KR20080087609A - Spray composition for sterilization and deodorization - Google Patents

Abstract

A spray composition for sterilization and deodorization is provided to exterminate various germs and molds that exist in various articles like clothing, a carpet, a bed, etc. A spray composition for sterilization and deodorization contains 0.1-2 weight% of 2,4,4-trichloro-2-hydroxy diphenyl ethers, 0.1-2 weight% of quaternary ammonium salt, 0.1-0.5 weight% of lavender extract, 2-10 weight% of polyoxyethylene sorbitan monooleate, 2-10 weight% of polyoxyethylene lauryl ether, 10-20 weight% of ethanol and 77-85.7 weight% of purified water. The lavender extract is obtained through vapor distillation of lavender flowers. Rosemary extract is able to be used as a substitute for the lavender extract.

Description

Spray composition for antibacterial deodorization {Spray composition for sterilization and deodorization}

1 is a graph showing the deodorizing effect of removing the smell of ammonia (NH ₃ ) using the antimicrobial deodorant spray composition according to the present invention;

Figure 2 relates to a graph showing the deodorizing effect of removing the smell of trimethylamine (TMA) using the antibacterial deodorant spray composition according to the present invention.

The present invention relates to an antimicrobial deodorant spray composition, and more particularly, it is excellent among effective ingredients such as 2,4,4-trichloro-2-hydroxy diphenyl ether, quaternary ammonium salt and lavender extract. It relates to an antimicrobial deodorant spray composition characterized in that it can perform the function of excellent antibacterial and deodorant against various bacteria, fungi, algae, etc. using the synergistic effect.

In general, the indoor environment of the house where people live is contaminated by various fungi such as bacteria and fungi that cannot be recognized by people's eyes, and especially when storing cooked food during the summer season, various germs are easily eaten. Odor generated by easily breeding through garbage, etc., not only gives an unpleasant feeling, but also has a harmful effect on people's health by various inhabitants. For example, the bed is inhabited by various bacteria such as mold, bacteria, and ticks, and house dust mites live in the bed while eating human dandruff or keratin, releasing harmful excreta. In addition, in the case of shoes, because the sweat easily inside the various bacteria easily proliferate, these bacteria are causing such as athlete's foot.

On the other hand, the moisture standing on the wall during the rainy season is easy to create an environment in which the fungus, etc. are causing the various diseases that occur in humans. In addition, in the case of clothing mold, mold is more likely to occur in cotton fiber, which is carbon-based than the main fiber of protein, and mold spores existing in clothes, carpets, and sofas float with dust when the room is dry, and various respiratory diseases Particular attention should be paid to the cause. In the case of washing clothes by normal washing, when the washing is completed, some bacteria and microorganisms are removed along with contamination. When dried or preserved, an unpleasant and nasty smell derived from bacteria is produced. In addition, clothing and towels are not unpleasant and unfavorable from a hygienic point of view, since a sample derived from sweat or sebum adheres to the fibers. As a method of removing nasty smells from such garments, a combination of perfumes, cyclodextrins and zinc salts, and sprays containing seaweed extracts and quaternary ammonium salts has been developed and used. Most of the type deodorants are effective for the purpose of urgent portable deodorization or for local use. However, these deodorants are not effective when deodorizing and treating textile products such as clothing or bath towels at home. There is a problem in the economic burden because it is weak to spray a large amount of deodorant.

The present invention utilizes excellent synergistic effects among active ingredients such as 2,4,4-trichloro-2-hydroxy diphenyl ether, quaternary ammonium salts, and lavender extracts to provide excellent antibacterial and deodorant properties for various bacteria, fungi, algae, and the like. Antibacterial deodorant, characterized in that by using the antimicrobial deodorant spray composition prepared to perform the function to kill various bacteria and fungi present in articles such as clothing, carpet, bed, etc. and to remove the smell The purpose is to provide a spray composition for use.

In particular, the present invention is characterized in that the cause of the bad smell can be fundamentally removed by removing the bacteria and fungi as the bad smell occurs as organic matter is decomposed by various bacteria and fungi.

According to a feature of the present invention for achieving the above object, the present invention in the antimicrobial deodorant spray composition,

0.1 to 2 wt% of 2,4,4-trichloro-2-hydroxy diphenyl ether, 0.1 to 2 wt% of quaternary ammonium salt, and 0.1 to 0.5 wt% of lavender extract, polyoxyethylene sorbent It is characterized by consisting of 2 to 10% by weight of non-molecular monooleate, 2 to 10% by weight of polyoxyethylene lauryl ether, 10 to 20% by weight of ethanol and 77 to 85.7% by weight of purified water.

And the antimicrobial deodorant spray composition according to the present invention is Streptococus piogenes ( Streptococus As a particularly effective composition for the sterilization of pyogenes ) and Pseudomonas aeruginosa , it is preferred for use in the use of textile products.

In addition, the antimicrobial deodorant spray composition according to the present invention, the lavender extract is characterized in that obtained by distilling the lavender flowers.

Hereinafter, the antimicrobial deodorant spray composition according to the present invention will be described in more detail.

2,4,4-trichloro-2-hydroxy diphenyl ether to be used in the antimicrobial deodorant spray composition according to the present invention is commonly referred to as triclosan, which is a compound represented by the following [Formula 1] It has excellent stability and has excellent antiseptic and antibacterial activity against microorganisms such as pathogenic fungi, Escherichia coli and Staphylococcus aureus. In the present invention, the content of 2,4,4-trichloro-2-hydroxy diphenyl ether is preferably 0.1 to 2% by weight based on the total weight of the composition. When the content of 2,4,4-trichloro-2-hydroxy diphenyl ether is less than 0.1% by weight, the effects described above are insignificant, and when the amount of 2,4,4-trichloro-2-hydroxydiphenylether is more than 2% by weight, there are problems of safety and formulation stability. It may occur.

In addition, the quaternary ammonium salt used in the present invention is an antifungal agent having excellent bactericidal action against fungal infections. The content of the quaternary ammonium salt is preferably 0.1 to 2% by weight based on the total weight of the composition.If the content of the quaternary ammonium salt is less than 0.1% by weight, the effects described above are insignificant, and if it is 2% by weight or more, There is a fear that problems with formulation stability occur.

Quaternary ammonium salts that can be used in the present invention are cetyl ammonium chloride, cetyl ammonium bromide, lauryl ammonium chloride, lauryl ammonium bromide, stearyl ammonium chloride, stearyl ammonium bromide, cetyl dimethyl ammonium chloride, cetyl dimethyl ammonium bromide, lauryl Dimethyl ammonium chloride, lauryl dimethyl ammonium bromide, stearyl dimethyl ammonium chloride, stearyl dimethyl ammonium bromide, cetyl trimethyl ammonium chloride, cetyl trimethyl ammonium bromide, lauryl trimethyl ammonium chloride, lauryl trimethyl ammonium bromide, stearyl trimethyl ammonium chloride, Stearyl Trimethyl Ammonium Bromide, Lauryl Dimethyl Ammonium Chloride, Dicetyl Ammonium Chloride, Dicetyl Ammonium Bromide, Dilauryl Cancer Chloride, dilauryl ammonium bromide, distearyl ammonium chloride, distearyl ammonium bromide, dicetyl methyl ammonium chloride, dicetyl methyl ammonium bromide, dilauryl methyl ammonium chloride, dilauryl methyl ammonium bromide, distearyl methyl ammonium chloride 1, or more selected from distearyl methyl ammonium bromide and mixed may be used.

And the quaternary ammonium salt, it is more preferable to use that the C ₈ to C ₃₀ alkyl carbon chain derived from tallow fatty acid or coconut fatty acid. Uji generally refers to alkyl groups derived from Uji fatty acids (usually hydrogenated Uji fatty acids) that have a mixture of C ₁₆ to C ₁₈ alkyl chains. Coconuts are generally due to alkyl groups derived from coconut fatty acids which have a mixture of alkyl chains in C ₁₄ in the C ₁₂ range. Examples of quaternary ammonium salts derived from tallow and coconut include ditallow dimethyl ammonium chloride, ditallow dimethyl ammonium methyl sulfate, di (hydrogenated tallow) dimethyl ammonium chloride, di (hydrogenated tallow) dimethyl ammonium acetate, ditalo Woodypropyl Ammonium Phosphate, Ditlow Dimethylammonium Nitrate, Di (coconuttalyl) dimethyl Ammonium Chloride, Di (coconuttalyl) dimethyl Ammonium Bromide, Tallow Ammonium Chloride, Coconut Ammonium Chloride, Stearamidopropyl PG-Dimonium Chloride Phosphate , Stearamidopropyl ethyldimonium ethosulfate, stearamidopropyl dimethyl (myristyl acetate) ammonium chloride, stearamidopropyl dimethyl ceteryl ammonium tosylate, stearamidopropyl dimethyl ammonium chloride, stearyl Shown propyl dimethyl ammonium Using a mixture by selecting one or more from the lactate.

The lavender extract in the present invention is a natural antimicrobial agent used as an active ingredient having an antimicrobial effect, and is preferably obtained by steam distillation from lavender flowers. It has astringent, bactericidal and antibacterial action. Ravenda extract also increases immune function, affects the internal organs, glands, and hormones, and increases resistance to bacterial viruses and fungi, affecting a wide range of skin diseases.

In the present invention, the content of the lavender extract is preferably 0.1 to 0.5% by weight based on the total weight of the composition. If the content of the lavender extract is less than 0.1% by weight, it is difficult to achieve the effect. When the content of the lavender extract exceeds 0.5% by weight, the production cost is increased. There is a concern that product stability may occur with economical loss.

The term "lavender extract" referred to in the present invention includes not only the flower extract of lavender but also the active ingredient itself having an antibacterial deodorizing function.

Lavanda is native to the Mediterranean coast and is a perennial plant of evergreen small trees. It grows to about 1m in size and blooms purple, purple, pink and white from June to August depending on the type. The plant has a violet rich scent that relaxes the mind throughout the plant, and once planted, has the advantage of being harvested and used continuously for 6-10 years. When harvesting flowers, pick a sunny day before the buds open and cut the stems and dry them in a well-ventilated shade. The name of Lavanda is Lavandula sp. , And there are over 40 varieties of varieties. The representative species is Lavandula. angustifolia ), fringe dravenda ( L. stoechas ), and spike lavender ( L, latifolia ).

Rosmarinus as an alternative to lavender extract in the present invention ( Rosmarinus officinalis extract can be used, the rosemary ( Rosmarinus officinalis ) extracts obtained by steam distillation from rosemary flowers, as well as lavender extracts. Rosemarine is a shrub-like perennial plant that belongs to Lamiaceae. The stem is gray with 4 squares. Leaves are narrow lancet-shaped, upper side is dark green, and lower side is silver white. The tip of the leaf is slightly curved downward. Between March and June, bluish white flowers bloom through the leaves. Rosemarine grows up to 100-150 cm tall.

In addition, polyoxyethylene sorbitan monooleate and polyoxyethylene lauryl ether used in the present invention are emulsifiers that uniformly disperse the active ingredients of the present invention in an emulsion state in a solvent. The content of polyoxyethylene sorbitan monooleate and polyoxyethylene lauryl ether, which are nonionic surfactants, is preferably 2 to 10% by weight, respectively. When the content of the nonionic surfactant is less than the range defined above, As described above, there is a concern that the role may be insignificant, and when it exceeds the above-mentioned range, the antimicrobial and deodorizing performance may decrease as the content of the active ingredients of the present invention decreases relative to the content of the nonionic surfactant. .

In addition, ethanol used as a solvent in the present invention not only uniformly disperses the active ingredients of the present invention in an emulsion state in the solvent, but also serves to sterilize various bacteria and fungi. The content of ethanol is preferably 10 to 20% by weight. When the content of ethanol is less than 10% by weight, the efficacy as described above is insignificant. As the content of the active ingredients of the present invention decreases, there is a concern that the sterilizing and deodorizing performance of various bacteria and fungi is lowered.

In addition, purified water used as a solvent in the present invention serves to uniformly disperse the active ingredients of the present invention in an emulsion state in the solvent. The content of purified water is preferably 77 to 85.7% by weight, when the content of purified water is less than 77% by weight, the active ingredients of the present invention may not be dispersed in an emulsion state sufficiently uniformly in a solvent. When it exceeds 7% by weight, as the content of the active ingredients of the present invention is relatively lower than the content of purified water, there is a concern that the sterilization and deodorization performance of various bacteria and fungi is lowered.

Hereinafter, the configuration of the present invention in detail through the following examples.

1. Preparation of antimicrobial deodorant spray composition

The antimicrobial deodorant spray composition was prepared according to the content of the compounding ratio of Table 1 below. The lavender extract used below was obtained by steam distillation.

                                                               (Unit: mg) Ingredient Example Comparative example One 2 3 4 One 2 3 4 2,4,4-trichloro-2-hydroxy diphenyl ether One 1.5 2 2.5 5 - - 2.5 Quaternary Ammonium Salts One 1.5 12 2.5 - 5 - 2.5 Lavenda Extract One 2 3 5 - - 5 - Polyoxyethylene sorbitan monooleate 2 5 5 10 2 5 5 10 Polyoxyethylene lauryl ether 10 5 5 2 10 5 5 2 ethanol 128 150 200 200 100 150 200 200 Purified water 857 835 773 778 883 825 785 783

2. Antibacterial test

The antimicrobial activity of the antimicrobial deodorant spray composition prepared according to the method 1 was Streptococcus piogenes ( Streptococcus pyogenes ) 308A, Staphylococcus aureus) SG 511, S Cherry Escherichia coli (Escherichia coli) DC O, rugi labor Pseudomonas (Pseudomonas aeruginosa) 9027, Salmonella typhimurium (Salmonella typhimurium ), Klebsiella oxytoca 1082 E and Enterobacter cloacae 1321 E were measured. In order to measure the antimicrobial activity of triclosan, quaternary ammonium salt and lavender extract, which are the active ingredients of the antimicrobial spray composition according to the present invention, the samples described in Table 1 above were inoculated with the respective bacteria by agar dilution. Incubated for 48 hours in anaerobic condition at 37 ℃ and the antimicrobial activity was measured as a minimum growth inhibitory concentration (MIC) (ug / ml) to significantly reduce the number of bacteria of the initial bacteria. The results are shown in the following [Table 2].

                                                           (Unit: MIC) Type of bacteria Example Comparative example One 2 3 4 One 2 3 4 Streptococcus Fiogenes 308A 0.3 0.2 0.1 0.1 1.0 0.1 1.0 0.5 Staphylococcus aureus SG 511 <0.01 <0.01 <0.01 <0.01 <0.01 1.0 10 <0.01 Escherichia coli DC O <0.01 <0.01 <0.01 <0.01 <0.01 10 100 <0.01 Pseudomonas Eruginosa 9027 10 10 10 1.0 100 100 100 100 Salmonella Typhimurium <0.01 <0.01 <0.01 <0.01 <0.01 10 100 <0.01 Klebsiella oxytoca 1082 E <0.01 <0.01 <0.01 <0.01 <0.01 10 100 <0.01 Enterobacter cloaca 1321 E <0.01 <0.01 <0.01 <0.01 0.1 100 10 0.08

As shown in Table 2, 2,4,4-trichloro-2-hydroxy diphenyl ether, quaternary ammonium salt, and Lavenda extract, respectively, were treated with the same concentration, as in the case of Comparative Examples 1 to 3, respectively. 2,4,4-trichloro, as in Examples 1 to 4, rather than when treated with 2,4,4-trichloro-2-hydroxy diphenyl ether and quaternary ammonium salts as in the case or in Comparative Example 4. It can be seen that the antimicrobial effect of the treatment with -2-hydroxy diphenyl ether, quaternary ammonium salts, and lavender extract was more excellent.

In addition, as in Examples 1 to 4, as the concentration of the lavender extract increased, it was found that the minimum growth inhibition concentration (MIC) decreased.

And in the embodiment of the present invention, as shown in the [Table 1] as shown in the antimicrobial activity test results using a lavender extract as a natural antimicrobial agent in [Table 2], but the same result can be obtained even when using a rose marine extract as a natural antimicrobial agent instead of lavender. Let's find out.

Therefore, it can be seen that as the fungus is reduced by the antimicrobial deodorant spray composition of the present invention, odor generated during decomposition of organic matter by fungi is naturally removed. As an example, the results of analyzing the deodorizing effect of removing odors of ammonia (NH ₃ ) and trimethylamine (TMA) using the sample of Example 2 are as shown in FIGS. 1 and 2. The flow proved to have the effect of removing odors of ammonia (NH ₃ ) and trimethylamine (TMA).

1 is a graph showing the deodorizing effect of removing the odor of ammonia (NH ₃ ) using the antimicrobial deodorant spray composition according to the present invention, it is carried out after filling a 5 liter chamber with ammonia having a concentration of 24 ppm 20 ml of the sample of Example 2 was added, and the results of observing the removal efficiency of ammonia (NH ₃ ) over time were as shown in Table 3 below.

                                                                (Concentration: ppm) division first 2 hours 4 hours 6 hours 8 hours 10 hours 12 hours Example 2 24 16.2 12.1 8.2 4.1 0.7 0.5

And, Figure 2 relates to a graph showing the deodorizing effect of removing the smell of trimethylamine (TMA) using the antimicrobial deodorant spray composition according to the present invention, trimethylamine having a concentration of 470 ppm in 5 L chamber ( TMA) was added, and then 20 ml of the sample of Example 2 was added, and the results of observing the removal efficiency of trimethylamine (TMA) over time were as shown in Table 4 below.

                                                          (Concentration: ppm) division first 3 hours 6 hours 10 hours 1 day later 2 days later Example 2 470 165 100 10 2.8 1.0

As shown in Table 3 and Table 4, the removal effect of ammonia (NH ₃ ) and trimethylamine (TMA) was analyzed using the sample of Example 2, and after 2 hours, ammonia (NH ₃ ) was analyzed. And as the concentration of trimethylamine (TMA) gradually decreases the effect of removing the compounds lasted for a long time it was found that there is a deodorizing effect to remove the odor by the antimicrobial deodorant spray composition.

Therefore, the antimicrobial deodorant spray composition according to the present invention can be used for all existing methods such as spraying, spraying, and sedimentation, which is advantageous for removing long-term odors such as landfills, sanitary treatment plants, sewage treatment plants, etc. It can be used for various odor removal in a wide range of industries such as industrial and barn agricultural and fish processing plants.

As described above, the present invention has proved its superiority through the above embodiments, but the present invention is not necessarily limited only to the above embodiments, and various modifications may be made without departing from the technical spirit of the present invention. Substitutions, modifications and variations are possible.

The present invention having the above structure utilizes excellent synergistic effects between active ingredients such as 2,4,4-trichloro-2-hydroxy diphenyl ether, quaternary ammonium salts, and lavender extracts, and provides a living environment and clothes, carpets, beds. It is advantageous for long-term deodorization such as waste landfill, sanitary treatment plant, sewage treatment plant, etc., and can be used in various ranges for deodorization in a wide range such as industrial and barn agricultural and aquatic processing plants such as exhaust gas removal of chemical plants.

Claims (5)

In the antimicrobial deodorant spray composition, 0.1 to 2 wt% of 2,4,4-trichloro-2-hydroxy diphenyl ether, 0.1 to 2 wt% of quaternary ammonium salt, and 0.1 to 0.5 wt% of lavender extract, polyoxyethylene sorbent Antimicrobial deodorant spray composition comprising 2 to 10% by weight of non-molecular monooleate, 2 to 10% by weight of polyoxyethylene lauryl ether, 10 to 20% by weight of ethanol and 77 to 85.7% by weight of purified water. The method of claim 1, The lavender extract is an antimicrobial deodorant spray composition, characterized in that obtained by steam distillation from the lavender flower. The method according to claim 1 or 2, The lavender extract is an antibacterial and deodorant spray composition, characterized in that the use of rose marine extract as a substitute. The method of claim 1, Cetyl ammonium chloride, cetyl ammonium bromide, lauryl ammonium chloride, lauryl ammonium bromide, stearyl ammonium chloride, stearyl ammonium bromide, cetyl dimethyl ammonium chloride, cetyl dimethyl ammonium bromide, lauryl dimethyl ammonium chloride, lauryl dimethyl ammonium bromide, Stearyl dimethyl ammonium chloride, stearyl dimethyl ammonium bromide, cetyl trimethyl ammonium chloride, cetyl trimethyl ammonium bromide, lauryl trimethyl ammonium chloride, lauryl trimethyl ammonium bromide, stearyl trimethyl ammonium chloride, stearyl trimethyl ammonium bromide, lauryl dimethyl ammonium Chloride, disetyl ammonium chloride, disetyl ammonium bromide, dilauryl ammonium chloride, dilauryl ammonium bromide De, distearyl ammonium chloride, distearyl ammonium bromide, dicetyl methyl ammonium chloride, dicetyl methyl ammonium bromide, dilauryl methyl ammonium chloride, dilauryl methyl ammonium bromide, distearyl methyl ammonium chloride, distearyl methyl ammonium chloride Antimicrobial deodorant spray composition characterized by using one or more selected from bromide and mixed. The method of claim 1, The quaternary ammonium salt, antimicrobial deodorant spray composition, characterized in that it is more preferable to use the C ₈ to C ₃₀ alkyl carbon chain extracted from Uji fatty acid or coconut fatty acid.

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