CN1094087A - The household liquids detergent composition that contains wormer - Google Patents
The household liquids detergent composition that contains wormer Download PDFInfo
- Publication number
- CN1094087A CN1094087A CN94104604A CN94104604A CN1094087A CN 1094087 A CN1094087 A CN 1094087A CN 94104604 A CN94104604 A CN 94104604A CN 94104604 A CN94104604 A CN 94104604A CN 1094087 A CN1094087 A CN 1094087A
- Authority
- CN
- China
- Prior art keywords
- wormer
- detergent composition
- mgk
- liquid detergent
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0017—Multi-phase liquid compositions
- C11D17/0021—Aqueous microemulsions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Abstract
The invention provides a kind of aqueous liquid detergent compositions that cleans crust and can expel insect, the washing composition part that comprises the surface-active detergent compound, at least a definite effective wormer material, after being enough to make on the described crust this liquid detergent composition of coating, can drive away the insect on it.This liquid detergent composition is substantially free of liquid hydrocarbon.
Description
The present invention relates to liquid detergent composition, said composition is suitable for washed hardened surface, and has the expelling parasite characteristic.The present invention more specifically relates to the full-service fluid detergent composition that contains the wormer material, also relates on some surfaces and article applying this detergent composition to wash and the anthelmintic method.
Common various insects in the family, for example Germany cockroach (Groton bug) or indoor cockroach all are classified as insect, and people have been devoted to its elimination or have made it controlled at least.Mosquitocide is sold on market for a long time, and, also found the multiple chemical agent that can effectively drive away cockroach.When using these chemical agents and wormer in the family, generally be with its coating or be sprayed on the surface of wall, floor, cabinet, drawer, parcel, container, woollen blanket, upholster and carpet and place that these insects may live on trees, for example between in the wall or floor.Yet, also at large wormer and hard surface detergent are not used together up to now, so that wash crust for example kitchen wall, baking box top, bathroom floor or similar surface in the family effectively, meanwhile on the surface of these coated compositions, can form the film of a considerable amount of wormer materials, thus can deinsectization.
Adding wormer at the polishing product that is used for the family floor, is known in the present technique field.U.S. Patent No. 3,018 217(Bruce) discloses and has contained the floor wax coating composition of dibutyl succinate as wormer.U.S. Patent No. 3,034, people such as 950(Goodhue) a kind of vermifuge compound is disclosed, said composition can be coated on the surface in wax in disperse.U.S. Patent No. 4,455 has been narrated the wormer prescription that comprises liquid aliphatic for example or aromatic hydrocarbon liquid vehicle in 308(Smolanoff).Can in this liquid hydrocarbon, add for example nonionogenic tenside of emulsifying agent, said composition is dispersed in the water so that use as finished product.U.S. Patent No. 4,822 614(Rodero) discloses wormer composition in a kind of alkyl solvent (for example isoparaffin class).
The invention provides a kind of can washed hardened surface and can the anthelmintic aqueous liquid detergent compositions, said composition comprises that (ⅰ) is selected from the washing composition part of the surface-active detergent compound that comprises negatively charged ion, nonionic, positively charged ion and zwitterionic detergent compounds; Water (ⅱ) by weight) at least about 50%(; (ⅲ) the wormer material of significant quantity, be enough to make crust to apply this detergent composition after, can drive away this lip-deep insect.This liquid detergent composition does not contain sterilant.
The present invention is based on discovery when washing specific surface or position with detergent composition of the present invention, and the expelling parasite characteristic of wormer material is enhanced at such position.This effect is that natural habit and the surface after washing and cleaning of not liking to rest on the clean surface because insect preference accumulates in filthy surface have increased in fact due to the wormer material.
Term used herein " insect " is a generalized, the insect of indication comprises the cockroach class, for example for example spider, flat lice and acarian of (american cockroach) cockroach of De Guo (Groton bug) and the U.S. and mosquito, moth, fly, flea, ant, lice and spider guiding principle insect.
Term " wormer material " refers to and comprises various materials, this material has disinsectization performance, can with the detergent composition compatibility of type described herein, and can be on the crust of coated detergent composition as the wormer directly generation effect fully that proves effective.
Be used for wormer material of the present invention and comprise following compounds, they can use separately or be used with other wormer material, and the parenthetic trade mark after following certain compound name is referred to as is meant its commerce or the general trade mark:
The new alkanamides of N-alkyl, wherein, the carbonatoms of alkyl is 1-4, the carbonatoms of new alkane acyl part is 7-14, the preferred new decyl amide of N-methyl;
N, the N-diethyl--toluamide (DEET);
The 2-hydroxyethyl-just-octyl group thioether (MGK 874);
1
N-octyl group-bicycloheptene-dicarboxyl imide (MGK 264);
Preferably include the mixture of above-mentioned two kinds of materials (66%MGK 264 and 33%MGK 874);
Hexahydro-dibenzofuran-carboxyl aldehyde (MGK 11);
Pyridinedicarboxylic acid two-just-propyl ester (MGK 326);
2-ethyl-1,3-hexylene glycol (Rutgers 612);
The 2-(normal-butyl)-and 2-ethyl-1, ammediol;
Dimethyl phthalate;
Dibutyl succinate (Tabutrex);
Piperonyl butoxide; With
Pyrethrum
(1)The MGK wormer is McLaughlin Gormley King Company; Minneapo-lis; Minnesota, the trade mark of USA..
Though above-mentioned wormer material is more long lasting, and be that the present invention is preferred, yet other effective wormer material also comprise for example peppermint (Cornmint) of essential oil class; Mentha piperita (Mentha arvensis L. syn.M.haplocalyxBrig); Spearmint (U.S. spearmint); Mentha cardica(mentha cardiaca); Lemongrass volatile oil; Lemon oil; Lemongrass; Cdear (Sabina virginiana L.); And pine tar.Terpenoid is the another kind of material with wormer characteristic, the most effectively (-)-limonene; (+)-limonene; (-)-Karvon; Terpane (eucalyptol); Linalool; Camphor glue; Geranial; α and β-terpinol; Fencholic acid; Borneol, iso-borneol, dl-Bornyl Acetate and isobornyl acetate.
In no commercially available wormer material, be useful for of the present invention as follows:
N, N-diethyl-cyclohexyl ethanamide (DECA)
1,2,3,6-tetrahydrochysene-1-(2-methyl isophthalic acid-oxo amyl group) piperidines
N, N-diethyl-3-cyclohexyl propionic acid amide (DCP)
2-ethyl-1-(2-methyl isophthalic acid-oxo-crotyl) piperidines
N, N-diethyl pelargonamide and
N, N-diethylbenzene ethanamide.
About the above-mentioned new alkanamides of N-alkyl, wherein alkyl preferable methyl or ethyl, most preferable.Preferred new decanoyl of new alkane acyl part or new tridecanoyl.
Detergent composition of the present invention contains one or more washing composition parts that is selected from the surface-active detergent compound of negatively charged ion, nonionic, positively charged ion and zwitterionic detergent, usually, the content of this washing composition part be about composition 1% to about 30%(by weight), preferably by weight from about 2% to about 20%().Preferred washing composition is the synthetic organic detergent of negatively charged ion or non-ionic type, and negatively charged ion and nonionic detergent composition usually are most preferred.The detailed description of relevant these many washing composition can be at Interscience Publishers, Inc.1958 publishes Schwartz, the Sur-face Active Agents and Detergents that Perry and Berch write, Vol, p.25-138 II is found in the literary composition.This compounds has also been done introduction in the article that is entitled as Deter-gents and Emulsifiers that John W.McCutcheon1973 publishes, these two kinds of publications all are incorporated in this as a reference.
Common employed anionic detergent is for example sodium, potassium or ammonium or rudimentary alkanol ammonium salts, for example a triethanolamine salt of an alkali metal salt.This anionic detergent can be the salt of the suitable acid of vitriol, sulfonate, phosphoric acid salt or phosphonate or other, but, and normally vitriol or sulfonate.Anionic detergent comprises having the 10-18 carbon atom usually, oleophilic group that the high-grade alkyl of preferred straight chain is arranged, however other oleophilic group can replace, and preferably includes the 12-16 carbon atom, for example the alkylbenzene of side chain.The example of the anionic detergent that is fit to comprises the high-grade fatty alcohol sulfonate, for example the tridecyl benzene sulfonic acid sodium salt; Linear alkylbenzene sulphonic acid, for example linear alkyl benzene sulphonate; Olefin sulfonate; With the sulfonic acid alkane ester.This anionic detergent particular certain cancers, but, sylvite, ammonium salt and some liquid detergent composition of triethanol ammonium salt pair are often more suitable.
Suitable nonionic detergent is lipophilic cpd or oleophilic moiety and rudimentary alkylene oxide or poly-alkoxyl group condensation product partly normally.Particularly preferred lipophilic cpd is the high fatty alcohol of 10-18 carbon atom, but also can use alkylphenol, for example octyl phenol and nonyl phenol.Preferred alkylene oxide is an oxyethane, and contains the 3-30 moles of ethylene oxide in common every mole of lipophilic cpd.Preferred this ethoxylate content is that every mole of high fatty alcohol contains the 3-10 mole, more preferably 6-7 mole, and for example every mole of high fatty alcohol (with every mole of nonionic detergent) contains 6.5 or 7 moles.The ethoxylate of wide region and close limit (BRE ' s and NRE ' s) all can use, difference therebetween is ethoxylate group quantity " distribution " (its mean value is in given range) wherein.For example, in nonionic detergent, the NRE ' s of every mole of average 5-10EtO group will have at least 70% EtO content in the polyethoxye group of 4-12 mole EtO, and preferably the EtO content in this scope is higher than 85%.Compare with NRE, the BRE nonionic detergent has the oxyethyl group content of a wider range, when the EtO chain when 5-10EtO scope (mean value), common scope is 1-15 mole EtO.The example of BRE nonionic detergent comprises that Shell Chemical Company is with Neodol
RTrade mark is sold comprises Neodol 25-7, Neodol 23-6.5 and Neodol 25-3.Can obtain the NRE nonionic detergent from Shell Develop-ment Company, the trade mark of this washing composition is 23-7P and 23-7Z.
The cation surface activating compound also can use.These compounds comprise the surface-active detergent compound, and they contain organic hydrophobic group (can form partial cation when these compounds are water-soluble) and anionic group.Typical cationic detergent is amine and quaternary ammonium compound.
The used quaternary ammonium compound of the present invention is known and the material of the softening type of Chang Weigao, comprises N, N-two-(senior) C
14-C
24, N, N-two-(rudimentary) C
1-4Alkyl quaternary ammonium salts, and the negatively charged ion that contains water soluble for example chlorion, bromide anion and iodide ion of halogen ion for example; Sulfate radical, methylsulfate and similar ion and heterocycleamide be tetrahydroglyoxaline for example.
For simplicity, this aliphatic quaternary ammonium salt structurally can be defined as follows:
In the formula, R and R
1Expression 14-24, the alkyl of preferred 14-22 carbon atom; R
2And R
3Expression 1-4, the low alkyl group of preferred 1-3 carbon atom, X represents to have water-soluble or dispersed negatively charged ion and comprises above-mentioned chlorion, bromide anion, iodide ion, sulfate radical and methylsulfate.
Particularly preferred several aliphatic quaternary ammonium salt comprises:
The stearic bicine diester alkyl dimethyl ammonium chloride
Two-h-tallow fat alkyl dimethyl ammonium chloride
Two-shea butter alkyl dimethyl ammonium chloride
Stearic bicine diester dimethyl sulfate ammonium methyl esters
Two-h-tallow fat dimethyl sulfate ammonium methyl esters
Zwitterionic detergent also is applicable to the present invention.This class washing composition is well-known in the present technique field, Schwartz, Perry and Berch in " Surface Active Agents and Detergents ", Vol. II, Interscience Publishers, Inc., New York(1958) in Chapter 4 thereof disclose the washing composition of many practicalities.The example of the zwitterionic detergent that is suitable for comprises: β-imino-diacetic alkyl propionates, RN(C
2H
4COOM)
2; With β-An Jibingsuan alkyl ester, RN(H) C
2H
4COOM.
