CN1170005C - 用于在传热流体和发动机冷却剂中保护轻金属的缓蚀剂和协同抑制剂组合 - Google Patents
用于在传热流体和发动机冷却剂中保护轻金属的缓蚀剂和协同抑制剂组合 Download PDFInfo
- Publication number
- CN1170005C CN1170005C CNB998120820A CN99812082A CN1170005C CN 1170005 C CN1170005 C CN 1170005C CN B998120820 A CNB998120820 A CN B998120820A CN 99812082 A CN99812082 A CN 99812082A CN 1170005 C CN1170005 C CN 1170005C
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- China
- Prior art keywords
- acid
- weight
- salt
- corrosion inhibitor
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 238000005260 corrosion Methods 0.000 title claims abstract description 60
- 230000007797 corrosion Effects 0.000 title claims abstract description 60
- 239000002826 coolant Substances 0.000 title claims abstract description 15
- 239000003112 inhibitor Substances 0.000 title claims description 22
- 229910052751 metal Inorganic materials 0.000 title abstract description 20
- 239000002184 metal Substances 0.000 title abstract description 20
- 239000012530 fluid Substances 0.000 title abstract description 10
- 238000012546 transfer Methods 0.000 title description 6
- 150000002739 metals Chemical class 0.000 title description 4
- 230000002195 synergetic effect Effects 0.000 title description 2
- -1 aromatic carboxylate acids Chemical class 0.000 claims abstract description 64
- 239000002253 acid Substances 0.000 claims abstract description 37
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000011777 magnesium Substances 0.000 claims abstract description 33
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 32
- 150000003839 salts Chemical class 0.000 claims abstract description 29
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 8
- 239000004411 aluminium Substances 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 13
- 239000003507 refrigerant Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 11
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 claims description 10
- 229910052728 basic metal Inorganic materials 0.000 claims description 9
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 8
- 150000007520 diprotic acids Chemical class 0.000 claims description 8
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 8
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 8
- 239000013529 heat transfer fluid Substances 0.000 claims description 7
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical group CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 150000003818 basic metals Chemical class 0.000 claims description 6
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 claims description 6
- 150000007518 monoprotic acids Chemical class 0.000 claims description 5
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 claims description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 4
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 4
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 claims description 3
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- 230000005764 inhibitory process Effects 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001340 alkali metals Chemical group 0.000 claims description 2
- 239000010953 base metal Substances 0.000 claims description 2
- 229910001960 metal nitrate Inorganic materials 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 44
- 229910000861 Mg alloy Inorganic materials 0.000 abstract description 6
- 229910000838 Al alloy Inorganic materials 0.000 abstract description 3
- 125000001931 aliphatic group Chemical group 0.000 abstract description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 79
- 230000002528 anti-freeze Effects 0.000 description 27
- 238000009472 formulation Methods 0.000 description 26
- 230000000052 comparative effect Effects 0.000 description 16
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- MNWFXJYAOYHMED-UHFFFAOYSA-N hexane carboxylic acid Natural products CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 8
- 229910052731 fluorine Inorganic materials 0.000 description 8
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 7
- 230000003628 erosive effect Effects 0.000 description 7
- 239000011737 fluorine Substances 0.000 description 7
- 229910045601 alloy Inorganic materials 0.000 description 6
- 239000000956 alloy Substances 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 239000012141 concentrate Substances 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000002161 passivation Methods 0.000 description 5
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 4
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 230000010287 polarization Effects 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 150000003852 triazoles Chemical class 0.000 description 3
- LNETULKMXZVUST-UHFFFAOYSA-M 1-naphthoate Chemical compound C1=CC=C2C(C(=O)[O-])=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- GANNOFFDYMSBSZ-UHFFFAOYSA-N [AlH3].[Mg] Chemical compound [AlH3].[Mg] GANNOFFDYMSBSZ-UHFFFAOYSA-N 0.000 description 2
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- LJOODBDWMQKMFB-UHFFFAOYSA-N cyclohexylacetic acid Chemical compound OC(=O)CC1CCCCC1 LJOODBDWMQKMFB-UHFFFAOYSA-N 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 229910000679 solder Inorganic materials 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- NSTREUWFTAOOKS-UHFFFAOYSA-N 2-fluorobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1F NSTREUWFTAOOKS-UHFFFAOYSA-N 0.000 description 1
- BBYDXOIZLAWGSL-UHFFFAOYSA-N 4-fluorobenzoic acid Chemical compound OC(=O)C1=CC=C(F)C=C1 BBYDXOIZLAWGSL-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical class [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- JRBRVDCKNXZZGH-UHFFFAOYSA-N alumane;copper Chemical compound [AlH3].[Cu] JRBRVDCKNXZZGH-UHFFFAOYSA-N 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical group [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 239000002173 cutting fluid Substances 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- HJZLEGIHUQOJBA-UHFFFAOYSA-N cyclohexane propionic acid Chemical compound OC(=O)CCC1CCCCC1 HJZLEGIHUQOJBA-UHFFFAOYSA-N 0.000 description 1
- XYYWOUGVLZCRAB-UHFFFAOYSA-N cyclohexanecarboxylic acid formic acid Chemical compound C(=O)O.C1(CCCCC1)C(=O)O XYYWOUGVLZCRAB-UHFFFAOYSA-N 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910021518 metal oxyhydroxide Inorganic materials 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000011885 synergistic combination Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/04—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in markedly acid liquids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/20—Antifreeze additives therefor, e.g. for radiator liquids
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/12—Oxygen-containing compounds
- C23F11/124—Carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/12—Oxygen-containing compounds
- C23F11/124—Carboxylic acids
- C23F11/126—Aliphatic acids
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Heat Treatments In General, Especially Conveying And Cooling (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98308380.9 | 1998-10-14 | ||
| EP98308380A EP0995785A1 (en) | 1998-10-14 | 1998-10-14 | Corrosion inhibitors and synergistic inhibitor combinations for the protection of light metals in heat-transfer fluids and engine coolants |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1323361A CN1323361A (zh) | 2001-11-21 |
| CN1170005C true CN1170005C (zh) | 2004-10-06 |
Family
ID=8235101
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB998120820A Expired - Fee Related CN1170005C (zh) | 1998-10-14 | 1999-10-11 | 用于在传热流体和发动机冷却剂中保护轻金属的缓蚀剂和协同抑制剂组合 |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US6398984B1 (enExample) |
| EP (2) | EP0995785A1 (enExample) |
| JP (1) | JP4386586B2 (enExample) |
| KR (1) | KR100626888B1 (enExample) |
| CN (1) | CN1170005C (enExample) |
| AT (1) | ATE231566T1 (enExample) |
| AU (1) | AU754798B2 (enExample) |
| BG (1) | BG65318B1 (enExample) |
| BR (1) | BR9914413B1 (enExample) |
| CA (1) | CA2347431C (enExample) |
| CZ (1) | CZ301124B6 (enExample) |
| DE (1) | DE69905072T2 (enExample) |
| ES (1) | ES2191459T3 (enExample) |
| PL (1) | PL192405B1 (enExample) |
| PT (1) | PT1133585E (enExample) |
| RU (1) | RU2227175C2 (enExample) |
| SI (1) | SI1133585T1 (enExample) |
| TR (1) | TR200101075T2 (enExample) |
| WO (1) | WO2000022189A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106283068A (zh) * | 2016-08-30 | 2017-01-04 | 句容宁武高新技术发展有限公司 | 新型缓蚀剂及其制备方法 |
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| DE10036031A1 (de) | 2000-07-24 | 2002-02-07 | Basf Ag | Gefrierschutzmittelkonzentrate auf Basis von Amiden und diese umfassende Kühlmittelzusammensetzungen zum Schutz von Magnesium und Magnesiumlegierungen |
| DE10128530A1 (de) | 2001-06-13 | 2002-12-19 | Basf Ag | Kühlmittel für Kühlsysteme in Brennstoffzellenantrieben enthaltend Azolderivate |
| EP1304367A1 (en) * | 2001-10-17 | 2003-04-23 | Texaco Development Corporation | Corrosion inhibiting compositions and methods for fuel cell coolant systems |
| KR20020039296A (ko) * | 2002-04-26 | 2002-05-25 | 유정근 | 난방수 배관에 있어 전기화학적 부식 및 미생물부식을억제하기 위한 조성물 제조방법 |
| KR100506779B1 (ko) * | 2002-05-27 | 2005-08-08 | 현대자동차주식회사 | 자동차 엔진 조립용 방청제 조성물 |
| EP1386952A3 (de) | 2002-08-02 | 2006-05-24 | Clariant Produkte (Deutschland) GmbH | Gefrierschutzmittel |
| JP2004244575A (ja) * | 2003-02-17 | 2004-09-02 | Thk Co Ltd | クーラントおよびそれを使用する機械加工装置 |
| WO2004074547A2 (en) * | 2003-02-19 | 2004-09-02 | Intellectual Concepts, Llc | Lower alkyl carboxylic acid moiety-containing anti- corrosion compositions and methods of use. |
| DE10313280A1 (de) | 2003-03-25 | 2004-10-07 | Basf Ag | Gefrierschutzmittelkonzentrate und Kühlmittelzusammensetzungen auf Basis von Polyglykolen und Amiden zum Schutz von Magnesium und dessen Legierungen |
| US8188016B2 (en) | 2003-07-08 | 2012-05-29 | Ntn Corporation | Lubricant composition and bearing using same |
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| RU2253697C1 (ru) * | 2004-04-29 | 2005-06-10 | Гаврилов Наум Беньяминович | Ингибитор коррозии латуни и углеродистых сталей |
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| US7435359B2 (en) * | 2004-12-21 | 2008-10-14 | Hercules Chemical Company Incorporated | Corrosion inhibiting heat transfer materials |
| JP5096685B2 (ja) * | 2006-03-30 | 2012-12-12 | 本田技研工業株式会社 | マグネシウムまたはマグネシウム合金用不凍液／冷却液組成物 |
| CN101395241A (zh) * | 2006-03-31 | 2009-03-25 | Cci株式会社 | 冷却剂组合物 |
| US7309453B2 (en) * | 2006-05-12 | 2007-12-18 | Intel Corporation | Coolant capable of enhancing corrosion inhibition, system containing same, and method of manufacturing same |
| US7790054B2 (en) * | 2007-06-28 | 2010-09-07 | Chevron U.S.A. Inc. | Antifreeze concentrate and coolant compositions and preparation thereof |
| US20090250654A1 (en) * | 2007-06-28 | 2009-10-08 | Chevron U.S.A. Inc. | Antifreeze concentrate and coolant compositions and preparation thereof |
| US20090001313A1 (en) * | 2007-06-28 | 2009-01-01 | Chevron U.S.A. Inc. | Antifreeze Concentrate and Coolant Compositions and Preparation Thereof |
| US8062546B2 (en) * | 2007-06-28 | 2011-11-22 | Chevron U.S.A. Inc. | Molybdate-free antifreeze concentrate and coolant compositions and preparation thereof |
| KR101430043B1 (ko) * | 2007-10-15 | 2014-08-14 | (주)티에스케이워터 | 밀폐형 난방시스템용 설비보호제 조성물 |
| KR100962792B1 (ko) * | 2008-05-26 | 2010-06-09 | 현대자동차주식회사 | 열산화 안정성이 우수한 부동액 조성물 |
| US20100270494A1 (en) * | 2009-04-22 | 2010-10-28 | Chevron U.S.A. Inc. | Hot test fluid containing vapor phase inhibition |
| ES2421184T3 (es) * | 2009-10-01 | 2013-08-29 | Rhein Chemie Rheinau Gmbh | Uso de aditivos de protección frente a la corrosión para la protección de aluminio y/o aleaciones de aluminio para procedimientos de acabado |
| DE102010002341A1 (de) * | 2010-02-25 | 2011-08-25 | Behr GmbH & Co. KG, 70469 | Wärmeübertrager und Bauteile für Kfz-Kühlkreisläufe |
| US20130014670A1 (en) | 2010-04-01 | 2013-01-17 | Commissariat a I'Energie Atomique et Aux Energies Altematives | Use of anticorrosion agents for conditioning magnesium metal, conditioning material thus obtained and preparation process |
| CN101922009B (zh) * | 2010-08-10 | 2012-05-09 | 北京化工大学 | 一种抑制镁合金在汽车发动机冷却液中腐蚀的缓蚀剂配方 |
| US20120043493A1 (en) * | 2010-08-19 | 2012-02-23 | Basf Se | Sound deadener composition with emulsion polymer and fluorinated compound |
| US8357310B2 (en) | 2010-11-10 | 2013-01-22 | Hamilton Sundstrand Space Systems International, Inc. | Aqueous based cooling of components having high surface area levels of aluminum or nickel |
| JP2013213265A (ja) * | 2012-04-03 | 2013-10-17 | Dai Ichi Kogyo Seiyaku Co Ltd | 防錆剤組成物及びこれを用いた防錆方法 |
| US8617416B1 (en) * | 2012-09-07 | 2013-12-31 | Prestone Products Corporation | Heat transfer fluids and corrosion inhibitor formulations for use thereof |
| US9994755B2 (en) | 2012-09-07 | 2018-06-12 | Prestone Products Corporation | Heat transfer fluids and corrosion inhibitor formulations for use thereof |
| RU2518583C1 (ru) * | 2012-12-20 | 2014-06-10 | Общество с ограниченной ответственностью "ФОТОН" | Концентрат охлаждающей жидкости |
| RU2539129C1 (ru) * | 2013-08-19 | 2015-01-10 | Федеральное государственное бюджетное учреждение науки Институт физической химии и электрохимии им. А.Н. Фрумкина Российской академии наук (ИФХЭ РАН) | Ингибитор кислотной коррозии металлов |
| KR101546935B1 (ko) * | 2013-09-06 | 2015-08-24 | 김영남 | 보일러용 난방수 조성물 |
| EP3156518A1 (en) * | 2015-10-14 | 2017-04-19 | Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung GmbH | Corrosion inhibitor composition for magnesium or magnesium alloys |
| DE102015014480A1 (de) | 2015-11-11 | 2017-05-11 | AMZ Holding GmbH | Silikathaltiges Kühlmittelkonzentrat |
| CN106350822A (zh) * | 2016-10-09 | 2017-01-25 | 广西大学 | 一种铝合金缓蚀剂 |
| BR112019010016B1 (pt) * | 2016-11-23 | 2023-11-14 | Basf Se | Composição de refrigerante, método para produzir composições de refrigerante, e, uso de uma composição de refrigerante |
| US11560505B2 (en) * | 2018-08-02 | 2023-01-24 | Prestone Products Corporation | Heat transfer fluids containing synergistic blends of corrosion inhibitor formulations |
| RU2725925C1 (ru) * | 2019-10-11 | 2020-07-07 | Общество с ограниченной ответственностью "Водные технологии инжиниринг" | Способ защиты от коррозии конденсаторов паровых турбин |
| CN113818020A (zh) * | 2021-08-26 | 2021-12-21 | 暨南大学 | 适用于含氯介质中的镁合金复配缓蚀剂及其制备方法 |
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| AU452099B2 (en) * | 1972-08-02 | 1974-08-29 | Applied Chemicals Pty. Limited | Aqueous corrosion inhibiting compositions |
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| US4851145A (en) * | 1986-06-30 | 1989-07-25 | S.A. Texaco Petroleum Nv | Corrosion-inhibited antifreeze/coolant composition |
| GB8922504D0 (en) * | 1989-10-05 | 1989-11-22 | Interox Chemicals Ltd | Hydrogen peroxide solutions |
| JP2772578B2 (ja) * | 1990-06-29 | 1998-07-02 | シーシーアイ株式会社 | 不凍液 |
| US5085791A (en) | 1990-10-01 | 1992-02-04 | Texaco Chemical Company | Corrosion-inhibited antifreeze/coolant composition containing cyclohexane acid(s) |
| RU2009158C1 (ru) * | 1991-07-01 | 1994-03-15 | Научно-исследовательский институт полимерных материалов | Охлаждающая жидкость для двигателей внутреннего сгорания |
| RU2050397C1 (ru) * | 1992-01-23 | 1995-12-20 | Товарищество с ограниченной ответственностью "ЭКСИТОН-М" | Антифриз |
| JPH0820763A (ja) * | 1994-07-06 | 1996-01-23 | Seiken Kagaku Kogyo Kk | 非アミン系不凍液 |
| JPH0885782A (ja) * | 1994-09-16 | 1996-04-02 | Nippon Chem Kogyo Kk | 不凍液組成物 |
| JP3845702B2 (ja) * | 1997-03-11 | 2006-11-15 | シーシーアイ株式会社 | 不凍液／冷却液組成物 |
-
1998
- 1998-10-14 EP EP98308380A patent/EP0995785A1/en not_active Withdrawn
-
1999
- 1999-10-11 WO PCT/IB1999/001659 patent/WO2000022189A1/en not_active Ceased
- 1999-10-11 BR BRPI9914413-1A patent/BR9914413B1/pt not_active IP Right Cessation
- 1999-10-11 AU AU58806/99A patent/AU754798B2/en not_active Ceased
- 1999-10-11 AT AT99946398T patent/ATE231566T1/de not_active IP Right Cessation
- 1999-10-11 RU RU2001110066/02A patent/RU2227175C2/ru not_active IP Right Cessation
- 1999-10-11 CA CA002347431A patent/CA2347431C/en not_active Expired - Fee Related
- 1999-10-11 JP JP2000576076A patent/JP4386586B2/ja not_active Expired - Lifetime
- 1999-10-11 TR TR2001/01075T patent/TR200101075T2/xx unknown
- 1999-10-11 CZ CZ20011220A patent/CZ301124B6/cs not_active IP Right Cessation
- 1999-10-11 EP EP99946398A patent/EP1133585B1/en not_active Expired - Lifetime
- 1999-10-11 DE DE69905072T patent/DE69905072T2/de not_active Expired - Lifetime
- 1999-10-11 ES ES99946398T patent/ES2191459T3/es not_active Expired - Lifetime
- 1999-10-11 PT PT99946398T patent/PT1133585E/pt unknown
- 1999-10-11 SI SI9930234T patent/SI1133585T1/xx unknown
- 1999-10-11 KR KR1020017004568A patent/KR100626888B1/ko not_active Expired - Fee Related
- 1999-10-11 PL PL347173A patent/PL192405B1/pl not_active IP Right Cessation
- 1999-10-11 CN CNB998120820A patent/CN1170005C/zh not_active Expired - Fee Related
- 1999-10-13 US US09/417,406 patent/US6398984B1/en not_active Expired - Fee Related
-
2001
- 2001-04-24 BG BG105466A patent/BG65318B1/bg unknown
- 2001-11-15 US US09/987,577 patent/US6676848B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106283068A (zh) * | 2016-08-30 | 2017-01-04 | 句容宁武高新技术发展有限公司 | 新型缓蚀剂及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2347431C (en) | 2007-09-04 |
| PT1133585E (pt) | 2003-06-30 |
| ES2191459T3 (es) | 2003-09-01 |
| EP1133585A1 (en) | 2001-09-19 |
| EP1133585B1 (en) | 2003-01-22 |
| US6398984B1 (en) | 2002-06-04 |
| PL192405B1 (pl) | 2006-10-31 |
| CA2347431A1 (en) | 2000-04-20 |
| CZ20011220A3 (cs) | 2001-12-12 |
| ATE231566T1 (de) | 2003-02-15 |
| SI1133585T1 (en) | 2003-06-30 |
| BG65318B1 (bg) | 2008-01-31 |
| WO2000022189A1 (en) | 2000-04-20 |
| DE69905072D1 (de) | 2003-02-27 |
| EP0995785A1 (en) | 2000-04-26 |
| AU754798B2 (en) | 2002-11-28 |
| KR20010080099A (ko) | 2001-08-22 |
| DE69905072T2 (de) | 2003-11-06 |
| BG105466A (en) | 2001-11-30 |
| US6676848B2 (en) | 2004-01-13 |
| BR9914413B1 (pt) | 2009-01-13 |
| BR9914413A (pt) | 2001-06-26 |
| CZ301124B6 (cs) | 2009-11-11 |
| KR100626888B1 (ko) | 2006-09-20 |
| JP4386586B2 (ja) | 2009-12-16 |
| JP2002527619A (ja) | 2002-08-27 |
| RU2227175C2 (ru) | 2004-04-20 |
| US20020053655A1 (en) | 2002-05-09 |
| AU5880699A (en) | 2000-05-01 |
| CN1323361A (zh) | 2001-11-21 |
| PL347173A1 (en) | 2002-03-25 |
| TR200101075T2 (tr) | 2001-09-21 |
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