CN114618552A - 一种3d缺陷态铁单原子催化剂氮化碳的制备及应用 - Google Patents
一种3d缺陷态铁单原子催化剂氮化碳的制备及应用 Download PDFInfo
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- CN114618552A CN114618552A CN202210258884.5A CN202210258884A CN114618552A CN 114618552 A CN114618552 A CN 114618552A CN 202210258884 A CN202210258884 A CN 202210258884A CN 114618552 A CN114618552 A CN 114618552A
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 116
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 title claims abstract description 86
- 230000007547 defect Effects 0.000 title claims abstract description 67
- 239000003054 catalyst Substances 0.000 title claims abstract description 58
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- 238000002360 preparation method Methods 0.000 title description 14
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- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 54
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- 229960000502 poloxamer Drugs 0.000 claims abstract description 18
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- 229940044631 ferric chloride hexahydrate Drugs 0.000 claims abstract description 11
- NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
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- 229910021642 ultra pure water Inorganic materials 0.000 claims description 16
- 239000012498 ultrapure water Substances 0.000 claims description 16
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 15
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- 238000000034 method Methods 0.000 claims description 13
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- 229940032296 ferric chloride Drugs 0.000 claims description 8
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- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 230000003287 optical effect Effects 0.000 claims description 8
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- 239000002351 wastewater Substances 0.000 claims description 8
- 229910052724 xenon Inorganic materials 0.000 claims description 8
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 claims description 8
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- 239000004098 Tetracycline Substances 0.000 abstract description 23
- 229960002180 tetracycline Drugs 0.000 abstract description 23
- 229930101283 tetracycline Natural products 0.000 abstract description 23
- 235000019364 tetracycline Nutrition 0.000 abstract description 23
- 150000003522 tetracyclines Chemical class 0.000 abstract description 23
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- CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical compound [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 description 2
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/02—Specific form of oxidant
- C02F2305/026—Fenton's reagent
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
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- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
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Abstract
Description
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CN202210258884.5A CN114618552B (zh) | 2022-03-16 | 2022-03-16 | 一种3d缺陷态铁单原子催化剂氮化碳的制备及应用 |
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CN202210258884.5A CN114618552B (zh) | 2022-03-16 | 2022-03-16 | 一种3d缺陷态铁单原子催化剂氮化碳的制备及应用 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN115448266A (zh) * | 2022-09-20 | 2022-12-09 | 安徽理工大学 | 一种三氧化二铁结合的α和β复合相氮化碳材料的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109603885A (zh) * | 2019-01-09 | 2019-04-12 | 天津大学 | 一种光辅助单原子催化降解水体中草甘膦的方法 |
CN109908936A (zh) * | 2019-03-14 | 2019-06-21 | 浙江师范大学 | 一种可见光响应的锰单原子负载氮化碳催化剂及其制备方法和应用 |
CN110449176A (zh) * | 2019-08-16 | 2019-11-15 | 江南大学 | 一种非贵金属单原子催化剂的制备方法及应用 |
CN113042082A (zh) * | 2021-03-24 | 2021-06-29 | 中南林业科技大学 | 一种单原子催化剂的制备方法与用途 |
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- 2022-03-16 CN CN202210258884.5A patent/CN114618552B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109603885A (zh) * | 2019-01-09 | 2019-04-12 | 天津大学 | 一种光辅助单原子催化降解水体中草甘膦的方法 |
CN109908936A (zh) * | 2019-03-14 | 2019-06-21 | 浙江师范大学 | 一种可见光响应的锰单原子负载氮化碳催化剂及其制备方法和应用 |
CN110449176A (zh) * | 2019-08-16 | 2019-11-15 | 江南大学 | 一种非贵金属单原子催化剂的制备方法及应用 |
CN113042082A (zh) * | 2021-03-24 | 2021-06-29 | 中南林业科技大学 | 一种单原子催化剂的制备方法与用途 |
Non-Patent Citations (2)
Title |
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SUFENG AN 等: "High-Density Ultra-small Clusters and Single- Atom Fe Sites Embedded in Graphitic Carbon Nitride (g‑C3N4) for Highly Efficient Catalytic Advanced Oxidation Processes", 《NANO》, vol. 12, pages 9441 * |
叶珊珊 等: "缺陷型石墨相氮化碳光催化剂的制备与应用研究进展", 《科学通报》, vol. 66, no. 30, pages 3822 - 3838 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115448266A (zh) * | 2022-09-20 | 2022-12-09 | 安徽理工大学 | 一种三氧化二铁结合的α和β复合相氮化碳材料的制备方法 |
CN115448266B (zh) * | 2022-09-20 | 2023-07-21 | 安徽理工大学 | 一种三氧化二铁结合的α和β复合相氮化碳材料的制备方法 |
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Effective date of registration: 20240325 Address after: Room 1013, 10th Floor, Unit 1, East Group, New City New World Phase III, No. 139 Laodong East Road, Guitang Street, Yuhua District, Changsha City, Hunan Province, 410007 Patentee after: Hunan Zhongda Zhijie Technology Co.,Ltd. Country or region after: China Address before: School of environmental science and engineering, Central South University of forestry science and technology, No. 498, Shaoshan South Road, Changsha City, Hunan Province, 410004 Patentee before: CENTRAL SOUTH University OF FORESTRY AND TECHNOLOGY Country or region before: China |