Can contain from about 1% to about 20% builder in the liquid detergent composition, to strengthen the detersive power of synthetic organic detergent.Builder can be inorganic or organic, and is water miscible or water-insoluble.Comprise the Tripyrophosphoric acid salt in the builder, for example tripoly phosphate sodium STPP; Carbonate, for example yellow soda ash; Bicarbonate salts, for example sodium bicarbonate; Borate family, for example borax; And silicates, for example water glass; The inorganic builder of water-insoluble comprises zeolite, for example hydrated zeolite 4A; With water miscible organic synergistic auxiliary agent, comprise Citrate trianion, gluconate, NTA and polyacetal carboxylate.
Can be contained in various auxiliarys in this detergent composition and be for example white dyes, static inhibitor, antiseptic-germicide, sterilant, whipping agent, antifoams, flow promoting agent, suspension agent, antioxidant, anti-gelling agent, decontamination promotor and enzyme.
Liquid detergent composition of the present invention generally includes from about 2% to about 20% surface-active detergent compound (preferred anionic and/or nonionic), from about 1% to about 20%(by weight) the builder salt of this washing composition, with from about 0.2% to about 20%, preferred 0.5%-10%(is by weight) the wormer material, rest part is mainly for example for example Virahol or acetone of toluenesulfonic acid sodium salt or the solvent that is suitable for the wormer material of water, auxiliary and optional emulsifying agent or hydrotropic agent.For the ease of in aqueous liquid detergent compositions, adding spices or perfume, be that external phase and oil or hydrocarbon are disperse phase usually with water, this liquid detergent composition is made the microemulsified shape.
In application test, on real kitchen floor, sales counter, draining board and the wall, in kitchen cabinet and under the refrigerator, in large quantities of rooms that cockroach occurs, with these surfaces of liquid detergent composition of the present invention coating or near compare with contrast surface and can find that cockroach obviously reduces, if handle wall, can find on the cabinet bottom at this place and the shelf and the minimizing of the cockroach in the pantry with detergent composition of the present invention.If with the door in liquid detergent composition processing of the present invention floor, wall, sales counter, rinse bath, cabinet, house or apartment, the influence degree that cockroach is invaded and harassed will reduce than the contrast apartment of uncoated wormer.
Embodiment 1
With following a kind of according to the present invention the composition of prescription as starting raw material, by the liquid composition of 6 kinds of different dilute strengths of dilution preparation, wherein corresponding N-methyl-Xin decyl amide (MNDA) the wormer material that contains 6 kinds of different contents.
The crust liquid washing agent
The composition weight percentage
Linear alkyl benzene sulphonate 4
Nonionic detergent
(1)2
MNDA 2.0
Cocoanut fatty acid 0.5
SODA ASH LIGHT 99.2 2
Sodium bicarbonate 1
Virahol 4
Water all the other
Spices 1
(1)The condensation product of the mixture of the Fatty Alcohol(C12-C14 and C12-C18) of 1 mole of 9-11 carbon atom and 6 moles of ethylene oxide.
Each MNDA percentage of 6 kinds of test detergent composition is all different, is respectively: 0.12,0.20,0.22,0.29,0.4 and 2.0%.
According to the following steps the deworming rates of each in the detergent composition of above-mentioned 6 kinds of washed hardened surfaces is tested, and with 3 kinds contain reference composition (promptly 3 kinds contain respectively 0.25,0.5 and 1.0%(by weight) acetone soln of MNDA) and the deworming rates that wormer had make comparisons.
Testing sequence
The Germany and the U.S. cockroach of insect-will form colony remain under 27 ℃ of conditions.The carpented ant of collecting from the log of the colony that accommodates queen remains under the condition identical with cockroach with worker ant.
Biological assay-measuring preceding 48 hours of beginning allows 50 male cockroaches of Germany adapt to plastics testing cage (51 * 28 * 20cm) the environment that there are food and water in the middle part.Teflon latex film is arranged on each limit of cage, and (Woonsocket R.I.) limits these insects and climbs at the bottom of the cage for Fluon AD-1, Northern products.Used determination object or 50 female cockroaches of Germany, 20 male cockroaches of the U.S. or 50 carpented ants and worker ant.
At test period, estimate the deworming rates of underproof different compositions.Testing sequence comprises the barrier (" cup ") that 53 * 3 inches bitumen sheets is arranged in solid figure, and handles this bitumen sheets with different subject composition.Surface after the processing inwardly.This method depends on the light avoiding reaction of cockroach.2 milliliters of subject composition are coated on the total inner surface of cup.The contrast cup is only with acetone or water treatment.Allow these glasss drying 1 hour, then, will contrast cup and handle cup and put upside down in each test cage.Food and water are infeeded central authorities' (outside cup) of each cage.Mid-term in photostage every day record rest on insect number on each glass inwall, write down altogether 25 days or the static insect number in finding treated or unprocessed cup when equating till.Behind each counting, the disturbance insect is also put upside down the position of handling cup and contrast cup.Therefore, can think arbitrary gives settled date disturbance insect a few days ago disturbance is irrelevant therewith.
Deworming rates is defined as hiding the percentage of the insect of treat surface, and calculates with following formula:
Deworming rates %=(100 * (N
t))/((N
t+ N
c))
In the formula, N
tBe the insect number on the treat surface, N
cIt is the insect number on the contrast surface of acetone treatment.With the fate that reaches 90% deworming rates is the deworming rates of several compounds of basic evaluation, this deworming rates based on (ⅰ) fully the maximum possible probit (maximum likelihood probit) of fate (ⅱ) time/deworming rates of deworming rates (100%) analyze (SASUser ' s Guide, SAS Institute 1985), can calculate 90% deworming rates (RT thus
90-10% insect is on treat surface, and 90% insect is on contrast surface) the measurement result of fate.
The deworming rates test-results is shown in Fig. 1, and it shows that the fate that reaches 90% deworming rates is the function of MNDA percentage ratio in subject composition.
As shown in the figure, can not reach 90% deworming rates not according to reference composition of the present invention (MNDA wormer content is 0.25%).On the contrary, composition of the present invention (MN-DA wormer content is 0.2%) just can reach 90% deworming rates in similar 3 days.
Claims (13)
1, a kind of washed hardened surface and energy anthelmintic aqueous liquid detergent compositions of being used for, said composition comprises that (i) is selected from the washing composition part of the surface-active detergent compound that comprises negatively charged ion, nonionic, positively charged ion and zwitterionic detergent compounds and its mixture; (ii) at least about the water of 50% (by weight); The (iii) wormer material of significant quantity is enough to make on the described crust behind this liquid detergent composition of coating, can drive away the insect on it, and described liquid detergent composition does not contain sterilant.
2, liquid detergent composition according to claim 1, wherein, described wormer material is selected from N, the N-diethyl--toluamide (DEET), the 2-hydroxyethyl-just-octyl group thioether (MGK 874), N-octyl group-bicycloheptene-dicarboxyl imide (MGK 264), a kind of mixture that comprises MGK 264 and MGK 874 combinations, hexahydro-dibenzofuran-carboxyl aldehyde (MGK 11), pyridinedicarboxylic acid two-just-propyl ester (MGK 326), 2-ethyl-1,3-hexylene glycol (Rutgers 612), the 2-(normal-butyl)-2-ethyl-1, ammediol, dimethyl phthalate, dibutyl succinate (Tabutrex), piperonyl butoxide, and pyrethrum.
3, according to the liquid detergent composition of claim 1, comprise the water-soluble solvent that is used for described wormer material in addition.
4, according to the liquid detergent composition of claim 3, wherein, described solvent is a Virahol.
5, according to the liquid detergent composition of claim 1, comprise by weight from about 2% to about 20%() described surface-active detergent compound, by weight from about 1% to about 20%() builder salt and by weight from about 0.2% to about 20%() described wormer material.
6, according to the liquid detergent composition of claim 5, wherein, described wormer material is N, the N-diethyl--toluamide.
7, according to the liquid detergent composition of claim 1, wherein, described wormer material is the new decyl amide of N-methyl.
8, the method for a kind of washed hardened surface and expulsion insect, be included in application of liquid detergent composition on the described crust, said composition comprises that (ⅰ) is selected from the washing composition part of the surface-active detergent compound that comprises negatively charged ion, nonionic, positively charged ion and zwitterionic detergent compounds and its mixture; Water (ⅱ) by weight) at least about 50%(; (ⅲ) the wormer material of significant quantity, be enough to make on the described crust this liquid detergent composition of coating after, can drive away the insect on it, described liquid detergent composition does not contain sterilant.
