CN113944055A - 一种再生涤纶机织面料的染整工艺 - Google Patents

一种再生涤纶机织面料的染整工艺 Download PDF

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CN113944055A
CN113944055A CN202111239420.1A CN202111239420A CN113944055A CN 113944055 A CN113944055 A CN 113944055A CN 202111239420 A CN202111239420 A CN 202111239420A CN 113944055 A CN113944055 A CN 113944055A
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洪必龙
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Huangbao Shishi Industrial Co ltd
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Abstract

本发明公开了一种再生涤纶机织面料的染整工艺，属于面料染整技术领域。所述染整工艺包括以下步骤：S1退浆：将再生涤纶用清水浸泡，向其中加入退浆剂进行退浆处理，浴比为1：20‑100；S2漂白：在退浆处理后的再生涤纶中加入漂白剂进行漂白处理；S3定型：将涤纶面料放入热定形机中进行热定形，热定形温度为100‑110℃，送布速度为25‑30m/min；S4染色：将经过初步定型的涤纶面料送入溢流染色机中，常温加入染色助剂，升温至50℃加入染色剂，0.7℃/min升温至85℃后，保温30min，降温将面料表面浮色清洗干净后，得到染色完成的面料；S5后处理。本发明染整工艺能有效提高再生涤纶的耐热性和染色性，同时能提高涤纶的柔软度和抗静电性，增强涤纶面料的使用品质。

Description

一种再生涤纶机织面料的染整工艺
技术领域
本发明属于面料染整技术领域，具体为一种再生涤纶机织面料的染整工艺。
背景技术
近年来，随着人们环境保护意识的不断加强，在满足个性化需求、审美观念，以及穿着服用性能、功能性、时尚性、舒适性的同时，高端针织面料领域对组织结构、原料组合等方面的要求越来越高，特别是环境友好型产品越来越受到市场的青睐。再生涤纶色丝对资源循环利用，同时回收再利用废弃物，绿色可持续发展；再生涤纶是指利用涤纶布料、废弃PET饮料瓶、纺丝废丝、泡泡料、浆块等废料制成，其中废弃PET饮料瓶的再生利用，不但可以减少环境污染，而且可以变废为宝，据统计，一吨再生涤纶纱线＝67000个塑料瓶＝减少二氧化碳4.2吨＝省石油0.0364吨＝省水6.2吨。
与普通涤纶相比，再生涤纶的吸湿性、透气性佳，可广泛应用于运动类服装的生产中。但是，再生涤纶的含油率较高、刚性大，且强力、耐热性不及普通涤纶，厂家生产的每批再生涤纶在性能、色泽上有一定差异，这就增加了其后续加工的难度。
发明内容
本发明的目的在于克服现有技术的缺点，提供一种再生涤纶机织面料的染整工艺，本发明染整工艺能有效提高再生涤纶的耐热性和染色性，同时能提高涤纶的柔软度和抗静电性，增强涤纶面料的使用品质。
本发明的目的通过以下技术方案来实现：
一种再生涤纶机织面料的染整工艺，包括以下步骤：
S1退浆：将再生涤纶用清水浸泡，向其中加入退浆剂进行退浆处理，浴比为1：20-100；
S2漂白：在退浆处理后的再生涤纶中加入漂白剂进行漂白处理；
S3定型：将涤纶面料放入热定形机中进行热定形，热定形温度为100-110℃，送布速度为25-30m/min；
S4染色：将经过初步定型的涤纶面料送入溢流染色机中，常温加入染色助剂，升温至50℃加入染色剂，0.7℃/min升温至85℃后，保温30min，降温将面料表面浮色清洗干净后，得到染色完成的面料；
S5后处理：在溢流染色机中加入抗静电剂并进行浸轧，脱水后再进行拉毛、梳毛、剪毛处理，得到再生涤纶机织面料。在再生涤纶针织物拉毛前应浸轧优选的抗静电剂，减少毛屑在布面上的沾附现象通过设计拉毛、梳毛、剪毛之间的生产工序，控制拉毛过程中织物进布张力、直针和弯针的转速，优化剪毛过程中刀距、刷距、转速等工艺参数，例如，在拉毛工序中普通涤纶针织物直针与弯针速度差值15r/min，而再生涤纶针织物直针与弯针速度差值19r/min，可保证再生涤纶面料在拉毛过程中张力较小，这样可有效解决再生涤纶针织绒类面料在拉毛过程中易脱毛的难题，达到良好的绒面效果。
优选的，所述步骤一中的助剂为乳化剂和分散剂。
优选的，所述乳化剂为脂肪醇与环氧乙烷缩合物，所述分散剂为硬脂酸单甘油酯。
优选的，所述步骤S2中的漂白剂为过氧化氢溶液。
优选的，所述步骤S4中的染色剂包括醋酸、芒硝、酸性匀染剂、阳离子染料。
优选的，所述步骤S4中的染色助剂为甲基丙烯磺酸钠与脂肪胺聚氧乙烯醚。
优选的，所述甲基丙烯磺酸钠与脂肪胺聚氧乙烯醚中的重量比为4：3。
优选的，所述抗静电剂为烷基磺酸、磷酸或二硫代氨基甲酸的碱金属盐。
本发明的有益效果为：由于再生涤纶含油率较高，在染色前要加强去油，选择高性能的前处理助剂，本发明采用的脂肪醇与环氧乙烷缩合物，以及硬脂酸单甘油酯，一方面，能将油污从纤维中剥离出来，乳化、分散到处理液中；另一方面，乳化分散体系要能够保持稳定，保证油污不在处理液中聚集、重新沾污到面料上，最终油污随残液一起排放；本发明中的助染剂为甲基丙烯磺酸钠，甲基丙烯磺酸钠能够很好的改善涤纶面料的染色性和耐热性，同时也能增加涤纶面料的手感，同时，由于此类耐热性不好，易变形，但回弹性高，温度升高会使其收缩，接近熔点时收缩严重，纤维变黄脆损，故在染色时采用多段式加温，在较低的起始温度下这类面料就有很快的上染速度；本发明中加入烷基磺酸、磷酸或二硫代氨基甲酸的碱金属盐，在有效提升涤纶面料抗静电性能的同时还能起到增强涤纶面料柔软度，以提高面料舒适度。
具体实施方式
下面结合具体实施例进一步详细描述本发明的技术方案，但本发明的保护范围不局限于以下所述。
实施例1
一种再生涤纶机织面料的染整工艺，包括以下步骤：
S1退浆：将再生涤纶用清水浸泡，向其中加入脂肪醇与环氧乙烷缩合物以及硬脂酸单甘油酯进行退浆处理，浴比为1：20；
S2漂白：在退浆处理后的再生涤纶中加入100％过氧化氢溶液进行漂白处理；
S3定型：将涤纶面料放入热定形机中进行热定形，热定形温度为100℃，送布速度为25m/min；
S4染色：将经过初步定型的涤纶面料送入溢流染色机中，常温加入甲基丙烯磺酸钠与脂肪胺聚氧乙烯醚，升温至50℃加入醋酸、芒硝、酸性匀染剂、阳离子红GTL，0.7℃/min升温至85℃后，保温30min，降温将面料表面浮色清洗干净后，得到染色完成的面料；
S5后处理：在溢流染色机中加入烷基磺酸、磷酸或二硫代氨基甲酸的碱金属盐并进行浸轧，脱水后再进行拉毛、梳毛、剪毛处理，得到再生涤纶机织面料。
实施例2
一种再生涤纶机织面料的染整工艺，包括以下步骤：
S1退浆：将再生涤纶用清水浸泡，向其中加入脂肪醇与环氧乙烷缩合物以及硬脂酸单甘油酯进行退浆处理，浴比为1：80；
S2漂白：在退浆处理后的再生涤纶中加入100％过氧化氢溶液进行漂白处理；
S3定型：将涤纶面料放入热定形机中进行热定形，热定形温度为105℃，送布速度为27m/min；
S4染色：将经过初步定型的涤纶面料送入溢流染色机中，常温加入甲基丙烯磺酸钠与脂肪胺聚氧乙烯醚，升温至50℃加入醋酸、芒硝、酸性匀染剂、阳离子红GTL，0.7℃/min升温至85℃后，保温30min，降温将面料表面浮色清洗干净后，得到染色完成的面料；
S5后处理：在溢流染色机中加入烷基磺酸、磷酸或二硫代氨基甲酸的碱金属盐并进行浸轧，脱水后再进行拉毛、梳毛、剪毛处理，得到再生涤纶机织面料。
实施例3
一种再生涤纶机织面料的染整工艺，包括以下步骤：
S1退浆：将再生涤纶用清水浸泡，向其中加入脂肪醇与环氧乙烷缩合物以及硬脂酸单甘油酯进行退浆处理，浴比为1：100；
S2漂白：在退浆处理后的再生涤纶中加入100％过氧化氢溶液进行漂白处理；
S3定型：将涤纶面料放入热定形机中进行热定形，热定形温度为100℃，送布速度为30m/min；
S4染色：将经过初步定型的涤纶面料送入溢流染色机中，常温加入甲基丙烯磺酸钠与脂肪胺聚氧乙烯醚，升温至50℃加入醋酸、芒硝、酸性匀染剂、阳离子红GTL，0.7℃/min升温至85℃后，保温30min，降温将面料表面浮色清洗干净后，得到染色完成的面料；
S5后处理：在溢流染色机中加入烷基磺酸、磷酸或二硫代氨基甲酸的碱金属盐并进行浸轧，脱水后再进行拉毛、梳毛、剪毛处理，得到再生涤纶机织面料。
对比例
本对比例与实施例2的工艺以及参数基本一致，不同之处在于本对比例没有加入作为染料助剂的甲基丙烯磺酸钠与脂肪胺聚氧乙烯醚。
通过对实施例1-实施例3以及对比例所染整处理后的涤纶面料进行用DatacolorSF-600测配色仪，在D65光源及10°视角下，用CIELab系统对染色织物进行测定，分别获得涤纶织物的表观色深值K/S值与色差△E，所得结果如下表1所示：
表1检测结果
项目 实施例1 实施例2 实施例3 对比例
K/S值 19.72 19.87 19.62 18.63
△E 0.83 0.72 0.81 0.93
从上表1可以看出实施例2的各方面检测数据均较为优异，为最优实施方案，同时甲基丙烯磺酸钠与脂肪胺聚氧乙烯醚对涤纶染色性有直接影响。
以上所述仅是本发明的优选实施方式，应当理解本发明并非局限于本文所披露的形式，不应看作是对其他实施例的排除，而可用于各种其他组合、修改和环境，并能够在本文所述构想范围内，通过上述教导或相关领域的技术或知识进行改动。而本领域人员所进行的改动和变化不脱离本发明的精神和范围，则都应在本发明所附权利要求的保护范围内。

Claims (8)

1.一种再生涤纶机织面料的染整工艺，其特征在于，包括以下步骤：
S1退浆：将再生涤纶用清水浸泡，向其中加入退浆剂进行退浆处理，浴比为1：20-100；
S2漂白：在退浆处理后的再生涤纶中加入漂白剂进行漂白处理；
S3定型：将涤纶面料放入热定形机中进行热定形，热定形温度为100-110℃，送布速度为25-30m/min；
S4染色：将经过初步定型的涤纶面料送入溢流染色机中，常温加入染色助剂，升温至50℃加入染色剂，0.7℃/min升温至85℃后，保温30min，降温将面料表面浮色清洗干净后，得到染色完成的面料；
S5后处理：在溢流染色机中加入抗静电剂并进行浸轧，脱水后再进行拉毛、梳毛、剪毛处理，得到再生涤纶机织面料。
2.根据权利要求1所述的一种再生涤纶机织面料的染整工艺，其特征在于，所述步骤一中的助剂为乳化剂和分散剂。
3.根据权利要求2所述的一种再生涤纶机织面料的染整工艺，其特征在于，所述乳化剂为脂肪醇与环氧乙烷缩合物，所述分散剂为硬脂酸单甘油酯。
4.根据权利要求1所述的一种再生涤纶机织面料的染整工艺，其特征在于，所述步骤S2中的漂白剂为过氧化氢溶液。
5.根据权利要求1所述的一种再生涤纶机织面料的染整工艺，其特征在于，所述步骤S4中的染色剂包括醋酸、芒硝、酸性匀染剂、阳离子染料。
6.根据权利要求1所述的一种再生涤纶机织面料的染整工艺，其特征在于，所述步骤S4中的染色助剂为甲基丙烯磺酸钠与脂肪胺聚氧乙烯醚。
7.根据权利要求6所述的一种再生涤纶机织面料的染整工艺，其特征在于，所述甲基丙烯磺酸钠与脂肪胺聚氧乙烯醚中的重量比为4：3。
8.根据权利要求1中所述的一种再生涤纶机织面料的染整工艺，其特征在于，所述抗静电剂为烷基磺酸、磷酸或二硫代氨基甲酸的碱金属。
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