CN114366682B - Insect-repellent, smell-repellent and antibacterial pet shampoo - Google Patents
Insect-repellent, smell-repellent and antibacterial pet shampoo Download PDFInfo
- Publication number
- CN114366682B CN114366682B CN202111455200.2A CN202111455200A CN114366682B CN 114366682 B CN114366682 B CN 114366682B CN 202111455200 A CN202111455200 A CN 202111455200A CN 114366682 B CN114366682 B CN 114366682B
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- China
- Prior art keywords
- ammonium chloride
- surfactant
- peg
- insect repellent
- trimethyl ammonium
- Prior art date
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- 239000002453 shampoo Substances 0.000 title claims abstract description 44
- 239000000077 insect repellent Substances 0.000 title claims abstract description 38
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 12
- 239000005871 repellent Substances 0.000 title abstract description 12
- -1 sulfuric acid ester Chemical class 0.000 claims abstract description 35
- 239000002781 deodorant agent Substances 0.000 claims abstract description 31
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 16
- 239000004519 grease Substances 0.000 claims abstract description 16
- 241000894006 Bacteria Species 0.000 claims abstract description 13
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 10
- 244000045947 parasite Species 0.000 claims abstract description 9
- 239000000575 pesticide Substances 0.000 claims abstract description 6
- 239000003755 preservative agent Substances 0.000 claims abstract 2
- 230000002335 preservative effect Effects 0.000 claims abstract 2
- VFKZECOCJCGZQK-UHFFFAOYSA-M 3-hydroxypropyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCO VFKZECOCJCGZQK-UHFFFAOYSA-M 0.000 claims description 20
- 239000004094 surface-active agent Substances 0.000 claims description 16
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- 239000003093 cationic surfactant Substances 0.000 claims description 12
- 239000010452 phosphate Substances 0.000 claims description 12
- 230000003385 bacteriostatic effect Effects 0.000 claims description 10
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 10
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- 239000011734 sodium Substances 0.000 claims description 8
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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Abstract
The invention discloses an insect-repellent, smell-repellent and antibacterial pet shampoo, which comprises an amphoteric surfactant, a nonionic surfactant, an insect repellent, a deodorant, grease and a preservative; the insect repellent is a pesticide
Description
Technical Field
The invention belongs to the technical field of pet care, and particularly relates to an insect-repellent, smell-repellent and antibacterial pet shampoo.
Background
Nowadays, pets are commonly kept as companion animals by people who are members of the family, and who are in close contact with the pet and even sleep together with the bed. However, most of the hair of the pet is dense, and the pet is favored to roll over in the grass mud, so that the pet is easy to carry and breed pathogens such as mosquitoes, lice, fleas, mites and the like, and is easy to be infected with various bacteria due to the body odor of the pet, so that great hidden danger exists for the health of the pet and the host. Therefore, when the pet is cleaned, not only dust and dirt on the fur of the pet are cleaned, but also the purposes of expelling parasites, removing peculiar smell, resisting and inhibiting bacteria are achieved.
However, most of the existing pet shampoos are single-effect products, so that people often need to use a plurality of different-effect pet shampoos for cleaning and nursing pets. And even if the household cleaning care product is multifunctional, various corresponding functional raw materials such as a compound insect repellent, a deodorant and a bacteriostatic agent are generally added to play roles in expelling insects, removing smell and inhibiting bacteria. However, compounding various functional raw materials in the product brings great requirements on the compatibility and stability of the product system, and increases the cost of the product. Therefore, the multi-effect integrated pet shampoo is rarely available in the market at present.
In addition, as the smell of the pet is sensitive, the odor can be removed by adopting a conventional essence masking mode, which has a certain influence on the pet, so that the disposable nursing product for the pet is more suitable for removing the odor by adopting a chemical method. The existing chemical deodorant comprises zinc ricinoleate and soybean ethyl morpholine sulfate, wherein the zinc ricinoleate has poor compounding performance with a formula, is not compatible with a cationic surfactant, and has an unsaturated structure, so that the soybean ethyl morpholine sulfate turns yellow under illumination. Also, pets have the habit of licking their hair, and therefore, as a pet shampoo, must be a product that achieves a practical non-toxic level.
Disclosure of Invention
The invention aims to provide the pet shampoo with the effects of expelling parasites, removing smell and inhibiting bacteria, and the pet shampoo has good effects of expelling parasites, removing smell and inhibiting bacteria, is low in irritation and is safe to pets.
The aim of the invention is achieved by the following technical scheme:
a pet shampoo with effects of expelling parasite, removing odor and inhibiting bacteria comprises amphoteric surfactant, nonionic surfactant, insect repellent, deodorant, oil and fat, and antiseptic; the insect repellent is a pesticideAn alkane-3, 8-diol; the deodorant has the following structure:
wherein R is 1 Is C14, C16, C18 or C20 alkyl, R2 is methyl, ethyl or propyl, R 3 Is methylene, ethylene or propylene.
The invention aims to obtain the pet shampoo with effective insect expelling, smell removing, bacteriostasis and low irritation:
firstly, the pet shampoo is compounded by adopting insect repellent and deodorant, so as to achieve the purposes of expelling insects and removing peculiar smell; wherein, toThe alkane-3, 8-diol (CAS number 42822-86-6) can act on lice, fleas, mosquitoes, nasal discharge insects, armyworms and the like as an insect repellent, and has long effective acting time; the deodorant is sulfuric acid ester or phosphoric acid ester with a specific structure, the property is stable, quaternary ammonium salt cationic groups in the structure have positive charges, and nitrogen or sulfur atoms in odor molecules contain lone pair electrons, so that the deodorant can attract odor molecules and combine with the odor molecules to achieve the effect of rapid and stable deodorization; furthermore, the inventors have found that the deodorant has a certain bacteriostatic effect in the system.
Meanwhile, through continuous researches of the inventor, the insect repellent and the deodorant are matched and applied to a formula system of the pet shampoo, so that the insect repellent and the deodorant have the effects of removing peculiar smell and expelling insects, and can achieve unexpected antibacterial effect in a synergistic way when being matched and used, and the effects of removing peculiar smell and expelling insects of the formula are further improved.
Through the research of the inventor, the reason why the insect repellent and the deodorant can synergistically improve the deodorizing, insect repellent and antibacterial effects of the pet shampoo is presumed to be as follows: 1. the deodorant is characterized in that a negatively charged sulfate group or phosphate group is present, and is opposite toThe hydroxyl of the alkane-3, 8-diol acts to form a larger molecular structure, and the macromolecular structure has stronger cell membrane penetrating capacity to bacteria and reactivity to odor molecules than any component alone, so that better antibacterial effect and odor removal effect are generated; 2. the deodorant reacts with odor molecules on pet body surface to relieve pet odor, and relieve +.>The alkane-3, 8-diol can more effectively exert the repellent effect of the smell on insects.
Furthermore, the inventor strictly controls the irritation of the formula from the aspect of the design of the whole formula; the PMD which has the same insect repellent effect as the mosquito repellent amine and is only one sixth of the mosquito repellent amine in toxicity is selected, and is a non-pesticide component, is the only natural active component of the insect repellent allowed to be used in the United states and European Union, and is safe and reliable; surfactants with low irritation are also used. The deodorant disclosed by the invention is nontoxic, has the characteristics of stable illumination performance, difficult yellowing, strong compounding capability and the like compared with the existing deodorant, and can be applied to an anionic surfactant system, a cationic surfactant system and a nonionic surfactant system.
In addition, the invention uses the oil and the surfactant to solubilize the pair in the formula systemAlkane-3, 8-diol. When the pet is cleaned, the surface active agent removes dirt on the surface of the pet, and the grease is deposited on the fur of the pet and assistedAuxiliary pairThe alkane-3, 8-diol is deposited on the fur of the pet, plays a role in expelling parasites, and further plays a synergistic deodorizing and antibacterial effect with the deodorant.
The addition amount of the insect repellent is 0.5-2% by mass percent; the addition amount of the deodorant is 0.1-0.5% by mass percent. The addition amount of the insect repellent and the deodorant can effectively cooperate to play roles of expelling insects, removing smell and resisting bacteria, and meanwhile, the stability of a formula system is ensured.
The pet shampoo also comprises one or more of anionic surfactant, cationic surfactant, emulsified silicone oil, pearling agent and thickener.
The amphoteric surfactant is one or more of betaine type amphoteric surfactant, imidazoline type amphoteric surfactant, amino acid type amphoteric surfactant and amine oxide type amphoteric surfactant.
The nonionic surfactant is one or more of alkanolamide surfactant and alkyl polyglycoside surfactant.
The anionic surfactant is one or more of fatty alcohol polyoxyethylene ether sodium sulfate, fatty alcohol polyoxyethylene ether ammonium sulfate, fatty alcohol sodium sulfate, fatty alcohol ammonium sulfate, fatty alcohol polyoxyethylene ether sodium carboxylate and fatty alcohol polyoxyethylene ether ammonium carboxylate.
The cationic surfactant is one or more of quaternary ammonium salt type surfactant and cationic guar gum.
Cationic guar gum in the cationic surfactant provides good wet combing effect, and smooth hand feeling is achieved during washing; the quaternary ammonium salt surfactant provides good softness and bulk of the dry comb, so that the quilt Mao Roushun is fluffy and does not collapse; the two components and the grease act together to achieve good dry and wet combing effect on the pet fur, and the two components of repairing and nourishing the pet fur and washing and protecting are combined. The deodorant and the cationic surfactant adopted by the invention can be stably compatible in the system, so that the pet fragrance can have the effects of removing peculiar smell and nursing pet fur.
The quaternary ammonium salt surfactant comprises soybean oil based dimethyl ammonium hydroxypropyl hydrolyzed wheat protein, hydroxypropyl trimethyl ammonium chloride hydrolyzed silk, hydroxypropyl trimethyl ammonium chloride hydrolyzed soybean protein, hydroxypropyl trimethyl ammonium chloride hydrolyzed collagen, hydroxypropyl trimethyl ammonium chloride hydrolyzed keratin, hydroxypropyl trimethyl ammonium chloride hydrolyzed casein, soybean oil based trimethyl ammonium chloride, starch hydroxypropyl trimethyl ammonium chloride, dimer linolenyl propyl PG-dimethyl ammonium chloride phosphate, dihydroxypropyl PEG-5 linolenyl ammonium chloride, panthenol hydroxypropyl stearyl dimethyl ammonium chloride, olive oil amide propyl PG-dimethyl ammonium chloride phosphate sodium, hydroxypropyl trimethyl ammonium chloride honey, hydrogenated starch hydrolysate hydroxypropyl trimethyl ammonium chloride, and myristyl amide propyl PG-dimethyl ammonium chloride phosphate, cinnamyl amide propyl trimethyl ammonium chloride, lactamidopropyl trimethyl ammonium chloride, linoleyl amide propyl PG-dimethyl ammonium chloride phosphate, cocoyl amide propyl PG-dimethyl ammonium chloride phosphate sodium, cocoyl PG-dimethyl ammonium chloride phosphate sodium, oleamidopropyl PG-dimethyl ammonium chloride, lauryl methyl glucitol polyether-10 hydroxypropyl dimethyl ammonium chloride, ricinoleic acid amide propyl trimethyl ammonium chloride, polyquaternium-6, polyquaternium-7, polyquaternium-10, polyquaternium-22, polyquaternium-39, polyquaternium-47, polyquaternium-53.
The cationic guar gum comprises one or more of guar hydroxypropyl trimethyl ammonium chloride and hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride.
The grease is one or more of synthetic ester, PEG modified water-soluble grease and vegetable grease; the oil is at least one selected from water-soluble olive oil, PEG-7 cocoyl glyceride, glyceryl caprylate/caprate, C12-15 lactate, PPG-3 octyl ether, PPG-3 myristyl alcohol ether, glyceryl oleate, di PPG-2 myristyl oleyl polyether-10 adipate, polyglyceryl ether-10-caprylate/caprate, PEG/PPG-8/3 distearate, polyglyceryl-3 laurate, phytosterol/octyldodecanol lauroyl glutamate, polyester-11, PEG-75 lanolin, PEG-7 olive oleate, sucrose cocoate, glyceryl oleate, polyglyceryl-10 oleate, polyglyceryl-3 caprate, peanut oil, olive oil, wheat germ oil, mango seed oil and avocado oil.
The thickener is selected from one or more of sodium chloride, PEG-150 pentaerythritol tetrastearate/PPG-2 hydroxyethyl cocoamide, PEG-120 methyl glucose dioleate, PEG-120 distearate, PEG-150 distearate, PEG-90 glycerol isostearate/laureth-2, laurinol lactoyl lactate, PEG-55 propylene glycol oleate and PEG-200 hydrogenated glycerol palmitoleate.
The emulsified silicone oil is polydimethylsiloxane and derivatives thereof, and comprises one or more of polydimethylsiloxane, ammonia-terminal polydimethylsiloxane, bis-aminopropyl polydimethylsiloxane and bis (C13-15 alkoxy) PG-ammonia-terminal polydimethylsiloxane.
The pearlizing agent is glycol distearate.
The total addition amount of the surfactant in the pet shampoo is 7-20% by mass percent.
As a recommended scheme, the content of the amphoteric surfactant in the pet shampoo is 6-15% by mass, the content of the nonionic surfactant is 0.5-3% by mass, the content of the anionic surfactant is less than or equal to 13% by mass, the content of the cationic surfactant is less than or equal to 1% by mass, the content of the grease is 0.2-2% by mass, the content of the emulsified silicone oil is less than or equal to 4% by mass, the content of the pearling agent is less than or equal to 2% by mass, and the content of the thickener is less than or equal to 3% by mass.
Compared with the prior art, the invention has the following beneficial effects:
1. the pet shampoo of the invention is compounded with deodorant and pair with specific structuresThe alkane-3, 8-diol not only can quickly and stably remove peculiar smell and effectively expel insects, but also can achieve unexpected antibacterial effect without adding any antibacterial agent, and is more effectiveFurther improves the deodorizing and insect-repellent effects of the system; namely, the invention adopts two specific deodorant and insect repellent to achieve the effects of expelling insects, removing smell and inhibiting bacteria.
The pet shampoo disclosed by the invention has low irritation, no irritation to eyes, safety to pets and stable formula system; and the auxiliary pair of grease in the formulaThe alkane-3, 8-diol is deposited on the fur of the pet, and further plays synergistic effects of expelling parasites, deodorizing and inhibiting bacteria with the deodorant.
2. The quaternary ammonium salt type surfactant or the cationic guar gum is added into the pet shampoo, and the quaternary ammonium salt type surfactant or the cationic guar gum and the grease are combined to act together, so that a good dry and wet carding effect on the pet fur can be achieved, the repairing and nutrition effects on the pet fur can be achieved, and the pet shampoo with functions of expelling parasites, removing smell and inhibiting bacteria can be achieved.
3. The pet shampoo disclosed by the invention can prevent pets from being challenged by pathogens such as mosquitoes and the like during outdoor activities, has ideal deodorizing and antibacterial effects, and can protect the household environment and sanitation.
Detailed Description
The invention is further illustrated by the following specific examples.
The pet shampoos of examples 1 to 10 and comparative examples 1 to 24 were prepared according to the formulations of tables 1 to 6, and the specific preparation method was:
(1) Adding enough water, starting stirring, and then adding citric acid and sodium citrate to control the pH value of the product to 7.0-7.5 on the basis of the pet shampoo formulations of the examples and the comparative examples;
(2) Adding cationic surfactant, stirring and heating to 50-60deg.C, maintaining the temperature, and stirring until the cationic surfactant is completely dissolved;
(3) Preserving heat, sequentially adding a nonionic surfactant, an amphoteric surfactant and an anionic surfactant, and stirring until the nonionic surfactant, the amphoteric surfactant and the anionic surfactant are completely dissolved;
(4) Preserving heat, sequentially adding grease, insect repellent, deodorant, pearling agent and thickener, and stirring to dissolve completely;
(5) Cooling to below 45deg.C, and adding antiseptic and essence; and continuously cooling to normal temperature to obtain the pet shampoo.
For the purpose of illustrating the scheme of the present invention, the 6 kinds of deodorants specifically used in examples and comparative examples have the following structures:
table 1 examples 1 to 6
Table 2 examples 7 to 10
Table 3 comparative examples 1 to 6 are pet shampoos to which no deodorant was added
Table 4 comparative examples 7 to 12 are pet shampoos without insect repellent
Table 5 comparative examples 13-18 are pet shampoos without insect repellent and deodorant.
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Table 6 comparative examples 19 to 24 are pet shampoos to which no grease was added
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The following performance tests were performed on examples 1 to 6 and comparative examples 1 to 24:
1. antibacterial effect test, the results are shown in table 7:
the testing method comprises the following steps: the test is carried out according to the 7.3 suspension quantification method in the standard QB/T2738-2012 evaluation of the antibacterial and bacteriostatic effects of daily chemical products, and the sample test concentration is 10% of the solution with the mass fraction, and the action time is 10 minutes.
