CN115464954B - 一种抗起球棉服面料及其生产工艺 - Google Patents

一种抗起球棉服面料及其生产工艺 Download PDF

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CN115464954B
CN115464954B CN202211135719.7A CN202211135719A CN115464954B CN 115464954 B CN115464954 B CN 115464954B CN 202211135719 A CN202211135719 A CN 202211135719A CN 115464954 B CN115464954 B CN 115464954B
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parts
fabric
fiber
surface layer
cotton
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CN115464954A (zh
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黄益财
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Wenzhou Mingsheng Clothing Co ltd
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Wenzhou Mingsheng Clothing Co ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
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    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本申请涉及布料加工领域，具体公开了一种抗起球棉服面料及其生产工艺。抗起球棉服面料包括由外之内依次设置的第一面层、中间纤维层和第二面层，所述第一面层由下述重量份的各原料制成：粘胶纤维，舒弹丝纤维，改性腈纶，氨纶，改性尼龙，偶联剂，引发剂，表面整理剂；所述改性腈纶是通过第二单体乙酸乙烯酯和十二烷基硫醇改性制得，所述改性尼龙是通过硅烷偶联剂、偏高岭土和芥酸酰胺改性制得；其生产工艺为：包括以下步骤：裁剪；对混纺面料片进行拉伸；在整体棉服面料上加入表面整理剂；进行杀菌，得到加工好的成品面料。本申请的抗起球棉服面料该组合物可用于制造棉服，其具有抗起球的优点；另外，本申请的制备方法具有容易控制优点。

Description

一种抗起球棉服面料及其生产工艺
技术领域
本申请涉及布料加工领域，更具体地说，它涉及一种抗起球棉服面料及其生产工艺。
背景技术
随着环保和健康的呼声越来越高，越来越多的人们提倡不穿诸如羽绒服等动物类皮毛制成的保暖防寒服，取而代之的是棉服，棉服的变化种类越来越多，技术含量和产品附加值也越来越高，棉服的变化趋向于一体化、简便化、时尚化、环保节能化。棉衣有好几种不同材质，如100％纯棉，纯棉+涤纶，亚麻，羊毛等，大多是以人造棉为主，即合成超细纤维。它可以模仿羽绒的蓬松感，但却有比较好的厌水效果，遇潮湿后也不会丧失保暖性，因为人造棉不吸收水分，只是利用阳光，空气，水，穿戴者的体温，在短时间内快速干燥。
目前，棉服的面料在使用过程中容易起球，进而影响棉服外观，棉服穿了一段时间后起毛起球，是不少消费者在日常生活中可能都遇到过的烦心事，因此起毛起球性能也是考察服装质量极为重要的指标之一，改善棉服面料的抗起球性能是重要的研究课题。