9, method according to Claim 8, described wormer material is selected from N, the N-diethyl--toluamide (DEET), the 2-hydroxyethyl-just-octyl group thioether (MGK 874), N-octyl group-bicycloheptene-dicarboxyl imide (MGK 264), a kind of mixture that comprises MGK 264 and MGK 874 combinations, hexahydro-dibenzofuran-carboxyl aldehyde (MGK 11), pyridinedicarboxylic acid two-just-propyl ester (MGK 326), 2-ethyl-1,3-hexylene glycol (Rutgers 612), the 2-(normal-butyl)-2-ethyl-1, ammediol, dimethyl phthalate, dibutyl succinate (Tabutrex), piperonyl butoxide, and pyrethrum.
10, method according to Claim 8, wherein, described detergent composition also comprises the solvent that is used for described wormer material.
11, according to the method for claim 10, wherein, described solvent is a Virahol.
12, method according to Claim 8, wherein, described detergent composition comprises from about 2% to about 20%(by weight) described surface-active detergent compound, by weight from about 1% to about 20%() builder salt and by weight from about 0.2% to about 20%() described wormer material.
13, method according to Claim 8, wherein, described wormer material is the new decyl amide of N-alkyl.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4413893A | 1993-04-08 | 1993-04-08 | |
| US4413793A | 1993-04-08 | 1993-04-08 | |
| US044,138 | 1993-04-08 | ||
| US044,137 | 1993-04-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1094087A true CN1094087A (en) | 1994-10-26 |
Family
ID=26721210
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94104604A Pending CN1094087A (en) | 1993-04-08 | 1994-04-07 | The household liquids detergent composition that contains wormer |
Country Status (24)
| Country | Link |
|---|---|
| EP (1) | EP0619363A1 (en) |
| JP (1) | JPH06313199A (en) |
| CN (1) | CN1094087A (en) |
| AU (1) | AU679484B2 (en) |
| BG (1) | BG98700A (en) |
| BR (1) | BR9401414A (en) |
| CA (1) | CA2119832A1 (en) |
| CZ (1) | CZ82994A3 (en) |
| DZ (1) | DZ1770A1 (en) |
| HN (1) | HN1994002558A (en) |
| HU (1) | HUT67855A (en) |
| MA (1) | MA23153A1 (en) |
| MY (1) | MY118351A (en) |
| NZ (1) | NZ260145A (en) |
| OA (1) | OA09933A (en) |
| PE (1) | PE6395A1 (en) |
| PL (1) | PL177733B1 (en) |
| PT (1) | PT101478B (en) |
| RO (1) | RO114630B1 (en) |
| SK (1) | SK40894A3 (en) |
| TN (1) | TNSN94029A1 (en) |
| UY (1) | UY23753A1 (en) |
| YU (1) | YU48782B (en) |
| ZA (1) | ZA942051B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1100859C (en) * | 1998-10-16 | 2003-02-05 | 乙基公司 | Turbine oil with exellent stability for oxidation at high temperature |
| CN102920617A (en) * | 2012-11-15 | 2013-02-13 | 四川大学 | Liquid type deet composition and preparation thereof |
| CN108991035A (en) * | 2018-08-27 | 2018-12-14 | 佛山科学技术学院 | A kind of insect repellent lotion for home textile |
| CN115895797A (en) * | 2022-12-14 | 2023-04-04 | 中山榄菊日化实业有限公司 | Floor cleaning agent with insect expelling effect |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5610130A (en) * | 1993-08-04 | 1997-03-11 | Colgate-Palmolive Company | Microemulsion all-purpose liquid cleaning compositions with insect repellent |
| ZA952386B (en) * | 1994-04-15 | 1996-09-23 | Colgate Palmolive Co | Microemulsion liquid cleaning compositions with insect repellent |
| AU681487B2 (en) * | 1994-04-15 | 1997-08-28 | Colgate-Palmolive Company, The | Microemulsion all purpose liquid cleaning compositions with insect repellent |
| EP0822859B1 (en) * | 1995-04-27 | 2004-04-07 | Goldschmidt Chemical Corporation | Compositions containing diol |
| US5674832A (en) * | 1995-04-27 | 1997-10-07 | Witco Corporation | Cationic compositions containing diol and/or diol alkoxylate |
| GB9509603D0 (en) * | 1995-05-11 | 1995-07-05 | Unilever Plc | Insect-repellant compositions comprising polymer and nonionic surfactant |
| GB9609668D0 (en) * | 1996-05-09 | 1996-07-10 | Unilever Plc | Insect-repellant compositions comprising antimicrobial agents and nonionic surfactant |
| US5610194A (en) * | 1996-06-10 | 1997-03-11 | Colgate-Palmolive Company | Insect repelling compositions comprising mixtures of an N-alkyl neoalkanamide and DEET |
| US6548469B2 (en) | 1996-10-17 | 2003-04-15 | Merck Patent Gmbh | Cleaning compositions |
| DE19642957A1 (en) * | 1996-10-17 | 1998-04-23 | Merck Patent Gmbh | cleaning supplies |
| FR2755141B1 (en) * | 1996-10-30 | 1999-01-29 | Johan A Benckiser Gmbh | INSECT REPELLENT COMPOSITION FOR SOLID SURFACE |
| CO5040174A1 (en) * | 1997-12-12 | 2001-05-29 | Colgate Palmolive Co | ANTIMICROBIAL COMPOSITIONS FOR MULTIPLE MICROEMULSION PURPOSES CONTAINING A CATIONIC TENSIOACTIVE |
| FR2777014B1 (en) * | 1998-04-06 | 2004-01-02 | Benckiser Nv | INSECT REPELLENT LIQUID DETERGENT COMPOSITION FOR SOLID SURFACES |
| GB2351737B (en) * | 1999-07-06 | 2003-11-05 | Helen Dolisznyj | An insecticidal cleaner |
| GB0119660D0 (en) * | 2001-08-11 | 2001-10-03 | Quest Int | Insect repellents |
| JP2003226894A (en) * | 2002-02-04 | 2003-08-15 | Johnson Co Ltd | Detergent composition, and detergent sheet |
| GB0504296D0 (en) * | 2005-03-02 | 2005-04-06 | Reckitt Benckiser Au Pty Ltd | Insect expellant floor cleaner additive |
| JP6061222B2 (en) * | 2012-12-27 | 2017-01-18 | 株式会社大阪製薬 | Sanitary pest control agent |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5182305A (en) * | 1986-08-08 | 1993-01-26 | Colgate-Palmolive Co. | N-aryl and n-cycloakyl neoalkanamide insect repellents |
| US5258408A (en) * | 1986-08-08 | 1993-11-02 | Colgate-Palmolive Company | Process of repelling insects from an area by application of N-alkyl neoalkanamide insect repellent thereto |
| US5006562A (en) * | 1986-08-08 | 1991-04-09 | Colgate-Palmolive Co. | Processes for repelling insects by means of N-alkyl neoalkanamide insect repellents |
| US4804683A (en) * | 1986-08-08 | 1989-02-14 | Colgate-Palmolive Company | N-alkyl neotridecanamide insect repellents |
| IL102433A (en) * | 1991-07-24 | 1996-08-04 | Colgate Palmolive Co | Liquid household cleaning composition with insect repellent |
-
1994
- 1994-03-21 NZ NZ260145A patent/NZ260145A/en unknown
- 1994-03-23 ZA ZA942051A patent/ZA942051B/en unknown
- 1994-03-28 HN HN1994002558A patent/HN1994002558A/en unknown
- 1994-03-29 PT PT101478A patent/PT101478B/en active IP Right Grant
- 1994-03-31 RO RO94-00531A patent/RO114630B1/en unknown
- 1994-04-01 MA MA23457A patent/MA23153A1/en unknown
- 1994-04-04 DZ DZ940034A patent/DZ1770A1/en active
- 1994-04-05 MY MYPI94000817A patent/MY118351A/en unknown
- 1994-04-05 AU AU59262/94A patent/AU679484B2/en not_active Ceased
- 1994-04-05 CA CA002119832A patent/CA2119832A1/en not_active Abandoned
- 1994-04-05 UY UY23753A patent/UY23753A1/en unknown
- 1994-04-06 BR BR9401414A patent/BR9401414A/en not_active IP Right Cessation
- 1994-04-07 JP JP6069363A patent/JPH06313199A/en active Pending
- 1994-04-07 OA OA60492A patent/OA09933A/en unknown
- 1994-04-07 PL PL94302938A patent/PL177733B1/en unknown
- 1994-04-07 CN CN94104604A patent/CN1094087A/en active Pending
- 1994-04-07 BG BG98700A patent/BG98700A/en unknown
- 1994-04-07 EP EP94200951A patent/EP0619363A1/en not_active Withdrawn
- 1994-04-07 HU HU9400997A patent/HUT67855A/en unknown
- 1994-04-08 CZ CZ94829A patent/CZ82994A3/en unknown
- 1994-04-08 SK SK408-94A patent/SK40894A3/en unknown
- 1994-04-08 TN TNTNSN94029A patent/TNSN94029A1/en unknown
- 1994-04-08 YU YU18194A patent/YU48782B/en unknown
- 1994-04-08 PE PE1994239736A patent/PE6395A1/en not_active Application Discontinuation
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1100859C (en) * | 1998-10-16 | 2003-02-05 | 乙基公司 | Turbine oil with exellent stability for oxidation at high temperature |
| CN102920617A (en) * | 2012-11-15 | 2013-02-13 | 四川大学 | Liquid type deet composition and preparation thereof |
| CN108991035A (en) * | 2018-08-27 | 2018-12-14 | 佛山科学技术学院 | A kind of insect repellent lotion for home textile |
| CN115895797A (en) * | 2022-12-14 | 2023-04-04 | 中山榄菊日化实业有限公司 | Floor cleaning agent with insect expelling effect |
Also Published As
| Publication number | Publication date |
|---|---|
| HU9400997D0 (en) | 1994-06-28 |
| AU679484B2 (en) | 1997-07-03 |
| PL177733B1 (en) | 2000-01-31 |
| DZ1770A1 (en) | 2002-02-17 |
| TNSN94029A1 (en) | 1995-04-25 |
| CA2119832A1 (en) | 1994-10-09 |
| EP0619363A1 (en) | 1994-10-12 |
| HUT67855A (en) | 1995-05-29 |
| SK40894A3 (en) | 1994-10-05 |
| MA23153A1 (en) | 1994-12-31 |
| PT101478B (en) | 1999-11-30 |
| CZ82994A3 (en) | 1995-01-18 |
| BR9401414A (en) | 1994-11-22 |
| YU48782B (en) | 1999-12-27 |
| JPH06313199A (en) | 1994-11-08 |
| NZ260145A (en) | 1995-12-21 |
| ZA942051B (en) | 1995-05-26 |
| AU5926294A (en) | 1994-10-13 |
| PT101478A (en) | 1995-01-31 |
| OA09933A (en) | 1994-11-15 |
| MY118351A (en) | 2004-10-30 |
| HN1994002558A (en) | 1997-08-13 |
| YU18194A (en) | 1996-10-09 |
| RO114630B1 (en) | 1999-06-30 |
| BG98700A (en) | 1995-03-31 |
| UY23753A1 (en) | 1994-09-23 |
| PE6395A1 (en) | 1995-03-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1094087A (en) | The household liquids detergent composition that contains wormer | |
| AU2002361849B2 (en) | Thickened toilet bowl cleaner | |
| US10781406B2 (en) | Methods of reduction preventing or removing biofilms | |
| ES2202825T3 (en) | CLEANING COMPOSITIONS OF HARD SURFACES. | |
| MXPA01001509A (en) | Acidic hard surface cleaning and disinfecting compositions. | |
| KR100230558B1 (en) | Liquid household cleaning composition with insect repellent | |
| US5573700A (en) | Liquid household cleaning composition with insect repellent | |
| CN1234067A (en) | Detergents | |
| RU2061743C1 (en) | Liquid detergent composition for solid surface cleansing and insect repellenting and a method of solid surface cleansing | |
| EP0467618A1 (en) | Novel broad spectrum antimicrobial system for hard surface cleaners | |
| US5569411A (en) | Liquid household cleaning composition with insect repellent | |
| KR100230559B1 (en) | Liquid household cleaning composition with insect repellent | |
| IL109126A (en) | Liquid household cleaning composition with insect repellent | |
| MXPA99003717A (en) | Low residue aqueous hard surface cleaning and desinfecting compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |