CN117616055A - 具有宽短链支化分布的聚乙烯共聚物 - Google Patents

具有宽短链支化分布的聚乙烯共聚物 Download PDF

Info

Publication number
CN117616055A
CN117616055A CN202280048171.4A CN202280048171A CN117616055A CN 117616055 A CN117616055 A CN 117616055A CN 202280048171 A CN202280048171 A CN 202280048171A CN 117616055 A CN117616055 A CN 117616055A
Authority
CN
China
Prior art keywords
polyethylene
group
density
10min
pellet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202280048171.4A
Other languages
English (en)
Chinese (zh)
Inventor
V·卡利哈里
J·H·海恩
J·钟
C·G·布莱克利
M·G·索恩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co Conn
Original Assignee
WR Grace and Co Conn
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WR Grace and Co Conn filed Critical WR Grace and Co Conn
Publication of CN117616055A publication Critical patent/CN117616055A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/37—Elution or crystallisation fractionation, e.g. as determined by. TREF or Crystaf
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN202280048171.4A 2021-05-13 2022-05-13 具有宽短链支化分布的聚乙烯共聚物 Pending CN117616055A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US202163188027P 2021-05-13 2021-05-13
US63/188027 2021-05-13
PCT/US2022/029208 WO2022241225A1 (en) 2021-05-13 2022-05-13 Polyethylene copolymer with broad short chain branching distribution

Publications (1)

Publication Number Publication Date
CN117616055A true CN117616055A (zh) 2024-02-27

Family

ID=84029840

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202280048171.4A Pending CN117616055A (zh) 2021-05-13 2022-05-13 具有宽短链支化分布的聚乙烯共聚物

Country Status (9)

Country Link
US (1) US20240228682A1 (https=)
EP (1) EP4337703A4 (https=)
JP (1) JP2024517952A (https=)
KR (1) KR20240007240A (https=)
CN (1) CN117616055A (https=)
BR (1) BR112023023672A2 (https=)
CA (1) CA3218823A1 (https=)
MX (1) MX2023013427A (https=)
WO (1) WO2022241225A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024144126A1 (ko) * 2022-12-29 2024-07-04 주식회사 엘지화학 폴리에틸렌 수지 조성물

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2141833T3 (es) * 1993-08-06 2000-04-01 Exxon Chemical Patents Inc Catalizadores de polimerizacion, su produccion y uso.
JP2006233225A (ja) * 1997-12-25 2006-09-07 Mitsui Chemicals Inc エチレン・α−オレフィン共重合体およびその製造方法
RU2326904C2 (ru) * 2002-06-04 2008-06-20 Юнион Карбайд Кемикалз Энд Пластикс Текнолоджи Корпорейшн Полимерные композиции и способ изготовления труб
WO2008051824A2 (en) * 2006-10-23 2008-05-02 Dow Global Technologies Inc. Polyethylene compositions, methods of making the same, and articles prepared therefrom
US8354485B2 (en) * 2007-08-29 2013-01-15 Albemarle Corporation Aluminoxane catalyst activators derived from dialkylaluminum cation precursor agents, processes for making same, and use thereof in catalysts and polymerization of olefins
TWI555574B (zh) * 2011-03-09 2016-11-01 亞比馬利股份有限公司 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途
US10899858B2 (en) * 2016-04-22 2021-01-26 China Petroleum & Chemical Corporation Polyethylene material and application thereof
WO2018063581A1 (en) * 2016-09-27 2018-04-05 Dow Global Technologies Llc Films having desirable mechanical properties and articles made therefrom
US11214631B2 (en) * 2017-11-14 2022-01-04 Exxonmobil Chemical Patents Inc. (Di)silicon bridged metallocenes that produce polyethylene with broad molecular weight distribution and high molecular weight
WO2021022011A1 (en) * 2019-07-31 2021-02-04 Dow Global Technologies Llc Polymerization catalysts for production of polyethylene with high molecular weight
CN114729078A (zh) * 2019-10-25 2022-07-08 布拉斯科有限公司 齐格勒-纳塔生产的聚乙烯及其方法

Also Published As

Publication number Publication date
BR112023023672A2 (pt) 2024-01-30
MX2023013427A (es) 2024-03-01
EP4337703A4 (en) 2025-03-19
WO2022241225A1 (en) 2022-11-17
US20240228682A1 (en) 2024-07-11
KR20240007240A (ko) 2024-01-16
JP2024517952A (ja) 2024-04-23
EP4337703A1 (en) 2024-03-20
CA3218823A1 (en) 2022-11-17

Similar Documents

Publication Publication Date Title
KR101767702B1 (ko) 고 Ｍｚ/Ｍｗ 폴리올레핀 제조용 촉매조성물
KR101836542B1 (ko) 수소 첨가없이 넓은 분자량 분포의 폴리올레핀 제조를 위한 촉매
JP4020862B2 (ja) コモノマー少量組込み触媒とコモノマー多量組込み触媒を含有する混合メタロセン触媒系
JP4117822B2 (ja) 触媒組成物、重合方法、及びそれらから得られた重合体
JP5279188B2 (ja) 触媒組成物及び押出コーティング用途のポリオレフィン
CN1157427C (zh) 烯烃聚合方法
JP2004521159A (ja) オレフィン重合方法、ポリマー並びにその組成物
CN105745234A (zh) 硼桥接的双茚基茂金属催化剂系统和由其产生的聚合物
JP2017519865A (ja) ポリエチレン樹脂
CN115322276A (zh) 用于产生具有长链支化的高密度聚乙烯的双催化剂体系
WO2015152268A1 (ja) エチレン・α－オレフィン共重合体及びオレフィン系樹脂組成物
JPWO2015152266A1 (ja) エチレン・α−オレフィン共重合体及びオレフィン系樹脂組成物
JP2009504859A (ja) オレフィンの重合のための触媒組成物、それを用いた重合方法、およびその調製方法
CN110520297A (zh) 新颖聚乙烯组合物及其制造和使用方法
CN102143999A (zh) 聚乙烯厚膜和制备聚乙烯的方法
JP2004515576A (ja) 触媒担持法及び担持触媒による重合
EP1448633B2 (en) Two-step polymerization process
CN112969724B (zh) 混合催化剂比的在线调节和烯烃聚合
JP7585497B2 (ja) オレフィン系重合体およびその製造方法
CN117616055A (zh) 具有宽短链支化分布的聚乙烯共聚物
JP2009197226A (ja) エチレン共重合体、該エチレン共重合体を含む熱可塑性樹脂組成物およびこれらから得られる成形体
JP5731100B2 (ja) ポリマーフィルム
CN117715944A (zh) 烯烃聚合催化剂及其制造方法
JP2017066182A (ja) 食品容器用エチレン・α−オレフィン共重合体及びそれよりなる中空成形容器
CN110770265B (zh) 催化剂体系及其使用方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination