KR100769852B1 - Mothproof and antifungal treatment composition for textile and textile treatment method using said composition - Google Patents
Mothproof and antifungal treatment composition for textile and textile treatment method using said composition Download PDFInfo
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- KR100769852B1 KR100769852B1 KR1020060047920A KR20060047920A KR100769852B1 KR 100769852 B1 KR100769852 B1 KR 100769852B1 KR 1020060047920 A KR1020060047920 A KR 1020060047920A KR 20060047920 A KR20060047920 A KR 20060047920A KR 100769852 B1 KR100769852 B1 KR 100769852B1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/12—Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/006—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with wool-protecting agents; with anti-moth agents
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Abstract
Description
본 발명은 섬유용 방충 및 항균가공제 조성물 및 상기 조성물을 이용한 섬유가공방법에 관한 것으로, 보다 상세하게는 용매로서의 글리콜 에테르 50 내지 85중량%와, 방충제로서의 제충국 추출물인 피레트린 또는 시네린(pyrethrin or cinerin) 2 내지 10중량%와, 에스테르화 촉매 0.8 내지 2중량%와, 향균제로서의 이소치아졸린 5 내지 20중량% 및 계면활성제 2 내지 8중량%를 포함하는 섬유용 방충 및 항균가공제 조성물 및 상기 조성물을 이용한 섬유가공방법에 관한 것이다.The present invention relates to a fiber insect repellent and antimicrobial agent composition and a fiber processing method using the composition, more specifically, 50 to 85% by weight of a glycol ether as a solvent, pyrethrin or pyrethrin as a pesticide extract as a repellent cinerin) a fiber insect repellent and antimicrobial agent composition comprising 2 to 10% by weight, an esterification catalyst of 0.8 to 2% by weight, 5 to 20% by weight of isothiazoline as an antibacterial agent and 2 to 8% by weight of a surfactant, and the composition It relates to a fiber processing method using.
섬유는 현재 의복을 비롯한 각종 물품의 기초소재로 사용되고 있으며, 그 종류와 가공방법 등도 상당히 다양하다. 특히, 본 발명과 같이 방충, 항균기능을 부여한 것과 같은 기능성 섬유의 발달도 상당하다. 최근에는 아토피의 한 원인으로 꼽히는 집먼지진드기나 모기 등의 해충에 대한 기피와 항균처리에 대한 관심이 높아지고 있다. 일반적으로, 기존의 섬유용 방충가공제는 합성 농약 원료인 퍼머트린(permethrin)을 사용하여 스프레이 방법 등으로 섬유를 처리하는 방법이 알려져 있다. 대한민국 등록특허 제426175호의 등록공보에는 폴리비닐 아세테이트가 들어있는 배쓰에 직물을 통과시키는 단계; 및 (b) 이 직물을 퍼메트린이 들어있는 배쓰에 통과시키는 단계로 구성되는, 세탁가능한 최종 제품으로 만들려고 하는 직물에 퍼메트린을 부가하는 방법이 개시되어 있다. '해충 퇴치용 텐트 직물'에 관한 샘슨(Samoson) 등의 미국 특허 제 5,198,287 호에는 유효수명이 6개월 이상인 살충성 퍼메트린이 포함된 방수 및 난연성 피복물이 피복된 텐트 직물에 관해 기재되어 있다. 이 특허에 따라 제조된 텐트의 퍼메트린의 수명을 연장시키는 요인은 퍼메트린을 텐트의 안쪽면에다 피복시킨다는 것이다. 또한, '해충 퇴치 및 보호막을 갖는 직물'에 관한 샘슨의 미국 특허 제 5,252,387 호에는 퍼메트린이 산소와 자외선에 의해 분해되는 것을 막기 위해 퍼메트린 위에 보호막을 덮음으로서 해충 퇴치용 직물내에 퍼메트린을 보존시키는 방법이 기재되어 있다. 세탁 가능한 완제품에 해충 퇴치제로서 퍼메트린을 사용할 때 생기는 또 다른 문제점은 제품을 여러번 세탁하고 난 후에도 퍼메트린이 직물내에 보존되어야한다는 점이다. '직물 상에서의 아밀로펙틴-퍼메트린 조합물의 상승효과'에 관한 맥낼리(Mcnally)의 미국 특허 제5,089,298 호에는 여러번 세탁하고 난 후에도 퍼메트린을 완제품내에 보존시키는 문제를 해결하는 방법을 제시하고 있다. 상기 특허는 퍼메트린과 아밀로펙틴, 수용성 형태의 전분을 옷에 침투시키면 퍼메트린만을 침투시킨 옷보다 굉장히 많이 세탁하고 난 후에도 퍼메트린이 옷안에 보존된 다는 것을 적시하고 있다. Fiber is currently used as a base material for various items including clothing, and the variety and processing methods thereof are quite diverse. In particular, as in the present invention, the development of functional fibers such as those that impart insect repellent and antibacterial function is also considerable. Recently, interest in evasion and antibacterial treatment against pests such as house dust mites and mosquitoes, which is one of the causes of atopy, has been increasing. In general, a conventional method for treating insect repellent fiber is known to treat the fiber by a spray method using a permethrin (synthetic pesticide raw material). Korean Patent Publication No. 426175 discloses a step of passing a fabric through a bath containing polyvinyl acetate; And (b) passing the fabric through a bath containing permethrin, a method of adding permethrin to a fabric to be made into a washable final product. Samson et al., US Pat. No. 5,198,287, for 'Pest Control Tent Fabrics,' describes a tent fabric coated with a pesticidal permethrin having a shelf life of at least six months. A factor that extends the life of permethrin in tents made according to this patent is that the permethrin is coated on the inside of the tent. Samson's U.S. Pat. It is described. Another problem with using permethrin as a pest control agent in washable finished products is that the permethrin must be preserved in the fabric even after the product has been washed several times. McNally's US Pat. No. 5,089,298 on the synergistic effect of amylopectin-permethrin combinations on fabrics provides a solution to the problem of preserving permethrins in finished products even after multiple washings. The patent indicates that infiltrating permethrin, amylopectin, and water-soluble starch into clothing preserves permethrin in the garment after much more washing than permethrin-only clothing.
한편, 독성이 낮은 천연재료를 이용한 방충, 향균가공제의 개발도 활발하게 이루어지고 있다. 대한민국 공개특허공보 제2005-100587호에는 항균제로는 트리클 로산(2,4,4`-트리클로로-2`-하이드록시디페닐에테르) 0.1~10중량%이고, 방충(해충퇴치)제로는 제충국제, 아네톨, 시트로넬라, 디레몬, 제라니올, 시트랄, 네롤, 유칼립투스 중에서 1종 또는 2종 이상 선택되어진 물질로서 0.1~40중량%를 갖는 마이크로캡슐화 기술을 도입한 섬유코팅제 조성물이 개시되어 있다. On the other hand, the development of insect repellents, antimicrobial processing agents using low-toxic natural materials are also actively made. Korean Patent Publication No. 2005-100587 discloses triclosan (2,4,4`-trichloro-2`-hydroxydiphenyl ether) as an antibacterial agent in an amount of 0.1 to 10% by weight, and an insect repellent agent as an insect repellent agent. 1, 2 or more selected from anetol, citronella, diremonol, geraniol, citral, nerol, eucalyptus, and a fiber coating agent composition that incorporates microencapsulation technology having 0.1 to 40% by weight. Is disclosed.
그러나, 전술한 문헌을 포함한 기존의 상기 방법은 될 때 독성이 강하여 인체에 미치는 영향이 있으며 항균효과와 병용되지 않고 석유계 용제를 사용하는 문제가 있으며, 퍼메트린은 살충성의 수명이 비교적 짧기 때문에 제한적으로만 사용되어왔다. 그 이유는 산소 및 자외선이 있는 상태에서는 퍼메트린이 활성이 없고 살충성이 없는 물질로 분해기기 때문이다. 또한, 상기 방충 또는 항균가공제를 이용한 섬유의 가공처리방법이 스프레이나, 단순함침 또는 마이크로 캡슐화하는 방법에 그쳐 섬유조직과의 낮은 결합강도로 인해 세탁 후 급격히 방충 및 항균효과가 저하되고 경시변화가 심한 문제점이 있다.However, the existing method including the above-mentioned literature has a strong toxicity when it has an effect on the human body, there is a problem using petroleum-based solvents in combination with the antibacterial effect, permethrin is limited because of the relatively short life of pesticides Only has been used. This is because in the presence of oxygen and ultraviolet light, permethrins decompose into inert and non-pestifying substances. In addition, the processing method of the fiber using the insect repellent or antimicrobial processing agent is only spraying, simple impregnation or micro-encapsulation method, due to the low bonding strength with the fiber tissue sharply lowers the insect repellent and antibacterial effect after washing and severe change over time There is a problem.
따라서, 본 발명의 기술적 과제는 천연추출물을 기반으로 하여 인체에 무해하고 섬유와의 친화도를 높여 내세탁성을 제고하고 경시변화가 적으면서도 안전하고 간편한 방법으로 섬유가공을 할 수 있는 섬유용 방충 및 항균가공제 조성물을 제공하는 것이다.Therefore, the technical problem of the present invention is harmless to the human body based on the natural extracts to increase the affinity with the fibers to improve the washing resistance and the fiber insect repellent can be processed in a safe and simple way with little change over time And it provides an antimicrobial agent composition.
본 발명의 또 다른 기술적 과제는 상기 조성물을 이용한 섬유가공방법을 제공하는 것이다.Another technical problem of the present invention is to provide a fiber processing method using the composition.
상기 기술적 과제를 달성하기 위하여, 본 발명은 용매로서의 글리콜 에테르 50 내지 85중량%와, 방충제로서의 제충국 추출물인 피레트린 또는 시네린(pyrethrin or cinerin) 2 내지 10중량%와, 에스테르화 촉매 0.8 내지 2중량%와, 향균제로서의 이소치아졸린 5 내지 20중량% 및 계면활성제 2 내지 8중량%를 포함하는 섬유용 방충 및 항균가공제 조성물을 제공한다.In order to achieve the above technical problem, the present invention is 50 to 85% by weight of a glycol ether as a solvent, 2 to 10% by weight of pyrethrin or cinerin as a insect repellent extract as an insect repellent, 0.8 to 2 esterification catalyst It provides a fiber insect repellent and antimicrobial agent composition comprising a weight percent, 5 to 20% by weight of isothiazoline as an antibacterial agent and 2 to 8% by weight surfactant.
또한, 본 발명은 상기 글리콜 에테르가 부틸글리콜(BG), 부틸디글리콜(BDG), 부틸트리글리콜(BTG), 부틸프로필디글리콜(BFDG), 메틸글리콜(MG), 메틸디글리콜(MDG), 메틸트리글리콜(MTG), 메틸폴리글리콜(MPG), 메틸프로필렌글리콜(MFG),메틸프로필렌디글리콜(MFDG)로 구성된 군으로부터 선택된 1종 이상인 것을 특징으로 하는 섬유용 방충 및 항균가공제 조성물을 제공한다.In the present invention, the glycol ether is butyl glycol (BG), butyl diglycol (BDG), butyl triglycol (BTG), butylpropyl diglycol (BFDG), methyl glycol (MG), methyl diglycol (MDG), Provides a fiber insect repellent and antimicrobial agent composition, characterized in that at least one selected from the group consisting of methyl triglycol (MTG), methyl polyglycol (MPG), methyl propylene glycol (MFG), methyl propylene diglycol (MFDG). .
또한, 본 발명은 상기 에스테르화 촉매가 차아인산, 파라톨루엔 설페이트 및 선형알킬설페이트로 구성된 군으로부터 선택된 1종 이상인 것을 특징으로 하는 섬유용 방충 및 항균가공제 조성물을 제공한다.The present invention also provides a fiber insect repellent and antimicrobial agent composition, characterized in that the esterification catalyst is at least one selected from the group consisting of hypophosphorous acid, paratoluene sulfate and linear alkyl sulfate.
또한, 본 발명은 상기 계면활성제가 캐스터 오일 에톡실레이티드(Castor oil ethoxylated)계, 폴리옥시에틸렌 라우릴 에스테르(Polyoxyethylene Lauryl ester), 폴리옥시에틸렌 올레일 에스테르(Polyoxyethylene Oleyl ester), 폴리옥시에틸렌 스테아릴 에스테르(Polyoxyethylene Stearyl ester) 및 폴리옥시에틸렌 패티 에스테르(Polyoxyethylene Fatty ester)계 계면활성제로 구성된 군으로부터 선택된 1종 이상인 것을 특징으로 하는 섬유용 방충 및 항균가공제 조성물을 제공한다.In addition, the present invention, the surfactant is castor oil ethoxylated (Castor oil ethoxylated) system, polyoxyethylene lauryl ester (Polyoxyethylene Lauryl ester), polyoxyethylene Oleyl ester (polyoxyethylene Oleyl ester), polyoxyethylene ste It provides a fiber insect repellent and antimicrobial agent composition, characterized in that at least one member selected from the group consisting of an aryl ester (Polyoxyethylene Stearyl ester) and a polyoxyethylene Fatty ester-based surfactant.
본 발명의 또 다른 기술적 과제를 달성하기 위하여, 본 발명의 또 다른 측면 은, 상기 섬유용 방충 및 항균가공제 조성물과 섬유를 에스테르화 반응시키는 단계를 포함하는 섬유가공방법을 제공한다. In order to achieve another technical problem of the present invention, another aspect of the present invention provides a fiber processing method comprising the step of esterifying the fiber insect repellent and antimicrobial agent composition for the fiber.
또한, 본 발명은 상기 에스테르화 반응이 150 내지 200℃ 온도범위에서 0.1 내지 2분 동안 수행되는 것을 특징으로 하는 섬유가공방법을 제공한다. In addition, the present invention provides a fiber processing method, characterized in that the esterification reaction is carried out for 0.1 to 2 minutes in the temperature range of 150 to 200 ℃.
또한, 본 발명은 상기 섬유용 방충 및 항균가공제 조성물과 상기 섬유가 0.1:1 내지 10:1 범위의 무게비로 혼합되는 것을 특징으로 하는 섬유가공방법을 제공한다. In addition, the present invention provides a fiber processing method, characterized in that the fiber insect repellent and antimicrobial agent composition and the fiber is mixed in a weight ratio of 0.1: 1 to 10: 1.
이하에서 본 발명을 보다 상세히 설명한다. Hereinafter, the present invention will be described in more detail.
본 발명의 섬유용 방충 및 항균가공제 조성물은 용매로서의 글리콜 에테르 50 내지 85중량%와, 방충제로서의 제충국 추출물인 피레트린 또는 시네린(pyrethrin or cinerin) 2 내지 10중량%와, 에스테르화 촉매 0.8 내지 2중량%와, 향균제로서의 이소치아졸린 5 내지 20중량% 및 계면활성제 2 내지 8중량%를 포함한다. 상기 제충국 추출물인 피레트린과 시네린은 방제효과가 있으면서도 인체에 대한 독성이 거의 없어 이를 이용한 방제제가 많이 개발되었다. 또한, 전술한 바와 같이, 섬유의 방충가공에도 상기 피네트린을 포함한 방충가공제가 개발되어 있다. 그러나, 전술한 방충가공제를 기존의 방법으로 섬유에 처리하는 경우 석유계 용제를 사용하여 그 자체로 인체유독성이 있으며 섬유조직과 방충가공제간의 결합은 물리적 결합에 그치는 것이어서, 내세탁성이 약하고 시간의 경과에 따라 급격히 그 효과가 저감되는 문제가 있었다. 본 발명의 섬유용 방충 및 항균가공제 조성물은 석유계 용제를 사용하지 않아 인체유독성을 현저하게 낮추고, 섬유조직의 -OH기와 상기 피네트린 및 시네린의 -COOR(R은 알킬기)간의 에스테르화 반응을 통해 화학결합을 유도하여 내세탁성을 강화하고 경시변화를 적게 한다. 본 발명의 섬유용 방충 및 항균가공제 조성물이 적용되는 섬유는 그 분자구조 중 -OH기를 포함하고 있는 것을 그 대상으로 한다.Fiber insect repellent and antimicrobial agent composition of the present invention is 50 to 85% by weight of glycol ether as a solvent, 2 to 10% by weight of pyrethrin or cinerin as a pesticide extract as insect repellent, 0.8 to 2 esterification catalyst Wt%, 5-20 wt% of isothiazoline as antibacterial agent and 2-8 wt% of surfactant. Pyrethrin and cinerine, the extracts of Pyrethrum, have a control effect, but have little toxicity to the human body, and many control agents have been developed using the same. In addition, as described above, the insect repellent agent containing the above-mentioned finnetrin has also been developed for the insect repellent processing of fibers. However, when the above-mentioned insect repellent treatment agent is treated to the fiber by the conventional method, it is toxic to human body by using petroleum-based solvents, and the bond between the fiber tissue and the insect repellent agent is only a physical bond. There has been a problem that the effect is rapidly reduced with progress. The insect repellent and antimicrobial agent composition for the fiber of the present invention does not use a petroleum-based solvent, significantly reducing human toxicity, and esterification reaction between the -OH group of the fibrous tissue and the -COOR (R is an alkyl group) of the fibrin and cinerine. Induces chemical bonds to enhance laundry resistance and reduce changes over time. The fiber to which the insect repellent and antimicrobial agent composition for fibers of the present invention is applied is intended to include -OH group in its molecular structure.
본 발명의 섬유용 방충 및 항균가공제 조성물은 용매로서의 글리콜 에테르 50 내지 85중량%를 포함한다. 글리콜 에테르는 유기용매로서의 성질도 탁월하고 또한 물과 상용성이 높기 때문에, 본 발명의 섬유가공제 조성물의 용제로 사용한 것이다. 따라서, 본 발명의 섬유용 방충 및 항균가공제 조성물을 이용한 섬유가공은 별도의 기계나 공정을 요하지 않고 고온다습한 조건하에서 수행되는 텐터작업과 병행하여 이루어질 수 있기 때문에 매우 경제적이고 간편하다. 상기 글리콜 에테르의 바람직한 예로는 부틸글리콜(BG), 부틸디글리콜(BDG), 부틸트리글리콜(BTG), 부틸프로필디글리콜(BFDG), 메틸글리콜(MG), 메틸디글리콜(MDG), 메틸트리글리콜(MTG), 메틸폴리글리콜(MPG), 메틸프로필렌글리콜(MFG),메틸프로필렌디글리콜(MFDG)로 구성된 군으로부터 선택된 1종 이상인 것이 바람직하다. Fiber insect repellent and antimicrobial agent composition of the present invention comprises 50 to 85% by weight of the glycol ether as a solvent. The glycol ether is used as a solvent of the fiber processing agent composition of the present invention because of its excellent organic solvent properties and high compatibility with water. Therefore, the fiber processing using the fiber insect repellent and antimicrobial processing agent composition of the present invention is very economical and simple because it can be performed in parallel with the tenter operation performed under high temperature and high humidity conditions without requiring a separate machine or process. Preferred examples of the glycol ethers include butyl glycol (BG), butyl diglycol (BDG), butyl triglycol (BTG), butylpropyl diglycol (BFDG), methyl glycol (MG), methyl diglycol (MDG) and methyl tree It is preferable that it is at least 1 type selected from the group consisting of glycol (MTG), methyl polyglycol (MPG), methyl propylene glycol (MFG), and methyl propylene diglycol (MFDG).
또한, 본 발명의 섬유용 방충 및 항균가공제 조성물은 방충제로서의 제충국 추출물인 피레트린 또는 시네린(pyrethrin or cinerin) 2 내지 10중량%를 포함한다. 상기 피레트린 및 시네린의 방충효과 등은 이미 알려져 있는 것이므로 본 명세서에서 더 이상의 상세한 설명은 하지 않기로 한다.In addition, the insect repellent and antimicrobial agent composition for fibers of the present invention contains 2 to 10% by weight of pyrethrin or cinerin, which is an insect repellent extract as a repellent. The insect repellent effect of the pyrethrin and cinerine is already known and thus will not be described in detail herein.
또한, 본 발명의 섬유용 방충 및 항균가공제 조성물은 에스테르화 촉매 0.8 내지 2중량%를 포함한다. 전술한 바와 같이, 본 발명의 섬유용 방충 및 항균가공 제 조성물은 상기 피레트린 또는 시네린을 섬유조직의 -OH기와 반응시켜 에스테르 화합물을 형태로 제조하며 이를 위해 에스테르화 촉매를 사용한다. 상기 에스테르화 촉매는 특별히 제한되는 것은 아니며, 인체에 무해하고 본 발명의 가공방법 및 가공조건에 적합한 것이면 모두 사용가능하다. 상기 에스테르화 촉매의 바람직한 예로는 차아인산, 파라톨루엔 설페이트 및 선형알킬설페이트로 구성된 군으로부터 선택된 1종 이상인 것이 바람직하다. In addition, the insect repellent and antimicrobial agent composition for fibers of the present invention contains 0.8 to 2% by weight of an esterification catalyst. As described above, the insect repellent and antimicrobial agent composition for textiles of the present invention reacts the pyrethrin or cinerine with -OH groups of the fibrous tissue to prepare an ester compound in the form of an esterification catalyst. The esterification catalyst is not particularly limited and may be used as long as it is harmless to the human body and suitable for the processing method and processing conditions of the present invention. Preferred examples of the esterification catalyst are at least one selected from the group consisting of hypophosphorous acid, paratoluene sulfate and linear alkyl sulfate.
본 발명의 섬유용 방충 및 항균가공제 조성물은 계면활성제 2 내지 8중량%를 포함한다. 상기 계면활성제는 방충 및 항균성분인 피네트린/시네린과 이소치아졸린을 용매에 용해하는데 도움을 주고 수용액 환경하에서 상기 유기물 성분이 침전되는 것을 방지하는 역할을 수행한다. 상기 계면활성제는 특별한 제한이 있는 것은 아니며, 본 발명의 사용환경에 적합하고 인체 유해성이 없거나 적은 것이면 된다. 상기 계면활성제의 바람직한 예로는 캐스터 오일 에톡실레이티드(Castor oil ethoxylated)계, 폴리옥시에틸렌 라우릴 에스테르(Polyoxyethylene Lauryl ester), 폴리옥시에틸렌 올레일 에스테르(Polyoxyethylene Oleyl ester), 폴리옥시에틸렌 스테아릴 에스테르(Polyoxyethylene Stearyl ester) 및 폴리옥시에틸렌 패티 에스테르(Polyoxyethylene Fatty ester)계 계면활성제로 이루어진 군으로부터 선택된 1종 이상인 것이 바람직하다.Fiber insect repellent and antimicrobial agent composition of the present invention comprises a surfactant 2 to 8% by weight. The surfactant assists in dissolving the insecticide and antimicrobial agents, such as pinhrine / cinerine and isothiazoline, in a solvent and serves to prevent precipitation of the organic component in an aqueous solution environment. The surfactant is not particularly limited and may be suitable for the use environment of the present invention and have little or no human hazard. Preferred examples of the surfactant include castor oil ethoxylated, polyoxyethylene lauryl ester, polyoxyethylene oleyl ester, polyoxyethylene stearyl ester (Polyoxyethylene Stearyl ester) and polyoxyethylene Fatty ester (Polyoxyethylene Fatty ester) is preferably at least one member selected from the group consisting of.
본 발명의 섬유용 방충 및 항균가공제 조성물은 향균제로서의 이소치아졸린 5 내지 20중량%를 포함한다. 이소치아졸린은 항균제로서 이미 알려진 물질이며 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자라면 잘 알 수 있을 것이므로 본 명세서에서 더 이상의 상세한 설명은 하지 않기로 한다.The insect repellent and antimicrobial agent composition for fibers of the present invention contains 5 to 20% by weight of isothiazoline as an antibacterial agent. Isothiazoline is a substance already known as an antimicrobial agent and will be well understood by those skilled in the art to which the present invention pertains.
본 발명의 섬유용 방충 및 항균가공제 조성물은 후술하는 것과 같이 섬유 및 직물의 제조, 가공단계에서 섬유가공제로서 사용될 수도 있으며, 섬유완제품의 후처리 즉 섬유용 방충 및 항균 린스제조, 집먼지 진드기, 모기의 기피제의 스프레이 및 바르는 크림제제의 원료로도 사용되어 질 수가 있다.The insect repellent and antimicrobial agent composition for textiles of the present invention may be used as a fiber processing agent in the manufacturing and processing of fibers and fabrics, as described below. It can also be used as a raw material for spraying and applying creams.
본 발명의 또 다른 측면은 상기 섬유용 방충 및 항균가공제 조성물과 섬유를 에스테르화 반응시키는 단계를 포함하는 섬유가공방법을 제공한다. 상기 에스테르화 반응은 150 내지 200℃ 온도범위에서 0.1 내지 2분 동안 수행되는 것이 바람직하고, 상기 섬유용 방충 및 항균가공제 조성물과 상기 섬유는 0.1:1 내지 10:1 범위의 무게비로 혼합되는 것이 바람직하다. 전술한 것과 같이, 종래의 섬유가공방법은 항균제 등을 섬유에 물리적 흡착시키는 것으로, 세탁 후 그 효과가 급격히 저하되고 경시변화가 심한 문제가 있다. 본 발명의 섬유가공방법은 섬유의 -OH기에 상기 방충 및 항균성분을 에스테르 결합을 통해 화학적으로 결합시키는 것으로, 종래의 가공방법에 비해 내세탁성이 우수하고 경시변화가 적은 장점이 있다. 또한, 본 발명의 섬유용 방충 및 항균가공제 조성물은 수분이 많은 환경하에서도 가공이 가능하기 때문에 상기 섬유가공방법은 별도의 설비나 공정을 요하지 않고 기존의 설비와 공정을 활용하여 가공처리를 수행할 수 있다. 다만, 본 발명의 섬유가공방법은 다소의 고온처리가 요구됨에 따라 고온공정에서 가공공정이 수행되는 것이 바람직하고, 본 발명의 바람직한 태양인 실시예에서는 고온다습한 환경하에서 수행되는 텐터공정에서 방충 및 항균처리를 병행하여 수행하였다. Another aspect of the present invention provides a fiber processing method comprising the step of esterifying the fiber with the insect repellent and antimicrobial agent composition for the fiber. The esterification reaction is preferably carried out for 0.1 to 2 minutes at a temperature range of 150 to 200 ℃, the insect repellent and antimicrobial composition for the fiber and the fiber is preferably mixed in a weight ratio of 0.1: 1 to 10: 1 range. Do. As described above, the conventional fiber processing method is to physically adsorb the antimicrobial agent to the fiber, the effect is sharply lowered after washing, there is a problem with a severe change over time. The fiber processing method of the present invention is to chemically bond the insecticide and the antibacterial component to the -OH group of the fiber through an ester bond, and has the advantage of excellent washing resistance and less change with time than the conventional processing method. In addition, the fiber insect repellent and antimicrobial agent composition of the present invention can be processed even in a humid environment, the fiber processing method does not require a separate equipment or process to be processed using existing equipment and processes. Can be. However, in the fiber processing method of the present invention, it is preferable that the processing process is performed at a high temperature process as some high temperature treatment is required, and in the preferred embodiment of the present invention, insect repellent and antibacterial in a tenter process performed under a high temperature and high humidity environment. Treatment was performed in parallel.
이하에서는 본 발명의 바람직한 실시예를 통해 본 발명을 더욱 상세히 설명한다. 다만, 하기 실시예는 본 발명에 대한 이해를 돕기 위한 것일 뿐, 본 발명의 범위가 하기 실시예로만 제한되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to preferred embodiments of the present invention. However, the following examples are merely to help the understanding of the present invention, the scope of the present invention is not limited only to the following examples.
실시예 1(방충 및 항균가공제 조성물의 제조)Example 1 (Preparation of Insect Repellent and Antimicrobial Composition)
교반장치(mechanical stirrer), 온도계, 증류장치 그리고 점적 펀넬(dropping funnel)이 장착된 2L 4구 반응용기에 제충국 추출물인 피레트린과 시네린(pyrethrin & cinerin) 5g과 촉매로서 파라톨루엔 설페이트 2g, 용매로서 부틸디글리콜(BDG) 80g, 항균제로서의 이소치아졸린(isothiazoline) 10g 및 계면활성제로서 캐스터 오일 에톡실레이티드(Castor oil ethoxylated) 3g을 투입하였다. 그 다음, 교반온도를 60℃까지 승온하고 1시간동안 교반하여 섬유용 방충 및 항균가공제 조성물을 제조하였다. In a 2L four-necked reaction vessel equipped with a mechanical stirrer, thermometer, distillation and dropping funnel, 5 g of pyrethrin & cinerin, a pyrethrin and cinerin extract, and 2 g of paratoluene sulfate as a catalyst, solvent 80 g of butyldiglycol (BDG), 10 g of isothiazoline as an antimicrobial agent, and 3 g of castor oil ethoxylated were added as a surfactant. Then, the stirring temperature was raised to 60 ℃ and stirred for 1 hour to prepare a fiber insect repellent and antimicrobial agent composition.
실시예 2(실시예 1의 조성물을 이용한 섬유가공)Example 2 (Fiber Processing Using Composition of Example 1)
상기 실시예 1에서 제조된 섬유용 방충 및 항균가공제 조성물을 이용하여 섬유가공을 수행하였다. 상기 실시예 1에서 제조한 조성물을 섬유무게 대비 2 내지3의 중량%로 투입하며, 텐타기계 망글의 픽업(pick up)율을 75%의 수분을 유지 후 110℃로 건조하고 180℃에서 12초간 열처리하여 방충 및 항균가공처리를 하였다. Fiber processing was performed using the insect repellent and antimicrobial agent compositions for fibers prepared in Example 1. The composition prepared in Example 1 was added at a weight ratio of 2 to 3 based on the weight of the fiber, and the pick up rate of the tenta machine mangle was maintained at 75% of moisture, dried at 110 ° C, and then at 180 ° C for 12 seconds. Heat treatment was performed for insect repellent and antibacterial treatment.
실시예 3(방충 및 항균효과의 검증)Example 3 (verification of insect repellent and antibacterial effect)
상기 실시예 1 및 2에서 제조한 섬유용 방충 및 항균가공제 조성물 및 상기 조성물로 처리한 섬유원단의 항균, 방충효과 및 인체유독성 테스트를 수행하였다.The antibacterial and antimicrobial agent compositions for the fibers prepared in Examples 1 and 2 and the antimicrobial, insect repellent effect and human toxicity test of the fiber fabric treated with the composition were performed.
항균테스트는 상기 실시예 2에서와 같이 가공처리된 면원단 0.4g 및 가공처리하지 않은 면원단 0.4g(대조편) 각각 3개에 황색포도상구균 Straphyloccus aureus ATCC 6538과 폐렴쌍구균 Klebsiella pneumoniae ATCC 4352를 접종한 후 시간경과에 따른 생균의 평균개체수를 측정하는 방법으로 수행되었다. 하기 표 1은 그 결과를 나타낸 것이다. 하기 표 1에서 볼 수 있는 것과 같이, 본 발명의 섬유용 방충 및 항균가공제 조성물로 처리한 원단의 경우 뛰어난 항균효과를 나타내었다.The antibacterial test was inoculated with 3 grams of treated cotton fabric 0.4g and 0.4g untreated cotton fabric (control) as in Example 2, respectively, inoculated with Staphylococcus aureus Straphyloccus aureus ATCC 6538 and Klebsiella pneumoniae ATCC 4352. Afterwards, this was performed by measuring the average number of living organisms over time. Table 1 shows the results. As can be seen in Table 1, in the case of the fabric treated with the fiber insect repellent and antimicrobial agent composition of the present invention showed an excellent antibacterial effect.
상기 표에서, Ma:대조편의 접종 직후의 생균수, Mb:대조편의 18시간 경과 후의 생균수 및 Mc:시험편의 18시간 경과 후의 생균수이고, 증가율은 Mb/Ma, 정균감소율은 [(Mb-Mc)/Mb]X100이다.In the above table, Ma: viable count immediately after inoculation of the control, Mb: viable count after 18 hours of the control, and Mc: viable count after 18 hours of the test, the increase rate is Mb / Ma, and the bacteriostatic reduction rate is [(Mb- Mc) / Mb] X100.
또한, 방충테스트는 직경 3.5cm, 높이 1cm의 프라스틱제 접시에 상기 실시예 1에서 제조한 본 발명의 섬유용 방충 및 항균가공제 조성물을 처리한 원단과 처리되지 않는 원단을 놓고 그 위에 유인물질인 배지 0.05g을 배치한 시험시료 3개와 상기 섬유용 방충 및 항균가공제 조성물로 처리하지 않은 것을 제외하고는 모든 조건이 동일한 대조시료를 준비하였다. 상기 프라스틱제 접시 주변에 약 30,000마리/g 농도의 2종의 집먼지진드기배지를 균일하게 펴놓고, 24시간 동안 방치한 다음 상기 프라스틱제 접시에 침입한 생존 진드기의 개체수를 측정하는 방법으로 방충효과를 테스트 하였다. 하기 표 2는 그 결과를 정리한 것이다.In addition, the insect repellent test is placed on a plastic dish of 3.5 cm in diameter, 1 cm in height and the fabric and the untreated fabric treated with the fiber insect repellent and antimicrobial processing agent composition of the present invention prepared in Example 1, the medium is attracted thereon Except for three test samples placed 0.05g and not treated with the fiber insect repellent and antimicrobial agent composition, all the same control samples were prepared. The insect repellent effect was measured by uniformly spreading two kinds of house dust mite medium having a concentration of about 30,000 grains / g around the plastic dish, leaving it for 24 hours, and measuring the number of surviving ticks invading the plastic dish. Was tested. Table 2 summarizes the results.
또한, 본 발명의 섬유용 방충 및 항균가공제 조성물의 인체유해성을 테스트하였다. 테스트는 실시예 1에서 제조한 섬유용 방충 및 항균가공제 조성물의 희석액(0.5%)을 적신 거즈를 20명의 피부에 직접 접촉하게 하고 48시간 경과 후 피부로부터 제거하고 육안판정 및 현미경판정을 통해 자극여부를 판정하였다. 하기 표 3은 그 결과를 정리한 것이다. 하기 표 3 중 A-stage는 원형피구, B-stage는 deep furrow, C-stage는 shallow furrow, vanishing furrow, irregular rigdes and furrows, created ridge 및 lamellar scale 여부이고, D-stage는 부종, 홍반, 구진 등의 발생여부를 판단한 것이다.In addition, the human harmfulness of the fiber insect repellent and antimicrobial agent composition of the present invention was tested. The test was carried out by direct contact with 20 skins of gauze moistened with the diluent (0.5%) of the fiber insect repellent and antimicrobial agent composition prepared in Example 1 and removed from the skin after 48 hours and irritated by visual and microscopic examination. Was determined. Table 3 summarizes the results. In Table 3, A-stage is circular dodge, B-stage is deep furrow, C-stage is shallow furrow, vanishing furrow, irregular rigdes and furrows, created ridge and lamellar scale, D-stage is edema, erythema, papule It is judged whether or not.
상기 테스트 결과에서 볼 수 있는 것과 같이, 본 발명의 섬유용 방충 및 항균가공제 조성물 및 상기 조성물을 이용하여 가공한 섬유원단은 진드기 등의 해충의 기피성과 유해병균에 대한 항균성이 우수하고 피부에 직접 사용하더라도 독성이 없어 섬유류의 가공제로 사용하기 적합함을 확인할 수 있었다. As can be seen from the test results, the fiber insect repellent and antimicrobial agent composition of the present invention and the fiber fabric processed using the composition is excellent in the repellent of pests such as mites and antibacterial against harmful pathogens and directly used on the skin Even though it was not toxic, it could be confirmed that it is suitable for use as a processing agent for fibers.
상기한 바와 같이, 본 발명의 섬유용 방충 및 항균가공제 조성물 및 섬유가공방법은 독성이 낮은 천연물질인 제충국 추출물인 피레트린 및 시네린과 항균제인 이소치아졸린을 배합하여 방충기능과 항균기능을 통합하였으며, 인체에 대한 독성 이 낮으면서도 우수한 방충 및 항균성을 부여하였고, 섬유와 에스테르 결합을 통하여 부착성능을 개선함으로 내세탁성의 향상과 효과의 경시변화가 적으며, 다른 섬유용 가공제와의 상용성이 우수하여 별도의 2차적 공정이 필요가 없으므로 가공시간의 단축과 별도의 설비가 필요치 않아 경제성이 우수하다. As described above, the fiber insect repellent and antimicrobial processing agent composition and fiber processing method of the present invention combines insect repellent and antibacterial function by combining pyrethrin and cinerine with antibacterial isothiazoline, which is a low-toxic natural substance It has low toxicity to human body and gives excellent insect repellent and antibacterial property, and improves adhesion performance through fiber and ester bond, improving washing resistance and little change of effect over time, and compatibility with other textile processing agents. Because of this superiority, there is no need for a separate secondary process, so it is economical because it shortens the processing time and does not require a separate facility.
앞에서 설명된 본 발명의 실시예는 본 발명의 기술적 사상을 한정하는 것으로 해석되어서는 안 된다. 본 발명의 보호범위는 청구범위에 기재된 사항에 의하여만 제한되고, 본 발명의 기술 분야에서 통상의 지식을 가진 자는 본 발명의 기술적 사상을 다양한 형태로 개량 변경하는 것이 가능하다. 따라서 이러한 개량 및 변경은 통상의 지식을 가진 자에게 자명한 것인 한 본 발명의 보호범위에 속하게 될 것이다. The embodiments of the present invention described above should not be construed as limiting the technical idea of the present invention. The protection scope of the present invention is limited only by the matters described in the claims, and those skilled in the art can change and change the technical idea of the present invention in various forms. Therefore, such improvements and modifications will fall within the protection scope of the present invention, as will be apparent to those skilled in the art.
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| KR101563903B1 (en) | 2015-06-19 | 2015-10-29 | (주)동보텍스케어코리아 | Process for Manufacturing Anti-bug Cloth |
| KR20170024774A (en) * | 2015-08-26 | 2017-03-08 | (주)엔바이오 | Fabric treatment composition having functing of tick prevention |
| KR20180126278A (en) | 2017-05-17 | 2018-11-27 | 프라나 주식회사 | Antibacterial Fabrics Using Polyester Crops and Their Manufacturing Method |
| KR20220092034A (en) | 2020-12-24 | 2022-07-01 | 하태훈 | Antibacterial composition and antibacterial fabric using the composition and method for manufacturing the same |
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