发明内容
为了提高棉服面料的抗起球性能，本申请提供一种抗起球棉服面料及其生产工艺。
第一方面，本申请提供一种抗起球棉服面料，采用如下的技术方案：
一种抗起球棉服面料，包括由外之内依次设置的第一面层、中间纤维层和第二面层，所述第一面层由下述重量份的各原料制成：6-8份粘胶纤维，3-5份舒弹丝纤维，20-35份改性腈纶，10-15份氨纶，4-9份改性尼龙，1-2份偶联剂，0.5-1.2份引发剂，2-4份表面整理剂；所述改性尼龙是通过硅烷偶联剂、偏高岭土和芥酸酰胺改性制得。
通过采用上述技术方案，由于采用粘胶纤维和舒弹丝纤维结合，舒弹丝可与棉、毛、丝、麻、粘胶、涤纶等多种纤维混纺，能适应各种纺纱和印染条件，生产任意规格的产品。在保持其原有特性如舒适性、吸湿性、抗皱性等的基础上，舒弹丝可使面料更具弹性和舒适性，既能提供其他化纤原料无法匹敌的天然手感和悬垂性，又克服了传统氨纶面料弹性回复性差、不耐日晒和多次穿着后弹性松弛变形等缺点，使得第一面层更具有弹性，更加柔软，使得棉服布料穿着舒适，通过改变腈纶中第二单体的成分和添加链转移剂十二烷基硫醇，使得改性后的腈纶抗起球性能增强，提高了棉服面料的柔软性，通过改变聚合物或纤维的化学结构，提高纤维的抗起球性能，链转移剂十二烷基硫醇将长链分子分离开，使得腈纶中的分子量平均，进而使得腈纶柔顺度提高，氨纶纤维所以具有如此高的弹力是因为它的高分子链是由低熔点、无定型的"软"链段为母体和嵌在其中的高熔点、结晶的"硬"链段所组成。柔性链段分子链间以一定的交联形成一定的网状结构，由于分子链间相互作用力小，可以自由伸缩，造成大的伸长性能。刚性链段分子链结合力比较大，分子链不会无限制地伸长，造成高的回弹性，进而使得棉服面料更有弹性，避免了纤维起球，尼龙通过硅烷偶联剂、偏高岭土和芥酸酰胺改性，使得尼龙具有高强度、高韧性和高耐磨性，进而使得棉服面料抗起球的同时提高了面料的耐磨性，添加引发剂和表面整理剂，使得面料中的纤维可以抱合更加密切，使得断裂的纤维表面可以形成保护层，实现了棉服面料抗起球的性能。
优选的，所述改性腈纶的改性剂由下述重量份的各原料制成：23-36份水，5-10份乙酸乙烯酯，3-5份丙烯酸甲酯，2-4份硫酸盐-亚硫酸氢盐体系，5-8份十二烷基硫醇，1.5-3.2份氢氧化钠。
通过采用上述技术方案，乙酸乙烯酯可以使得腈纶提高柔软性，进而使得腈纶不容易变形，提高抗起球性能，溶液聚合是腈纶生产过程中最主要的聚合方法，由于聚丙烯腈中存在着很强的分子间作用力，因此引入适当的共聚单体有利于降低分子间作用力，提升纤维的柔软性。加入硫酸盐-亚硫酸氢盐体系，使得腈纶中的聚合物结合更加紧密，进而减少了纤维的断裂，提高了抗起球性能。加入十二烷基硫醇，使得腈纶柔顺度提高，加入氢氧化钠使得聚合物上形成凹凸的形状，使得纤维之间抱合更加密切，进而提高抗起球性能。
优选的，所述改性尼龙由下述重量份的各原料制成：45-56份尼龙，2-5份碳纤维，10-14份硅烷偶联剂，40-46份芥酸酰胺，12-15份偏高岭土。
通过采用上述技术方案，通过添加碳纤维等纤维状物质，与尼龙树脂经过双螺杆挤出机充分混炼挤出，能够明显改善材料的刚性强度和硬度。尼龙树脂本身具有很多固有的物理性能、化学性能和加工性能，经过挤出机混炼后，可以起到树脂的力学或其他性能，而树脂对材料可以起到粘合和传递载荷的作用，可以通过超细偏高岭土，增加韧性和耐低温性能，可以降低改性尼龙硬化后的脆性，提高冲击强度和伸长率，通过使用硅烷偶联剂，使得尼龙中有机聚合物和无机物质结合在一起，进而提高尼龙的耐磨性，提高混纺面料的抗起球性能。
优选的，所述改性尼龙的改性包括以下步骤：
(1)将碳纤维加入尼龙中，碳纤维与尼龙共混，得到共混物；
(2)在共混物中加入硅烷偶联剂不断搅拌，搅拌过程中加入偏高岭土和芥酸酰胺，共混制得改性尼龙。
通过采用上述技术方案，由于尼龙在共混过程中，在双螺杆挤出机高速剪切作用下，被剪切成一定长度的纤维，并均匀的分布在尼龙基体树脂中，混合挤出过程中，碳纤维会沿轴向方向产生一定程度的取向，当制品受到外力作用时，从基体传到碳纤维时，力的方向会发生变化，即沿取向方向传递，这种传递作用在一定程度上起到外力的分散作用，即能量分散作用，这就增强了材料承受外力作用的能力，在宏观上，显示出材料的拉伸强度、弯曲强度等力学性能的大幅度提高，在尼龙中加入刚性粒子时，通常在提高材料刚性的同时，降低了材料的韧性，填充量越高，其作用越显著，通过硅烷偶联剂和芥酸酰胺，使得尼龙耐磨性能增强，进而使得棉服面料更耐磨的同时抗起球性能也得到了提升。
优选的，所述引发剂为过硫酸铵，所述表面整理剂为双氨基官能团有机硅乳液。
通过采用上述技术方案，过硫酸铵用作四氟乙烯聚合时的引发剂。一些水溶性单体如丙烯酸及其酯、丙烯酰胺、醋酸乙烯酯等聚合或共聚出用其作引发剂，使得混纺后的布料中的纤维结合更加牢固，进而提高面料的抗起球性能，表面整理剂双氨基官能团有机硅乳液，是新一代高档纺织品的柔软整理剂，使得纤维表面形成保护层，摩擦后不易起球，能赋予织物卓越的柔软、平滑效果，适用于各种纤维的制成品。
优选的，所述第二面层包括羊毛纤维、发热纤维和醋酯纤维，所述羊毛纤维、发热纤维和醋酯纤维的质量比为(0.8-1.2)：(2.1-3.6)：(1.6-2.5)。
通过采用上述技术方案，发热纤维的发热性利用吸收人体的皮肤呼吸出来气态汗转换水分放热的过程，吸湿发热纤维水分吸收到饱和状态，放热将停止。释放水分后，再次吸收水分，因此可以重复产生热量，进而对棉服面料有更加保暖的效果，羊毛纤维的缩绒性，羊毛纤维及其织品在湿热条件下，经机械力作用，使羊毛集合体逐渐收缩紧密，并相互穿插纠缠、交编毡化，这种性质称羊毛的缩绒性，可提高织物厚度和紧度，产生整齐的绒面，外观优美，手感丰满，提高保暖性，醋酯纤维的纵向为附有条纹的光滑圆柱形，横断面为椭圆形。由于其结晶度和侧序度低，醋酯纤维的断裂强度差，在湿态时更差，但断裂延伸率高，弹性回复性明显较粘胶纤维强。醋酯纤维的吸湿量在标准条件下为6％-7％，在水中的膨胀性较低，其制成品易于洗涤，甚至用热水洗时几乎不会收缩。
优选的，所述中间纤维层包括连接纱和棉纤维，所述连接纱用于连接所述第一面层与所述第二面层。
通过采用上述技术方案，纤维层包括连接纱和棉纤维，使得棉服面料更加保暖，连接纱使得棉服面料结合为一体，方便对面料进行生产工艺加工。
第二方面，本申请提供一种抗起球棉服面料及其生产工艺，采用如下的技术方案：一种抗起球棉服面料的生产工艺，包括以下步骤：
S1：将第一面层混纺制得的面料和第二面层纺织出的混纺面料进行裁剪，得到混纺面料片；
S2:对混纺面料片进行拉伸，使第一面层和第二面层混纺面料片被撑展平整，然后通过中间纤维层将第一面层与第二面层连接在一起，得到整体棉服面料；
S3:在第一面层上加入表面整理剂，然后对拉伸之后的混纺面料片使用蒸汽进行熨烫；
S4:在熨烫的同时对混纺面料进行杀菌，得到加工好的成品面料。
通过采用上述技术方案，对混纺面料片进行拉伸，使第一面层和第二面层混纺面料片被撑展平整，然后通过中间纤维层将第一面层与第二面层连接在一起，得到整体棉服面料，使得棉服面料更加平整，提高了抗起球的性能，在整体棉服面料上加入表面整理剂，然后对拉伸之后的混纺面料片使用蒸汽进行熨烫，表面整理剂使得面料上形成涂层，使得纤维不会因为摩擦而断裂起球，熨烫后的面料强度变强，不易起球。
综上所述，本申请具有以下有益效果：
1、由于本申请采用粘胶纤维和舒弹丝纤维结合，由于通过改变腈纶中第二单体的成分和添加链转移剂十二烷基硫醇，使得改性后的腈纶抗起球性能增强，提高了棉服面料的柔软性，通过改变聚合物或纤维的化学结构，提高纤维的抗起球性能，链转移剂十二烷基硫醇将长链分子分离开，使得腈纶中的分子量平均，进而使得腈纶柔顺度提高，尼龙通过硅烷偶联剂、偏高岭土和芥酸酰胺改性，使得尼龙具有高强度、高韧性和高耐磨性，进而使得棉服面料抗起球的同时提高了面料的耐磨性，添加引发剂和表面整理剂，使得面料中的纤维可以抱合更加密切，使得断裂的纤维表面可以形成保护层，实现了棉服面料抗起球的性能。
2、本申请中优选采用乙酸乙烯酯和份丙烯酸甲酯结合制得丙烯腈聚合物，乙酸乙烯酯可以使得腈纶提高柔软性，进而使得腈纶不容易变形，提高抗起球性能，溶液聚合是腈纶生产过程中最主要的聚合方法，由于聚丙烯腈中存在着很强的分子间作用力，因此引入适当的共聚单体有利于降低分子间作用力，提升纤维的柔软性。加入硫酸盐-亚硫酸氢盐体系，使得腈纶中的聚合物结合更加紧密，进而减少了纤维的断裂，提高了抗起球性能。加入十二烷基硫醇，使得腈纶柔顺度提高，加入氢氧化钠使得聚合物上形成凹凸的形状，使得纤维之间抱合更加密切，进而提高抗起球性能。
3、本申请的方法，通过对混纺面料片进行拉伸，使第一面层和第二面层混纺面料片被撑展平整，然后通过中间纤维层将第一面层与第二面层连接在一起，得到整体棉服面料，使得棉服面料更加平整，提高了抗起球的性能，在整体棉服面料上加入表面整理剂，然后对拉伸之后的混纺面料片使用蒸汽进行熨烫，表面整理剂使得面料上形成涂层，使得纤维不会因为摩擦而断裂起球，熨烫后的面料强度变强，不易起球。
具体实施方式
以下实施例对本申请作进一步详细说明，予以特别说明的是：以下实施例中未注明具体条件者，按照常规条件或制造商建议的条件进行，以下实施例中所用原料除特殊说明外均可来源于普通市售。
偶联剂为硅烷偶联剂KH-570。
原料和/或中间体的制备例
制备例1
一种改性腈纶的改性剂，由下述重量份的各原料制成：23kg水，5kg乙酸乙烯酯，3kg丙烯酸甲酯，2kg硫酸盐-亚硫酸氢盐体系，5kg十二烷基硫醇，1.5kg氢氧化钠。
制备例2
一种改性腈纶的改性剂，由下述重量份的各原料制成：30kg水，8kg乙酸乙烯酯，4kg丙烯酸甲酯，3kg硫酸盐-亚硫酸氢盐体系，7kg十二烷基硫醇，2.5kg氢氧化钠。
制备例3
一种改性腈纶的改性剂，由下述重量份的各原料制成：36kg水，10kg乙酸乙烯酯，5kg丙烯酸甲酯，4kg硫酸盐-亚硫酸氢盐体系，8kg十二烷基硫醇，3.2kg氢氧化钠。
制备例4
一种改性尼龙，改性尼龙由下述重量份的各原料制成：45kg尼龙，2kg碳纤维，10kg硅烷偶联剂，40kg芥酸酰胺，12kg偏高岭土。
改性尼龙的改性包括以下步骤：
(1)将碳纤维加入尼龙中，碳纤维与尼龙共混，得到共混物；
(2)在共混物中加入硅烷偶联剂不断搅拌，搅拌过程中加入偏高岭土和芥酸酰胺，共混制得改性尼龙。
制备例5
一种改性尼龙，改性尼龙由下述重量份的各原料制成：51kg尼龙，3kg碳纤维，12kg硅烷偶联剂，43kg芥酸酰胺，14kg偏高岭土。
改性尼龙的改性包括以下步骤：
(1)将碳纤维加入尼龙中，碳纤维与尼龙共混，得到共混物；
(2)在共混物中加入硅烷偶联剂不断搅拌，搅拌过程中加入偏高岭土和芥酸酰胺，共混制得改性尼龙。
制备例6
一种改性尼龙，改性尼龙由下述重量份的各原料制成：56kg尼龙，5kg碳纤维，14kg硅烷偶联剂，46kg芥酸酰胺，15kg偏高岭土。
改性尼龙的改性包括以下步骤：
(1)将碳纤维加入尼龙中，碳纤维与尼龙共混，得到共混物；
(2)在共混物中加入硅烷偶联剂不断搅拌，搅拌过程中加入偏高岭土和芥酸酰胺，共混制得改性尼龙。
实施例
实施例1
一种抗起球棉服面料，包括第一面层、第二面层和中间纤维层，第一面层由下述重量份的各原料制成：6kg粘胶纤维，3kg舒弹丝纤维，20kg改性腈纶，10kg氨纶，4kg改性尼龙，1kg偶联剂，0.5kg引发剂，2kg表面整理剂，混纺制得第一面层面料。其中改性腈纶的改性剂是制备例2制得的，改性尼龙是制备例5制得的。
