CN105031701A - Environmentally-friendly plant source deodorant - Google Patents
Environmentally-friendly plant source deodorant Download PDFInfo
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- CN105031701A CN105031701A CN201510600201.XA CN201510600201A CN105031701A CN 105031701 A CN105031701 A CN 105031701A CN 201510600201 A CN201510600201 A CN 201510600201A CN 105031701 A CN105031701 A CN 105031701A
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Abstract
The invention relates to an environmentally-friendly plant source deodorant. The effective ingredients of the environmentally-friendly plant source deodorant include a clove extracting solution, a cryptolepis sinensis extracting solution, matrine and a cassia bark extracting solution, wherein the mass ratio of the clove extracting solution to the cryptolepis sinensis extracting solution to the matrine is 10-30:20-40:1-2. The effective ingredients of the environmentally-friendly plant source deodorant include the plant extracting solutions, can be degraded itself and does not cause secondary environmental pollution, the environmentally-friendly plant source deodorant does not cause irritability of skin or a respiratory system after being used, does not cause various adverse effects and has the advantages of being non-toxic, harmless and safe in use. The environmentally-friendly plant source deodorant further has bacterium-inhibiting, sterilizating and insecticidal activity, can eliminate gathering disoperation of mosquitoes and flies and reduce bacterial propagation, has the synergistic effect and is small in using amount and higher in control effect.
Description
Technical field
The present invention relates to public health field of deodorization, specifically a kind of plant source air clearing product, control for application of city life garbage process and public lavatory abnormal flavour.
Background technology
Along with the quickening of Development of China's Urbanization, townm refuse constantly increases, but the environmental sanitation work of a lot of Small Urban does not catch up with the development in city, in addition indivedual civic health consciousness is also not high, and often have the phenomenon of application of city life garbage stacking in heaps, rubbish in heaps not only distributes stench niff, also mosquito, fly is caused, near foul smell order and the resident that passes by cannot stand, the gathering of mosquitos and flies not only contaminated environment also spreads disease germs disease, larger to the life injury of resident.
Application of city life garbage foul gas is mainly from the anaerobic fermentation catabolic process of organic anaerobic fermentation process, particularly changing food waste.In microorganism using labile Organic substance all kinds of in rubbish if protein, fat and carbohydrate etc. are as in the process that nutrient substance is used, these organic substances are subject to the effect of microorganism and rot, and produce gaseous state metabolite or the intermediate product of the abnormal flavour such as ammonia, fatty acid, organic sulfur, inorganic sulfur and aromatic.
In order to remove the stink of application of city life garbage and public lavatory, people have also carried out the measure of some deodorization, spray in foul smell or volatilization fumet as passed through, be used for improving the sensation of people to place air, but fumet belongs to chemical products, removal effect is not occurred to odorant pollutant, after using, also secondary pollution is caused to environment.Fumet does not have bacteriostasis and sterilization function simultaneously, can not control the gathering harm of rubbish heap, public lavatory mosquitos and flies.
Summary of the invention
The object of the invention is for the deficiencies in the prior art, the agent of a kind of plant source environment-friendly deodorant is provided, the abnormal flavour that application of city life garbage or public lavatory distribute can not only be eliminated, possess bacteriostasis and sterilization simultaneously, repel mosquitoes and flies the function of assembling.
The present invention solves the problems of the technologies described above taked technical scheme, provides the agent of a kind of plant source environment-friendly deodorant, and the effective ingredient of described plant source environment-friendly deodorant agent is made up of Flos Caryophylli extracting solution, Radix Cryptolepis sinensis extracting solution, matrine and Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution.
Plant source environment-friendly deodorant of the present invention agent, all raw materials are all parts for natural plants or are formed through extracting by natural plants, and its bacteriostasis and sterilization had and disinsection efficiency are all derived from the various active composition contained in described raw material.Wherein:
Flos Caryophylli (EugeniacaryophyllataThunb.) is myrtle, simple and elegant and the delicate fragrance of its dry flower, and containing volatile oil, main component is eugenol, there is the effects such as parasite killing, anti-inflammation, antiviral, scavenging free radicals, there is stronger inhibitory action to escherichia coli, Bacillus typhi, Salmonella, staphylococcus aureus, also have inhibition in various degree to the bacillus subtilis in food, Aspergillus flavus, Aspergillus niger, yeast etc.
Radix Cryptolepis sinensis (Cryptolepissinensis (Lour.) Merr.) is asclepiadaceae plant, band point mild toxicity.
Matrine is made up through organic solvent extraction such as ethanol of the dry root of leguminous plant Radix Sophorae Flavescentis (SophoraflavescensAit), plant, fruit, it is active that matrine has multiple killing pests and suppressing bacteria, has good suppression and killing action to multiple fungus, coccus, bacillus; Matrine is also a kind of Study of Natural Plant Pesticides, to people and animals' low toxicity, can effectively prevent and treat the insects such as Pieris rapae, pine moth, trialeurodes vaporariorum, aphid, mosquitos and flies.
Cortex cinnamomi japonici (Ramulus Cinnamomi) (Cinnamomumtamala (Bauch.-Ham.) NeesetEberm), formal name used at school bavin osmanthus, also known as Cortex Cinnamomi, Cortex Cinnamomi or fragrant osmanthus, is Lauraceae, cinnamon.Can be used as food flavor or condiment for cooking, is one of spice used by the mankind the earliest.
The mass ratio of described Flos Caryophylli extracting solution, Radix Cryptolepis sinensis extracting solution and matrine is 10-30:20-40:1-2; In described plant source environment-friendly deodorant agent, Flos Caryophylli extracting solution accounts for 1.0-3.0%, Radix Cryptolepis sinensis extracting solution accounts for 2.0-5.0%, and matrine accounts for 0.1-0.2%, and Cortex cinnamomi japonici (Ramulus Cinnamomi) accounts for 1.0-3.0%.
Described Flos Caryophylli extracting solution, Radix Cryptolepis sinensis extracting solution and Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution are water extract or ethanol extract.
The surfactant that described plant source environment-friendly deodorant agent is selected is as well known to those skilled in the art, can be selected from one or more in sodium lauryl sulphate, dodecylbenzene sodium sulfonate, alkylnaphthalene sulfonate, alkyl benzene sulfonate calcium salt, polyvinylpyrrolidone, aliphatic acid polyethenoxy ether, polyoxyethylene carboxylate.
The invention provides the application of plant source environment-friendly deodorant agent, be applied to application of city life garbage heap, Biohazard Waste Disposal, garbage transfer station air Deodor or be applied to public lavatory, cities and towns abnormal flavour control.
The mechanism of plant source environment-friendly deodorant of the present invention agent is: plant extraction liquid atomization forms gaseous state and is distributed in contaminated area air, and odor molecules is adsorbed, and various reaction occurs at normal temperatures, generates tasteless nontoxic molecule.The mechanism of plant extraction liquid decompose odor molecule has: 1. acid-base reaction, containing alkaloid in plant source extracting solution, can react with the odor molecules such as hydrogen sulfide, hydrocyanic acid radical ion, impels odor molecules to change original molecular structure, makes it to lose stink; 2. catalytic oxidation, as hydrogen sulfide, can not react with the oxygen in air in the ordinary course of things, under the catalytic action of plant extraction liquid, can react with the oxygen in air.3. redox reaction, as formaldehyde has oxidisability, the effective molecule had in plant extraction liquid has reproducibility, can directly react.4. thermodynamics analysis, through the drop of atomization, its diameter is at 0.04mm.In this case, the surface energy of drop has reached 1/3 and 1/2 of some organic compound bond energys.In this case, be enough to destroy the key in foul smell molecule, make their instability, easily decompose.
The present invention has the following advantages and significant technique effect:
(1) effective ingredient of deodorizer of the present invention is made up of plant extraction liquid, can degrade voluntarily, can not produce secondary pollution to environment.
(2) deodorizer of the present invention can not cause skin or respiratory system allergy after using, and can not cause various untoward reaction, have nontoxic, harmless, use safety, easily advantage.
(3) deodorizer of the present invention has bacteriostasis and sterilization and insecticidal activity, and the gathering infringement that can repel mosquitoes and flies, decreases the propagation of pathogenic bacteria.
(4) effective ingredient of deodorizer of the present invention has synergistic function on bacteriostasis and sterilization, has 3 kinds of effective ingredient to use with within the scope of certain proportion and has consumption less, the advantage that preventive effect is higher.
Detailed description of the invention
Be described further technical scheme of the present invention and technique effect below in conjunction with specific embodiment, percentage ratio of the present invention is all weight percentage.Flos Caryophylli extracting solution described in the present embodiment, Radix Cryptolepis sinensis extracting solution and Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution are water extract.
Embodiment 1: Flos Caryophylli extracting solution, Radix Cryptolepis sinensis extracting solution, matrine and composition thereof Toxicity Determination to Aspergillus niger
Determine, after the effective inhibition concentration scope of each extracting solution, Flos Caryophylli extracting solution, Radix Cryptolepis sinensis extracting solution, matrine and composition thereof to be established 5 dosage process respectively by active constituent content through prerun, if clear water contrast.Carry out with reference to " farm-chemical indoor determination test rule antibacterial ", adopt mycelial growth rate method to measure medicament to the virulence of Aspergillus niger.Measure colony diameter by decussation method after 72h, calculate each process net growth mycelial growth inhibition rate.
Statistical analysis is carried out with DPS data processing software, mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) converts logarithm value (x) to, try to achieve virulence regression equation (y=a+bx) with method of least square, and calculate the EC of often kind of medicament thus
50value, the co-toxicity coefficient method (CTC) then proposed by nineteen sixties such as Sun Yunpei evaluates the potentiation of pharmacy mix, and as co-toxicity coefficient (CTC)>=120, compositions shows as potentiation; When CTC≤80, compositions shows as antagonism; As 80 < CTC < 120, compositions shows as summation action.Result of the test is in table 1.
Table 1 Flos Caryophylli extracting solution, Radix Cryptolepis sinensis extracting solution, matrine and composition thereof are to the toxicity test table of Aspergillus niger
As shown in Table 1, Flos Caryophylli extracting solution, Radix Cryptolepis sinensis extracting solution and matrine mixture in the proportion of 10-30:20-40:1-2 all shows obvious synergistic function to Aspergillus niger, and mutual mixture can reduce consumption, improves prevention effect.
The agent of embodiment 2:5.1% Flos Caryophylli extracting solution Radix Cryptolepis sinensis extracting solution matrine Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution plant source environment-friendly deodorant
By Flos Caryophylli extracting solution 1.0%, Radix Cryptolepis sinensis extracting solution 2.0%, matrine 0.1%, Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution 2%, sodium lauryl sulphate 2.5%, excess water complements to 100%, Homogeneous phase mixing under room temperature, is namely made into the plant source environment-friendly deodorant agent of 5.1% Flos Caryophylli extracting solution Radix Cryptolepis sinensis extracting solution matrine Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution.
This embodiment is applied to application of city life garbage deodorizing test.Monitoring condition: put the house refuse that a pile is about the generation stench that 200kg highly rots in the closed room of a 10m × 4m × 3m, around rubbish, about 0.6m place evenly lays 3 sampled points, sampled point is overhead highly respectively 1.0m, 1.3m, 1.6m, adopt this deodorization medicament to be watered 50 times of liquid and even spraying is carried out to rubbish surface, thoroughly squirt as standard with surface, interval is sprayed once for 2 hours again, altogether sprays twice.NH before measuring spray medicine and after the 2nd spray medicine in 60 minutes stenches
3, H
2s concentration.During mensuration, room atmosphere condition: atmospheric temperature is 32 DEG C, atmospheric pressure is 100.86kPa.
Monitoring method: ammonia adopts sodium hypochlorite one salicylic acid spectrophotography (GB/T14679); Hydrogen sulfide adopts ammonium alcohol polyvinyl phosphate to absorb a methylene-blue colorimetric method.
Result of the test is as shown in table 2, this deodorizer in rubbish deodorization to NH
3, H
2s has good removal effect, and the clearance of foul smell is more than 70%.Through second time spray medicine after 60 minutes, clearly, foul smell is eliminated sensorial effects fast.
Table 25.1% Flos Caryophylli extracting solution Radix Cryptolepis sinensis extracting solution matrine Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution deodorizer is applied to the test of application of city life garbage
Embodiment 3:8.1% Flos Caryophylli extracting solution Radix Cryptolepis sinensis extracting solution matrine Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution is applied to the field trial of application of city life garbage
By Flos Caryophylli extracting solution 2%, Radix Cryptolepis sinensis extracting solution 3.0%, matrine 0.1%, Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution 3%, aliphatic acid polyethenoxy ether 2.5%, polyvinylpyrrolidone 2.5%, excess water complements to 100%, at normal temperatures mix homogeneously, namely makes the plant source environment-friendly deodorant agent of 8.1% Flos Caryophylli extracting solution Radix Cryptolepis sinensis extracting solution matrine Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution.
Select dumping point in Yun Biao town, Heng County, Nanning to carry out field experimentation, and entrust environmental health inspection center of Nanning City to test refuse odor related compounds concentration and total number of bacteria.Measure Related Component concentration and total number of bacteria in refuse odor before spray medicine, the deodorant dilution agent 80 times will prepared afterwards, carries out even spraying to rubbish surface, thoroughly squirts as standard with surface.Within after spray medicine 60 minutes, measure related compounds concentration and total number of bacteria in refuse odor.Arrange another dumping point (house refuse about 2 tons) in contrast, two dumpings are separated by about 200 meters, and two dumping points all have fly to assemble simultaneously.
Odor concentration adopts triangle odor bag method (GB/T14675); Ammonia adopts sodium hypochlorite one salicylic acid spectrophotography (GB/T14679); Hydrogen sulfide adopts ammonium alcohol polyvinyl phosphate to absorb a methylene-blue colorimetric method; Total number of bacteria adopts micro-porous filter; Total hydrocarbon adopts gas chromatography (GB/T15263).
Result of the test is as shown in table 3, stacks house refuse NH after spray deodorant of point
3, H
2s, total hydrocarbon, total number of bacteria all greatly reduce, and have better clearance to antibacterial, deodorizing effect is obvious.On sense organ, spray latter 60 minutes, feel that stench obviously alleviates.Within after spraying the agent of plant source environment-friendly deodorant 60 minutes, 24 hours, observe the harm that reassociates all not having mosquito, fly.
Table 38.1% Flos Caryophylli extracting solution Radix Cryptolepis sinensis extracting solution matrine Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution sprays the field trial of Biohazard Waste Disposal
Note: odor concentration unit: dimensionless; Total number of bacteria unit: individual/m
3
The plant source environment-friendly deodorant agent of embodiment 45.2% Flos Caryophylli extracting solution Radix Cryptolepis sinensis extracting solution matrine Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution
Take Flos Caryophylli extracting solution 1.5%, Radix Cryptolepis sinensis extracting solution 2.5% by weight percentage, matrine 0.2%, Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution 1%, polyoxyethylene carboxylate 1.5%, polyvinylpyrrolidone 2.5%, excess water complements to 100%, at normal temperatures Homogeneous phase mixing, is namely made into the plant source environment-friendly deodorant agent of 5.2% Flos Caryophylli extracting solution Radix Cryptolepis sinensis extracting solution matrine Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution.
The abnormal flavour that the present embodiment is applied to public lavatory controls, and select a public lavatory of Nanning City, the inside abnormal flavour is heavier, has a small amount of mosquitos and flies to assemble simultaneously.The foul smell mainly NH of public lavatory
3and H
2s, has penetrating odor, people is sick in the stomach, uncomfortable in chest, headache, dyspnea.Medicament is diluted 80 times and be sprayed on public lavatory air and earth's surface with small-sized aerosol apparatus of holding, after 30 minutes, sensory effects clearly, and air has the fragrant aroma of plant source extracting solution, and simultaneously the penetrating odor such as ammonia is eliminated fast, and mosquitos and flies is dispersed.
Claims (4)
1. the agent of plant source environment-friendly deodorant, is characterized in that, described effective ingredient is made up of Flos Caryophylli extracting solution, Radix Cryptolepis sinensis extracting solution, matrine and Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution; The mass ratio of described Flos Caryophylli extracting solution, Radix Cryptolepis sinensis extracting solution and matrine is 10-30:20-40:1-2.
2. plant source environment-friendly deodorant according to claim 1 agent, it is characterized in that, in described plant source environment-friendly deodorant agent, Flos Caryophylli extracting solution accounts for 1.0-3.0%, Radix Cryptolepis sinensis extracting solution accounts for 2.0-5.0%, matrine accounts for 0.1-0.2%, and Cortex cinnamomi japonici (Ramulus Cinnamomi) accounts for 1.0-3.0%.
3. plant source environment-friendly deodorant according to claim 1 and 2 agent, is characterized in that, described Flos Caryophylli extracting solution, Radix Cryptolepis sinensis extracting solution and Cortex cinnamomi japonici (Ramulus Cinnamomi) extracting solution are water extract or ethanol extract.
4. plant source environment-friendly deodorant according to claim 3 agent, it is characterized in that, in described plant source environment-friendly deodorant agent, surfactant is one or more in sodium lauryl sulphate, dodecylbenzene sodium sulfonate, alkylnaphthalene sulfonate, alkyl benzene sulfonate calcium salt, polyvinylpyrrolidone, aliphatic acid polyethenoxy ether, polyoxyethylene carboxylate.
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Application publication date: 20151111 |