CN114317134A - Floor cleaning agent - Google Patents
Floor cleaning agent Download PDFInfo
- Publication number
- CN114317134A CN114317134A CN202111455199.3A CN202111455199A CN114317134A CN 114317134 A CN114317134 A CN 114317134A CN 202111455199 A CN202111455199 A CN 202111455199A CN 114317134 A CN114317134 A CN 114317134A
- Authority
- CN
- China
- Prior art keywords
- cleaning agent
- floor cleaning
- deodorant
- solvent
- insect repellent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 24
- 239000002781 deodorant agent Substances 0.000 claims abstract description 27
- 239000000077 insect repellent Substances 0.000 claims abstract description 20
- 239000002904 solvent Substances 0.000 claims abstract description 17
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 claims description 2
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 2
- FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 claims description 2
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 2
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 claims description 2
- -1 alkyl glycoside Chemical class 0.000 claims description 2
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical group C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 229930182470 glycoside Natural products 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 15
- 241000894006 Bacteria Species 0.000 abstract description 6
- 230000002401 inhibitory effect Effects 0.000 abstract description 3
- 244000045947 parasite Species 0.000 abstract description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract description 3
- 229910019142 PO4 Inorganic materials 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 2
- 239000010452 phosphate Substances 0.000 abstract description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 19
- 239000004744 fabric Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 12
- 229910021529 ammonia Inorganic materials 0.000 description 11
- 241000255925 Diptera Species 0.000 description 10
- 238000004140 cleaning Methods 0.000 description 7
- 241000238631 Hexapoda Species 0.000 description 6
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- 230000000474 nursing effect Effects 0.000 description 5
- 230000001846 repelling effect Effects 0.000 description 5
- 238000004332 deodorization Methods 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000003385 bacteriostatic effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000001877 deodorizing effect Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 241000256173 Aedes albopictus Species 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 241000258963 Diplopoda Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 208000036071 Rhinorrhea Diseases 0.000 description 1
- 206010039101 Rhinorrhoea Diseases 0.000 description 1
- MQTPMDMFXZTBDK-UHFFFAOYSA-N [Na+].Cl[O-].OC(=O)C1=CC=CC=C1O Chemical compound [Na+].Cl[O-].OC(=O)C1=CC=CC=C1O MQTPMDMFXZTBDK-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000000022 bacteriostatic agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- GCLHJQAARCBHBB-UHFFFAOYSA-N ethyl sulfate;morpholin-4-ium Chemical compound C1COCC[NH2+]1.CCOS([O-])(=O)=O GCLHJQAARCBHBB-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 229940100530 zinc ricinoleate Drugs 0.000 description 1
- GAWWVVGZMLGEIW-GNNYBVKZSA-L zinc ricinoleate Chemical compound [Zn+2].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O GAWWVVGZMLGEIW-GNNYBVKZSA-L 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a floor cleaning agent, which comprises a nonionic surfactant, an insect repellent, a deodorant and a solvent; the insect repellent is a pair
Description
Technical Field
The invention belongs to the technical field of household cleaning and nursing, and particularly relates to a floor cleaning agent.
Background
At present, home cleaning and nursing are more and more emphasized, people do not simply consider that the home cleaning and nursing only cleans stains and dust, but keep the environment and articles clean and comfortable, and pay more attention to the problems of mosquito, bacteria breeding, environmental odor and the like. Therefore, the demand for household cleaning and nursing with multiple functions is increasing.
Wherein, the floor cleaning agent used as a main household cleaning and nursing product generally adopts a water-based system and is used for removing various dirt on the floor, such as oil stain, dust and the like; however, the existing floor cleaners have only a simple cleaning effect, and thus it is difficult to satisfy the needs of most families, especially those of nursery and pet-raising families, based on various household environmental problems such as the above-mentioned problems of mosquitoes, bacteria and bad smell.
In addition, the floor cleaning agent is required to be capable of penetrating and removing dirt on the floor, and to have a strong detergency, and is also required to be harmless to the human body and safe to the environment.
Disclosure of Invention
The invention aims to provide a floor cleaning agent which can clean floors and achieve the effects of expelling parasites, removing peculiar smell and inhibiting bacteria.
The purpose of the invention is realized by the following technical scheme:
a floor cleaning agent comprises nonionic surfactant, insect repellent, deodorant, and solvent; the insect repellent is a pair
An alkane-3, 8-diol, said deodorant having the structure:
wherein R is1Is C14, C16, C18 or C20 alkyl, R2Is methyl, ethyl or propyl, R3Is methylene, ethylene or propylene.
Firstly, the invention compounds the pair in the existing system of floor cleaning agent
Alkane-3, 8-diol (CAS number 42822-86-6) and deodorant with specific structure can make floor cleaning agent have the effects of expelling parasite and removing odor. Wherein the selected pairs of the present invention
The alkane-3, 8-diol can effectively act on mosquitoes,Rhinorrhea, millipedes, etc., which have long effective time and low toxicity, and are the only natural active components of insect repellents allowed to be used in the United states and European Union; the deodorant adopted by the invention is sulfate or phosphate with a specific structure, and the concentration of the positive charges of quaternary ammonium salt cationic groups in the structure is combined with lone pair electrons in nitrogen or sulfur atoms in organic molecules with peculiar smell, or the organic molecules with peculiar smell are neutralized, so that the deodorant can quickly and stably deodorize; compared with the existing deodorant, such as zinc ricinoleate and soyabean ethyl sulfate morpholine, the deodorant has the characteristics of stable illumination performance, difficult yellowing, strong compounding capability and the like, and can be applied to an anionic surfactant system, a cationic surfactant system and a nonionic surfactant system; moreover, the inventor researches and discovers that the deodorant has a certain bacteriostatic action.
Secondly, the floor cleaning agent disclosed by the invention adopts a nonionic surfactant compounded solvent, so that stains are effectively cleaned, wherein the solvent can increase the permeation effect on stubborn dirt and improve the detergency of a system.
Moreover, through the research of the inventor, the insect repellent and the deodorant selected by the invention can be stably compatible in a system with a surfactant, and simultaneously, the insect repellent and the deodorant have the due deodorizing and insect repelling effects and have a synergistic effect, so that the insect repellent and the deodorant can achieve an unexpected antibacterial effect under the condition that no antibacterial agent is added when the insect repellent and the deodorant are matched for use, and the insect repellent and the deodorant effects of the floor cleaning agent are further improved.
Through the research of the inventor, the reason why the insect repellent and the deodorant can synergistically improve the odor-removing, insect-repelling and bacteriostatic effects of the formula system is presumed as follows: 1. the deodorant is characterized by the presence of negatively charged sulfate groups or phosphate groups, and
the hydroxyl group of the alkane-3, 8-diol acts to form a larger molecular structure which has stronger penetrating power to the cell membrane of bacteria and reaction activity to peculiar smell molecules than any single component,thereby generating better bacteriostasis effect and odor removing effect; 2. the deodorant reacts with odor molecules to reduce the odor of the floor, thereby reducing the odor of the floor
The alkane-3, 8-diol can more effectively exert the function of repelling insects by the smell of the alkane-3, 8-diol.
The floor cleaning agent comprises the following components in percentage by mass: 0.5-1% of nonionic surfactant, 2-5% of solvent, 0.2-0.5% of insect repellent and 5% of deodorant.
The nonionic surfactant is preferably one or more of alkyl glycoside and fatty alcohol-polyoxyethylene ether.
The solvent is preferably one or more of an alcohol solvent and an alcohol ether solvent.
Further, the solvent is one or more of ethanol, isopropanol, 2-methyl-2, 4-pentanediol, propylene glycol propyl ether, propylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol propyl ether and dipropylene glycol butyl ether.
Compared with the prior art, the invention has the following beneficial effects:
the floor cleaning agent of the invention is compounded with deodorant and pair with specific structures
The alkane-3, 8-diol and the alkyl-3, 8-diol have a synergistic effect, can quickly and stably deodorize and effectively expel insects, achieve an unexpected antibacterial effect under the condition of not adding any bacteriostatic agent, and further improve the insect expelling and deodorizing effects of the system;
the deodorant and the insect repellent can be stably compatible in a formula system, so that the floor cleaning agent has a cleaning effect and also has the effects of expelling insects, removing peculiar smell and inhibiting bacteria; and the formula system is mild, harmless to human body and safe to environment.
Detailed Description
The present invention will be further described with reference to the following specific examples.
The floor cleaning agents of examples 1 to 9 and comparative examples 1 to 12 were prepared according to the formulations of tables 1 to 4, and the specific preparation method was:
(1) adding sufficient water, starting stirring and heating, heating to 50-60 ℃, adding a nonionic surfactant, and stirring until the nonionic surfactant is completely dissolved;
(2) preserving heat, sequentially adding the insect repellent, the deodorant and the solvent, and stirring until the insect repellent, the deodorant and the solvent are completely dissolved;
(3) cooling to below 45 deg.C, and adding appropriate amount of essence; and continuously cooling to normal temperature to obtain the floor cleaning agent.
The floor cleaning agents of examples 1 to 6 and comparative examples 1 to 12 were tested for antibacterial effect, deodorizing effect, and mosquito repellent effect, and then compared.
Among them, 6 kinds of deodorants specifically used in examples and comparative examples are the following structures in order to illustrate the scheme of the present invention:
TABLE 1
TABLE 2
TABLE 3
TABLE 4
The test method of the antibacterial effect, the deodorization effect and the mosquito repellent effect comprises the following steps:
1. and (3) testing the antibacterial effect:
the test method comprises the following steps: the test is carried out according to a 7.3 suspension quantitative method in standard QB/T2738-2012 'evaluation of antibacterial and bacteriostatic effects of daily chemical products', the test concentration of the sample is 1% solution, and the action time is 5 minutes.
2. And (3) testing the deodorization effect:
the test method comprises the following steps: the odor eliminating performance of the soaked fabric is tested by taking ammonia gas as odor, the fabric material is selected from rabbit hair or wool, the soaking method is to soak the fabric material in 1 percent solution for 10 minutes without water, the fabric material is dried at room temperature, and the soaking solution adopts the formula listed in the embodiment. Cutting the fabric into a circle with the diameter of 4cm, sucking 0.1mL of ammonia water on a glass dish, placing the glass dish at the bottom of a dryer, placing the fabric on a tray of the dryer, sucking ammonia for 14h, and extracting with 100.0mL of distilled water at 40 ℃ for 2h after the ammonia sucking is finished. The ammonia content in the extraction liquid is measured by adopting HJ 534-2009 sodium hypochlorite-salicylic acid spectrophotometry for measuring ammonia in environmental air, and the deodorization rate of the soaked fabric is indirectly obtained by dividing the difference value of the ammonia adsorbed on the fabric which is not soaked and the soaked fabric by the difference value of the total ammonia adsorbed on the fabric which is not soaked and the ammonia adsorbed on the fabric which is not soaked.
The deodorization ratio (ammonia adsorption on soaked fabric-ammonia adsorption on non-soaked fabric)/(total ammonia amount-ammonia adsorption on non-soaked fabric) is multiplied by 100%
3. Mosquito repelling rate test
Reference standard GB/T13917.9-2009 "pesticide registration hygienic insecticide indoor efficacy test and evaluation part 9: repellents (repellents);
test insects: aedes albopictus (Aedes albopictus), uninoculated female adults 4-7 days after emergence;
the test conditions are as follows: the temperature is 25 +/-2 ℃, and the relative humidity is 60-70%;
the test method comprises the following steps: selecting 4 qualified testers, circling skin area of 50mm × 50mm on each side of their both hands, wherein the 1% solution smearing amount of sample for one hand is 1.5 μ L/cm2The dosage of (a) was applied, exposing 40mm x 40mm of skin, closely covering the rest, and blank on the other hand. Immediately after smearing, the repellency rate test is carried out. Each tester puts the control hand into the mosquito cage, and immediately times, records the number of mosquito stops and the testing time is 5 minutes. The tester then places the hands coated with the sample into a mosquito cage, tests in the same manner and records the number of mosquito stalls. The repellency rate was calculated from replicate test data as follows:
P＝(N-K)/N×100％
in the formula, P is the repelling rate,%; n is the total number of the control hand mosquitoes in unit of 'one'; k is the total number of the hand mosquitoes which are washed by the sample, and the unit is 'only'.
It should be noted that the above-mentioned embodiments are only illustrative and not restrictive, and any modifications or changes within the meaning and range of equivalents to the technical solutions of the present invention by those skilled in the art should be considered to be included in the protection scope of the present invention.
Claims (5)
1. A floor cleaning agent is characterized by comprising a nonionic surfactant, an insect repellent, a deodorant and a solvent; the insect repellent is a pair
An alkane-3, 8-diol, said deodorant having the structure:
wherein R is1Is C14, C16, C18 or C20 alkyl, R2Is methyl, ethyl or propyl, R3Is methylene, ethylene or propylene.
2. The floor cleaning agent according to claim 1, wherein the additive amount of each component is as follows by mass percent: 0.5-1% of nonionic surfactant, 2-5% of solvent, 0.2-0.5% of insect repellent and 1-5% of deodorant.
3. The floor cleaning agent according to claim 1 or 2, wherein the nonionic surfactant is one or more of alkyl glycoside and fatty alcohol-polyoxyethylene ether.
4. The floor cleaning agent according to claim 1 or 2, wherein the solvent is one or more of an alcohol solvent and an alcohol ether solvent.
5. The floor cleaning agent according to claim 4, wherein the solvent is one or more selected from the group consisting of ethanol, isopropanol, 2-methyl-2, 4-pentanediol, propylene glycol propyl ether, propylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol propyl ether, and dipropylene glycol butyl ether.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111455199.3A CN114317134B (en) | 2021-11-30 | 2021-11-30 | Floor cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111455199.3A CN114317134B (en) | 2021-11-30 | 2021-11-30 | Floor cleaning agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114317134A true CN114317134A (en) | 2022-04-12 |
| CN114317134B CN114317134B (en) | 2023-10-20 |
Family
ID=81049386
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111455199.3A Active CN114317134B (en) | 2021-11-30 | 2021-11-30 | Floor cleaning agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114317134B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115895797A (en) * | 2022-12-14 | 2023-04-04 | 中山榄菊日化实业有限公司 | Floor cleaning agent with insect expelling effect |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010248126A (en) * | 2009-04-16 | 2010-11-04 | Dainippon Jochugiku Co Ltd | Insecticide for rice tub |
| JP2011026290A (en) * | 2009-06-27 | 2011-02-10 | Dainippon Jochugiku Co Ltd | Mite repellent for bedding |
| JP2011195512A (en) * | 2010-03-19 | 2011-10-06 | Dainippon Jochugiku Co Ltd | Moth repellent for bedding |
| CN112043612A (en) * | 2020-08-19 | 2020-12-08 | 广州市浪奇实业股份有限公司 | Low-sensitivity mosquito-proof composition without organic solvent |
-
2021
- 2021-11-30 CN CN202111455199.3A patent/CN114317134B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010248126A (en) * | 2009-04-16 | 2010-11-04 | Dainippon Jochugiku Co Ltd | Insecticide for rice tub |
| JP2011026290A (en) * | 2009-06-27 | 2011-02-10 | Dainippon Jochugiku Co Ltd | Mite repellent for bedding |
| JP2011195512A (en) * | 2010-03-19 | 2011-10-06 | Dainippon Jochugiku Co Ltd | Moth repellent for bedding |
| CN112043612A (en) * | 2020-08-19 | 2020-12-08 | 广州市浪奇实业股份有限公司 | Low-sensitivity mosquito-proof composition without organic solvent |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115895797A (en) * | 2022-12-14 | 2023-04-04 | 中山榄菊日化实业有限公司 | Floor cleaning agent with insect expelling effect |
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| CN114317134B (en) | 2023-10-20 |
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