CN1178949C - 作为聚合催化剂的环戊二烯基过渡金属配合物 - Google Patents

作为聚合催化剂的环戊二烯基过渡金属配合物 Download PDF

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Publication number
CN1178949C
CN1178949C CNB998044105A CN99804410A CN1178949C CN 1178949 C CN1178949 C CN 1178949C CN B998044105 A CNB998044105 A CN B998044105A CN 99804410 A CN99804410 A CN 99804410A CN 1178949 C CN1178949 C CN 1178949C
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CN
China
Prior art keywords
title complex
group
alkyl
independently
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB998044105A
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English (en)
Chinese (zh)
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CN1302303A (zh
Inventor
Rt
R·T·李
L·G·麦库罗
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Westlake Longview Corp
Original Assignee
Eastman Chemical Co
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Publication date
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Publication of CN1302303A publication Critical patent/CN1302303A/zh
Application granted granted Critical
Publication of CN1178949C publication Critical patent/CN1178949C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CNB998044105A 1998-04-02 1999-03-18 作为聚合催化剂的环戊二烯基过渡金属配合物 Expired - Fee Related CN1178949C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/053,924 US6100414A (en) 1998-04-02 1998-04-02 Cyclopentadienyl transition metal compounds useful as polymerization catalysts
US09/053,924 1998-04-02

Publications (2)

Publication Number Publication Date
CN1302303A CN1302303A (zh) 2001-07-04
CN1178949C true CN1178949C (zh) 2004-12-08

Family

ID=21987486

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB998044105A Expired - Fee Related CN1178949C (zh) 1998-04-02 1999-03-18 作为聚合催化剂的环戊二烯基过渡金属配合物

Country Status (7)

Country Link
US (1) US6100414A (https=)
EP (1) EP1066302B1 (https=)
JP (1) JP2002510700A (https=)
CN (1) CN1178949C (https=)
BR (1) BR9909354A (https=)
DE (1) DE69902452T2 (https=)
WO (1) WO1999051615A1 (https=)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6706827B1 (en) 1998-06-08 2004-03-16 Samsung Atofina Co. Ltd. Metallocene catalysts for olefin or styrene polymerization and polymerization method using the metallocene catalysts
KR100287955B1 (ko) * 1998-06-08 2001-05-02 유현식 올레핀계 또는 스티렌계 중합용 신규 메탈로센 촉매 및 이를 이용한 중합방법
KR100288272B1 (ko) * 1998-10-13 2001-05-02 유현식 올레핀 중합용 신규 메탈로센 촉매 및 제조방법
GB9929353D0 (en) * 1999-12-13 2000-02-02 Univ Leeds Metallocene synthesis
US7894174B2 (en) * 2004-08-23 2011-02-22 Monolithic Power Systems, Inc. Method and apparatus for fault detection scheme for cold cathode fluorescent lamp (CCFL) integrated circuits
EP2059187A2 (en) * 2006-09-08 2009-05-20 Uop Llc Use of noncalcium zeolites with added calcium salt in hemostatic devices and products
CN101453818B (zh) 2007-11-29 2014-03-19 杭州茂力半导体技术有限公司 放电灯的电路保护和调节装置
KR102215341B1 (ko) 2012-12-17 2021-02-16 솔브레인 주식회사 금속 전구체 및 이를 이용하여 제조된 금속 함유 박막
EP2801579B1 (en) * 2013-05-08 2016-10-19 Arlanxeo Netherlands B.V. Metal complex with a Lewis base ligand
KR102363032B1 (ko) * 2018-03-21 2022-02-16 주식회사 엘지화학 전이금속 복합체의 제조 방법
KR20230102179A (ko) * 2021-12-30 2023-07-07 (주)디엔에프 인듐 화합물, 이의 제조방법, 인듐 함유 박막증착용 조성물 및 인듐 함유 박막의 제조방법

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3007725A1 (de) * 1980-02-29 1981-09-17 Hansjörg Prof. Dr. 2000 Hamburg Sinn Verfahren zur herstellung von polyethylen, polypropylen und copolymeren
DE3127133A1 (de) * 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
US4752597A (en) * 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5196490A (en) * 1987-06-17 1993-03-23 The Dow Chemical Company Process for preparation of syndiotactic polystyrene
US5045517A (en) * 1987-06-17 1991-09-03 The Dow Chemical Company Catalyst and process for preparation of syndiotactic polystyrene
US4978730A (en) * 1987-12-24 1990-12-18 Idemitsu Kosan Company Limited Process for producing styrene-based polymers and catalyst for use therein
US5340892A (en) * 1989-09-29 1994-08-23 Idemitsu Kosan Co., Ltd. Process for producing styrene polymers
US5066741A (en) * 1990-03-22 1991-11-19 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers
DE4139261A1 (de) * 1991-11-29 1993-06-03 Basf Ag Ethylen-copolymerisate niederer dichte
US5563284A (en) * 1994-09-09 1996-10-08 Phillips Petroleum Company Cyclopentadienyl-type ligands, metallocenes, catalyst systems, preparation, and use
DE69502028T2 (de) * 1994-10-31 1998-12-10 Dsm N.V., Heerlen Katalytische zusammensetzung und verfahren zur olefinpolymerisation
US5591874A (en) * 1995-09-29 1997-01-07 Eastman Chemical Company Process for the preparation of 2,5-dihydrofuran compounds
DE19602543A1 (de) * 1996-01-25 1997-07-31 Basf Ag Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶0¶-Alkenen in Gegenwart von Metallocenkomplexen mit kationisch funktionalisierten Cyclopentadienylliganden
WO1997042228A1 (en) * 1996-05-03 1997-11-13 Dsm N.V. Supported catalyst composition and process for the polymerization of olefin monomers

Also Published As

Publication number Publication date
DE69902452T2 (de) 2002-12-12
JP2002510700A (ja) 2002-04-09
WO1999051615A1 (en) 1999-10-14
EP1066302B1 (en) 2002-08-07
CN1302303A (zh) 2001-07-04
DE69902452D1 (de) 2002-09-12
BR9909354A (pt) 2000-12-12
US6100414A (en) 2000-08-08
EP1066302A1 (en) 2001-01-10

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