CN118938597A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2023-077813 2023-05-10
JP2023077813A JP2024162373A (ja) 2023-05-10 2023-05-10 化学増幅ポジ型レジスト組成物及びレジストパターン形成方法

Publications (1)

Publication Number Publication Date
CN118938597A true CN118938597A (zh) 2024-11-12

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Country Status (6)

Country Link
US (1) US20240402599A1 (https=)
EP (1) EP4462188A3 (https=)
JP (1) JP2024162373A (https=)
KR (1) KR102824420B1 (https=)
CN (1) CN118938597A (https=)
TW (1) TWI892627B (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN121226211A (zh) * 2025-02-07 2025-12-30 信越化学工业株式会社 锍盐、化学增幅抗蚀剂组成物及图案形成方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2023133147A (ja) * 2022-03-11 2023-09-22 信越化学工業株式会社 化学増幅レジスト材料及びパターン形成方法

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3955384B2 (ja) 1998-04-08 2007-08-08 Azエレクトロニックマテリアルズ株式会社 化学増幅型レジスト組成物
JPH11327143A (ja) 1998-05-13 1999-11-26 Fujitsu Ltd レジスト及びレジストパターンの形成方法
TWI224713B (en) 2000-01-27 2004-12-01 Fuji Photo Film Co Ltd Positive photoresist composition
JP4231622B2 (ja) 2000-01-27 2009-03-04 富士フイルム株式会社 ポジ型レジスト組成物
JP4226803B2 (ja) 2000-08-08 2009-02-18 富士フイルム株式会社 ポジ型感光性組成物
EP1179750B1 (en) 2000-08-08 2012-07-25 FUJIFILM Corporation Positive photosensitive composition and method for producing a precision integrated circuit element using the same
JP4025162B2 (ja) 2002-09-25 2007-12-19 信越化学工業株式会社 高分子化合物及びポジ型レジスト材料並びにこれを用いたパターン形成方法
JP4816921B2 (ja) 2005-04-06 2011-11-16 信越化学工業株式会社 新規スルホン酸塩及びその誘導体、光酸発生剤並びにこれを用いたレジスト材料及びパターン形成方法
JP4716037B2 (ja) 2006-04-11 2011-07-06 信越化学工業株式会社 ケイ素含有膜形成用組成物、ケイ素含有膜、ケイ素含有膜形成基板及びこれを用いたパターン形成方法
JP2008026500A (ja) 2006-07-20 2008-02-07 Dainippon Printing Co Ltd 高ドライエッチング耐性ポリマー層を付加したフォトマスクブランクスおよびそれを用いたフォトマスクの製造方法
JP5083528B2 (ja) 2006-09-28 2012-11-28 信越化学工業株式会社 新規光酸発生剤並びにこれを用いたレジスト材料及びパターン形成方法
KR101116963B1 (ko) 2006-10-04 2012-03-14 신에쓰 가가꾸 고교 가부시끼가이샤 고분자 화합물, 레지스트 재료, 및 패턴 형성 방법
JP4858714B2 (ja) 2006-10-04 2012-01-18 信越化学工業株式会社 高分子化合物、レジスト材料、及びパターン形成方法
JP2009053518A (ja) 2007-08-28 2009-03-12 Fujifilm Corp 電子線、x線またはeuv用レジスト組成物及び該レジスト組成物を用いたパターン形成方法
JP5201363B2 (ja) 2008-08-28 2013-06-05 信越化学工業株式会社 重合性アニオンを有するスルホニウム塩及び高分子化合物、レジスト材料及びパターン形成方法
JP5544098B2 (ja) 2008-09-26 2014-07-09 富士フイルム株式会社 感活性光線性または感放射線性樹脂組成物、及び該感光性組成物を用いたパターン形成方法
TWI400226B (zh) 2008-10-17 2013-07-01 Shinetsu Chemical Co 具有聚合性陰離子之鹽及高分子化合物、光阻劑材料及圖案形成方法
JP4813537B2 (ja) 2008-11-07 2011-11-09 信越化学工業株式会社 熱酸発生剤を含有するレジスト下層材料、レジスト下層膜形成基板及びパターン形成方法
JP5368270B2 (ja) 2009-02-19 2013-12-18 信越化学工業株式会社 新規スルホン酸塩及びその誘導体、光酸発生剤並びにこれを用いたレジスト材料及びパターン形成方法
JP5381905B2 (ja) 2009-06-16 2014-01-08 信越化学工業株式会社 化学増幅ポジ型フォトレジスト材料及びレジストパターン形成方法
KR101841000B1 (ko) 2010-07-28 2018-03-22 스미또모 가가꾸 가부시키가이샤 포토레지스트 조성물
JP5491450B2 (ja) 2011-05-30 2014-05-14 信越化学工業株式会社 高分子化合物、化学増幅レジスト材料、該化学増幅レジスト材料を用いたパターン形成方法。
JP5411893B2 (ja) 2011-05-30 2014-02-12 信越化学工業株式会社 スルホニウム塩、高分子化合物、該高分子化合物を用いた化学増幅型レジスト組成物及びレジストパターン形成方法
JP5852851B2 (ja) 2011-11-09 2016-02-03 富士フイルム株式会社 パターン形成方法、感活性光線性又は感放射線性樹脂組成物、感活性光線性又は感放射線性膜、及び、電子デバイスの製造方法
JP6212873B2 (ja) * 2012-02-23 2017-10-18 住友化学株式会社 レジスト組成物及び塩
JP5812030B2 (ja) 2013-03-13 2015-11-11 信越化学工業株式会社 スルホニウム塩及び高分子化合物、レジスト材料及びパターン形成方法
JP6217561B2 (ja) 2014-08-21 2017-10-25 信越化学工業株式会社 新規オニウム塩化合物及びレジスト組成物並びにパターン形成方法
JP6323302B2 (ja) * 2014-11-07 2018-05-16 信越化学工業株式会社 新規オニウム塩化合物及びそれを用いたレジスト組成物並びにパターン形成方法
JP6515831B2 (ja) * 2015-02-25 2019-05-22 信越化学工業株式会社 化学増幅ポジ型レジスト組成物及びレジストパターン形成方法
JP6512049B2 (ja) * 2015-09-15 2019-05-15 信越化学工業株式会社 レジスト材料及びパターン形成方法
JP6561731B2 (ja) * 2015-09-29 2019-08-21 Jsr株式会社 感放射線性樹脂組成物、レジストパターン形成方法、酸拡散制御剤及び化合物
WO2019087626A1 (ja) 2017-10-31 2019-05-09 東洋合成工業株式会社 光酸発生剤、レジスト組成物及び、該レジスト組成物を用いたデバイスの製造方法
JP6833657B2 (ja) 2017-11-07 2021-02-24 東京エレクトロン株式会社 基板をプラズマエッチングする方法
JP6874738B2 (ja) 2018-05-25 2021-05-19 信越化学工業株式会社 化学増幅ネガ型レジスト組成物及びレジストパターン形成方法
JP7318338B2 (ja) * 2019-06-17 2023-08-01 Jsr株式会社 感放射線性樹脂組成物、レジストパターン形成方法、酸拡散制御剤及び化合物
JP7318565B2 (ja) 2020-03-03 2023-08-01 信越化学工業株式会社 反射型マスクブランクの製造方法
JP7656485B2 (ja) * 2021-05-13 2025-04-03 信越化学工業株式会社 高分子化合物の製造方法
JP7644050B2 (ja) * 2021-06-10 2025-03-11 信越化学工業株式会社 ポジ型レジスト材料及びパターン形成方法
JP7739928B2 (ja) * 2021-10-15 2025-09-17 信越化学工業株式会社 光酸発生剤、化学増幅レジスト組成物及びパターン形成方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN121226211A (zh) * 2025-02-07 2025-12-30 信越化学工业株式会社 锍盐、化学增幅抗蚀剂组成物及图案形成方法

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EP4462188A2 (en) 2024-11-13
TW202502709A (zh) 2025-01-16
EP4462188A3 (en) 2024-12-04
US20240402599A1 (en) 2024-12-05
TWI892627B (zh) 2025-08-01
KR20240163530A (ko) 2024-11-19
JP2024162373A (ja) 2024-11-21
KR102824420B1 (ko) 2025-06-23

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