CN115531218A - Micro-bead skin care product and preparation method thereof - Google Patents
Micro-bead skin care product and preparation method thereof Download PDFInfo
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The invention relates to the field of skin care products, and particularly discloses a micro-bead skin care product and a preparation method thereof. A skin care product comprises water phase and oil phase, wherein the oil phase is uniformly distributed in the water phase in the form of micro-beads. A method for preparing a microgel bead skin care product, comprising: 1) Mixing solvent, humectant, whitening agent, thickener, chelating agent, and antioxidant, and maintaining at 69-71 deg.C to obtain water phase mixture; 2) Mixing castor oil/IPDI copolymer, caprylic/capric triglyceride, triglyceride (ethyl hexanoate), and white Potentilla chinensis seed oil, and heating to 99-101 deg.C to obtain oil phase mixture; 3) Cooling the oil phase mixture to 69-71 deg.C, adding into the water phase mixture at a rotation speed of 30-40r/min, stirring, and cooling to 37-39 deg.C to obtain a premix; 4) Adding pH regulator and skin conditioner, and mixing to obtain the final product. The invention has the advantage of prolonging the persistence of moisture retention in the skin.
Description
Technical Field
The invention relates to the field of skin care products, in particular to a micro-bead skin care product and a preparation method thereof.
Background
The skin care product is a product for protecting skin, can improve the texture of the skin by using the skin care product, and plays a great role in improving the spirit and the image of people.
Moisturizing and moisture-keeping are the most basic functions of skin care products, the horny layer on the surface is easy to fall off due to dry skin, so that the skin is tight, and the skin problem can be effectively improved by moisturizing the skin through the skin care products.
The moisturizing and moisturizing are realized by mainly absorbing water components in the skin care product by the skin to replenish water of the skin and forming a protective barrier by oil components to reduce water loss, so that the moisturizing and moisturizing skin care product generally comprises a water phase component and an oil phase component, and the water phase component and the oil phase component are coated on the surface of the skin in a certain proportion in order to exert the effect better, so that the water phase component and the oil phase component in the skin care product are matched in a certain proportion and uniformly dispersed, and the water and the oil are incompatible, so that the water and the oil are mixed by adding an emulsifier in the existing skin care product.
However, after the emulsifier is added, the water and the oil can be combined, so that when the skin care product is coated on the skin, the water and the oil can contact the skin at the same time, in the coating process, the emulsifying system can be damaged due to the action of external force, the sequence of the water phase and the oil phase absorbed by the skin is very random, and after the oil phase is absorbed firstly, the water phase is difficult to permeate into the skin and blocks the absorption of the water phase, so that a large amount of water phase components are unlikely to be absorbed and evaporated by the skin, the water replenishing and moisturizing effects cannot be exerted to the maximum extent, the persistence of skin moisture can be kept, and therefore, the skin care product has an improvement space.
Disclosure of Invention
In order to prolong the durability of keeping the moisture of the skin, the application provides a micro-bead skin care product and a preparation method thereof.
In a first aspect, the present application provides a microgel skin care product, which adopts the following technical scheme:
a microgel skin care product characterized in that: consists of a water phase and an oil phase, wherein the oil phase is uniformly distributed in the water phase in the form of micro-bead.
By adopting the technical scheme, the oil phase is uniformly distributed in the water phase in the form of micro-bead, so that when the micro-bead skin care product is used, the micro-bead can release oil phase components only by being squeezed through external force, the water phase components can be in contact with the skin preferentially in the smearing process, then the micro-bead of the oil phase can play a certain massage role, then the micro-bead is gradually squeezed through pressure in the smearing process, the oil phase components are released to form a moisturizing layer, the skin is moisturized after moisturizing, the moisturizing effect of the water phase and the moisturizing effect of the oil phase are better and fully played, meanwhile, active ingredients with moisturizing effects can be added into the water phase, the active ingredients can permeate into the skin along with the water phase, the chemical moisturizing effect can be played in the skin, the oil phase covers the skin on the top layer, the physical moisturizing effect can be played, the water phase components absorbed by the skin are prevented from evaporating, the water is better locked into the skin, the active ingredients permeating into the water phase into the skin along with the water phase can be maintained in the skin persistently, the moisturizing effect can be played, the moisturizing effect of the skin can be better, the moisture can be effectively prolonged, and the lasting time of the skin can be prolonged.