第二面层包括羊毛纤维、发热纤维和醋酯纤维，所述羊毛纤维、发热纤维和醋酯纤维的质量比为0.8：2.1：1.6。
中间纤维层包括连接纱和棉纤维，所述连接纱用于连接所述第一面层与所述第二面层。
一种抗起球棉服面料的生产工艺，包括以下步骤：
S1：将第一面层混纺制得的面料和第二面层纺织出的混纺面料进行裁剪，得到混纺面料片；S2:对混纺面料片进行拉伸，使第一面层和第二面层混纺面料片被撑展平整，然后通过中间纤维层将第一面层与第二面层连接在一起，得到整体棉服面料；
S3:在整体棉服面料上加入表面整理剂，然后对拉伸之后的混纺面料片使用蒸汽进行熨烫；
S4:在高温蒸汽熨烫的同时对混纺面料进行杀菌，得到加工好的成品面料。
实施例2
一种抗起球棉服面料，包括第一面层、第二面层和中间纤维层，所述第一面层由下述重量份的各原料制成：7kg粘胶纤维，4kg舒弹丝纤维，24kg改性腈纶，13kg氨纶，6kg改性尼龙，1.5kg偶联剂，0.8kg引发剂，3kg表面整理剂，混纺制得第一面层面料。其中改性腈纶的改性剂是制备例2制得的，改性尼龙是制备例5制得的。
第二面层包括羊毛纤维、发热纤维和醋酯纤维，所述羊毛纤维、发热纤维和醋酯纤维的质量比为1.0：2.5：1.8。
中间纤维层包括连接纱和棉纤维，所述连接纱用于连接所述第一面层与所述第二面层。
一种抗起球棉服面料的生产工艺，包括以下步骤：
S1：将第一面层混纺制得的面料和第二面层纺织出的混纺面料进行裁剪，得到混纺面料片；S2:对混纺面料片进行拉伸，使第一面层和第二面层混纺面料片被撑展平整，然后通过中间纤维层将第一面层与第二面层连接在一起，得到整体棉服面料；
S3:在整体棉服面料上加入表面整理剂，然后对拉伸之后的混纺面料片使用蒸汽进行熨烫；
S4:在高温蒸汽熨烫的同时对混纺面料进行杀菌，得到加工好的成品面料。
实施例3
一种抗起球棉服面料，包括第一面层、第二面层和中间纤维层，所述第一面层由下述重量份的各原料制成：8kg粘胶纤维，5kg舒弹丝纤维，35kg改性腈纶，15kg氨纶，9kg改性尼龙，2kg偶联剂，1.2kg引发剂，4kg表面整理剂，混纺制得第一面层面料。其中改性腈纶的改性剂是制备例2制得的，改性尼龙是制备例5制得的。
第二面层包括羊毛纤维、发热纤维和醋酯纤维，所述羊毛纤维、发热纤维和醋酯纤维的质量比为1.2：3.6：2.5。
中间纤维层包括连接纱和棉纤维，所述连接纱用于连接所述第一面层与所述第二面层。
一种抗起球棉服面料的生产工艺，包括以下步骤：
S1：将第一面层混纺制得的面料和第二面层纺织出的混纺面料进行裁剪，得到混纺面料片；S2:对混纺面料片进行拉伸，使第一面层和第二面层混纺面料片被撑展平整，然后通过中间纤维层将第一面层与第二面层连接在一起，得到整体棉服面料；
S3:在整体棉服面料上加入表面整理剂，然后对拉伸之后的混纺面料片使用蒸汽进行熨烫；
S4:在高温蒸汽熨烫的同时对混纺面料进行杀菌，得到加工好的成品面料。
对比例
对比例1
一种抗起球棉服面料，与实施例3的不同之处在于：第一面层棉服面料中未添加改性腈纶。
对比例2
一种抗起球棉服面料，与实施例3的不同之处在于：第一面层棉服面料中改性腈纶替换为腈纶。
对比例3
一种抗起球棉服面料，与实施例3的不同之处在于：第一面层棉服面料中未添加改性尼龙。
对比例4
一种抗起球棉服面料，与实施例3的不同之处在于：第一面层棉服面料中改性尼龙替换为尼龙。
对比例5
一种抗起球棉服面料，与实施例3的不同之处在于：第一面层棉服面料中未添加氨纶。
对比例6
一种抗起球棉服面料，与实施例3的不同之处在于：第一面层棉服面料中未添加粘胶纤维。
对比例7
一种抗起球棉服面料，与实施例3的不同之处在于：第一面层棉服面料中未添加舒弹丝纤维。
对比例8
一种抗起球棉服面料，与实施例3的不同之处在于：第一面层棉服面料中未添加表面整理剂。
对比例9
一种抗起球棉服面料，与实施例3的不同之处在于：第二面层棉服面料中未添加发热纤维。
对比例10
一种抗起球棉服面料，与实施例3的不同之处在于：第二面层棉服面料中未添加醋酯纤维。
性能检测试验
力学性能测试：YG061电子纱线强伸度仪。参数的设定参照GB/T14344—2003《合成纤维长丝拉伸性能试验方法》标准。试验在恒温恒湿条件下进行，温度为(20.0±2.0)℃，相对湿度为(65±2)％。
检测方法/试验方法
表1
结合实施例1-实施例3和对比例1-对比例10并结合表1可以看出，实施例3的断裂伸长率较高，断裂强度较高，定向摩擦系数较低，说明改性腈纶和改性尼龙对避免了纤维起球，尼龙通过硅烷偶联剂、偏高岭土和芥酸酰胺改性，使得尼龙具有高强度、高韧性和高耐磨性，进而使得棉服面料抗起球的同时提高了面料的耐磨性，添加引发剂和表面整理剂，使得面料中的纤维可以抱合更加密切，使得断裂的纤维表面可以形成保护层，实现了棉服面料抗起球的性能。
通过观察实施例3和其他实施例的定向摩擦系数，实施例3的摩擦系数明显升高，说明采用了第一面层和第二面层进行配合，从而降低面料纤维在使用过程中存在的定向摩擦效用，使其在使用过程中，进一步改善面料定向摩擦效应，通过采用各个纤维混纺，进一步改善面料的抗起球性能的技术方案是成立的。
本具体实施例仅仅是对本申请的解释，其并不是对本申请的限制，本领域技术人员在阅读完本说明书后可以根据需要对本实施例做出没有创造性贡献的修改，但只要在本申请的权利要求范围内都受到专利法的保护。

Claims (4)

1.一种抗起球棉服面料，其特征在于，包括由外至内依次设置的第一面层、中间纤维层和第二面层，所述第一面层由下述重量份的各原料制成：6-8份粘胶纤维，3-5份舒弹丝纤维，20-35份改性腈纶，10-15份氨纶，4-9份改性尼龙，1-2份偶联剂，0.5-1.2份引发剂，2-4份表面整理剂；所述改性尼龙是通过硅烷偶联剂、偏高岭土和芥酸酰胺改性制得；
改性腈纶的改性剂由下述重量份的各原料制成：23-36份水，5-10份乙酸乙烯酯，3-5份丙烯酸甲酯，2-4份硫酸盐-亚硫酸氢盐体系，5-8份十二烷基硫醇，1.5-3.2份氢氧化钠；
所述改性尼龙由下述重量份的各原料制成：45-56份尼龙，2-5份碳纤维，10-14份硅烷偶联剂，40-46份芥酸酰胺，12-15份偏高岭土；
所述表面整理剂为双氨基官能团有机硅乳液；
所述中间纤维层包括连接纱和棉纤维；
所述第二面层包括羊毛纤维、发热纤维和醋酯纤维，所述羊毛纤维、发热纤维和醋酯纤维的质量比为（0.8-1.2）：（2.1-3.6）：（1.6-2.5）。
2.根据权利要求1所述的一种抗起球棉服面料，其特征在于：所述改性尼龙的改性包括以下步骤：
（1）将碳纤维加入尼龙中，碳纤维与尼龙共混，得到共混物；
（2）在共混物中加入硅烷偶联剂不断搅拌，搅拌过程中加入偏高岭土和芥酸酰胺，共混制得改性尼龙。
3.根据权利要求1所述的一种抗起球棉服面料，其特征在于：所述引发剂为过硫酸铵。
4.如权利要求1所述的一种抗起球棉服面料的生产工艺，其特征在于：包括以下步骤：
S1：将第一面层混纺制得的面料和第二面层纺织出的混纺面料进行裁剪，得到混纺面料片；
S2:对混纺面料片进行拉伸，使第一面层和第二面层混纺面料片被撑展平整，然后通过中间纤维层将第一面层与第二面层连接在一起，得到整体棉服面料；
S3:在第一面层上加入表面整理剂，然后对拉伸之后的混纺面料片使用蒸汽进行熨烫；
S4:在熨烫的同时对混纺面料进行杀菌，得到加工好的成品面料。
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