TABLE 7
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2. And (3) deodorizing effect test:
the testing method comprises the following steps: the deodorizing performance of the washed fabric is tested by taking ammonia gas as odor, the fabric material is selected from rabbit hair or wool, the washing method is according to 10.1.1 in standard GB/T20944.3-2008, the detergent adopts the formula of the pet shampoo listed in the example, and the concentration of the detergent is 20g/L. The fabric was cut into a round shape with a diameter of 4cm, 0.1mL of ammonia water was sucked up on a glass dish, the glass dish was placed at the bottom of the dryer, the fabric was placed on a tray of the dryer, ammonia was sucked up for 14 hours, and after the ammonia suction was completed, 100.0mL of distilled water was used for extraction at 40℃for 2 hours. The ammonia content in the extract was measured using HJ 534-2009 "determination of ambient air ammonia sodium hypochlorite-salicylic acid spectrophotometry", and the deodorizing ratio of the washed fabric was indirectly obtained by dividing the difference between the unwashed fabric and the adsorbed ammonia on the washed fabric by the difference between the total ammonia amount and the adsorbed ammonia on the unwashed fabric, and the results are shown in table 8.
Deodorization efficiency = (ammonia adsorbed on fabric after washing-ammonia adsorbed on unwashed fabric)/(total ammonia amount-ammonia adsorbed on unwashed fabric) ×100%
TABLE 8
3. Mosquito repelling rate test
Reference standard GB/T13917.9-2009 "pesticide registration hygienic pesticide indoor efficacy test and evaluation part 9: repellent(s);
test insects: aedes albopictus (Aedes albopictus), female adults that did not draw blood 4-7 days after eclosion;
test conditions: the temperature is 25+/-2 ℃ and the relative humidity is 60-70%;
the test method comprises the following steps: 4 qualified testers were selected, and a 50mm by 50mm skin area was circled on each of their backs, one hand was washed at a sample concentration of 10% by mass, and washed clean, air-dried naturally, exposing 40mm by 40mm skin, and closely covering the rest, the other hand being a blank. Immediately after air-drying, the repellency test was performed. Each tester firstly puts the control hand into the mosquito cage, immediately counts time, records the stopping number of mosquitoes and tests for 5 minutes. Then the tester puts the hand washed by the sample into a mosquito cage, tests the hand in the same way and records the stopping number of mosquitoes. The repellency was calculated from the repeated test data as follows, the results are shown in Table 9: p= (N-K)/nx100%
Wherein P is the repellent rate,%; n is the total stopping number of the control hand mosquitoes, and the unit is 'only'; k is the total number of hand and mosquito stopping after sample washing, and the unit is "only".
TABLE 9
| Test item | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Example 6 |
| Repellent rate% | 78.25 | 80.51 | 85.48 | 88.69 | 90.36 | 95.28 |
| Test item | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 | Comparative example 5 | Comparative example 6 |
| Repellent rate% | 68.84 | 70.27 | 75.96 | 78.33 | 80.68 | 82.97 |
| Test item | Comparative example 7 | Comparative example 8 | Comparative example 9 | Comparative example 10 | Comparative example 11 | Comparative example 12 |
| Repellent rate% | 1.51 | 1.67 | 0 | 1.51 | -1.60 | -1.67 |
| Test item | Comparative example 13 | Comparative example 14 | Comparative example 15 | Comparative example 16 | Comparative example 17 | Comparative example 18 |
| Repellent rate% | 0 | 1.51 | 1.67 | -1.51 | 1.60 | -1.60 |
| Test item | Comparative example 19 | Comparative example 20 | Comparative example 21 | Comparative example 22 | Comparative example 23 | Comparative example 24 |
| Repellent rate% | 44.26 | 65.35 | 79.65 | 81.04 | 82.66 | 83.37 |
4. For a pair ofResidual effect test of alkane-3, 8-diol on pet hair:
(1) Detection equipment: GC-MS (gas chromatograph-mass spectrometer)
(2) Measurement method
Chromatographic parameters:
chromatographic column: non-polar ultra-high inertness, capillary column;
heating program: the initial temperature is 50 ℃, and the temperature is raised to 280 ℃ at 20 ℃/min and kept for 3min;
carrier gas (He) flow rate 1.0mL/min; the temperature of the sample inlet is 250 ℃; the sample injection amount is 1 mu L; split ratio: 50:1.
Mass spectrometry parameters:
ionization mode: EI, electron bombardment energy 70eV; the temperature of the ion source is 230 ℃, and the temperature of the quaternary rod is 150 ℃; the temperature of the transmission line is 250 ℃; the Full Scan (Full Scan) mode was used with a mass number range of 35.00-350.00 amu and a solvent delay of 3min.
(3) Drawing of a Standard Curve
Preparing the pair with chromatographic pure ethanolThe concentrations of the series of standard solutions of the alkane-3, 8-diol were 2.90mg/mL, 1.45mg/mL, 0.724mg/mL and 0.362mg/mL, respectively. And (3) carrying out sample injection analysis according to the parameter setting of the measuring method (2).
(4) Residual quantity detection
20g of pet shampoo was taken and diluted with water to 200mL of pet shampoo solution. 10g of animal hair (such as dog hair/cat hair/wool) is taken out, soaked in a 10% mass fraction sample solution for 10 minutes, and then taken out, and washed clean with tap water. The cleaned dog hair is naturally dried, then is soaked in 100mL of ethanol with chromatographic purity, is subjected to suction filtration, is washed with the animal hair for 3 to 4 times by using 10mL of ethanol, is subjected to suction filtration, and is subjected to constant volume to 200mL by using the ethanol to obtain solution A. And 2. According to the parameter setting of the measurement method, filtering by a 0.22 mu m filter membrane, and analyzing by sample injection. Detecting pairs in solution AThe content of alkane-3, 8-diol. And calculate the pair +.>The adsorption rate of the alkane-3, 8-diol is shown in Table 10./>
For a pair ofAlkane-3, 8-diol adsorption rate/% = p +.>Concentration of alkane-3, 8-diol A/p->Concentration of alkane-3, 8-diol B X100%
For a pair ofThe concentration A of the alkane-3, 8-diol is p>Alkane-3, 8-diol concentration;
for a pair ofThe concentration B of the alkane-3, 8-diol is the concentration B of the p-o-n of the pet shampoo solution used for soaking dog hair>Alkane-3, 8-diol concentration.
Table 10
It should be noted that the above-mentioned embodiments are merely for further explanation of the present invention and are not intended to limit the present invention, and any modifications or variations within the meaning and scope of the technical solutions of the present invention, which are considered to be included in the scope of the present invention by those skilled in the art.
Claims (9)
1. A pet shampoo with functions of expelling parasites, removing smell and inhibiting bacteria is characterized in that: the insect repellent comprises an ampholytic surfactant, a nonionic surfactant, an insect repellent, a deodorant, grease and a preservative, wherein the total addition amount of the surfactant is 7-20% by mass, the addition amount of the insect repellent is 0.5-2%, the addition amount of the deodorant is 0.1-0.5%, and the addition amount of the grease is 0.2-2%;
the insect repellent is a pesticideAn alkane-3, 8-diol; the deodorant has the following structure:
wherein R is 1 Is C14, C16, C18 or C20 alkyl, R 2 Is methyl, ethyl or propyl, R 3 Is methylene, ethylene or propylene.
2. The insect repellent, odor eliminating and bacteriostatic pet shampoo of claim 1, wherein: also comprises anionic surfactant, cationic surfactant, emulsified silicone oil, pearling agent and thickener.
3. The insect repellent, odor eliminating and bacteriostatic pet shampoo of claim 2, wherein: the amphoteric surfactant is one or more of betaine type amphoteric surfactant, imidazoline type amphoteric surfactant, amino acid type amphoteric surfactant and amine oxide type amphoteric surfactant.
4. The insect repellent, odor eliminating and bacteriostatic pet shampoo of claim 2, wherein: the nonionic surfactant is one or more of alkanolamide surfactant and alkyl polyglycoside surfactant.
5. The insect repellent, odor eliminating and bacteriostatic pet shampoo of claim 2, wherein: the anionic surfactant is one or more of fatty alcohol polyoxyethylene ether sodium sulfate, fatty alcohol polyoxyethylene ether ammonium sulfate, fatty alcohol sodium sulfate, fatty alcohol ammonium sulfate, fatty alcohol polyoxyethylene ether sodium carboxylate and fatty alcohol polyoxyethylene ether ammonium carboxylate.
6. The insect repellent, odor eliminating and bacteriostatic pet shampoo of claim 2, wherein: the cationic surfactant is one or more of quaternary ammonium salt type surfactant and cationic guar gum; the quaternary ammonium salt surfactant comprises soybean oil based dimethyl ammonium hydroxypropyl hydrolyzed wheat protein, hydroxypropyl trimethyl ammonium chloride hydrolyzed silk, hydroxypropyl trimethyl ammonium chloride hydrolyzed soybean protein, hydroxypropyl trimethyl ammonium chloride hydrolyzed collagen, hydroxypropyl trimethyl ammonium chloride hydrolyzed keratin, hydroxypropyl trimethyl ammonium chloride hydrolyzed casein, soybean oil based trimethyl ammonium chloride, starch hydroxypropyl trimethyl ammonium chloride, dimer linolenyl propyl PG-dimethyl ammonium chloride phosphate, dihydroxypropyl PEG-5 linolenyl ammonium chloride, panthenol hydroxypropyl stearyl dimethyl ammonium chloride, olive oil amide propyl PG-dimethyl ammonium chloride phosphate sodium, hydroxypropyl trimethyl ammonium chloride honey, hydrogenated starch hydrolysate hydroxypropyl trimethyl ammonium chloride, and myristyl amide propyl PG-dimethyl ammonium chloride phosphate, cinnamyl amide propyl trimethyl ammonium chloride, lactamidopropyl trimethyl ammonium chloride, linoleyl amide propyl PG-dimethyl ammonium chloride phosphate, cocoyl amide propyl PG-dimethyl ammonium chloride phosphate sodium, cocoyl PG-dimethyl ammonium chloride phosphate sodium, oleamidopropyl PG-dimethyl ammonium chloride, lauryl methyl glucitol polyether-10 hydroxypropyl dimethyl ammonium chloride, ricinoleic acid amide propyl trimethyl ammonium chloride, polyquaternium-6, polyquaternium-7, polyquaternium-10, polyquaternium-22, polyquaternium-39, polyquaternium-47, polyquaternium-53; the cationic guar gum comprises guar hydroxypropyl trimethyl ammonium chloride and hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride.
7. The insect repellent, odor eliminating and bacteriostatic pet shampoo of claim 2, wherein: the grease is one or more of synthetic ester, PEG modified water-soluble grease and vegetable grease; the oil is at least one selected from water-soluble olive oil, PEG-7 cocoyl glyceride, glyceryl caprylate/caprate, C12-15 lactate, PPG-3 octyl ether, PPG-3 myristyl alcohol ether, glyceryl oleate, di PPG-2 myristyl oleyl polyether-10 adipate, polyglyceryl ether-10 caprylate/caprate, PEG/PPG-8/3 distearate, polyglyceryl-3 laurate, phytosterol/octyldodecanol lauroyl glutamate, polyester-11, PEG-75 lanolin, PEG-7 olive oleate, sucrose cocoate, polyglyceryl-10 oleate, polyglyceryl-3 caprate, peanut oil, olive oil, wheat germ oil, mango seed oil and avocado oil.
8. The insect repellent, odor eliminating and bacteriostatic pet shampoo of claim 2, wherein: the thickener is selected from one or more of sodium chloride, PEG-150 pentaerythritol tetrastearate/PPG-2 hydroxyethyl cocoamide, PEG-120 methyl glucose dioleate, PEG-120 distearate, PEG-150 distearate, PEG-90 glycerol isostearate/laureth-2, laurinol lactoyl lactate, PEG-55 propylene glycol oleate and PEG-200 hydrogenated glycerol palmitoleate; the emulsified silicone oil is polydimethylsiloxane and derivatives thereof, including but not limited to polydimethylsiloxane, ammonia-terminal polydimethylsiloxane, bis-aminopropyl polydimethylsiloxane, bis (C13-15 alkoxy) PG-ammonia-terminal polydimethylsiloxane; the pearlizing agent is glycol distearate.
9. The insect repellent, odor eliminating and bacteriostatic pet shampoo of claim 2, wherein: according to mass percentage, the content of the amphoteric surfactant is 6-15%, the content of the nonionic surfactant is 0.5-3%, the content of the anionic surfactant is 0-13%, the content of the cationic surfactant is 0-1%, the content of the emulsified silicone oil is 0-4%, the content of the pearling agent is 0-2%, and the content of the thickening agent is 0-3%.
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