Preferably, the diameter of the micro-coagulated beads formed by the oil phase is 0.1-0.2mm.
Through adopting above-mentioned technical scheme, through the little coagulated ball that forms specific diameter for when paining, the pearl can not be crowded brokenly prematurely, makes aqueous phase component by a large amount of absorption back, and the pearl breaks release oil phase component just, makes the skin absorb the process that covers oil phase component behind the aqueous phase component earlier and changes in the realization, thereby realizes the effect of extension moisturizing efficiency of moisturizing better, has prolonged the persistence that keeps skin moisture better.
Preferably, the water phase comprises the following components in parts by mass:
63.7526667 to 64.9931269 parts of solvent;
humectant 17.72713-18.09755 shares;
0.1-0.102 part of whitening agent;
0.308-0.352 parts of thickening agent;
0.029-0.031 parts of chelating agent;
0.00515-0.00517 part of antioxidant;
0.31-0.33 parts of pH regulator;
7.3675931-7.3896133 parts of skin conditioner;
the oil phase comprises the following components in parts by mass:
0.6-0.8 part of castor oil/IPDI copolymer;
2.48-2.52 parts of caprylic/capric triglyceride;
5.58-5.62 parts of glycerol tri (ethyl hexanoate);
0.5-1 part of chinarue seed oil;
the mass ratio of the water phase to the oil phase is 90.06-90.84:9.16-9.94;
the aqueous phase and the oil phase do not contain an emulsifier.
By adopting the technical scheme, the oil phase micro-coagulated beads can be uniformly and stably dispersed in the water phase component through the thickening agent in the water phase, so that the water phase component and the oil phase component in the micro-coagulated bead skin care product are uniformly dispersed, when the micro-coagulated beads are extruded to the skin to be smeared, the water phase component and the oil phase component are in a stable proportion, and the proportion of the water phase component and the oil phase component is kept to ensure the effects of moisturizing the skin.
The oil phase comprises castor oil/IPDI copolymer, caprylic/capric triglyceride, triglyceride (ethyl hexanoate) and meadowfoam seed oil, and is matched with a specific proportion, so that the oil phase can form stable micro beads in the water phase, and is matched with the thickening agent, the micro beads are uniformly dispersed and cannot form layering with the water phase, the micro beads are not easy to break, the effect that the micro beads are broken and released when being smeared on the skin under external force is ensured, the process that the skin firstly absorbs the water phase components and then covers the oil phase components is realized, and the effects of water replenishing and moisture retention are better and lasting.
Through not adding the emulsifier, avoid the emulsifier to destroy the stability that little coagulated beads and water phase mix dispersion for little coagulated beads can be more stably dispersed in the middle of the aqueous phase component, can make aqueous phase component and oil phase component all shaping comparatively transparent state moreover, be difficult for forming turbid phenomenon, make little pearl cosmetics have more beautiful outward appearance, cooperate transparent container, can make little pearl cosmetics have better sight, change in attracting consumers.
Preferably, the thickening agent is a compound of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, cellulose gum and tamarind seed gum.
By adopting the technical scheme, the acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, the cellulose gel and the tamarind seed gel are specifically selected to be compounded to form the thickening agent, and the content of the thickening agent in the water phase is matched, so that the micro beads can be better prevented from floating upwards and layering, and can be more uniformly dispersed in the water phase component, the proportional relation between the water phase component and the oil phase component in the micro bead cosmetics extruded from the container can be better kept, and the effects of water replenishing and moisture retention can be guaranteed.
Preferably, the mass ratio of the acrylic acid (ester)/C10-30 alkanol acrylate crosslinked polymer to the cellulose gum to the tamarind seed gum is 0.19-0.21:0.09-0.11:0.028-0.032.
By adopting the technical scheme, the acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, the cellulose gum and the tamarind seed gum are specifically selected according to the mass ratio, so that the effect of mutual matching of the acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, the cellulose gum and the tamarind seed gum is better, micro-coagulated beads of the oil phase are better kept to be uniformly dispersed in the water phase component, the ratio of the water phase component to the oil phase component is better maintained when the micro-coagulated bead cosmetic is extruded from the container to the skin, and the effect of moisturizing is better.
In a second aspect, the present application provides a method for preparing a microgel skin care product, which adopts the following technical scheme:
the preparation method of the microgel bead skin care product is characterized by comprising the following steps: the method comprises the following steps:
step 1), uniformly mixing a solvent, a humectant, a whitening agent, a thickening agent, a chelating agent, an antioxidant and a preservative until the components are completely dissolved, and keeping the temperature at 69-71 ℃ to obtain a water-phase mixture;
step 2), uniformly mixing the castor oil/IPDI copolymer, caprylic/capric triglyceride, triglyceride (ethyl hexanoate) and meadowfoam seed oil, and heating to 99-101 ℃ to obtain an oil phase mixture;
step 3), cooling the oil phase mixture to 69-71 ℃, adding the oil phase mixture into the water phase mixture at the rotating speed of 30-40r/min, continuously stirring and stopping heating, stirring and cooling to 37-39 ℃ to obtain a premix;
and 4), cooling the premix to 34-36 ℃, adding a pH regulator and a skin conditioner, and uniformly mixing to obtain the micro-bead skin care product.
Through adopting above-mentioned technical scheme, in adding the water phase mixture through the oil phase mixture under 69-71 ℃, the specific rotational speed of cooperation carries out the low-speed stirring, and cool down while stirring, at the in-process of cooling, liquid oil phase mixture solidifies gradually into the pearl, shearing force through stirring bring, make the pearl constantly cut, thereby form the pearl that congeals, stability when adding the water phase mixture through controlling the oil phase mixture, thereby the selection of certain limit that goes on stirring time, through the selection to stirring time and the cooperation of stirring speed, adjust the particle diameter of the pearl that congeals that forms, thereby obtain the pearl that congeals that the particle diameter is 0.1-0.2mm.
The castor oil/IPDI copolymer, the caprylic/capric triglyceride, the triglyceride (ethyl hexanoate) and the meadowfoam seed oil are uniformly mixed and heated to 99-101 ℃, so that the castor oil/IPDI copolymer, the caprylic/capric triglyceride, the triglyceride (ethyl hexanoate) and the meadowfoam seed oil are fully mixed at high temperature, the effect of mutual synergistic cooperation is realized, and the effect of forming the micro-bead shape after cooling is realized.
Preferably, in the step 3), when the oil phase mixture is added into the water phase mixture, the oil phase mixture is uniformly added into the water phase mixture, and the time for adding the oil phase mixture into the water phase mixture is controlled to be 2-3min.
By adopting the technical scheme, the speed of adding the oil phase mixture into the water phase mixture is controlled, the oil phase mixture is prevented from excessively fast entering the water phase mixture in a large amount, the oil phase mixture is easier to stir and cut, micro-coagulated beads with similar diameters and uniform sizes are formed in the cooling process, the oil phase components are more uniformly distributed in the water phase component, the stable proportion of the water phase component and the oil phase component is better ensured when the micro-coagulated bead skin care product is extruded to the skin, and the efficacy and the durability of moisturizing are ensured.
Preferably, in the step 3), when the temperature is reduced to 37-39 ℃ by stirring, the temperature is reduced by a natural cooling mode, and the ambient temperature is kept at 25-30 ℃.
By adopting the technical scheme, the cooling speed and the cooling time are proper through specifically selecting the cooling mode, the formed micro beads are stable in structure and proper in size, when the micro beads are smeared on the skin, the effect that the skin firstly absorbs the water phase components and then covers the oil phase components is better exerted, the water replenishing and moisturizing effects are better, and the durability is longer.
In summary, the present application has the following beneficial effects:
1. according to the skin care product, the oil phase is uniformly distributed in the water phase in a micro-bead shape, so that when the skin care product is used, the oil phase component can be released only by the micro-bead being squeezed through an external force, in the smearing process, the water phase component can be better and preferentially contacted with the skin, then the micro-bead of the oil phase can play a certain massage role, then the micro-bead is gradually squeezed through pressure in the smearing process, the oil phase component is released, a moisturizing layer is formed, the skin is moisturized first and then is moisturized, the moisturizing effect of the water phase and the moisturizing effect of the oil phase are better and fully played, meanwhile, the active component with the moisturizing effect can be added into the water phase, the active component can permeate into the skin along with the water phase, the chemical moisturizing effect can be played in the skin, the oil phase covers the top layer of the skin, the physical moisturizing effect is played, the evaporation of the water phase component absorbed by the skin is blocked in the skin better, the moisture can be kept in the skin along with the water phase, the lasting moisturizing effect can be played, the moisturizing effect is effectively prolonged, and the moisture retention of the skin can be kept for a long time.
2. In the application, the oil phase preferably comprises castor oil/IPDI copolymer, caprylic/capric triglyceride, triglyceride (ethyl hexanoate) and meadowfoam seed oil, and is matched in a specific proportion, so that the oil phase can form stable micro beads in the water phase, and is matched with the thickening agent, the micro beads are uniformly dispersed and cannot form layering with the water phase, the micro beads are not easy to break, the effect that the micro beads are broken and released when being smeared to the skin and subjected to external force is ensured, the process that the skin firstly absorbs water phase components and then covers the oil phase components is realized during use, and the water replenishing and moisturizing effects are better and durable.
3. The method comprises the steps of adding an oil phase mixture into a water phase mixture at 69-71 ℃, matching with a specific rotating speed to carry out low-speed stirring, and cooling while stirring, wherein the liquid oil phase mixture is gradually solidified into coagulated beads in the cooling process, and the coagulated beads are continuously cut by shearing force brought by stirring, so that the coagulated beads are formed, the stability when the oil phase mixture is added into the water phase mixture is controlled, the selection within a certain range of stirring time is carried out, the particle size of the formed coagulated beads is adjusted by matching the selection of the stirring time with the stirring speed, and the coagulated beads with the particle size of 0.1-0.2mm are obtained.
Detailed Description
The present application will be described in further detail with reference to examples.
Examples 1 to 3
A skin care product comprises water phase and oil phase, wherein the oil phase is in form of micro beads, the micro beads are uniformly distributed in the water phase, and the diameter of the micro beads is 0.15 + -0.05 mm.
The aqueous phase consisted of the following components:
solvents, humectants, whitening agents, thickeners, chelating agents, preservatives, antioxidants, pH regulators, skin conditioners.
Wherein the solvent is water.
The humectant is a compound of 1, 3-propylene glycol, glycerol, sorbitol, trehalose, betaine, sodium hyaluronate, methyl glucitol polyether-20, 1, 2-hexanediol, ethylhexyl glycerol, butanediol, 1, 2-pentanediol, and caprylyl hydroximic acid.
The whitening agent is niacinamide.
The thickening agent is a compound of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, cellulose gum and tamarind seed gum.
The chelating agent is disodium EDTA.
The antioxidant is p-hydroxyacetophenone.
The pH regulator is arginine.
The skin conditioner is a compound of an apple fruit cell culture extract, an alpine edelweiss callus extract, a grape fruit cell extract, a bilberry fruit extract, a chamomile extract, an extract of the rhizome/root of dandelion, a Chinese violet extract, a peony root extract, an extract of mallow flower, a honeysuckle flower extract, an aloe vera leaf juice, a yeast extract and a secondary split yeast fermentation product filtrate.
The apple fruit cell culture extract, the alpine edelweiss callus extract, the grape fruit cell extract, the cranberry fruit extract, the chamomile flower extract, the dandelion rhizome/root extract, the Chinese violet extract, the peony root extract, the mallow flower extract and the honeysuckle flower extract are all from the market, and are extracted by water, wherein the ratio of the extracts is 10:1.
aloe vera leaf juice is purchased from Guangzhou Youran Biotech limited.
The yeast extract is purchased from Angel Yeast Ltd.
The secondary fission yeast fermentation product filtrate is purchased from Wuhu Tefei biological products industry research institute, inc.
The oil phase consists of the following components:
castor oil/IPDI copolymer, caprylic/capric triglyceride, tris (ethylhexanoate), meadowfoam seed oil.
In examples 1-3, the specific amounts (in Kg) of each component charged are detailed in Table 1.
