JP2010248126A - Insecticide for rice tub - Google Patents
Insecticide for rice tub Download PDFInfo
- Publication number
- JP2010248126A JP2010248126A JP2009099452A JP2009099452A JP2010248126A JP 2010248126 A JP2010248126 A JP 2010248126A JP 2009099452 A JP2009099452 A JP 2009099452A JP 2009099452 A JP2009099452 A JP 2009099452A JP 2010248126 A JP2010248126 A JP 2010248126A
- Authority
- JP
- Japan
- Prior art keywords
- rice
- menthane
- diol
- insect repellent
- insecticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000007164 Oryza sativa Nutrition 0.000 title claims abstract description 64
- 235000009566 rice Nutrition 0.000 title claims abstract description 64
- 239000002917 insecticide Substances 0.000 title abstract description 14
- 240000007594 Oryza sativa Species 0.000 title description 52
- LMXFTMYMHGYJEI-UHFFFAOYSA-N p-menthane-3,8-diol Chemical compound CC1CCC(C(C)(C)O)C(O)C1 LMXFTMYMHGYJEI-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229930006948 p-menthane-3,8-diol Natural products 0.000 claims abstract description 21
- 241000196324 Embryophyta Species 0.000 claims abstract description 6
- 241000209094 Oryza Species 0.000 claims abstract 12
- 239000000077 insect repellent Substances 0.000 claims description 43
- 239000002781 deodorant agent Substances 0.000 claims description 5
- 230000000694 effects Effects 0.000 abstract description 16
- 239000005871 repellent Substances 0.000 abstract description 12
- 230000002940 repellent Effects 0.000 abstract description 12
- 241000607479 Yersinia pestis Species 0.000 abstract description 10
- 235000013305 food Nutrition 0.000 abstract description 7
- 241000238631 Hexapoda Species 0.000 abstract description 3
- 230000001877 deodorizing effect Effects 0.000 abstract description 2
- 241001465754 Metazoa Species 0.000 abstract 1
- 241000254154 Sitophilus zeamais Species 0.000 abstract 1
- 241000254171 Curculionidae Species 0.000 description 11
- -1 terpene compound Chemical class 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 5
- 235000002566 Capsicum Nutrition 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000000749 insecticidal effect Effects 0.000 description 4
- 244000144972 livestock Species 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 241000254173 Coleoptera Species 0.000 description 3
- 241000255925 Diptera Species 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000006002 Pepper Substances 0.000 description 3
- 235000016761 Piper aduncum Nutrition 0.000 description 3
- 240000003889 Piper guineense Species 0.000 description 3
- 235000017804 Piper guineense Nutrition 0.000 description 3
- 235000008184 Piper nigrum Nutrition 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 244000195452 Wasabia japonica Species 0.000 description 3
- 235000000760 Wasabia japonica Nutrition 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- 241001674044 Blattodea Species 0.000 description 2
- 244000056139 Brassica cretica Species 0.000 description 2
- 235000003351 Brassica cretica Nutrition 0.000 description 2
- 235000003343 Brassica rupestris Nutrition 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 241000237509 Patinopecten sp. Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical compound C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 2
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 229940094952 green tea extract Drugs 0.000 description 2
- 235000020688 green tea extract Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000010460 mustard Nutrition 0.000 description 2
- 239000000419 plant extract Substances 0.000 description 2
- 235000020637 scallop Nutrition 0.000 description 2
- 235000007586 terpenes Nutrition 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- MBDOYVRWFFCFHM-SNAWJCMRSA-N (2E)-hexenal Chemical compound CCC\C=C\C=O MBDOYVRWFFCFHM-SNAWJCMRSA-N 0.000 description 1
- KHWTYGFHPHRQMP-UHFFFAOYSA-N (4-propan-2-ylcyclohexyl)methanol Chemical compound CC(C)C1CCC(CO)CC1 KHWTYGFHPHRQMP-UHFFFAOYSA-N 0.000 description 1
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 description 1
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- FQERLIOIVXPZKH-UHFFFAOYSA-N 1,2,4-trioxane Chemical compound C1COOCO1 FQERLIOIVXPZKH-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- AZUVBPVDRHGGEP-UHFFFAOYSA-N 6a,9a-dimethyl-4,5,7,8,9,9a-hexahydro-6aH-dipyrrolo(2,3-b;3',2',1'-hi)indole Natural products CC(=C)C1CCC(C)=CCCC(C)=CCCC(C)=CC1O AZUVBPVDRHGGEP-UHFFFAOYSA-N 0.000 description 1
- JDLKFOPOAOFWQN-VIFPVBQESA-N Allicin Natural products C=CCS[S@](=O)CC=C JDLKFOPOAOFWQN-VIFPVBQESA-N 0.000 description 1
- 240000002234 Allium sativum Species 0.000 description 1
- 240000003291 Armoracia rusticana Species 0.000 description 1
- 235000011330 Armoracia rusticana Nutrition 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- 240000008574 Capsicum frutescens Species 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000289763 Dasygaster padockina Species 0.000 description 1
- 244000004281 Eucalyptus maculata Species 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920002148 Gellan gum Polymers 0.000 description 1
- 241000218791 Ginkgoaceae Species 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- WSTYNZDAOAEEKG-UHFFFAOYSA-N Mayol Natural products CC1=C(O)C(=O)C=C2C(CCC3(C4CC(C(CC4(CCC33C)C)=O)C)C)(C)C3=CC=C21 WSTYNZDAOAEEKG-UHFFFAOYSA-N 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- 235000008708 Morus alba Nutrition 0.000 description 1
- 241000207834 Oleaceae Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 231100000674 Phytotoxicity Toxicity 0.000 description 1
- 241000209504 Poaceae Species 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 241000256011 Sphingidae Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 239000005844 Thymol Substances 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 244000273928 Zingiber officinale Species 0.000 description 1
- 235000006886 Zingiber officinale Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000005456 alcohol based solvent Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- JDLKFOPOAOFWQN-UHFFFAOYSA-N allicin Chemical compound C=CCSS(=O)CC=C JDLKFOPOAOFWQN-UHFFFAOYSA-N 0.000 description 1
- 235000010081 allicin Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 229960002504 capsaicin Drugs 0.000 description 1
- 235000017663 capsaicin Nutrition 0.000 description 1
- 239000001390 capsicum minimum Substances 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- VAROLYSFQDGFMV-UHFFFAOYSA-K di(octanoyloxy)alumanyl octanoate Chemical compound [Al+3].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O VAROLYSFQDGFMV-UHFFFAOYSA-K 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 229940113120 dipropylene glycol Drugs 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000004611 garlic Nutrition 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 235000008397 ginger Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 235000009569 green tea Nutrition 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 229940027779 persimmon extract Drugs 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 229940095050 propylene Drugs 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010677 tea tree oil Substances 0.000 description 1
- 229940111630 tea tree oil Drugs 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Catching Or Destruction (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
本発明は、米びつ用防虫剤に関するものである。 The present invention relates to an insect repellent for rice vines.
従来より、米びつ用途、もしくは貯蔵穀物類の主害虫であるコクゾウムシ対策が種々提案されている。例えば、特開平6−38678号公報に示されるように、アリシン、カプサイシン等を成分とする米の抗菌、抗カビ、防虫を目的とした品質保存剤が公知であり、特許第3409176号公報には、ペリラアルデヒドを主成分とする薬剤を含浸した液含浸部材からなる米びつ防虫具が、一方、特開平11−222409号公報には、有効成分として天然物由来のティートリーオイル及び/又はパインオイルを含有してなるコクゾウムシ忌避剤が記載されている。
また、最近、ワサビ、カラシ、トウガラシ、ニンニク等を使用したコクゾウムシの忌避剤が米びつ用として多く市販されている。これらは、使用する薬剤が食品であるため薬害の心配はないが、忌避効果が弱く、効果を確保するには大量に使用する必要がある。また、匂いが強いため米への匂い移りが避けられず、しかも人に対して刺激があるという問題も有する。
Conventionally, various countermeasures have been proposed for rice vines or measures against weevil which is a main pest of stored grains. For example, as disclosed in JP-A-6-38678, a quality preservative for the purpose of antibacterial, antifungal, and insect-proofing rice containing allicin, capsaicin and the like is known, and Japanese Patent No. 3409176 discloses In addition, a rice vine insect repellent composed of a liquid impregnated member impregnated with a drug mainly composed of perilaldehyde, while JP-A-11-222409 contains a tea tree oil and / or pine oil derived from natural products as an active ingredient A weevil repellent is described.
Recently, many weevil repellents using horseradish, mustard, pepper, garlic and the like have been marketed for rice. Since these drugs are foods, there is no worry of phytotoxicity, but the repellent effect is weak and it is necessary to use a large amount to ensure the effect. Moreover, since the smell is strong, the odor transfer to the rice is inevitable, and there is also a problem that the person is stimulated.
本発明は、コクゾウムシに代表される食品害虫に対する忌避効果並びに防虫効果と人畜に対する安全性に優れ、使い易く実用性の高い米びつ用防虫剤を提供することを目的とする。 An object of the present invention is to provide an insect repellent for rice vines which is excellent in repellent effect against food pests represented by weevil, insect repellent effect and safety against human livestock, and is easy to use and highly practical.
本発明は、以下の構成が上記目的を達成するために優れた効果を奏することを見出したものである。
(1)防虫成分としてp−メンタン−3,8−ジオールを含有し、米びつ内に設置される米びつ用防虫剤。
(2)前記p−メンタン−3,8−ジオールとともに植物由来消臭成分を含有する(1)記載の米びつ用防虫剤。
(3)前記p−メンタン−3,8−ジオールの含有量が、米びつの容量に対して0.02〜1.0g/10Lである(1)又は(2)記載の米びつ用防虫剤。
(4)前記p−メンタン−3,8−ジオールを0.1〜100mg/cm2担持させた繊維質担体を通気性容器に収納してなり、この通気性容器には米びつへの固定手段が備えられている(1)ないし(3)のいずれか記載の米びつ用防虫剤。
The present invention has been found that the following constitution has an excellent effect for achieving the above-mentioned object.
(1) An insect repellent for rice vines containing p-menthane-3,8-diol as an insect repellant component and installed in the rice jar.
(2) The insect repellent for rice vines according to (1), which contains a plant-derived deodorant component together with the p-menthane-3,8-diol.
(3) The insecticide for rice vests according to (1) or (2), wherein the content of the p-menthane-3,8-diol is 0.02 to 1.0 g / 10 L with respect to the capacity of the rice bins.
(4) A fibrous carrier carrying 0.1 to 100 mg / cm 2 of p-menthane-3,8-diol is housed in a breathable container, and this breathable container has a means for fixing to the rice bin. The insect repellent for rice vines according to any one of (1) to (3).
本発明の米びつ用防虫剤は、コクゾウムシに代表される食品害虫に対する忌避効果並びに防虫効果と人畜に対する安全性に優れ、米への匂い移りがなく、使い易いのでその実用性は極めて高い。 The insect repellent for rice vines of the present invention has excellent repellent effect against food pests represented by weevil weevil, insect repellent effect and safety for human livestock, has no odor transfer to rice, and is easy to use, so its practicality is extremely high.
本発明の米びつ用防虫剤は、防虫成分として、p−メンタン−3,8−ジオールを含有する。p−メンタン−3,8−ジオールは、レモンユーカリの精油に含まれる物質で、天然由来成分であっても合成品のいずれであってもよい。p−メンタン−3,8−ジオールには、立体構造に基づくトランス体とシス体が存在するが、本発明においては、両者の異性体の任意の割合の混合物を使用することができる。本化合物については、蚊などの飛翔害虫用忌避剤の忌避成分として公知であるが、コクゾウムシに代表される食品害虫に対する防虫効果についてはこれまで検討された報告はない。 The insect repellent for rice vines of the present invention contains p-menthane-3,8-diol as an insect repellent component. p-menthane-3,8-diol is a substance contained in the essential oil of lemon eucalyptus and may be either a naturally derived component or a synthetic product. In p-menthane-3,8-diol, there exist a trans isomer and a cis isomer based on a steric structure, but in the present invention, a mixture of both isomers in any ratio can be used. Although this compound is known as a repellent component of a repellent for flying insect pests such as mosquitoes, there has been no report to date regarding the insect repellent effect against food pests represented by the weevil.
しかるに、本発明者らは、この化合物のコクゾウムシ等に対する防虫効果を鋭意検討し、試験の結果、テルペン系化合物のなかでは特に優れた忌避効果ないし防虫効果を奏することを見出した。そして、この化合物は人畜に対して安全性が高く、匂いも弱いことから本用途に極めて有用であることを実証し、本発明を完成するに至ったものである。 However, the present inventors diligently investigated the insect repellent effect of this compound against weevil etc., and as a result of the test, they found that the terpene compound exhibits particularly excellent repellent effect or insect repellent effect. And since this compound is highly safe for human livestock and has a weak odor, it has been proved that it is extremely useful for this application, and the present invention has been completed.
本発明では、通常上記p−メンタン−3,8−ジオールに各種の成分を加えて防虫組成物を調製し、これを種々の形態の米びつ用防虫剤に適用する。p−メンタン−3,8−ジオールの米びつ用防虫剤全体量に対する配合量は、米びつ用防虫剤の形態によっても異なるが、米びつの容量として10L当たり0.02〜1.0g程度に設定するのが好ましい。0.02g未満であると防虫効果が十分でなく、一方1.0gを超えるとベタつき感が出るなど実用的でない。 In the present invention, an insect repellent composition is usually prepared by adding various components to the above-mentioned p-menthane-3,8-diol, and this is applied to an insect repellent for various forms of rice. The blending amount of p-menthane-3,8-diol with respect to the total amount of the insecticide for rice vines varies depending on the form of the insecticide for rice vines, but the capacity of rice vine is set to about 0.02 to 1.0 g per 10 liters. Is preferred. If it is less than 0.02 g, the insect repellent effect is not sufficient, while if it exceeds 1.0 g, it is not practical, such as a sticky feeling.
本発明の米びつ用防虫剤には、上記p−メンタン−3,8−ジオールとともに植物由来消臭成分を配合するのが好ましい。このような植物抽出物としては、イネ科、ツバキ科、イチョウ科、モクセイ科、クワ科、ミカン科、キントラノオ科、カキノキ科の中から選ばれた一種以上を用いるのが適当であり、緑茶抽出物や柿抽出物が代表的である。なお、植物由来消臭成分の配合量は、p−メンタン−3,8−ジオールに対し、0.01〜0.1倍量程度で十分である。
植物抽出物の成分として知られる、例えばポリフェノール類は、消臭成分として公知であるが、本発明の米びつ用防虫剤において、p−メンタン−3,8−ジオールの効力増強成分として作用するという知見は全く新規なものである。その理由として、防虫成分が揮散する際に何らかの相互作用を及ぼしているものと推定される。
It is preferable to mix a plant-derived deodorant component with the p-menthane-3,8-diol in the insect repellent for rice vines of the present invention. As such a plant extract, it is appropriate to use one or more selected from the family Gramineae, Camelliaaceae, Ginkgoaceae, Oleaceae, Mulberry, Citrus, Kintranoaceae, Oysteraceae, and extract green tea. The product and the cocoon extract are typical. In addition, about 0.01-0.1 times amount is sufficient with respect to p-menthane-3,8-diol as the compounding quantity of a plant-derived deodorant component.
Known as a component of a plant extract, for example, polyphenols are known as deodorizing components, but in the insect repellent for rice vines of the present invention, the knowledge that they act as potentiating components of p-menthane-3,8-diol Is completely new. The reason is presumed to have some interaction when the insect repellent component is volatilized.
本発明の米びつ用防虫剤は、使用場面のニーズに合わせて、液状、ゲル状、固形状、シート状など種々の防虫組成物、並びに形態を採用しうる。
液状の防虫組成物を調製するにあたっては、水のほか、エタノール、イソプロパノールのようなアルコール系溶剤、1,3−ブチレングリコール、プロピレングリコール、ジプロピレングリコールのようなグリコール系溶剤、ジエチレングリコールモノブチルエーテル、プロピレングリコールモノメチルエーテル等のグリコールエーテル系溶剤、脂肪族炭化水素系溶剤等の各種溶剤や、界面活性剤(可溶化剤)などが適宜用いられる。
界面活性剤としては、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレン高級アルキルエーテル(ポリオキシエチレンラウリルエーテル、ポリオキシエチレンオレイルエーテル)、ポリオキシエチレン高級脂肪酸エステル、ポリオキシエチレンポリオキシプロピレンアルキルエーテル等の非イオン系界面活性剤や、ラウリルアミンオキサイド、ステアリルアミンオキサイド、ラウリル酸アミドプロピルジメチルアミンオキサイド等の高級アルキルアミンオキサイド系界面活性剤などを例示できる。
The insect repellent for rice vines of the present invention can adopt various insect repellent compositions and forms such as liquid, gel, solid and sheet according to the needs of the usage scene.
In preparing a liquid insect repellent composition, in addition to water, alcohol solvents such as ethanol and isopropanol, glycol solvents such as 1,3-butylene glycol, propylene glycol and dipropylene glycol, diethylene glycol monobutyl ether, propylene Various solvents such as glycol ether solvents such as glycol monomethyl ether, aliphatic hydrocarbon solvents, and surfactants (solubilizers) are used as appropriate.
Surfactants include polyoxyethylene hydrogenated castor oil, polyoxyethylene higher alkyl ether (polyoxyethylene lauryl ether, polyoxyethylene oleyl ether), polyoxyethylene higher fatty acid ester, polyoxyethylene polyoxypropylene alkyl ether, etc. Nonionic surfactants and higher alkylamine oxide surfactants such as laurylamine oxide, stearylamine oxide, amidopropyldimethylamine oxide lauryl, and the like can be exemplified.
また、安定化剤、pH調整剤、着色剤などを適宜配合してもよく、あるいは、例えば、「緑の香り」と呼ばれる青葉アルコールや青葉アルデヒド等を添加してリラックス効果を付与することもできる。
更に、ゲル状体の調製に用いられるゲル化剤としては、カラギーナン、キサンタンガム、ジェランガム、ゼラチン、オクチル酸アルミニウム、12−ヒドロキシステアリン酸などがあげられる。
In addition, a stabilizer, a pH adjuster, a colorant, and the like may be appropriately blended, or, for example, green leaf alcohol or green leaf aldehyde called “green fragrance” may be added to impart a relaxing effect. .
Further, examples of the gelling agent used for preparing the gel-like body include carrageenan, xanthan gum, gellan gum, gelatin, aluminum octylate, 12-hydroxystearic acid and the like.
本発明の米びつ用防虫剤は、上記防虫組成物を固体担体に含浸又は保持させたものを米びつ内に設置し、固体担体から防虫成分を揮散させる方式が好ましい。固体担体としては、パルプ、リンター、レーヨン等の繊維質担体、ケイ酸塩、シリカ、ゼオライト等の無機多孔質担体、トリオキサン、アダマンタン等の昇華性担体等があげられる。好ましくは、p−メンタン−3,8−ジオールを0.1〜100mg/cm2担持させた繊維質担体を通気性容器に収納し、この通気性容器を適当な固定手段を用いて米びつの上蓋の裏に固定したり、米の中に埋設するか、あるいは表面に置くようにすればよい。 As the insect repellent for rice vines of the present invention, a method in which the above insect repellant composition is impregnated or held in a solid carrier is placed in the rice jar and the insect repellant component is volatilized from the solid carrier. Examples of the solid carrier include fibrous carriers such as pulp, linter and rayon, inorganic porous carriers such as silicate, silica and zeolite, and sublimable carriers such as trioxane and adamantane. Preferably, a fibrous carrier carrying 0.1 to 100 mg / cm 2 of p-menthane-3,8-diol is housed in an air permeable container, and this air permeable container is covered with an upper lid of rice using appropriate fixing means. It can be fixed to the back of the rice, buried in rice, or placed on the surface.
通気性容器の形状や構成は何ら限定されないが、例えば、開閉可能な米俵状の通気性ケース内にマット挟持部材を設置し、これに防虫組成物含浸パルプ製マットを挟設してなるものや、防虫組成物含浸パルプ製マットを収納した扁平状の通気性ケース、あるいは、紙、織布、不織布、多孔シート等を用いた袋状の通気性容器に防虫組成物含浸パルプ製マットを収納してなるものがあげられる。 The shape and configuration of the breathable container are not limited at all, but, for example, a mat holding member is installed in a rice straw-shaped breathable case that can be opened and closed, and a mat made of pulp impregnated with an insect repellent composition is sandwiched between them Or a flat air-permeable case containing an insect repellent composition-impregnated pulp mat, or a bag-like air-permeable container using paper, woven fabric, nonwoven fabric, porous sheet, etc. What can be made.
このようにして得られた本発明の米びつ用防虫剤を、米びつ内に設置すれば、コクゾウムシ、カツオブシムシ、チャタテムシ、シバンムシ、ゴキブリ、アリ類等の食品につく害虫はもちろん、蚊類、蚋、ユスリカ類、ハエ類、チョウバエ類、イガ類などの各種害虫に対して1ケ月ないし2ケ月間の長期間にわたり実用的な防虫効果を奏するものである。そして、本発明で防虫成分として用いるp−メンタン−3,8−ジオールは、従来のワサビ、カラシ、ショウガやトウガラシ等に較べて匂いが極めて弱く、米への匂い移りもほとんどないのでその実用性は極めて高い。 If the insecticide for rice vines of the present invention thus obtained is installed in the rice vine, not only pests on foods such as weevil, cutlet worm, scallop, beetle, cockroach, ants, but also mosquitoes, moths, chironomids It exhibits a practical insect repellent effect over a long period of one to two months against various pests such as mosses, flies, butterflies and moths. In addition, p-menthane-3,8-diol used as an insect repellent component in the present invention has a very weak odor compared to conventional wasabi, mustard, ginger, pepper, etc., and has almost no odor transfer to rice, so its practicality. Is extremely expensive.
次に具体的な実施例に基づき、本発明の米びつ用防虫剤について更に詳細に説明する。 Next, based on a concrete Example, the insecticide for rice vines of this invention is demonstrated in detail.
大きさが3×7cmで厚さ1mmのリンター製マットに、p−メンタン−3,8−ジオールを210mg、緑茶エキスを6mg、及び灯油(脂肪族炭化水素系溶剤)を20mg含有させ、このマットを開口部を有する扁平状のポリエステル製容器(米びつの上蓋の裏に固定用の両面テープ付き)に収納して、本発明の米びつ用防虫剤を調製した。
この米びつ用防虫剤を米びつ(容量:10L)の上蓋の裏に固定して使用したところ、およそ1ケ月間にわたり、米びつ内でコクゾウムシ、カツオブシムシ、チャタテムシ、シバンムシ、ゴキブリ等を見かけることがなかった。
A linter mat with a size of 3 x 7 cm and a thickness of 1 mm contains 210 mg of p-menthane-3,8-diol, 6 mg of green tea extract, and 20 mg of kerosene (aliphatic hydrocarbon solvent). Was stored in a flat polyester container having an opening (with a double-sided tape for fixing on the back of the upper lid of the rice bottle) to prepare the insecticide for rice bottle of the present invention.
When this insecticide for rice was fixed and used on the back of the upper lid of rice (capacity: 10 L), weevil, cutworm, scallop, hornworm, cockroach, etc. were not found in the rice for about one month.
[殺虫効力試験]
実施例1に準じて、表1に示す各種米びつ用防虫剤を調製し、容量が約6Lの密閉容器の中に入れた。コクゾウムシ及びシバンムシ成虫を各30匹投入し、7日後の致死率を求めたところ、表1の如くであった。
[Insecticidal efficacy test]
In accordance with Example 1, various rice insect repellents shown in Table 1 were prepared and placed in a sealed container having a capacity of about 6 L. When 30 weevil and adult beetle were introduced and the mortality after 7 days was determined, it was as shown in Table 1.
試験の結果、本発明の米びつ用防虫剤は、防虫成分として配合したp−メンタン−3,8−ジオールの作用に基づき、コクゾウムシ及びシバンムシ成虫に対して従来のワサビ成分やトウガラシ成分に較べて優れた殺虫効力を示し、p−メンタン−3,8−ジオールの高い忌避効果を加味すると、食品につく害虫の防虫剤として実用性の高いことが認められた。また、緑茶エキスや柿抽出物の植物由来消臭成分を配合することによって、殺虫効力が向上することも明らかとなった。
さらに、いずれも火気に対する危険性が低く使用性の面でも優れたものであった。
これに対し、比較例に示すように、同じテルペン系化合物のマイヨール、あるいは忌避成分として一般的なチモールは、その殺虫効力が低いうえ匂いが強く米びつ用防虫剤の防虫成分としては不適であった。
As a result of the test, the insect repellent for rice vine according to the present invention is superior to conventional wasabi and capsicum components against the weevil and the beetle based on the action of p-menthane-3,8-diol blended as an insect repellent component. In view of the insecticidal efficacy, and taking into account the high repellent effect of p-menthane-3,8-diol, it was confirmed that it was highly practical as an insect repellent for food pests. Moreover, it became clear that insecticidal efficacy improves by mix | blending the plant-derived deodorant component of a green tea extract or a persimmon extract.
Furthermore, all of them were low in danger to fire and excellent in terms of usability.
On the other hand, as shown in the comparative examples, the same terpene compound mayol or thymol, which is a general repellent component, has a low insecticidal effect and has a strong odor and is not suitable as an insect repellent component for rice vest repellents. .
[匂いの移行試験]
米びつ(容量:10L)の中に米を入れ、その上に実施例2に準じて調製した米びつ用防虫剤を置いた。5日後、米びつ用防虫剤を取り除き、その周囲の米へ匂いがどの程度移ったかに付き、モニター10人による官能試験を行った。その結果を表2に示す。
[Odor transfer test]
Rice was put into the rice bin (capacity: 10 L), and an insecticide for rice bin prepared according to Example 2 was placed thereon. After 5 days, the insecticide for the rice vine was removed, and how much the odor moved to the surrounding rice was subjected to a sensory test with 10 monitors. The results are shown in Table 2.
試験の結果、天然由来のp−メンタン−3,8−ジオールを防虫成分とする本発明の米びつ用防虫剤は、米への匂い移りがなく、しかも人畜への毒性が非常に低いのでその実用性は極めて高い。
一方、ワサビ成分やトウガラシ成分は、匂いが強いため米への匂い移りが避けられず、また人に対して刺激があるという難点を有する。
As a result of the test, the insect repellent for rice vines of the present invention containing p-menthane-3,8-diol derived from nature as an insect repellent component has no odor transfer to rice and is extremely low in toxicity to human livestock. The nature is extremely high.
On the other hand, the wasabi component and the pepper component have a strong odor, so that the odor transfer to the rice cannot be avoided, and there is a problem that the human is irritating.
本発明は、米びつ用防虫剤だけでなく、広範な害虫防除分野において須らく利用可能である。
The present invention can be used not only for insecticides for rice vines but also in a wide range of pest control fields.
Claims (4)
A fibrous carrier carrying 0.1 to 100 mg / cm 2 of p-menthane-3,8-diol is housed in a breathable container, and the breathable container is provided with means for fixing to the rice bin. The insect repellent for rice vines according to any one of claims 1 to 3, wherein
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009099452A JP5234650B2 (en) | 2009-04-16 | 2009-04-16 | Insect repellent for rice |
TW102147868A TWI551218B (en) | 2009-01-19 | 2009-06-18 | Insect repellent method for rice bin |
TW98120456A TWI444138B (en) | 2009-01-19 | 2009-06-18 | Method for preventing odor-spread of creeping pest repelling compound |
KR1020090054945A KR101591090B1 (en) | 2009-01-19 | 2009-06-19 | Method for preventing odor-spread of creeping pest repelling compound |
CN200910150416.0A CN101779619B (en) | 2009-01-19 | 2009-06-19 | Method for preventing odor-spread of creeping pest repelling compound |
HK10109689.5A HK1143035A1 (en) | 2009-01-19 | 2010-10-13 | Method for preventing odor-spread of creeping pest repelling compound |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009099452A JP5234650B2 (en) | 2009-04-16 | 2009-04-16 | Insect repellent for rice |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2010248126A true JP2010248126A (en) | 2010-11-04 |
JP5234650B2 JP5234650B2 (en) | 2013-07-10 |
Family
ID=43310930
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009099452A Active JP5234650B2 (en) | 2009-01-19 | 2009-04-16 | Insect repellent for rice |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP5234650B2 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012254963A (en) * | 2011-05-13 | 2012-12-27 | Dainippon Jochugiku Co Ltd | Method for repelling insect pest in eating and drinking material housing body |
JP2013177341A (en) * | 2012-02-28 | 2013-09-09 | Kao Corp | Insect-controlling agent |
JP2015105245A (en) * | 2013-11-29 | 2015-06-08 | 白元アース株式会社 | Insect-repelling deodorizer |
JP2016108311A (en) * | 2014-12-04 | 2016-06-20 | エステー株式会社 | Insect repellent and insect repelling method for grains/dry foods |
CN114317134A (en) * | 2021-11-30 | 2022-04-12 | 广州市浪奇实业股份有限公司 | Floor cleaning agent |
JP7406020B2 (en) | 2017-11-17 | 2023-12-26 | 大日本除蟲菊株式会社 | Flying pest control product for closed spaces containing food |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60199804A (en) * | 1984-03-26 | 1985-10-09 | Nippon Kayaku Co Ltd | Repellent for injurious organism |
JP2000247807A (en) * | 1999-02-26 | 2000-09-12 | Fumakilla Ltd | Inhibitor against coming flying action and/or blood sucking one of vermin |
JP2004182704A (en) * | 2002-12-06 | 2004-07-02 | S T Chem Co Ltd | Insect controlling agent for grain and dried food product, and method for controlling insect of grain and dried food |
JP2010132628A (en) * | 2007-12-28 | 2010-06-17 | Dainippon Jochugiku Co Ltd | Repellent for grape pest, and method for repelling grape pest |
JP2010184919A (en) * | 2009-01-19 | 2010-08-26 | Dainippon Jochugiku Co Ltd | Method for preventing migration of smell of crawling vermin repelling component |
-
2009
- 2009-04-16 JP JP2009099452A patent/JP5234650B2/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60199804A (en) * | 1984-03-26 | 1985-10-09 | Nippon Kayaku Co Ltd | Repellent for injurious organism |
JP2000247807A (en) * | 1999-02-26 | 2000-09-12 | Fumakilla Ltd | Inhibitor against coming flying action and/or blood sucking one of vermin |
JP2004182704A (en) * | 2002-12-06 | 2004-07-02 | S T Chem Co Ltd | Insect controlling agent for grain and dried food product, and method for controlling insect of grain and dried food |
JP2010132628A (en) * | 2007-12-28 | 2010-06-17 | Dainippon Jochugiku Co Ltd | Repellent for grape pest, and method for repelling grape pest |
JP2010184919A (en) * | 2009-01-19 | 2010-08-26 | Dainippon Jochugiku Co Ltd | Method for preventing migration of smell of crawling vermin repelling component |
Non-Patent Citations (1)
Title |
---|
JPN6013012742; Entomologia Experimentalis et Applicata Vol. 129, 2008, P. 107-117 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012254963A (en) * | 2011-05-13 | 2012-12-27 | Dainippon Jochugiku Co Ltd | Method for repelling insect pest in eating and drinking material housing body |
JP2013177341A (en) * | 2012-02-28 | 2013-09-09 | Kao Corp | Insect-controlling agent |
JP2015105245A (en) * | 2013-11-29 | 2015-06-08 | 白元アース株式会社 | Insect-repelling deodorizer |
JP2016108311A (en) * | 2014-12-04 | 2016-06-20 | エステー株式会社 | Insect repellent and insect repelling method for grains/dry foods |
JP7406020B2 (en) | 2017-11-17 | 2023-12-26 | 大日本除蟲菊株式会社 | Flying pest control product for closed spaces containing food |
CN114317134A (en) * | 2021-11-30 | 2022-04-12 | 广州市浪奇实业股份有限公司 | Floor cleaning agent |
CN114317134B (en) * | 2021-11-30 | 2023-10-20 | 广州浪奇日用品有限公司 | Floor cleaning agent |
Also Published As
Publication number | Publication date |
---|---|
JP5234650B2 (en) | 2013-07-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5818860B2 (en) | 匍匐 Pest repellent and repellant method | |
JP4829589B2 (en) | Flying pest repellent | |
JP5234650B2 (en) | Insect repellent for rice | |
JP5665359B2 (en) | Insecticide for clothing pests | |
JP5730485B2 (en) | Mite repellent for bedding | |
JP4999310B2 (en) | Flying pest repellent | |
JP4823645B2 (en) | Flying pest repellent | |
JP6344976B2 (en) | Indoor mite repellent efficacy enhancer and indoor mite repellent method using the same | |
KR101090218B1 (en) | Flying pest repellent composition | |
JP6538424B2 (en) | Insect and insect repellent method for grain and dry matter | |
JP2006001864A (en) | Indoor tarsonemidae repellent, and article using the same and used for repelling tarsonemidae | |
JP2011195512A (en) | Moth repellent for bedding | |
JP2018104475A (en) | Water-based insecticide composition for heat evapotranspiration and heat evapotranspiration method of water-based insecticide composition for heat evapotranspiration | |
JP5980131B2 (en) | Insecticide for clothing | |
JP5646200B2 (en) | Insecticide for clothing | |
JP6656753B2 (en) | Insect repellent and mite repellent for clothing | |
JPS60139606A (en) | Transpiring composition | |
JP2011246364A (en) | Clothes pest egg hatching inhibitor and pest controlling method using the same | |
TWI836334B (en) | Acarines repellent composition and acarines repellent product | |
JP6833963B2 (en) | Indoor dust mite repellent | |
JP2004175745A (en) | Insect-proofing agent for grain/dried food product and method for controlling insect pest for grain/dried food product | |
TWI444138B (en) | Method for preventing odor-spread of creeping pest repelling compound | |
JP2022064533A (en) | Aqueous agent for thermal transpiration | |
JP2000239107A (en) | Low-smelling acaricide | |
WO2017126045A1 (en) | Insect repellent and insect repellent method for cereal and dry food |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20120331 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130308 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20130319 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20130319 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 Ref document number: 5234650 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20160405 Year of fee payment: 3 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |