CN1173814A - 含烷基糖苷酯的美容清洁组合物 - Google Patents
含烷基糖苷酯的美容清洁组合物 Download PDFInfo
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- CN1173814A CN1173814A CN96191814A CN96191814A CN1173814A CN 1173814 A CN1173814 A CN 1173814A CN 96191814 A CN96191814 A CN 96191814A CN 96191814 A CN96191814 A CN 96191814A CN 1173814 A CN1173814 A CN 1173814A
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Classifications
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Abstract
一种美容清洁组合物,以水溶性胶囊包装(优选明胶),组合物包含:(a)30—85%重量(优选60—85%)的C1－C4烷基糖苷的C10－C22脂肪酸酯(优选含以重量计50%以上的单酯);(b)10—20%重量的C10－C20烷基硫酸的碱金属盐;(c)1—30%重量的烷氧基脱水山梨醇的C10－C22脂肪酸酯(优选聚氧乙烯(20)脱水山梨醇单月桂酸酯);(d)0—30%重量的C10－C22脂肪酸二羟烷基酰胺(优选椰子脂肪酸二羟乙基酰胺)和最多4%重量的(优选最多3%重量)水,组合物的粘度为6500—15000mPas,优选7000—12000mPas(20℃时)。组合物中也可存在有效剂量的功能性添加剂。
Description
本发明涉及一种以水溶性胶囊包装的美容清洁组合物。
传统的美容清洁组合物，如洗发剂和洗浴剂、淋浴产品和泡沫洗浴制品等均基于烷基硫酸钠，甚至更多情况下基于烷基醚硫酸钠。为了稳定和增加泡沫，也为了不刺激皮肤，经常添加椰子二羟乙基酰胺，但这会导致明显的、难以控制的粘度增加，且会使溶液的颜色加深。有时为进一步减少对皮肤的刺激而添加内铵盐，它还可增强阴离子性的月桂基醚硫酸钠和两性的油基内铵盐之间的粘度协同作用，产生粘度很大的(胶状)产物。
美国专利说明书US-A-3,705,102(Armour-Dial Inc.)公开了一种洗浴组合物，它含有一种高泡沫的洗涤剂和一种胶囊包装的复合物，复合物中含有润肤剂、脂肪聚氧乙烯材料(HLB＝10-12)和甲基聚硅氧烷除泡剂。使用时，洗涤剂产生丰富的泡沫。经过一段时间之后，胶囊中的物质释放出来，消除洗涤剂产生的泡沫，同时向使用者提供一种润肤剂。该方法的缺点在于胶囊有可能提早释放其内含物，且不能在整个清洗过程中提供润肤剂。这种润肤剂的存在使皮肤有一种轻松的感觉。
因而，有人提出将所有美容清洁组合物包装于水溶性胶囊之中，胶囊优选由明胶制造的。此处的问题在于，烷基硫酸碱金属盐和胺盐(如月桂基硫酸三乙醇胺)等大多数高泡沫的洗涤剂通常含有相当的水分，这种相对高含量的水分的存在，使得明胶胶囊过软，甚至破裂，从而不适时地释放其内含物。另一个问题是胶囊的生产过程中，美容清洁组合物应当有相对较高的粘度，以使其能够包装。而使用时，在胶囊破裂之后，组合物应当迅速溶解或分散于水环境之中。
现已发现，这些问题可通过下述方法解决：以水溶性胶囊提供美容清洁组合物，胶囊优选由明胶制造的，该组合物包含一种烷基硫酸的碱金属盐，一种含有1到4个碳原子的烷基的烷基糖苷脂肪酸酯，和一种烷氧基化的(优选环氧乙烷)脱水山梨醇(或脱水己糖醇)脂肪酸酯，也可含有一种脂肪酸二羟烷基酰胺。
现已发现，产物的粘度取决于施加于其上的剪切力。如例1中发现，在极低的剪切力(低于10秒-1)下，产物粘度为8000mPas；增加剪切力(至50秒-1)，粘度增加到8300mPas；恒定剪切力为50秒-1，粘度进一步增加为9100mPas。若剪切力此时下降，粘度进一步增加到15000mPas。其后，粘度又开始下降。因而人们认为该产品表现出剪切稠化或膨胀，同时表现出触变性。在该产品制造完毕到被使用之间的时间里，该流变特性是有利的。在该类产品制造完成后，需要相对较高的粘度(8000-12000mPas)。若该产品制造完成后静置，在较低的剪切力下，其粘度将会降至初始值，所以使用时，该产物将容易溶解或分散于水中。
并且，让人惊奇的是，尽管已知一定量的烷基硫酸碱金属盐对皮肤有刺激作用，但是最终组合物对皮肤的温和程度与C1-C4烷基糖苷的纯脂肪酸酯相似。
因而，本发明涉及到一种以水溶性胶囊包装的美容清洁组合物，包含：
(a)30％到85％重量的烷基糖苷酯，它有一含1到4个碳原子的烷基和含10到22个碳原子的直链或支链、饱和或不饱和的脂肪酸；
(b)10％到20％重量的含10到20个碳原子的烷基硫酸碱金属盐；
(c)1％到30％重量的直链或支链、饱和或不饱和脂肪酸的脱水山梨醇酯，其中脂肪酸含10到22个碳原子，该酯用10-80摩尔的C1-C4亚烷基氧化物烷氧基化；
(d)0％到30％重量的直链或支链、饱和或不饱和C10-C22脂肪酸二羟烷基酰胺；及
(e)至多4％重量的水，
该组合物粘度为6500到15000mPas。
含有1到4个碳原子的烷基的烷基糖苷脂肪酸酯优选甲基葡萄糖苷、甲基果糖苷、乙基糖苷或乙基果糖苷的脂肪酸酯。脂肪酸可以是含有10到22个碳原子的直链或支链、饱和或不饱和的脂肪酸。优选的脂肪酸为月桂酸、棕榈酸、硬脂酸和异硬脂酸。也可使用脂肪酸混合物，如椰子脂肪酸、棕榈核脂肪酸和牛脂脂肪酸，优选使用其中的辛酸及更小的脂肪酸基本上被去除的椰子脂肪酸。通常烷基糖苷的脂肪酸酯包括单、二、三酯和更高级的酯。使用的酯包括至少50％重量，优选至少75％重量的单酯。该酯也可包括高达15％重量的游离脂肪酸，但优选游离脂肪酸含量尽可能低，如低于3％重量。通常使用30％到85％重量的烷基糖苷酯，优选60％到85％重量，最优选70％到80％重量的烷基糖苷酯。
烷基硫酸的碱金属盐优选钠盐。烷基硫酸盐含10到20个碳原子，如十二烷基、月桂基、十六烷基、十四烷基和十八烷基硫酸盐，优选月桂基硫酸盐。由于可能刺激皮肤，通常不使用胺盐或链烷醇胺盐，而使用10％到20％重量的C10-C20烷基硫酸碱金属盐。
烷氧基化的脱水山梨醇脂肪酸酯来源于脱水山梨醇(或脱水己糖醇)。脂肪酸可为含有10到22个碳原子的直链或支链、饱和或不饱和的脂肪酸，如月桂酸、硬脂酸、棕榈酸、油酸、异硬脂酸等。
脱水山梨醇脂肪酸酯以C1-C4亚烷基氧化物(优选环氧乙烷)或这类亚烷基氧化物的混合物烷氧基化。平均每摩尔脱水山梨醇脂肪酸酯与10到80摩尔的亚烷基氧化物反应，优选使用聚氧乙烯(20)脱水山梨醇单月桂酸酯。烷氧基化的脱水山梨醇脂肪酸酯的用量为占组合物总重量的1％-30％，优选占总重量的5％-25％。
脂肪酸二羟烷基酰胺来源于含有10到22个碳原子的直链或支链、饱和或不饱和的脂肪酸，如月桂酸或椰子酸，其中辛酸或更小的脂肪酸基本上被去除。后一例中使用的术语为“椰子脂肪酸二羟烷基酰胺”，这些二羟烷基酰胺是优选的。
二羟烷基酰胺的羟烷基可含有2到5个碳原子，这些基团可以相同或不同，亦可为单羟烷基或多羟烷基。优选使用椰子脂肪酸二羟乙基酰胺。脂肪酸二羟烷基酰胺的用量可高达占组合物总重量的30％，优选占总重量的15％到25％。
由于存在一定量的水分可能会导致明胶胶囊的不适时破裂，美容清洁组合物中水含量不得超过总重量的4％，优选不超过总重量的3％。
根据本发明的美容清洁组合物也可包括有效剂量(通常可达10％重量，但也可超过此用量)的功能性添加剂，添加剂选自香料、螯合剂(如EDTA)、防腐剂、杀菌剂、草药(或草药提取物)、维生素、缓冲剂、保湿剂、润肤剂(如脂肪酸和/或脂肪醇的酯)、粘度控制剂(如2到8个碳原子的一元醇)、抗氧化剂、染料、泡沫促进剂(如较高级的烷基氧化胺)以及它们的混合物。
该美容清洁组合物的粘度在20℃时使用配备No SV1转轴的旋转粘度计测得为6500到15000mPas，优选7000到12000mPas。
水溶性胶囊材料优选明胶，但也可使用如聚乙烯醇等其它材料。胶囊的释放时间可通过选择胶囊壁的厚度和明胶种类(不同的表层强度)来控制。胶囊壁厚可为0.1mm到1mm，容积可为5ml。
根据1991年的Seifen-Oele-Fette-Wachse 117卷第4期124-131页的报道，尤其是128页和129页的报道，甲基葡萄糖苷月桂酸酯和甲基葡萄糖苷异硬脂酸酯与重量百分比浓度12％的月桂基醚硫酸钠的水溶液结合使用时，表现出卓越的稠化特性。然而，月桂基硫酸钠和月桂基醚硫酸钠之间有明显的差异。如果一特定物质对月桂基醚硫酸钠水溶液有稠化效应，也无法预测它对几乎无水的月桂基硫酸钠就会有同样的效果。并且，根据129页的图9和图10可以清楚地看到，缺少了盐的存在就明显没有稠化效果，因而本发明不能由该出版物推出。
本发明将根据以下实施例进行说明。
实施例1
一种美容清洁组合物，通过混合以下成分制备得到(重量百分比)
乙基葡萄糖苷月桂酸酯 67.0％
月桂基硫酸钠 12.0％
Polysorbate-20 10.0％
乙醇(96％) 5.0％
乙二胺四乙酸(重量百分比浓度为40％的水溶液) 4.0％
水 0.6％
香料 0.1％
润肤剂 0.55％
柠檬酸(重量百分比浓度为60％的水溶液) 0.75％
100.00％乙基葡萄糖苷月桂酸酯含65.5％重量的单酯、14.8％重量的二酯、19.1％重量的三酯、0.6％重量的更高级的酯。Polysorbate-20(注册商标；ex.Atlas Chem)为聚氧乙烯(20)脱水山梨醇单月桂酸酯，其中平均存在20摩尔环氧乙烷，其HLB值为16.7，25℃时粘度为330cSt(mm2S-1)。
混合后得到一种透明的液体，其重量百分比浓度1％的水溶液的pH为5.7，粘度为8000 mPas(20℃时以配备No.SV1转轴的旋转粘度计测得)。它是一种对皮肤极其温和、泡沫丰富的美容清洁组合物。
流变特性：低于10秒-1的剪切力时粘度为8000mPas；剪切力增加(达到50秒-1)，粘度增加到8300mPas。恒定剪切力(50秒-1)3分钟，粘度增加到9100mPas。剪切力下降，粘度在3分钟内增加到15000mPas。
制得明胶片并将其以已知方式通过制造胶囊的机器，制得壁厚为0.2-0.7mm，容积为5ml的胶囊，该胶囊用来包装上述制得的美容清洁组合物。
实施例2和3
采用下述配方重复实施例1(各成分含量以占全部组合物的重量百分比计)：
实施例2 实施例3乙基葡萄糖苷月桂酸酯(同实施例1) 39％ 40％月桂酸 4％ -月桂基硫酸钠 12％ 12％椰子脂肪酸二羟乙基酰胺 20％ 20％Polysorbate-20(同实施例1) 20％ 20％乙醇(96％) 1％ 4％香料 0.10％ 0.10％润肤剂 0.55％ 0.55％水 3.35％ 3.35％
100.00％ 100.00％两例中明胶胶囊均按例1中所述包装各成分，使用时产生泡沫丰富、对皮肤温和的美容清洁组合物。
Claims (19)
1.包装于水溶性胶囊中的美容清洁组合物，它包含：
(a)30％到85％重量的烷基糖苷酯，它有一含1到4个碳原子的烷基和含10到22个碳原子的直链或支链、饱和或不饱和的脂肪酸；
(b)10％到20％重量的含10到20个碳原子的烷基硫酸碱金属盐；
(c)1％到30％重量的直链或支链、饱和或不饱和脂肪酸的脱水山梨醇酯，其中脂肪酸含10到22个碳原子，该酯用10-80摩尔的C1-C4亚烷基氧化物烷氧基化；
(d)0％到30％重量的直链或支链、饱和或不饱和C10-C22脂肪酸二羟烷基酰胺；及
(e)至多4％重量的水，
该组合物粘度为6500到15000mPas。
2.根据权利要求1的美容清洁组合物，其中(a)为含1或2个碳原子的烷基的烷基葡萄糖苷的C10-C22脂肪酸酯。
3.根据权利要求1的美容清洁组合物，其中(a)含有至少50％重量的单酯。
4.根据权利要求1的美容清洁组合物，其中(a)含有至少75％重量的单酯。
5.根据权利要求1的美容清洁组合物，其中(a)含有至多3％重量的游离脂肪酸。
6.根据权利要求1的美容清洁组合物，其中(a)中的脂肪酸选自月桂酸、棕榈酸、硬脂酸、异硬脂酸和椰子脂肪酸，椰子脂肪酸中的辛酸或更小的脂肪酸被去除。
7.根据权利要求1的美容清洁组合物，其中(a)的用量为占全部组合物重量的60％到85％。
8.根据权利要求1的美容清洁组合物，其中(b)为月桂基硫酸钠。
9.根据权利要求1的美容清洁组合物，其中(b)中的亚烷基氧化物为环氧乙烷。
10.根据权利要求1的美容清洁组合物，其中(b)为聚氧乙烯(20)脱水山梨醇单月桂酸酯。
11.根据权利要求1的美容清洁组合物，它含有占全部组合物重量5％到25％的(b)。
12.根据权利要求1的美容清洁组合物，其中(d)为椰子脂肪酸二羟乙基酰胺。
13.根据权利要求的美容清洁组合物，它含有占全部组合物重量15％到25％的(d)。
14.根据权利要求1的美容清洁组合物，它含有至多3％重量的水。
15.根据权利要求1的美容清洁组合物，它含有占全部组合物重量达10％的功能性添加剂，添加剂选自香料、螯合剂、防腐剂、杀菌剂、草药、维生素、缓冲剂、保湿剂、润肤剂、粘度控制剂、抗氧化剂、染料、泡沫促进剂及它们的混合物。
16.根据权利要求1的美容清洁组合物，其粘度为6500到15000mPas(20℃)。
17.根据权利要求1的美容清洁组合物，其粘度为7000到12000mPas(20℃)。
18.根据权利要求1的美容清洁组合物，其中胶囊材料为明胶。
19.一种泡沫洗浴制品，它含有根据权利要求1-18的美容清洁组合物。
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| CN104411289A (zh) * | 2012-06-15 | 2015-03-11 | 卢布里佐尔先进材料有限公司 | 用于表面活性剂体系的烷基糖苷基胶束增稠剂 |
Families Citing this family (11)
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| DE19721708A1 (de) * | 1997-05-23 | 1998-11-26 | Henkel Kgaa | Verkapseltes Reinigungsmittel |
| BR9911398B1 (pt) * | 1998-06-23 | 2011-07-26 | espessante lÍquido para sistemas tensoativos. | |
| WO2001085895A1 (en) * | 2000-05-12 | 2001-11-15 | Unilever N.V. | Unit dose cleaning product |
| DE10032118B9 (de) * | 2000-07-01 | 2006-12-07 | Wella Ag | Antithixotropes kosmetisches Mittel |
| US7125828B2 (en) | 2000-11-27 | 2006-10-24 | The Procter & Gamble Company | Detergent products, methods and manufacture |
| ES2431044T5 (es) | 2000-11-27 | 2022-05-27 | Procter & Gamble | Método de lavado de vajillas |
| US8940676B2 (en) | 2000-11-27 | 2015-01-27 | The Procter & Gamble Company | Detergent products, methods and manufacture |
| US8283300B2 (en) | 2000-11-27 | 2012-10-09 | The Procter & Gamble Company | Detergent products, methods and manufacture |
| JP2007503418A (ja) | 2003-08-27 | 2007-02-22 | バイヤースドルフ・アクチエンゲゼルシヤフト | 局所使用中に個別には感知不能になる外皮を有するカプセル |
| WO2012142452A2 (en) | 2011-04-13 | 2012-10-18 | Biosafe Technologies, Inc. | Cleaning, insecticide, insect repellant, glue solvent and anti-irritation composition |
| JP7068425B2 (ja) | 2019-11-25 | 2022-05-16 | 花王株式会社 | 皮膚洗浄剤 |
Family Cites Families (6)
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| US3705102A (en) * | 1971-01-18 | 1972-12-05 | Armour Dial Inc | Composition and method of defoaming bubble baths |
| US4597885A (en) * | 1985-01-02 | 1986-07-01 | Pharmacaps, Inc. | Encapsulated foaming bath composition |
| GB2192404B (en) * | 1986-07-09 | 1990-08-01 | Scherer Ltd R P | Encapsulated products |
| DK76889D0 (da) * | 1989-02-17 | 1989-02-17 | Novo Industri As | Fremgangsmaade til fremstilling af organiske forbindelser |
| JP2751503B2 (ja) * | 1989-12-25 | 1998-05-18 | ライオン株式会社 | シャンプー組成物 |
| JPH04331295A (ja) * | 1991-04-30 | 1992-11-19 | Lion Corp | 洗浄剤組成物 |
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- 1996-02-05 EP EP96904035A patent/EP0808152A1/en not_active Ceased
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104411289A (zh) * | 2012-06-15 | 2015-03-11 | 卢布里佐尔先进材料有限公司 | 用于表面活性剂体系的烷基糖苷基胶束增稠剂 |
| CN104411289B (zh) * | 2012-06-15 | 2017-12-26 | 卢布里佐尔先进材料有限公司 | 用于表面活性剂体系的烷基糖苷基胶束增稠剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0808152A1 (en) | 1997-11-26 |
| BR9607118A (pt) | 1997-11-04 |
| WO1996024328A1 (en) | 1996-08-15 |
| KR19980701954A (ko) | 1998-06-25 |
| AU4789296A (en) | 1996-08-27 |
| JPH10513189A (ja) | 1998-12-15 |
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