TABLE 1
In examples 1 to 3, the microgel bead skin care products were prepared as follows:
step 1), adding water, 1, 3-propylene glycol, glycerol, sorbitol, nicotinamide, trehalose, betaine, acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, sodium hyaluronate, disodium EDTA, cellulose gum, tamarind seed gum, methyl glucitol polyether-20, 1, 2-hexanediol, ethylhexyl glycerol and p-hydroxyacetophenone into a main pot, homogenizing at 2400r/min for 5min, then continuously homogenizing and heating to 85 +/-1 ℃, continuously homogenizing and keeping the temperature for 15min, stopping homogenizing, cooling to 70 ℃, adding butanediol, 1, 2-pentanediol, caprylyl hydroxamic acid, 2400r/min, homogenizing for 3min, keeping the temperature for 70 +/-1 ℃, and obtaining an aqueous phase mixture for later use.
And 2) putting the castor oil/IPDI copolymer, caprylic/capric triglyceride, triglyceride (ethyl hexanoate) and white Potentilla chinensis seed oil into an oil pot, stirring for 3min at the rotation speed of 120r/min, continuously stirring and heating to 100 +/-1 ℃ to obtain an oil phase mixture.
And 3), cooling the oil phase mixture to 70 +/-1 ℃, then adding the oil phase mixture into the water phase mixture at a constant speed, controlling the time for adding the oil phase mixture into the water phase mixture for 2min and the rotating speed to be 30r/min, continuously stirring and stopping heating, keeping the constant temperature at 25 ℃, and naturally cooling the materials in the pot to 38 +/-1 ℃ to obtain the premix.
And 4) stopping stirring, naturally cooling the premix to 35 +/-1 ℃, adding arginine, an apple fruit cell culture extract, an alpine edelweiss callus extract, a grape fruit cell extract, a cranberry fruit extract, a chamomile extract, an extract of roots and stems of dandelion, a Chinese violet extract, a peony root extract, an extract of malva sylvestris, a honeysuckle flower extract, an aloe barbadensis leaf juice, a yeast extract and a bifidus yeast fermentation product filtrate, stirring at the rotating speed of 30r/min for 3min, and uniformly mixing to obtain the microgel skin care product.
Example 4
Compared with example 2, the micro-bead skin care product is different only in that:
the preparation method of the micro-bead skin care product comprises the following steps:
and 3), cooling the oil phase mixture to 70 +/-1 ℃, then adding the oil phase mixture into the water phase mixture at a constant speed, controlling the time for adding the oil phase mixture into the water phase mixture for 3min and the rotating speed to be 40r/min, continuously stirring and stopping heating, keeping the constant temperature environment at 30 ℃, and naturally cooling to reduce the temperature of materials in the pot to 38 +/-1 ℃ to obtain the premix.
Comparative example 1
A skin care product differing from example 2 only in that:
the skin care product also contains 0.2kg of glyceryl stearate and 1kg of cetyl alcohol, and the content of water is adjusted to 64.1728968kg.
Glyceryl stearate and cetyl alcohol are added into the main pot together with water in the step 1) and heated and mixed.
Comparative example 2
A skin care product, which differs from example 2 only in that:
the caprylic/capric triglyceride, the triglyceride (ethyl hexanoic acid) ester and the meadowfoam seed oil are equivalently replaced by the castor oil/IPDI copolymer.
Comparative example 3
A skin care product, which differs from example 2 only in that:
the caprylic acid/capric acid triglyceride is used for replacing the castor oil/IPDI copolymer, the triglyceride (ethyl caproic acid) ester and the meadowfoam seed oil in equal amount.
Comparative example 4
A skin care product, which differs from example 2 only in that:
tri (ethyl hexanoate) is used to replace castor oil/IPDI copolymer, caprylic/capric triglyceride, and meadowfoam seed oil in equal amounts.
Comparative example 5
A skin care product, which differs from example 2 only in that:
the castor oil/IPDI copolymer, caprylic/capric triglyceride, and tri (ethyl hexanoic) ester were replaced with white Potentilla seed oil in equal amounts.
Experiment 1
Physical forms of the micro-bead skin care products prepared in the examples and the skin care products prepared in the respective proportions were observed.
Experiment 2
After face cleaning, the micro-bead skin care products of the examples and the skin care product of the comparative example 1 are respectively used for uniformly smearing the micro-bead skin care product or the skin care product on the face in a smearing massage mode, and the smearing massage time is one minute.
Before the micro-condensed bead skin care product or skin care product is used, the moisture content of the skin is detected by a skin moisture meter CM825 after the face is cleaned, and the moisture content of the skin is detected by the skin moisture meter CM825 again after the micro-condensed bead skin care product or skin care product is used for 2h, 12h and 24h respectively.
The specific assay data for experiment 1 is detailed in table 2.
The specific assay data for experiment 2 is detailed in table 3.
TABLE 2
| Physical form | |
| Example 1 | The micro-beads are uniformly distributed in the water phase, and the micro-beads and the water phase are relatively transparent |
| Example 2 | The micro-beads are uniformly distributed in the water phaseThe medium and the condensed beads and the water phase are relatively transparent |
| Example 3 | The micro beads are uniformly distributed in the water phase, and the micro beads and the water phase are relatively transparent |
| Example 4 | The micro-beads are uniformly distributed in the water phase, and the micro-beads and the water phase are relatively transparent |
| Comparative example 1 | Water and oil compatible to form turbid suspension system without beading |
| Comparative example 2 | Water and oil demixing without beading |
| Comparative example 3 | Water and oil demixing without beading |
| Comparative example 4 | Water and oil stratification without beading |
| Comparative example 5 | Water and oil stratification without beading |
As can be seen from the data in Table 2, the addition of an emulsifier to the aqueous phase results in an increase in the compatibility of the oil phase with the aqueous phase, thereby achieving water-oil intermixing without beading of the oil phase.
When the castor oil/IPDI copolymer, caprylic/capric triglyceride, triglyceride (ethyl hexanoate) or meadowfoam seed oil is adopted alone in the oil phase, the oil phase can not form a bead shape, but forms a water-oil layered state, and only when the castor oil/IPDI copolymer, caprylic/capric triglyceride, triglyceride (ethyl hexanoate) and meadowfoam seed oil are compounded, the oil phase can form a bead shape in the water phase.
TABLE 3
According to the data in table 3, the micro-bead skin care products of examples 1 to 4 form micro-beads, when the oil phase is applied, the water phase and the oil phase are firstly absorbed by the skin, and then the micro-beads gradually break in the application process to release the oil phase, so that the oil phase covers the surface of the skin, and thus the moisturizing and moisturizing effects of the micro-bead skin care products are extremely exerted, so that the persistence of the moisturizing and moisturizing effects is greatly prolonged, while the skin care product of comparative example 1 is added with the emulsifier, and the oil and the water are mixed with each other, so that when the skin care product is used, the sequence of the water phase and the oil phase absorbed by the skin is random, the skin cannot absorb the water phase substances and then covers the oil phase substances, the moisturizing and moisturizing effects are relatively exerted, and particularly the persistence of the skin care product is obviously reduced.
The specific embodiments are only for explaining the present application and are not limiting to the present application, and those skilled in the art can make modifications to the embodiments without inventive contribution as required after reading the present specification, but all the embodiments are protected by patent law within the scope of the claims of the present application.
Claims (8)
1. A micro-bead skin care product is characterized in that: consists of a water phase and an oil phase, wherein the oil phase is uniformly distributed in the water phase in the form of micro-bead.
2. The microgel bead skin care product according to claim 1, wherein: the diameter of the micro-coagulated beads formed by the oil phase is 0.1-0.2mm.
3. A microgel bead skin care product according to claim 1 or 2, wherein: the water phase comprises the following components in parts by mass:
63.7526667-64.9931269 parts of solvent;
humectant 17.72713-18.09755 shares;
0.1-0.102 part of whitening agent;
0.308-0.352 parts of thickening agent;
0.029-0.031 parts of chelating agent;
0.00515-0.00517 part of antioxidant;
0.31-0.33 part of pH regulator;
7.3675931-7.3896133 parts of skin conditioner;
the oil phase comprises the following components in parts by mass:
0.6-0.8 part of castor oil/IPDI copolymer;
2.48-2.52 parts of caprylic/capric triglyceride;
5.58-5.62 parts of glycerol tri (ethyl hexanoate);
0.5-1 part of chinarue seed oil;
the mass ratio of the water phase to the oil phase is 90.06-90.84:9.16-9.94;
the aqueous phase and the oil phase do not contain an emulsifier.
4. A microgel bead skin care product in accordance with claim 3, wherein: the thickening agent is a compound of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, cellulose gum and acid soybean seed gum.
5. The microgel bead skin care product according to claim 4, wherein: the mass ratio of the acrylic acid (ester)/C10-30 alkanol acrylate crosslinked polymer to the cellulose gum to the tamarind seed gum is 0.19-0.21:0.09-0.11:0.028-0.032.
6. A method for preparing a microgel bead skin care product according to any one of claims 1 to 5, wherein: the method comprises the following steps:
step 1), uniformly mixing a solvent, a humectant, a whitening agent, a thickening agent, a chelating agent, an antioxidant and a preservative until the components are completely dissolved, and keeping the temperature at 69-71 ℃ to obtain a water-phase mixture;
step 2), uniformly mixing the castor oil/IPDI copolymer, caprylic/capric triglyceride, triglyceride (ethyl hexanoate) and meadowfoam seed oil, and heating to 99-101 ℃ to obtain an oil phase mixture;
step 3), cooling the oil phase mixture to 69-71 ℃, adding the oil phase mixture into the water phase mixture at the rotating speed of 30-40r/min, continuously stirring and stopping heating, stirring and cooling to 37-39 ℃ to obtain a premix;
and 4), cooling the premix to 34-36 ℃, adding a pH regulator and a skin conditioner, and uniformly mixing to obtain the micro-bead skin care product.
7. The method for preparing a microgel bead skin care product according to claim 6, wherein: in the step 3), when the oil phase mixture is added into the water phase mixture, the oil phase mixture is added into the water phase mixture at a constant speed, and the time for adding the oil phase mixture into the water phase mixture is controlled to be 2-3min.
8. The method for preparing a microgel bead skin care product according to claim 6, wherein: in the step 3), stirring and cooling to 37-39 ℃, cooling in a natural cooling mode, and keeping the ambient temperature at 25-30 ℃.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116251040A (en) * | 2023-03-23 | 2023-06-13 | 深圳市护家科技有限公司 | Cosmetic composition containing particles and preparation method thereof |
| CN116421501A (en) * | 2023-03-23 | 2023-07-14 | 深圳市护家科技有限公司 | Micro-essence composition and preparation method thereof |
| CN116509759A (en) * | 2023-06-29 | 2023-08-01 | 深圳市护家科技有限公司 | Oily particle composition for coating active substance and external skin preparation |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1198513A (en) * | 1966-08-11 | 1970-07-15 | Roussel Uclaf | A Process for the Preparation of Homogeneous Beadlets Incorporating Active Ingredients(s). |
| KR20150116655A (en) * | 2014-04-08 | 2015-10-16 | 주식회사 엘지생활건강 | Cosmetic composition stabilizing insoluble functional ingredient |
| US20150305990A1 (en) * | 2012-10-23 | 2015-10-29 | Genic Co., Ltd. | Oil-in-water form organogel cosmetic composition having variable transparency |
| CN106176325A (en) * | 2016-09-07 | 2016-12-07 | 高宝化妆品（中国）有限公司 | A kind of moisturizing crystallite dew and preparation method thereof |
| CN107019660A (en) * | 2017-04-27 | 2017-08-08 | 养生堂（上海）化妆品研发有限公司 | Moisture-keeping cosmetics composition |
| CN108721132A (en) * | 2018-05-30 | 2018-11-02 | 上海中翊日化有限公司 | A kind of suspension oil droplet toner and preparation method thereof containing Sucrose acetoisobutyrate |
| CN109106681A (en) * | 2018-09-28 | 2019-01-01 | 广东芭薇生物科技股份有限公司 | Micro- solidifying pearl cleawhite over-night essences of one kind and preparation method thereof |
| CN109846792A (en) * | 2018-09-28 | 2019-06-07 | 广东芭薇生物科技股份有限公司 | Micro- solidifying pearl Moisturizer of one kind and preparation method thereof |
| CN110101627A (en) * | 2019-06-18 | 2019-08-09 | 杭州悦萱堂化妆品有限公司 | A kind of essence dew and preparation method thereof with suspension microballon |
| FR3106751A1 (en) * | 2020-02-04 | 2021-08-06 | ABC Texture | Cosmetic composition in the form of an aqueous gel containing in suspension gelled lipid beads in which sun filters are incorporated. |
| CN113274308A (en) * | 2021-07-09 | 2021-08-20 | 泉后(广州)生物科技研究院有限公司 | Two-phase skin care composition and preparation method thereof |
| CN113952892A (en) * | 2021-12-03 | 2022-01-21 | 花安堂生物科技集团有限公司 | Method for preparing suspended micro-droplets by utilizing negative pressure |
-
2022
- 2022-10-24 CN CN202211303264.5A patent/CN115531218B/en active Active
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1198513A (en) * | 1966-08-11 | 1970-07-15 | Roussel Uclaf | A Process for the Preparation of Homogeneous Beadlets Incorporating Active Ingredients(s). |
| US20150305990A1 (en) * | 2012-10-23 | 2015-10-29 | Genic Co., Ltd. | Oil-in-water form organogel cosmetic composition having variable transparency |
| KR20150116655A (en) * | 2014-04-08 | 2015-10-16 | 주식회사 엘지생활건강 | Cosmetic composition stabilizing insoluble functional ingredient |
| CN106176325A (en) * | 2016-09-07 | 2016-12-07 | 高宝化妆品（中国）有限公司 | A kind of moisturizing crystallite dew and preparation method thereof |
| CN107019660A (en) * | 2017-04-27 | 2017-08-08 | 养生堂（上海）化妆品研发有限公司 | Moisture-keeping cosmetics composition |
| CN108721132A (en) * | 2018-05-30 | 2018-11-02 | 上海中翊日化有限公司 | A kind of suspension oil droplet toner and preparation method thereof containing Sucrose acetoisobutyrate |
| CN109106681A (en) * | 2018-09-28 | 2019-01-01 | 广东芭薇生物科技股份有限公司 | Micro- solidifying pearl cleawhite over-night essences of one kind and preparation method thereof |
| CN109846792A (en) * | 2018-09-28 | 2019-06-07 | 广东芭薇生物科技股份有限公司 | Micro- solidifying pearl Moisturizer of one kind and preparation method thereof |
| CN110101627A (en) * | 2019-06-18 | 2019-08-09 | 杭州悦萱堂化妆品有限公司 | A kind of essence dew and preparation method thereof with suspension microballon |
| FR3106751A1 (en) * | 2020-02-04 | 2021-08-06 | ABC Texture | Cosmetic composition in the form of an aqueous gel containing in suspension gelled lipid beads in which sun filters are incorporated. |
| CN113274308A (en) * | 2021-07-09 | 2021-08-20 | 泉后(广州)生物科技研究院有限公司 | Two-phase skin care composition and preparation method thereof |
| CN113952892A (en) * | 2021-12-03 | 2022-01-21 | 花安堂生物科技集团有限公司 | Method for preparing suspended micro-droplets by utilizing negative pressure |
Non-Patent Citations (3)
| Title |
|---|
| 上海家化联合股份有限公司: ""美加净酵米焕活微凝珠精华"", pages 1 - 2, Retrieved from the Internet <URL:https://hzpba.nmpa.gov.cn/gccx/> * |
| 我是NANA: ""迪奥、香奈儿提升颜值的秘术！谁看了不心动？"", pages 1 - 7, Retrieved from the Internet <URL:https://zhuanlan.zhihu.com/p/372558986> * |
| 韩冰;吴继卫;: "羟丙基甲基纤维素制备水凝胶微球", 黑龙江科技信息, no. 05, pages 138 - 139 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116251040A (en) * | 2023-03-23 | 2023-06-13 | 深圳市护家科技有限公司 | Cosmetic composition containing particles and preparation method thereof |
| CN116421501A (en) * | 2023-03-23 | 2023-07-14 | 深圳市护家科技有限公司 | Micro-essence composition and preparation method thereof |
| CN116509759A (en) * | 2023-06-29 | 2023-08-01 | 深圳市护家科技有限公司 | Oily particle composition for coating active substance and external skin preparation |
| CN116509759B (en) * | 2023-06-29 | 2023-08-29 | 深圳市护家科技有限公司 | Oily particle composition for coating active substance and external skin preparation |
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