CN105155258A - Anti-mite fabric care composition and application method thereof - Google Patents
Anti-mite fabric care composition and application method thereof Download PDFInfo
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- CN105155258A CN105155258A CN201510419999.8A CN201510419999A CN105155258A CN 105155258 A CN105155258 A CN 105155258A CN 201510419999 A CN201510419999 A CN 201510419999A CN 105155258 A CN105155258 A CN 105155258A
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Abstract
The invention discloses an anti-mite fabric care composition and an application method thereof. The composition comprises (a) 0.05 to 3.0% of an anti-mite agent which is one or a composition of more than two selected from the group consisting of geraniol, benzyl benzoate, 2-(2-Hydroxypropan-2-yl)-5-methylcyclohexanol and tannic acid, and (b) the balance of a carrier. The composition has substantial anti-mite performance. The anti-mite fabric care composition is suitable for being used in a stock solution injection manner or acts on a fabric or furniture with mites in the form of stock solution spray under the action of a spraying device so as to kill the mites.
Description
Technical field
The present invention relates to a kind of Fabrid care composition, belong to daily use chemicals fabric care product technical field, particularly relate to a kind of can the Fabrid care composition of remarkable anti-acarid performance and using method thereof.
Background technology
Acarid belongs to the small animal of a class build of Arthropoda Arachnoidea Acari, and body size is generally all in 0.5 millimeter, and there is mouthpart front end, and feeding habits are various, as dandruff etc.Find that acarid has kind more than 50000, is only second to insect in the world.Many mite species and medical research have substantial connection.The healthy relation of acarid and people is very close, acarid is distributed widely in the place such as dark corner, carpet, mattress, pillow, sofa, air-conditioning, summer sleeping mat in room, wherein the distribution of dirt mite the widest, have the greatest impact, the corpse of acarid, secretion and excreta are all anaphylactogens, people can be made to occur the diseases such as allergic dermatitis, asthma, bronchitis, ephritis, allergic rhinitis, the medium of the transmissions such as acarid or bacterium, virus, Chlamydia, therefore acarid serious harm health.
In order to prevent acarid to the harm of human body, row expert set about from human contact the most frequently fabric start with, attempt exploitation fabric care product, go solve acarid harm problem.It is directly kill acarid that usual way mainly contains three kinds: one, as killed mite method, trapping method; Two is do not allow acarid close, as avoided the method for keeping away; Three is stop acarid to enter fabric, as blocked method.By taking the methods such as Exposure to Sunlight, heating, electromagnetic wave, infrared ray can make fabric drying, destroy the life condition of acarid, then can be dead when its moisture is below 10%.Deoxidation, the oxygen content reduced in air are also a kind of methods of killing mite.Chemistry kills mite as used pyrethrum extract isoborneol, dehydroacetic acid, aromatic carbonate, diphenyl ether, piperazine agriculture, Folithion etc., and many pesticides and bactericide are all good acaricides.Trapping method is first lured acarid, then kills, and thisly lured sex inducement, food lures, lays eggs to lure and lure with pheromones.Avoiding the method for keeping away is use repellent, and this is some materials with the aroma and flavor making acarid fear, and the medicine DEET and the betanaphthol that are commonly referred to as repellent are representative.Blocked method adopts fine and close fabric not allow acarid pass through, and also some situation uses repellent to strengthen this barrier effect further.
In textile industry, by anti-acaricidal composition to be joined in fabric thus to give fabric good anti-mite effect.If Japanese Zhong Fang company is base material with acrylic fibers, is applied to DEET, Dalmatian chrysanthemum phenol, diphenyl ether or organophosphor when its spinning is in gel state, makes mite-proof agent enter under fiber sheath, improve its anti-mite property.Supreme Being three drugmaker is at non-drawing-off Polyester Filament after anti-mite process, then carries out adding hot gas spring and having made mite-assistant fiber.Ai Kesilan company of Japan also uses same method, just contains mite-proof agent with cyclodextrin and has made coating agent.Also have a kind of mode be in fabric post-treatment process, by anti-mite working substance by carrier adsorption on fabric.The process of textile industry anti-mite can obtain desirable anti-mite effect in a short time, but along with the wearing and tearing of fabric, washing, its anti-mite active ingredient can run off gradually, and its anti-mite effect also can be deteriorated.
Chinese daily chemical articles industry is attempted in cleaning product, adding anti-acaricidal composition, by removing acarid in fabric laundering process.
Chinese patent CN1836509A discloses N, and the utilization of N diethylbenzene yl acetamide compound in anti-mite is antibacterial, illustrates that this material applies in laundry soap, washing powder, liquid detergent, thus imparting washing agent kills mite, drives the effect of mite.
Chinese patent CN102051279B discloses a kind of except mite liquid detergent, its main active component and mass fraction thereof are: dodecyldimethylammonium hydroxide inner salt 5-10 part, sodium sulfate of polyethenoxy ether of fatty alcohol 7-12 part, fatty alcohol-polyoxyethylene ether 6-10 part, sodium n-alkylbenzenesulfonate 4-8 part, antibacterial and mouldproof drives mite agent (MGU-350) 0.5-1 part, chelating agent 0.2-0.5 part, thickener 1-5 part.This invention except mite liquid detergent strong detergency, not injured surface, and there is the effect except mite.
Chinese patent CN103865672A discloses except mite liquid detergent, comprise the component of following weight portion: Lonzabac 12.100 0.5 ~ 6 part, anion surfactant 6 ~ 31 parts, non-ionic surface active agent 12 ~ 43 parts, thickener 0.1 ~ 0.5 part, chelating agent 0.1 ~ 0.5 part, deionized water 40 ~ 60 parts.The liquid detergent of this invention selects function admirable, gentle, safety non-toxic, biodegradation rapidly surfactant with except mite agent composite, can effectively remove and kill all kinds of acarid while clean.
Above-mentioned invention provides by adding anti-mite active ingredient thus the method for the anti-mite effect of imparting washing agent in washing agent, but consumer adopts finite concentration to wash when using product, anti-acaricidal composition in washing agent concentration in wash solution is diluted, except mite effect can weaken greatly; In addition anti-acaricidal composition hydrophobic substance often, can carry out emulsification to except acaricidal composition containing more surfactant in washing agent, also can weaken the effect except mite in washing process.
Summary of the invention
In order to solve above-mentioned prior art Problems existing, the object of the present invention is to provide a kind of mite-assistant fabrics care composition, said composition has significant anti-mite effect.
summary of the invention
A kind of mite-assistant fabrics care composition, said composition contains:
(a) 0.05 ~ 5.0% mite-proof agent, mite-proof agent be selected from arbitrarily geraniol, Ergol, the Meng glycol, one or more composition in tannic acid;
B () surplus is carrier.
detailed Description Of The Invention
Composition each key element of the present invention is described in detail in detail below.Except as otherwise noted, all percentage used herein, ratio and ratio are all by the weight percent meter of described composition.Unless otherwise expressly stated, all mean value is all by the weighing scale of described composition or its component.
mite-proof agent
The present invention contains 0.05 ~ 5.0% mite-proof agent, and preferably 0.1 ~ 2.0%, more excellent is 0.2 ~ 1.0%.Mite-proof agent be selected from arbitrarily geraniol, Ergol, the Meng glycol, one or more composition in tannic acid.
Geraniol has following structural formula:
Geraniol can select the raw material extracted from plant also can adopt the raw material of commercial synthesis, and this raw material is mature industry raw material, and the raw material of the GERANIOL series provided as BASF AG can be applicable to the present invention.
Ergol has following structural formula:
Benzoic acid Bian fat is the ripe raw material of industry, and the commercially available benzoic acid Bian fat meeting light industry standard QB/T1780-2014 is all suitable for the present invention and uses.
The Meng, diolation formal name used at school was called 2-hydroxyl-alpha, and alpha, 4-trimethyl-cyclohexane methyl alcohol, has following structural formula:
The Meng, glycol was mature industry raw material, can adopt commercialization matured product, the Geranodyle raw material provided as selected Givaudan company.
Tannic acid is also known as tannic acid, and drawn in the plants such as fruit pod, pomegranate, Folium toxicodendri verniciflni, smoke tree, witch hazel tree extracted by Chinese nutgall, Turkey's gall, tower, the tannic acid that the present invention adopts can adopt the industrialization commodity deriving from plant of commercially available maturation.
carrier
Carrier is the fluid product used to above-mentioned mite-proof agent be made the certain density consumer of convenience, carrier can be selected from water, various alcohol, ether solvents and arbitrary composition thereof, preferred employing water is as carrier, and the consumption of carrier accounts for 65.0 ~ 99.5% of total composition.
Concrete alcoholic solvent is selected from the monohydric alcohol of C2 ~ C6, as ethanol, propyl alcohol, isopropyl alcohol, butanols, isobutanol; The dihydroxylic alcohols of C2 ~ C6, as; Ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, 1,3-BDO, BDO, hexylene glycol, isoprene.
Concrete ether solvent is selected from following material: diethylene glycol, dipropylene glycol, TC, diethylene glycol monobutyl ether, polyoxypropylene (9) two glyceryl ether.
surfactant
Can add surfactant in the present invention, play the effect of hydrotropy, surfactant is selected from one or more any combination in non-ionic surface active agent, anion surfactant, cationic surfactant.The addition of surfactant is 0.2 ~ 20.0%.
non-ionic surface active agent
Non-ionic surface active agent comprises poly alkyl alcohol alkoxyl ether, alkyl amine oxide, sorbitan ester, APG and their derivative and their mixture.
Poly alkyl alcohol alkoxyl ether is the material corresponding to following general formula: R
1(C
mh
2mo)
noH, wherein R
1for C8-C16 alkyl group, m is 2 ~ 4, and n is 2 ~ 12.Preferably, R
1for alkyl group, it can be and comprises 8 to 16 carbon atoms, the primary alkyl-group of more excellent 10 to 14 carbon atoms or secondary alkyl group.In one embodiment, poly alkyl alcohol alkoxyl ether can be ethoxylation material, and its per molecule comprises 2 to 12 ethyleneoxy moieties, more preferably per molecule 3 to 10 ethyleneoxy moieties.The poly alkyl alcohol alkoxyl ether product of commercialization maturation can be selected, as SHELL company NEODOL series linear primary alcohol ethoxylate product, DOW company ECOSURFEH series ethoxylation and the third oxidation 2-ethylhexanol product, BASF AG LutensolXL series ethoxylation and third is oxidized 3-propyl enanthol product and BASF AG LutensolXP series ethoxylation 3-propyl enanthol product.
Being applicable to poly alkyl alcohol alkoxyl ether another one example of the present invention is the nonionic Cremophor RH40 that rilanit special and oxirane react to each other and obtains, can available from BASF, and trade names are CremophorCO40.
Amine oxide (amineoxide, be called for short OA) is the oxide of the direct chemical combination of nitrogen-atoms in oxygen and tertiary amine molecule.Amine oxide has structural formula: R
1n (O) (CH
2r
2)
2, R in formula
1for the alkyl of C8 ~ C20, it can be saturated or undersaturated, straight chain or branching.R
2be selected from from hydrogen, methyl and-CH
2oH.
Sorbitan ester is the esterification dehydrating prods of sorbierite.Preferred sorbitan ester comprises and is selected from following material: the ethoxylate of C10-C26 acyl group sorbitan one ester and C10-C26 acyl group sorbitan diester and described ester and their mixture; wherein in described ester, one or more in nonesterified oh group preferably comprises 1 to about 6 oxygen ethylene unit.With regard to object of the present invention, the sorbitan ester comprising unsaturated group (such as, E494) can be utilized.Be applicable to commercially produced product of the present invention optional Corda naturally company's T ween product.
APG is a kind of safe surfactant, there is following structural formula:
Wherein, n is 6 to 24, p is 1.1 to 3, and preferred n is 8 to 16.Suitable APG is as BASF AG Glucopon series alkyl glycoside product.
anion surfactant
Anion surfactant is selected from sulfonate surfactant, carboxylate surfactant, one or more mixture of sulfated surfactant; Preferably from alkylbenzenesulfonate, the alkyl sulfate of C8 to C18, the ethoxylated fatty alcohol sulfate of C8 to C18, alpha-alkene sulfonate, fatty acid alkyl ester sulfonate, the one of ethoxylized fatty alcohol ether carboxylate, and their mixture.
cationic surfactant
Composition of the present invention is also containing 0.5 ~ 20.0% percentage by weight cationic surfactant, and cationic surfactant is the quaternary ammonium salt cationic with soft function, is selected from ester group type quaternary ammonium salt, dialkyl quaternary ammonium salt any one or two kinds of compositions.
ester based quaternary ammonium salt CATION
In the present invention, preferred ester group type quaternary ammonium salt, it has following structure:
In formula, R selects following carbonyl group:
R is (1) group preferably;
Each R1 is independently selected from straight chain or the alkyl of C11 ~ C21 containing side chain and their mixture;
Each R2 is independently selected from the alkyl of C1 ~ C6, hydroxy alkyl and their mixture, preferable methyl or hydroxy alkyl;
Digital m in formula is selected from 1 ~ 4, and preferably 2; Numeral n is selected from 1 ~ 4, preferably 2;
X is the anion contended with cation group;
Ester based quaternary ammonium salt of the present invention, carry out ester reaction, and then quaternization obtains by C12 ~ C22 aliphatic acid and triethanolamine.Aliphatic acid is optional from tallow fatty acid or vegetable fatty acid, as being selected from the aliphatic acid of C12 ~ C22 of castor oil, coconut oil, palm oil, corn oil, mustard oil, olive oil, peanut oil, rapeseed oil, sunflower oil, soya-bean oil, butter; Also single aliphatic acid through separation and purification can be selected from arbitrarily as certain herbaceous plants with big flowers acid, different tridecanoic acid, laurate, tetradecanoic acid, hexadecanoic acid, palmitoleic acid, stearic acid, oleic acid, isostearic acid, 2 ethyl hexanoic acid, arachidic acid, cis gadoleic acid, behenic acid, erucic acid or their any mixture.
Described aliphatic acid is preferably containing unrighted acid composition, and iodine number is 0 ~ 90, and preferably 10 ~ 90, be more preferably 15 ~ 85, most preferably be 15 ~ 55.
The ester reaction of triethanolamine can be obtained by known technique, and the method as described in WO-A-9101295 carries out ester reaction.
Preferably ester process conditions are: the esterification temperature adopting 120 DEG C ~ 220 DEG C, 2 ~ 12 little the reaction times, the Stress control of reaction is in 5mbar ~ 200mbar vacuum range, preferred catalyst is hypophosphorous acid and p-methyl benzenesulfonic acid, also need to add stabilizing agent and antioxidant, as tocopherol, BHT, BHA, citric acid etc., the mol ratio of aliphatic acid and triethanolamine is generally 1.5:1 ~ 2.5:1, is more preferably 1.6:1 ~ 2.0:1.
The ester product of aliphatic acid can adopt known quaterisation to obtain ester based quaternary ammonium salt, as the mode described in WO-A-9101295, carries out quaternized to the product of esterification.Preferred alkylating reagent comprises the halide of C1 ~ C3 straight or branched alkyl, phosphate, carbonic acid ester or sulfuric ester.The example of preferred alkylating reagent includes but not limited to methyl chloride, benzyl chloride, dithyl sulfate, dimethyl carbonate, trimethyl phosphate, dimethyl suflfate or their mixture.
The working substance of final product is the mixture of mono-esterquat, diester quaternary ammonium, three ester quats, represents respectively with following three kinds of structural formulas:
Wherein R represents above-mentioned each fatty acid chain applicable of the present invention, and X represents anion, is selected from chlorion, bromide ion, methylsulfate, ethyl sulphate, and Q is the alkyl of C1 ~ C3.
Described monoesters, dibasic acid esters, three ester quats can draw the weight percent content of each component by the analytical method mentioned with Publication about Document: Characterizationofquarternizedtriethanolamineesters (esterquarts) byHPLC, HRCGCandNMR, A.J.WilkesC.Jacobs, G.Walraven and J.M:Talbot-4thWorldSurfactantsCongress, Barcelona, 1996.
Mono-esterquat in described ester based quaternary ammonium salt, diester quaternary ammonium, three ester quat weight percent distribution are selected as follows:
Mono-esterquat: 30 ~ 45%;
Diester quaternary ammonium: 50 ~ 60%;
Three ester quats: 0.1 ~ 10%;
Be applicable to ester based quaternary ammonium salt of the present invention and can select ripe commercial product, the TEP-88 of such as Solvay; The SP-90 of Si Taipan company; The RewoquatWe28 of Ying Chuan company.
dialkyl quaternary ammonium salt
Be applicable to cation quaternary ammonium salt of the present invention and can also select dialkyl quaternary ammonium salt, it has following structural formula:
Wherein R1 is selected from the alkyl of C8 ~ C22, and R2 is selected from the alkyl of C1 ~ C4, and X represents anion, is selected from chlorion, bromide ion, methylsulfate, ethyl sulphate.Suitable dialkyl quaternary ammonium salt can be selected from: two Ns of ester group ammonium chlorides, two Ns of ester group dimethyl ammonium methyl sulfate, two (hydrogenation ox ester group) alkyl dimethyl ammonium chloride, VARISOFT TA100.
antibacterial mildew inhibitor
The present invention can also add the antibacterial mildew inhibitor of 0.2 ~ 5.0% as required, makes the present invention have effect of antibacterial and mouldproof.
Described antibacterial mildew inhibitor is selected from arbitrarily phenols antimicrobial compound as parachlorometaxylenol (PCMX), Butylated hydroxy benzene, Yoshinox BHT or butylated hydroxyanisol; Anilid antimicrobial compound is as triclocarban (TCC); Cationic compound is as zephiran, Dialkyl dimethyl ammonium chloride; Biguanides antimicrobial compound is as polihexanide hydrochloride (PHMB); Triclosan; Dichloro is raw; Or their multiple any combination.
Parachlorometaxylenol (PCMX) can purchased from NetchemIncCanada company.
Butyl hydroxyanisol or BHA can purchased from AshlandChemicalCo.
Triclocarban can purchased from Lanxess company, and product commodity are called PreventolSB.
Zephiran, Dialkyl dimethyl ammonium chloride, biguanides antimicrobial compound such as polihexanide hydrochloride (PHMB) can purchased from Lonza company.
Triclosan, dichloro life can available from BASF.
Composition of the present invention can add auxiliary agent as required, and described auxiliary agent accounts for total composition 0.05 ~ 5%, and auxiliary agent can comprise preservative agent, essence, pigment.
essence
In order to make consumer enjoy joyful impression in use daily chemical products process, formula engineer often adds essence in the product.The composition of the normally various different boiling perfume material of essence, perfume material from natural extraction, also can be obtained by chemical industry synthesis.Various perfume material is combined in one piece according to the concept of product and experience by perfumer, adds perfume material composition and gives product joyful fragrance.
Various perfume material is known obtainable, the normally chemical substance such as aldehyde, ketone, ester, the characteristic of various perfume material and their blending purposes can with reference to " spices and aroma chemical (aroma chemicals) " (PerfumeandFlavorchemical (aromachemicals)), StephenArctender, volume I and II, Aurthor, Montclair, H.J. and theMerckIndex, the 8th edition.Usually available perfume material has isoquinolines, ligustral (Ligustral), linalool, linalool oxide, linalyl formate, menthones, methyl acetophenone, methyl amyl ketone, Methyl anthranilate, benzoic acid methyl esters, methyl benzylacetate, methyleugenol, methyl heptenone, methyl heptyne carbonic acid ester, methyl heptyl ketone, methyl hexyl ketone, methyl phenyl methyl esters, gaultherolin, methyl-N-methyl Aminobenzoate, nerol, caprylolactone, octanol, p-cresols, p-cresols methyl ether, p-methoxyacetophenone, p-methyl acetophenone, phenoxetol, ethylalbenzene, phenethyl acetate, phenylethyl alcohol, phenylethyldimethyl carbinol, acetic acid isoprene ester, desinsection propyl ester (PropylBornate), pulegone, rose oxide, safrol, 4-terpineol, α-terpineol, ambrotone, citronellol, ethyl cinnamate, Asiatic sweet leaf alcohol, 2,4,6-trimethylbenzaldehyde, jasminolene, 2,6-dimethyl-2-heptanol, diisobutyl carbinol (DIBC), allyl hexanoate, pentyl acetate, amyl propionate, anisaldehyde, anisole, dimethyl benzyl carbinol, dimethyl benzyl carbinol ester, ethyl acetate, ethyl acetoacetate, ethyl pentyl group ketone, ethyl benzoate, ethyl butyrate, ethyl hexyl ketone, ethyl phenylacetate, cineole, eugenol, acetic acid turnip ester, acetic acid Flor ester (cyclacet), Frutene (tricyclo decenyl propionate), hexenol, acetic acid hexene ester, hexyl acetate, hexyl formate, black nightshade alcohol, laurine, indone, isoamyl alcohol, isomenthone, isopulegyl acetate, salethyl, phenethyl isobutyrate,phenylethyl isobutyrate, ethyl hexyl ketone, propylpentyl ketone, dibutyl ketone, hept-ylmethyl ketone, 4,5-dihydro toluene, octanal, citral, geranial, benzoic acid isopropyl ester, cyclohexane propionic acid, campholenic aldehyde, sad, octanol, anisaldehyde, 1-ethyl-4-nitrobenzene, heptyl formate, 4-isopropyl-phenol, 2-isopropyl-phenol, 3-isopropyl-phenol, diallyl disulfide, 4-methyl isophthalic acid-phenyl-2 pentanone, 2-propyl group furans, allyl hexanoate, styrene, different eugenyl methyl ether, indoles cycloalkanes, suberic acid diethylester, L-menthones, racemic menthones, isobutyric acid p-toluene ester, butyl butyrate, ethyl hexanoate, propyl valerate, n-pentyl propionate, hexyl acetate, methyl heptanoate, trans 3,3,5-cyclonols, 3,3,5-cyclonol, p-ethyl anisate, 2-ethyl-1-hexanol, benzyl isobutyrate, 2,5-thioxene, 2-isobutyl crotonate, capryl nitrile, nonyl lactone, nerol, 1-vinyl enanthol, cineole, 4-terpineol, dihydrocarveol, O-Anisic Acid ethyl ester, cyclohexanecarboxylate, 2-ethyl hexanal, ethyl pentyl group methyl alcohol, sec-n-octyl alcohol, sec-n-octyl alcohol, ethyl methylphenylglycidate, diisobutyl ketone, coumarone, propyl isovalerate, isobutyl isobutyrate (IBIB), isoamyl propionate, acetic acid 2-ethyl butyl ester, 6-methyl-tetrahydro quinoline, eugenyl methyl ether, dihydro cinnamon acetoacetic ester, 3,5-dimethoxy-p, toluene, ethyl benzoate, positive butyrophenone, α-terpineol, o-methyl benzoic acid methyl ester, methyl p-methyl benzoate, m-methyl benzoic acid methyl ester, the secondary butyl ester of n-butyric acie, Isosorbide-5-Nitrae-cineole, fenchol, pinacol, cis 2-pinacol, 2,4, dimethyl acetophenone, isoeugenol, safrol, methyl 2-octynoate, o-methyl anisole, p-cresyl methyl ether, benzocaine, linalool, phenyl butyrate, two butyric acid glycol esters, diethyl phthalate, phenyl mercaptan, cumic alcohol, m-methylquinoline, 6-methylquinoline, lepidin, 2-ethylo benzene formaldehyde, 4-ethylo benzene formaldehyde, o-ethyl-phenol, p-ethyl-phenol, m-ethyl-phenol, (+)-pulegone, 2,4-dimethylbenzaldehyde, 2,5-dimethylbenzaldehyde, ethyl sorbate, benzyl propionate, 1,3-dimethyl butyrate yl acetate, isobutyl isobutyrate, 2,6-xylenols, 2,4-xylenols, 2,5-xylenols, 3,5-xylenols, methyl cinnamate, hexyl methyl ether, benzylisoeugenol, gaultherolin, butyl propyl group ketone, ethyl pentyl group ketone, hexyl methyl ketone, 2,3-xylenols, 3,4, xylenols, pentadacanolide, benzaldehyde, benzyl acetate, benzylacetone, benzyl alcohol, benzyl formate, benzyl isovalerate, benzyl propionate, β γ hexenol, camphor glue, L-CARVONE, d-carvol, cinnamyl alcohol, cinnamyl formate, cis-jasmone, cis 3-vinyl acetate, cuminyl alcohol, ligustral (CyclalC).
pigment
In order to give outward appearance shades of colour, can add various pigment raw material as required, be applicable to pigment of the present invention and be selected from but be not limited to following colouring substance: direct dyes pigment, this type of pigment mostly is water colo(u)r, preferred bisazo or trisazo-type; ACID DYES pigment; Basic-dyeable fibre pigment; Basic-dyeable fibre pigment.
occupation mode
Mite-proof agent usually exceedes certain mass action and just has anti-mite effect in acarid, the anti-mite product of prior art fabric nursing mostly is washing agent, the poor reason of its effect is that washing agent is diluted by water in washing process, and the concentration of mite-proof agent greatly reduces and causes anti-mite deleterious.Acarid reproductive capacity is extremely strong, prevents acarid from can prevent it from breeding by the method regularly killed.The mode that Fabrid care composition of the present invention is applicable to adopting stoste to spray is ejected into mite-proof agent and the fabric of acarid, furniture eliminates acarid thus the effect playing anti-mite.
Mite-assistant fabrics care composition tool of the present invention has the following advantages and beneficial effect:
1) present composition is suitable for processing fabric, easy to use, effectively can kill the acarid on fabric, furniture fast;
2) present composition is to human-body safety, harmless.
Detailed description of the invention
Below by way of concrete preferred embodiment, mite-assistant fabrics care product of the present invention is described in further detail, but the present invention is not limited in following embodiment.In following examples
embodiment 1 ~ 6
A kind of mite-assistant fabrics care composition, it is made up of following raw material components, shown in the visible following table 1 of material composition table:
Its raw material components of mite-assistant fabrics care composition (unit: weight percentage %) of table 1 embodiment 1 ~ 6
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | |
| Geraniol | 2.0 | 0.8 | 0.1 | --- | --- | --- |
| The Meng glycol | --- | --- | --- | 2.0 | 0.8 | 0.1 |
| CO40 | 2.0 | 1.5 | 0.5 | 2.0 | 1.5 | 0.5 |
| PHMB | 0.8 | --- | --- | 0.8 | --- | --- |
| BHA | --- | 0.2 | --- | --- | 0.2 | --- |
| TCC | ---- | --- | 0.1 | ---- | --- | 0.1 |
| Essence | 0.1 | 0.2 | 0.1 | 0.1 | 0.2 | 0.1 |
| Propylene glycol | 6 | 5 | 2.0 | 6 | 5 | 2.0 |
| Water | To 100 | To 100 | To 100 | To 100 | To 100 | To 100 |
Wherein geraniol, CO40 available from BASF; PHMB is purchased from Lonza company; BHA can purchased from AshlandChemicalCo; Triclocarban can purchased from Lanxess company.
The preparation technology of embodiment 1 ~ 6 is as follows:
1) add deionized water in agitated kettle in the ratio of table 1, open and stir, add PHMB;
2) Oil soluble materials as geraniol/Meng glycol/BHA/ essence/TCC and CO40 and mixed with propylene glycol even;
3) by step 2) mixture that is made into slowly joins in agitated kettle and stirs;
embodiment 7 ~ 12
A kind of mite-assistant fabrics care composition, it is made up of following raw material components, shown in the visible following table 2 of material composition table:
Its raw material components of table 2 embodiment 7 ~ 12 mite-assistant fabrics care composition (unit: weight percentage %)
TEP88 is provided by Solvay, and Bardac208-ME is provided by Lonza company.
The preparation technology of embodiment 7 ~ 8 is as follows:
1) add fresh water (FW) in the ratio of table 2 toward ingredients pot, then add Bardac208-ME raw material, open and stir;
2) Oil soluble materials Ergol/triclosan/essence and surfactant and mixed with propylene glycol even;
3) by step 2) mixture of gained joins in ingredients pot and stirs.
The preparation technology of embodiment 9 is as follows:
1) Ergol is mixed with TEP88, be heated to 45 DEG C, be uniformly mixed;
2) add fresh water (FW) in the ratio of table 2 toward ingredients pot, open and stir, be warming up to 45 DEG C;
3) benzoic acid and TEP88 mixture are joined in ingredients pot be uniformly dispersed;
4) treat that ingredients pot temperature is down to 35 DEG C, add essence and stir.
The preparation technology of embodiment 10 ~ 12 is as follows:
Add fresh water (FW) in the ratio of table 2 toward ingredients pot, then add Bardac208-ME, tannic acid raw material, stir.
effect test example
1, anti-mite performance evaluation
1993, Japanese clothing item capability and performance countermeasure consultation was investigated mite-assistant fabrics exploitation actuality, proposed " anti-mite evaluation method and standard ".1998, this industry organization proposed again " mite-assistant fabrics avoid keep away test method ", has carried out strict regulation further to acarid, culture medium, Rearing Condition and computational methods etc.The Institute for the Control of Agrochemicals of the Ministry of Agriculture,PRC of China released in 2003 and knows clearly " hygienic insecticide test of pesticide effectiveness method of testing and evaluation ", and its content comprises " go out mite and drive mite test of pesticide effectiveness method and evaluation criterion ".
Anti-mite efficacy assessments method of the present invention mainly with reference to the standard of the Ministry of Agriculture, mainly contains two kinds of evaluation methods:
2, to go out full experimental evaluation step
1) for examination acarid: dirt mite, female male imago.
2) operating procedure.Get the testing sample 3 piece basically identical with culture dish floor space (diameter is 8.5cm) as test group, get the identical untreated thing of 1 piece of area more as a control group, then culture dish is placed in respectively, culture dish inner rim smears white oil and vaseline 1: 1 mixture in case acarid climbs out of, 200 acarids are put at culture dish center, when 30 minutes, put into acarid feed 0.05g in culture dish central authorities, be placed in (25 ± 1) DEG C water-impermeable incubator and cultivate.48 as a child checked dead acarid number.
3, mite experimental procedure is driven
Get 7 culture dishes (diameter 60mm, high 15mm), culture dish centered by 1, all the other 6 culture dishes are put around center culture dish and are contacted between two with center culture dish, and contact position adhesive tape clings.Finally being bonded at by 7 culture dishes in viscose glue plate-making makes its position be fixed.
Put into examination worm in the culture dish of center and be no less than 1000, around the area determinand consistent with vessel 1 piece or tester 1 piece are put into, anti-acarid feed 0.05g on nothing to be measured and tester in 6 culture dish intervals.Experimental rig is placed with in lid porcelain dish, is finally placed in water-impermeable incubator.
With the acarid number on disecting microscope observed and recorded determinand and tester.
4, result calculates
Mite rate of going out represents with percentage (%), presses formulae discovery:
P＝R/N×100
In above formula:
P-mite rate of going out;
R-death examination borer population
N-test examination borer population.
Drive mite rate to represent, by following formulae discovery with percentage (%):
P
c＝(1-N
t/N
0)×100
In above formula:
P
c-drive mite rate;
N
t-determinand examination borer population;
N
0-tester examination borer population.
5, fabric pretreatment
Test fabric: circular pieces of cloth pure cotton knitting cotton being cut into diameter 5cm.
Evenly be sprayed onto by test sample on circular pieces of cloth, every sheet cloth sprays 0.5 gram.
6, test result
(1) the mite experimental result of going out of embodiment 1-12:
Table 3 goes out mite experimental result
| Dead acarid number | Experiment examination borer population | To go out mite rate | |
| Embodiment 1 | 998 | 1000 | 99.80％ |
| Embodiment 2 | 980 | 1000 | 98.00％ |
| Embodiment 3 | 977 | 1000 | 97.70％ |
| Embodiment 4 | 996 | 1000 | 99.60％ |
| Embodiment 5 | 960 | 1000 | 96.00％ |
| Embodiment 6 | 959 | 1000 | 95.90％ |
| Embodiment 7 | 999 | 1000 | 99.90％ |
| Embodiment 8 | 995 | 1000 | 99.50％ |
| Embodiment 9 | 990 | 1000 | 99.00％ |
| Embodiment 10 | 890 | 1000 | 89.00％ |
| Embodiment 11 | 880 | 1000 | 88.00％ |
| Embodiment 12 | 800 | 1000 | 80.00％ |
As can be seen from Table 3, embodiment of the present invention 1-12 miticidal effect is good.
(2) embodiment 1-12 drives mite experimental result
Table 4 drives mite experimental result
As can be seen from Table 4, embodiment of the present invention 1-12 all has and good drives mite effect.
Above-described embodiment is the present invention's preferably embodiment; but embodiments of the present invention are not restricted to the described embodiments; change, the modification done under other any does not deviate from Spirit Essence of the present invention and principle, substitute, combine, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (10)
1. a mite-assistant fabrics care composition, is characterized in that, said composition contains:
(a) 0.05 ~ 5.0% mite-proof agent, mite-proof agent be selected from arbitrarily geraniol, Ergol, the Meng glycol, one or more composition in tannic acid;
B () surplus is carrier.
2. mite-assistant fabrics care composition according to claim 1, is characterized in that: said composition contains the mite-proof agent of 0.1 ~ 2.0% percentage by weight, is preferably the mite-proof agent of 0.2 ~ 1.0%.
3. mite-assistant fabrics care composition according to claim 1, is characterized in that: the surfactant of said composition also containing 0.2 ~ 20.0% percentage by weight; Described surfactant is selected from arbitrarily one or more combinations in non-ionic surface active agent, anion surfactant, cationic surfactant.
4. mite-assistant fabrics care composition according to claim 3, is characterized in that: described non-ionic surface active agent is selected from poly alkyl alcohol alkoxyl ether, nonionic Cremophor RH40, alkyl amine oxide, sorbitan ester, APG and their derivative and their mixture;
Described anion surfactant is selected from sulfonate surfactant, carboxylate surfactant, one or more mixture of sulfated surfactant; Preferably from alkylbenzenesulfonate, the alkyl sulfate of C8 to C18, the ethoxylated fatty alcohol sulfate of C8 to C18, alpha-alkene sulfonate, fatty acid alkyl ester sulfonate, the one of ethoxylized fatty alcohol ether carboxylate, and their mixture;
Described cationic surfactant is the quaternary ammonium salt cationic with soft function, is selected from ester group type quaternary ammonium salt, dialkyl quaternary ammonium salt any one or two kinds of compositions.
5. the mite-assistant fabrics care composition according to any one of Claims 1 to 4, is characterized in that: said composition also contains the antibacterial mildew inhibitor of 0.2 ~ 5.0%; Described antibacterial mildew inhibitor is selected from arbitrarily phenols antimicrobial compound, anilid antimicrobial compound or cationic compound.
6. mite-assistant fabrics care composition according to claim 5, is characterized in that: described phenols antimicrobial compound is selected from parachlorometaxylenol (PCMX), Butylated hydroxy benzene, Yoshinox BHT or butylated hydroxyanisol; Described anilid antimicrobial compound is selected from triclocarban (TCC); Described cationic compound is selected from zephiran, Dialkyl dimethyl ammonium chloride; Described biguanides antimicrobial compound is selected from polihexanide hydrochloride (PHMB), triclosan, dichloro life or their multiple any combination.
7. mite-assistant fabrics care composition according to claim 6, it is characterized in that: said composition can also add auxiliary agent as required, described auxiliary agent accounts for total composition 0.05 ~ 5%, and auxiliary agent can comprise preservative agent, essence, pigment; Described essence obtains from natural extraction or by chemical industry synthesis; The normally chemical substance such as aldehyde, ketone, ester;
Described pigment is selected from but is not limited to following colouring substance: water-soluble direct dyes pigment, ACID DYES pigment, basic-dyeable fibre pigment, the preferred bisazo of described water-soluble direct dyes pigment or trisazo-type.
8. mite-assistant fabrics care composition according to claim 7, is characterized in that: described carrier can be selected from water or various alcohol, ether solvents and arbitrary composition thereof, preferably adopts water; Described carrier accounts for 65.0 ~ 99.5% of total composition.
9. mite-assistant fabrics care composition according to claim 8, is characterized in that: described alcoholic solvent is selected from the monohydric alcohol of C2 ~ C6 or the dihydroxylic alcohols of C2 ~ C6; Described ether solvent is selected from following material: diethylene glycol, dipropylene glycol, TC, diethylene glycol monobutyl ether, polyoxypropylene (9) two glyceryl ether.
10. the using method of a mite-assistant fabrics care composition, it is characterized in that: use mite-assistant fabrics care composition according to any one of claim 1-9, the mode being adopted stoste to spray or utilize sprayer unit to act on the fabric of acarid or furniture with stoste Sprayable to eliminate acarid.
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| CN110592940A (en) * | 2019-08-13 | 2019-12-20 | 广州市迅泰通信设备有限公司 | Mosquito-repellent non-woven fabric and preparation method thereof |
| CN112314641A (en) * | 2020-11-04 | 2021-02-05 | 东方万佳科技有限公司 | Botanical mite killing bag |
| CN113930965A (en) * | 2021-11-22 | 2022-01-14 | 广州立白企业集团有限公司 | Fabric sterilization composition |
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