CN115895797A - Floor cleaning agent with insect expelling effect - Google Patents
Floor cleaning agent with insect expelling effect Download PDFInfo
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- CN115895797A CN115895797A CN202211606777.3A CN202211606777A CN115895797A CN 115895797 A CN115895797 A CN 115895797A CN 202211606777 A CN202211606777 A CN 202211606777A CN 115895797 A CN115895797 A CN 115895797A
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- insect
- floor cleaner
- repellent effect
- repellent
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- 230000000694 effects Effects 0.000 title claims abstract description 36
- 241000238631 Hexapoda Species 0.000 title description 16
- 239000012459 cleaning agent Substances 0.000 title description 9
- 239000000077 insect repellent Substances 0.000 claims abstract description 34
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 23
- 230000000844 anti-bacterial effect Effects 0.000 claims description 17
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 16
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 16
- 239000003899 bactericide agent Substances 0.000 claims description 13
- 239000002736 nonionic surfactant Substances 0.000 claims description 9
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims description 8
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 8
- -1 alkyl glycoside Chemical class 0.000 claims description 8
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 8
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 8
- 150000002191 fatty alcohols Chemical class 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 229920002675 Polyoxyl Polymers 0.000 claims description 5
- 238000009472 formulation Methods 0.000 claims description 5
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 claims description 4
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 claims description 4
- 238000005187 foaming Methods 0.000 claims description 4
- 229930182470 glycoside Natural products 0.000 claims description 4
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 229920002413 Polyhexanide Polymers 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 2
- 239000002738 chelating agent Substances 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 125000000623 heterocyclic group Chemical group 0.000 claims description 2
- 229960001047 methyl salicylate Drugs 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 claims description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 229940061605 tetrasodium glutamate diacetate Drugs 0.000 claims description 2
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical group [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- CFJYNSNXFXLKNS-UHFFFAOYSA-N p-menthane Chemical compound CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 241000894007 species Species 0.000 claims 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims 1
- 230000003385 bacteriostatic effect Effects 0.000 abstract description 7
- 150000001875 compounds Chemical class 0.000 abstract description 7
- 241000588724 Escherichia coli Species 0.000 abstract description 3
- 241000191967 Staphylococcus aureus Species 0.000 abstract description 3
- 239000003599 detergent Substances 0.000 abstract 2
- 239000000523 sample Substances 0.000 description 18
- 238000012360 testing method Methods 0.000 description 13
- 239000005871 repellent Substances 0.000 description 11
- 230000002940 repellent Effects 0.000 description 11
- 241000238657 Blattella germanica Species 0.000 description 10
- 230000001846 repelling effect Effects 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 8
- 239000002994 raw material Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 241001674044 Blattodea Species 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 230000002035 prolonged effect Effects 0.000 description 3
- FAMJUFMHYAFYNU-UHFFFAOYSA-N 1-methyl-4-(propan-2-yl)cyclohex-1-ene Chemical compound CC(C)C1CCC(C)=CC1 FAMJUFMHYAFYNU-UHFFFAOYSA-N 0.000 description 2
- 241000255925 Diptera Species 0.000 description 2
- 241000700605 Viruses Species 0.000 description 2
- 230000000507 anthelmentic effect Effects 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 229940099259 vaseline Drugs 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- KFDNQUWMBLVQNB-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].[Na].[Na].[Na].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KFDNQUWMBLVQNB-UHFFFAOYSA-N 0.000 description 1
- 241000256111 Aedes <genus> Species 0.000 description 1
- 208000019901 Anxiety disease Diseases 0.000 description 1
- 244000165852 Eucalyptus citriodora Species 0.000 description 1
- 235000004722 Eucalyptus citriodora Nutrition 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000036506 anxiety Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004459 forage Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006179 pH buffering agent Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a floor cleaner with insect-repellent effect, which can greatly prolong the insect-repellent time by using a compound of a cationic surfactant and an insect repellent. Meanwhile, by utilizing the advantages of the two components, the bacteriostatic rate of the detergent on escherichia coli and staphylococcus aureus is not less than 99%, and the detergent has the advantage of low cost.
Description
Technical Field
The invention belongs to the field of floor cleaners, and particularly relates to a floor cleaner with an insect-repellent effect.
Background
The floor is a carrier for bearing life activities in home, and is contacted by people at all times in home life, so that the requirements or the sensitivity of people on the sanitary environment of the floor are higher and higher, and the floor is particularly suitable for places frequently used in living rooms, kitchens, toilets and the like. However, these scenes are easily attacked by insects, such as cockroaches climb out to forage at night, mosquitoes invade everywhere, and the like, and at ordinary times, these insects often hide in a dark and humid environment, the environment is dirty, and they are easy to transmit bacteria, viruses and the like in activities, so that the safety and health of people are affected.
At present, household floor cleaning agents in the market mainly remove dirt and clean, and due to epidemic situations, a plurality of floor cleaning agent products in the market are added with some bactericide components, so that the floor cleaning agents have certain bacteriostatic and sterilizing effects, and the worries of the public about invisible bacteria and viruses are relieved to a certain extent. However, insects such as mosquitoes and cockroaches which are often seen in domestic environments are really the pests which most dislike consumers and most transmit bacteria and influence domestic sanitary environments. Most of the currently marketed floor cleaners are free of insect-repellent components, and some floor cleaners are declared to have insect-repellent effects, and basically, some perfume is added to achieve insect-repellent effects, so that the actual insect-repellent effect is common. Meanwhile, the added perfume is easy to volatilize, and when the volatilization amount reaches a certain amount, the effect of repelling insects is very poor, and the insect repelling effect of 24 hours or more lasting is often not achieved. Therefore, there is an urgent need to develop a long-lasting floor cleaner with insect repellent effect to solve the consumer's anxiety to the maximum extent.
Disclosure of Invention
The inventors of the present application have found that a surfactant commonly used in floor cleaner formulations is a nonionic surfactant, and when an insect-repellent ingredient is directly added to the formulation system, the insect-repellent effect is effective for a short period of time, but cannot be sustained for a long time, and the practical application is greatly affected. Through long-term research, the anthelmintic time can be greatly prolonged when the quaternary ammonium salt bactericide and the eucalyptus citriodora oil and other anthelmintic components are compounded and used. Meanwhile, when the quaternary ammonium salt and the guanidine bactericide are compounded, the bacteriostasis rate of escherichia coli and staphylococcus aureus is not less than 99%, and the preparation method has the advantage of low cost.
Furthermore, the invention provides a floor cleaning agent with insect-repelling effect, which comprises the following components in percentage by weight:
further, the nonionic surfactant comprises fatty alcohol polyoxyl EO/PO.
Further, the fatty alcohol polyoxyl EO/PO has the following structural formula: R1-EOm/POn-H
Wherein: r1 is a linear or branched alkyl or alkenyl group having 5 to 18 carbon atoms, EO is an ethoxylated vinyl group, and PO is an ethoxylated propenyl group. EO/PO are linked by random or block polymerization. m and n represent the average addition number, m is 1 to 50, and n is 0.5 to 20.
Further, the fatty alcohol polyoxyl EO/PO is available from raw material manufacturers such as BASF, solvay, and Londow, and specific classes include Pluronic PE Series raw material of BASF, antarox Series of Solvay, rhodasurf Series, HIF Series of Londow, and the like.
Furthermore, the addition amount of the nonionic surfactant in the formula is 1-10%, preferably 1.0-4.0%.
Further, the nonionic surfactant further comprises an auxiliary low-foaming nonionic surfactant, such as fatty alcohol polyoxyethylene ether (Lutensol XL 70), alkylphenol polyoxyethylene ether, alkyl glycoside, and the like, preferably alkyl glycoside, and the specific types include GREENAPG 0810 (shanghai kaiki chemical industry), GREENAPG IC 08 (shanghai kaiki chemical industry), and the like.
Further, the auxiliary low-foaming surfactant is 0.0-2.0%, preferably 0.0-1.0% in the formula.
Further, the bactericide is a compound of a cationic surfactant and a guanidine bactericide. Experiments show that the cationic surfactant not only can endow the formula with degerming capability, but also is beneficial to prolonging the insect-repellent effect of the insect repellent.
Further, the cationic surfactant is a cationic surfactant containing a quaternary ammonium group.
Further, the cationic surfactant is one or more of alkyl quaternary ammonium salt, quaternary ammonium salt containing hetero atom, quaternary ammonium salt containing benzene ring and quaternary ammonium salt containing heterocycle, preferably alkyl quaternary ammonium salt, and more preferably dodecyl dimethyl benzyl ammonium chloride (1227) and hexadecyl trimethyl ammonium chloride (1631).
Furthermore, the dosage of the cationic surfactant is 0.1-5.0%.
Further, the guanidine bactericide may be PHMG and PHMB. By compounding the cationic surfactant and the guanidine bactericide, the formula can have the bacteriostatic effect on escherichia coli and staphylococcus aureus reaching over 99 percent when diluted by 100 times.
Furthermore, the dosage of the guanidine bactericide is 0.1-5.0%.
Further, the insect repellent is one or more of menthene glycol, methyl salicylate and 1, 8-cineole, and is preferably menthene glycol.
Further, the amount of the insect repellent is 0.2 to 2.0%.
Further, the solvent is one or more of isohexane glycol, ethanol, propylene glycol and glycerol, preferably isohexane glycol.
Further, the chelating agent is tetrasodium glutamate diacetate and/or tetrasodium ethylene diamine tetraacetic acid.
Further, the floor cleaner may also include other optional additional functional materials, including pH adjusters, such as amines, acids, and other pH buffering agents.
Advantageous effects
The floor cleaner formula obtained by the invention has the following effects:
1) By using the degerming compound formula, when the cleaning agent is diluted by 100 times or more for use, the bacteriostatic rate can reach 99%;
2) The insect repellant is compounded with the cationic bactericide, so that the insect repelling time of the formula is prolonged to more than 72 hours;
3) By using the insect expelling component, the repellent rate of the formula diluted by 5 times or more to the German cockroach reaches more than 85 percent, and the repellent rate to the Aedes mosquito reaches more than 50 percent.
Drawings
FIG. 1 shows the report of the external test for repelling insects given by the sample of the example in the third party testing unit.
Fig. 2 shows a diagram of a storage case test experiment in the insect repelling experiment.
Figure 3a shows the repellent effect of the base formulation on german cockroach in the initial state of the repellent experiment.
Fig. 3b shows the repellent effect of the compounded cationic surfactant on german cockroach in the initial state in the insect repelling experiment.
Figure 4a shows the repellency effect of the base formulation on german cockroach after 72 hours of application in the insect repellent experiment.
Fig. 4b shows the repellent effect of the compounded cationic surfactant on german cockroach after 72 hours of pesticide application in the insect repelling experiment.
Detailed Description
The invention will be further illustrated with reference to the following specific examples. It should be understood that these examples are for illustrative purposes only and are not intended to limit the scope of the present invention. Further, it should be understood that various changes or modifications of the present invention may be made by those skilled in the art after reading the teaching of the present invention, and such equivalents may fall within the scope of the present invention as defined in the appended claims.
Examples 1 to 5
Weighing the raw materials according to the weight percentage shown in the table 1, and mixing to obtain the cleaning agent.
Control sample
Weighing the raw materials according to the weight percentage shown in the table 1, and mixing to obtain the cleaning agent.
TABLE 1
The bottom in the storage box is divided into two parts, and from the storage box mouth 10cm scribble a layer vaseline paraffin mixture (2) to prevent that the cockroach from escaping, scribble the sample to be measured (dilution multiple 1. Recording the number of the test insects at the blank end and the pesticide application end after 24h, and calculating the repelling rate: (blank end-sample end)/total x 100%, the results are shown in Table 2.
Table 2 insect repellent performance test
According to the evaluation method of the antibacterial and bacteriostatic effects of QB/T2738-2012 daily chemical products, namely 7.3 the antibacterial effect test method (suspension quantification method) of antibacterial daily chemical products, the antibacterial performance of each embodiment when diluted 100 times is shown in Table 3.
TABLE 3 bacteriostatic Properties test
The detergency was measured according to QB/T4532-2013, and the results are shown in Table 4.
TABLE 4 detergency test results
| Sample (I) | Comparative sample | Example 1 | Example 2 | Embodiment 3 | Example 4 | Example 5 |
| Detergency (%) | 95.6％ | 93.9％ | 94.0％ | 94.2％ | 95.1％ | 95.6％ |
Test 5 insect repellent test
Dividing a storage box (as shown in figure 2) into two equal parts, coating a layer of vaseline and paraffin mixture (2. And (3) recording the number of the test insects at the blank end and the application end after 24h, and calculating the repelling rate: the calculation method comprises the following steps: (blank end-sample end)/total × 100%. Wherein, the blank end is a sample of a basic formula, namely a sample without adding a cationic surfactant and with adding an insect repellent; the pesticide application end is a sample of the compound cationic surfactant, namely a sample added with the cationic surfactant and the insect repellent at the same time.
As shown in fig. 3a and 3b, both the basic formula sample and the sample of the compound cationic surfactant generate repellent effects on german cockroach in the initial state, which indicates that the initial repellent effects of the basic formula sample and the sample of the compound cationic surfactant on german cockroach can reach 100%.
As shown in fig. 4a and 4b, after the basic formula sample and the compound surfactant sample are coated for 72 hours, insect repelling effect tests are carried out, and tests show that the repellent effect of the sample added with the cationic surfactant on the german cockroach can reach 93.3%, and the repellent effect of the sample not added with the cationic surfactant on the german cockroach is 46.7%. The cationic surfactant is added according to the formula relative to the basic formula, so that the repellent effect of the product on the German cockroach is prolonged.
Claims (10)
1. A floor cleaner with insect-repellent effect comprises the following components in percentage by weight:
2. the floor cleaner having insect repellent effect of claim 1, wherein the nonionic surfactant comprises fatty alcohol polyoxyl EO/PO, and the fatty alcohol polyoxyl EO/PO has the following structural formula: R1-EOm/POn-H
Wherein: r1 is a linear or branched alkyl or alkenyl group having 5 to 18 carbon atoms, EO is an ethoxylated vinyl group, and PO is an ethoxylated propenyl group. EO/PO are bonded by random polymerization or block polymerization, m and n represent average addition numbers, m is 1 to 50, and n is 0.5 to 20.
3. The floor cleaner having insect-repellent effect according to claim 2, wherein the nonionic surfactant is added in an amount of 1.0 to 4.0% in the formulation.
4. The floor cleaner with insect-repellent effect according to claim 1, wherein the nonionic surfactant further comprises an auxiliary low-foaming nonionic surfactant which is one or more of fatty alcohol polyoxyethylene ether (Lutensol XL 70), alkylphenol polyoxyethylene ether and alkyl glycoside, preferably alkyl glycoside, and the auxiliary low-foaming surfactant is 0.0-2.0%, preferably 0.0-1.0% in the formula.
5. The floor cleaner having insect-repellent effect according to any one of claims 1 to 4, wherein the bactericide is a cationic surfactant and guanidine bactericide complex.
6. The floor cleaner having an insect-repellent effect according to claim 5, wherein the cationic surfactant is a cationic surfactant containing a quaternary ammonium group, and the cationic surfactant is one or more of alkyl quaternary ammonium salt, quaternary ammonium salt containing hetero atom, quaternary ammonium salt containing benzene ring and quaternary ammonium salt containing heterocycle, preferably alkyl quaternary ammonium salt, and more preferably the species are dodecyl dimethyl benzyl ammonium chloride (1227) and hexadecyl trimethyl ammonium chloride (1631).
7. The floor cleaner having insect-repellent effect according to claim 5, wherein the cationic surfactant is used in an amount of 0.1 to 5.0%.
8. The floor cleaner having insect-repellent effect according to claim 5, wherein the guanidine bactericide is PHMG or PHMB.
9. The floor cleaner having insect-repellent effect according to claim 5, wherein the guanidine bactericide is used in an amount of 0.1 to 5.0%.
10. The floor cleaner having insect-repellent effect according to any one of claims 1 to 5, wherein the insect-repellent agent is one or more of menthane glycol, methyl salicylate, 1, 8-cineole, preferably menthane glycol; the dosage of the insect repellent is 0.2 to 2.0 percent; the solvent is one or more of isohexane glycol, ethanol, propylene glycol and glycerol, preferably isohexane glycol; the chelating agent is tetrasodium glutamate diacetate and/or tetrasodium ethylene diamine tetraacetate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211606777.3A CN115895797A (en) | 2022-12-14 | 2022-12-14 | Floor cleaning agent with insect expelling effect |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211606777.3A CN115895797A (en) | 2022-12-14 | 2022-12-14 | Floor cleaning agent with insect expelling effect |
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| CN115895797A true CN115895797A (en) | 2023-04-04 |
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| CN202211606777.3A Pending CN115895797A (en) | 2022-12-14 | 2022-12-14 | Floor cleaning agent with insect expelling effect |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1094087A (en) * | 1993-04-08 | 1994-10-26 | 科尔加特·帕尔莫利弗公司 | The household liquids detergent composition that contains wormer |
| CN111117805A (en) * | 2019-12-10 | 2020-05-08 | 中山榄菊日化实业有限公司 | Floor cleaner composition and preparation method thereof |
| CN114317134A (en) * | 2021-11-30 | 2022-04-12 | 广州市浪奇实业股份有限公司 | Floor cleaning agent |
| CN114467934A (en) * | 2021-11-30 | 2022-05-13 | 广州市浪奇实业股份有限公司 | Antibacterial and insect-expelling composition |
-
2022
- 2022-12-14 CN CN202211606777.3A patent/CN115895797A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1094087A (en) * | 1993-04-08 | 1994-10-26 | 科尔加特·帕尔莫利弗公司 | The household liquids detergent composition that contains wormer |
| CN111117805A (en) * | 2019-12-10 | 2020-05-08 | 中山榄菊日化实业有限公司 | Floor cleaner composition and preparation method thereof |
| CN114317134A (en) * | 2021-11-30 | 2022-04-12 | 广州市浪奇实业股份有限公司 | Floor cleaning agent |
| CN114467934A (en) * | 2021-11-30 | 2022-05-13 | 广州市浪奇实业股份有限公司 | Antibacterial and insect-expelling composition |
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