CN116060117A - 一种催化柴油加氢裂化催化剂及其制备方法 - Google Patents
一种催化柴油加氢裂化催化剂及其制备方法 Download PDFInfo
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- CN116060117A CN116060117A CN202111269809.0A CN202111269809A CN116060117A CN 116060117 A CN116060117 A CN 116060117A CN 202111269809 A CN202111269809 A CN 202111269809A CN 116060117 A CN116060117 A CN 116060117A
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- molecular sieve
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- 239000003054 catalyst Substances 0.000 title claims abstract description 47
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 25
- 238000004517 catalytic hydrocracking Methods 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000002808 molecular sieve Substances 0.000 claims abstract description 54
- 229910052751 metal Inorganic materials 0.000 claims abstract description 27
- 239000002184 metal Substances 0.000 claims abstract description 27
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims abstract description 16
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 14
- 229910004298 SiO 2 Inorganic materials 0.000 claims abstract description 9
- XGBWXISUZXYULS-UHFFFAOYSA-N 2,3-ditert-butylpyridine Chemical compound CC(C)(C)C1=CC=CN=C1C(C)(C)C XGBWXISUZXYULS-UHFFFAOYSA-N 0.000 claims abstract description 7
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 238000001914 filtration Methods 0.000 claims description 23
- 239000011148 porous material Substances 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- LXPCOISGJFXEJE-UHFFFAOYSA-N oxifentorex Chemical compound C=1C=CC=CC=1C[N+](C)([O-])C(C)CC1=CC=CC=C1 LXPCOISGJFXEJE-UHFFFAOYSA-N 0.000 claims description 12
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 11
- 239000003153 chemical reaction reagent Substances 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 150000007524 organic acids Chemical class 0.000 claims description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 6
- 229910052721 tungsten Inorganic materials 0.000 claims description 6
- 239000010937 tungsten Substances 0.000 claims description 6
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- XZRHNAFEYMSXRG-UHFFFAOYSA-N 2,5-dimethylbenzoic acid Chemical compound CC1=CC=C(C)C(C(O)=O)=C1 XZRHNAFEYMSXRG-UHFFFAOYSA-N 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 3
- CHZLVSBMXZSPNN-UHFFFAOYSA-N 2,4-dimethylbenzenesulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C(C)=C1 CHZLVSBMXZSPNN-UHFFFAOYSA-N 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 239000003223 protective agent Substances 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000013589 supplement Substances 0.000 claims description 2
- 230000001502 supplementing effect Effects 0.000 claims description 2
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 claims description 2
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 claims description 2
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 15
- 239000000126 substance Substances 0.000 abstract description 8
- 229930195733 hydrocarbon Natural products 0.000 abstract description 4
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 4
- 125000003118 aryl group Chemical group 0.000 abstract description 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 2
- 239000012065 filter cake Substances 0.000 description 20
- 238000005470 impregnation Methods 0.000 description 16
- 230000002572 peristaltic effect Effects 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- IRLYGRLEBKCYPY-UHFFFAOYSA-N 2,5-dimethylbenzenesulfonic acid Chemical compound CC1=CC=C(C)C(S(O)(=O)=O)=C1 IRLYGRLEBKCYPY-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000005096 rolling process Methods 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 5
- 238000004523 catalytic cracking Methods 0.000 description 5
- 238000005336 cracking Methods 0.000 description 5
- 239000002283 diesel fuel Substances 0.000 description 5
- 238000002791 soaking Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- UWKQJZCTQGMHKD-UHFFFAOYSA-N 2,6-di-tert-butylpyridine Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=N1 UWKQJZCTQGMHKD-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 238000004876 x-ray fluorescence Methods 0.000 description 2
- 229910003110 Mg K Inorganic materials 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000004230 steam cracking Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/80—Mixtures of different zeolites
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
- C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J29/166—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
Abstract
Description
原料油 | 催化柴油 |
<![CDATA[密度(20℃),g/cm<sup>3</sup>]]> | 0.871 |
馏程,℃ | |
IBP/10% | 160/215 |
50%/90% | 308/- |
95%/EBP | -/387 |
Claims (14)
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CN202111269809.0A CN116060117B (zh) | 2021-10-29 | 2021-10-29 | 一种催化柴油加氢裂化催化剂及其制备方法 |
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CN202111269809.0A CN116060117B (zh) | 2021-10-29 | 2021-10-29 | 一种催化柴油加氢裂化催化剂及其制备方法 |
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CN116060117A true CN116060117A (zh) | 2023-05-05 |
CN116060117B CN116060117B (zh) | 2024-04-05 |
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Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120006724A1 (en) * | 2010-07-07 | 2012-01-12 | Yanze Du | Hydrocracking catalysts, processes for preparing the same and uses thereof |
CN103394368A (zh) * | 2013-07-22 | 2013-11-20 | 中海油(青岛)重质油加工工程技术研究中心有限公司 | 一种含复合分子筛的轻油型加氢裂化催化剂及其制备方法和应用 |
CN103551186A (zh) * | 2013-07-22 | 2014-02-05 | 中海油(青岛)重质油加工工程技术研究中心有限公司 | 一种含复合分子筛的中油型加氢裂化催化剂及其制备方法和应用 |
CN104549458A (zh) * | 2013-10-23 | 2015-04-29 | 中国石油化工股份有限公司 | 一种最大量生产乙烯原料加氢裂化催化剂及其制备方法 |
CN107344110A (zh) * | 2016-05-05 | 2017-11-14 | 中国石油化工股份有限公司 | 用于生产低直链烷烃含量加氢裂化尾油的催化剂及其制备方法和应用 |
WO2018192519A1 (zh) * | 2017-04-21 | 2018-10-25 | 武汉凯迪工程技术研究总院有限公司 | 优化型柴油加氢裂化催化剂载体及其制备方法 |
WO2018192520A1 (zh) * | 2017-04-21 | 2018-10-25 | 武汉凯迪工程技术研究总院有限公司 | 优化型柴油加氢裂化催化剂及其制备方法 |
CN109622028A (zh) * | 2018-12-31 | 2019-04-16 | 中海油天津化工研究设计院有限公司 | 一种高稳定性催化裂化柴油加氢裂化催化剂及其制备方法 |
US20200306736A1 (en) * | 2017-11-29 | 2020-10-01 | China Petroleum & Chemical Corporation | Modified y-type molecular sieve and preparation method thereof, hydrocracking catalyst and preparation method thereof, and method for hydrocracking hydrocarbon oil |
CN112642465A (zh) * | 2020-12-26 | 2021-04-13 | 中海油天津化工研究设计院有限公司 | 一种直馏柴油加氢裂化催化剂及其制备方法 |
-
2021
- 2021-10-29 CN CN202111269809.0A patent/CN116060117B/zh active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120006724A1 (en) * | 2010-07-07 | 2012-01-12 | Yanze Du | Hydrocracking catalysts, processes for preparing the same and uses thereof |
CN103394368A (zh) * | 2013-07-22 | 2013-11-20 | 中海油(青岛)重质油加工工程技术研究中心有限公司 | 一种含复合分子筛的轻油型加氢裂化催化剂及其制备方法和应用 |
CN103551186A (zh) * | 2013-07-22 | 2014-02-05 | 中海油(青岛)重质油加工工程技术研究中心有限公司 | 一种含复合分子筛的中油型加氢裂化催化剂及其制备方法和应用 |
CN104549458A (zh) * | 2013-10-23 | 2015-04-29 | 中国石油化工股份有限公司 | 一种最大量生产乙烯原料加氢裂化催化剂及其制备方法 |
CN107344110A (zh) * | 2016-05-05 | 2017-11-14 | 中国石油化工股份有限公司 | 用于生产低直链烷烃含量加氢裂化尾油的催化剂及其制备方法和应用 |
WO2018192519A1 (zh) * | 2017-04-21 | 2018-10-25 | 武汉凯迪工程技术研究总院有限公司 | 优化型柴油加氢裂化催化剂载体及其制备方法 |
WO2018192520A1 (zh) * | 2017-04-21 | 2018-10-25 | 武汉凯迪工程技术研究总院有限公司 | 优化型柴油加氢裂化催化剂及其制备方法 |
US20200306736A1 (en) * | 2017-11-29 | 2020-10-01 | China Petroleum & Chemical Corporation | Modified y-type molecular sieve and preparation method thereof, hydrocracking catalyst and preparation method thereof, and method for hydrocracking hydrocarbon oil |
CN109622028A (zh) * | 2018-12-31 | 2019-04-16 | 中海油天津化工研究设计院有限公司 | 一种高稳定性催化裂化柴油加氢裂化催化剂及其制备方法 |
CN112642465A (zh) * | 2020-12-26 | 2021-04-13 | 中海油天津化工研究设计院有限公司 | 一种直馏柴油加氢裂化催化剂及其制备方法 |
Non-Patent Citations (6)
Title |
---|
CHEN HL等: "Acidity and catalytic performance of ZSM-5/Y composite zeolite for heavy oil cracking", CHINESE JOURNAL OF CATALYSIS, vol. 25, no. 9, 30 September 2004 (2004-09-30), pages 715 - 720 * |
SHAO YC等: "A Single-Crystalline Hierarchical Zeolite via an Oriented Co-Growth of Nanocrystals Based on Synergy of Polyelectrolytes and Hetero-Atoms", CHEMCATCHEM, vol. 12, no. 10, 31 March 2020 (2020-03-31), pages 2702 - 2707 * |
宋烨;林伟;田辉平;龙军;: "不同改性ZSM-5分子筛负载Ni催化剂上1-庚烯芳构化和异构化性能研究", 石油炼制与化工, no. 08, 12 August 2016 (2016-08-12), pages 4 - 9 * |
张妮娜;裴婷;张媛;董昭;张新庄;: "多级孔ZSM-5分子筛的合成及其金属改性研究进展", 山东化工, no. 14, 23 July 2020 (2020-07-23), pages 55 - 57 * |
徐增益等: "双金属催化剂催化臭氧化苯甲酸钠的研究", 现代化工, vol. 41, no. 10, 27 August 2021 (2021-08-27), pages 162 - 167 * |
王瑞浦: "ZSM-5分子筛上1-己烯与正癸烷共进料反应研究", 中国博士学位论文全文数据库 (工程科技Ⅰ辑), no. 2, 15 February 2023 (2023-02-15), pages 017 - 49 * |
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