CN113818252B - 一种薄荷冰感硅油复合物及其制备方法 - Google Patents
一种薄荷冰感硅油复合物及其制备方法 Download PDFInfo
- Publication number
- CN113818252B CN113818252B CN202111230083.XA CN202111230083A CN113818252B CN 113818252 B CN113818252 B CN 113818252B CN 202111230083 A CN202111230083 A CN 202111230083A CN 113818252 B CN113818252 B CN 113818252B
- Authority
- CN
- China
- Prior art keywords
- silicone oil
- parts
- polyoxyethylene ether
- menthol
- ethylene oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920002545 silicone oil Polymers 0.000 title claims abstract description 65
- 150000001875 compounds Chemical class 0.000 title claims abstract description 36
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 title claims abstract description 33
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 229940041616 menthol Drugs 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 34
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 34
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 26
- 229920000570 polyether Polymers 0.000 claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 16
- 150000002193 fatty amides Chemical class 0.000 claims abstract description 16
- 239000012875 nonionic emulsifier Substances 0.000 claims abstract description 16
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 16
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 15
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 125000002091 cationic group Chemical group 0.000 claims abstract description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000002191 fatty alcohols Chemical group 0.000 claims abstract description 3
- 239000008368 mint flavor Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 9
- 230000001804 emulsifying effect Effects 0.000 claims description 7
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 6
- 229960002233 benzalkonium bromide Drugs 0.000 claims description 6
- KHSLHYAUZSPBIU-UHFFFAOYSA-M benzododecinium bromide Chemical group [Br-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 KHSLHYAUZSPBIU-UHFFFAOYSA-M 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000011265 semifinished product Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims description 4
- 229960000686 benzalkonium chloride Drugs 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 claims description 4
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims description 3
- CXRFDZFCGOPDTD-UHFFFAOYSA-M Cetrimide Chemical compound [Br-].CCCCCCCCCCCCCC[N+](C)(C)C CXRFDZFCGOPDTD-UHFFFAOYSA-M 0.000 claims description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 2
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims description 2
- 239000003279 phenylacetic acid Substances 0.000 claims description 2
- 229960003424 phenylacetic acid Drugs 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 claims description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims 6
- REIUXOLGHVXAEO-UHFFFAOYSA-N pentadecan-1-ol Chemical compound CCCCCCCCCCCCCCCO REIUXOLGHVXAEO-UHFFFAOYSA-N 0.000 claims 2
- RCNMYLIPBZPWMD-UHFFFAOYSA-M [Br-].C(CCCCCCCCCCCCC)C=1C(=[N+](C=CC=1)C)C Chemical compound [Br-].C(CCCCCCCCCCCCC)C=1C(=[N+](C=CC=1)C)C RCNMYLIPBZPWMD-UHFFFAOYSA-M 0.000 claims 1
- XIWFQDBQMCDYJT-UHFFFAOYSA-M benzyl-dimethyl-tridecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 XIWFQDBQMCDYJT-UHFFFAOYSA-M 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 12
- 235000013599 spices Nutrition 0.000 abstract description 6
- 235000006679 Mentha X verticillata Nutrition 0.000 abstract description 4
- 235000002899 Mentha suaveolens Nutrition 0.000 abstract description 4
- 235000001636 Mentha x rotundifolia Nutrition 0.000 abstract description 4
- 230000000052 comparative effect Effects 0.000 description 19
- 238000012360 testing method Methods 0.000 description 8
- 239000003205 fragrance Substances 0.000 description 7
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 235000016257 Mentha pulegium Nutrition 0.000 description 2
- 244000246386 Mentha pulegium Species 0.000 description 2
- 235000004357 Mentha x piperita Nutrition 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 235000001050 hortel pimenta Nutrition 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- XKTMPGNYHJBJNK-UHFFFAOYSA-N [Br-].[NH4+].C(CCCCCCCCCCCCC)C1=C(C(=NC=C1)C)C Chemical compound [Br-].[NH4+].C(CCCCCCCCCCCCC)C1=C(C(=NC=C1)C)C XKTMPGNYHJBJNK-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- ZCPCLAPUXMZUCD-UHFFFAOYSA-M dihexadecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCC ZCPCLAPUXMZUCD-UHFFFAOYSA-M 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- -1 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- CEYYIKYYFSTQRU-UHFFFAOYSA-M trimethyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)C CEYYIKYYFSTQRU-UHFFFAOYSA-M 0.000 description 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Cosmetics (AREA)
- Fats And Perfumes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明公开了一种薄荷冰感硅油复合物，制备原料包括聚醚改性硅油、异构醇聚氧乙烯醚、薄荷香料、非离子乳化剂、长链季铵盐阳离子表面活性剂、阳离子乳化剂、脂肪酰胺、固化剂和水，所述长链季铵盐阳离子表面活性剂的碳链个数为14‑18，所述非离子乳化剂选自含12‑15个碳链及2‑5个环氧乙烷的脂肪醇聚氧乙烯醚。通过本申请的薄荷冰感硅油复合物对织物进行后整理，不仅手感优良，且给人冰凉感及清香感，且清香感持久，让人清爽，既满足触觉又满足味觉，大大地提高了用户的体验度。本发明还提供一种薄荷冰感硅油复合物的制备方法。
Description
技术领域
本发明涉及纺织品后整理技术领域，更具体的涉及一种薄荷冰感硅油复合物及其制备方法。
背景技术
随着社会的发展，人民生活水平逐渐提高，人们对纺织品尤其是针织物的手感要求越来越高。现在，人们对针织面料除了软度和滑度的要求外，还要求其具有冰凉感。黄武欢等在棉用亲水冰感整理剂TF-4689的论文中公开了一种以端氨基聚醚、端环氧基聚醚硅油和硫酸二甲酯为原料，异丙醇为溶剂，在80～85℃下两步法反应10～12h，制得季铵盐改性三元嵌段硅油TF-4689的方法。该方法制得的亲水冰感整理剂TF-4689具有很好的离心稳定性，耐热、耐碱和耐盐稳定性，能赋予棉织物冰感手感。
然而织物具有冰感仅是一种触觉感受，倘若加入味觉效果，则能更进一步提高人们的体验度，触觉与味觉共同作用下，会让人无比舒畅。其中加入香料是提高味觉效果的一种方式，如薄荷香料，但薄荷香料属于油性物，其与硅油体系不容易混合乳化，如果是在原有的冰感硅油中直接加入香料，那么即使后续再补加乳化剂也是非常难将其乳化均匀和稳定的，乳液透明度也很差，即使勉强加入最终香料会在体系中慢慢分离出来，味觉无法持久，这是当下急需解决的技术难题。
发明内容
本发明的目的在于提供一种薄荷冰感硅油复合物，借助该薄荷冰感硅油复合物对织物进行后整理，使得织物柔软且手感优良，尤其是既能给人冰凉感还能给人清香感，且清香感持久，让人清爽，大大地提高了用户的体验度。
本发明的另一目的在于提供一种薄荷冰感硅油复合物的制备方法。
为实现上述目的，本发明提供了一种薄荷冰感硅油复合物，制备原料包括聚醚改性硅油、异构醇聚氧乙烯醚、薄荷香料、非离子乳化剂、长链季铵盐阳离子表面活性剂、阳离子乳化剂、脂肪酰胺、固化剂和水，长链季铵盐阳离子表面活性剂的碳链个数为14-18，非离子乳化剂选自含12-15个碳链及2-5个环氧乙烷的脂肪醇聚氧乙烯醚。
在本申请薄荷冰感硅油复合物技术方案中，采用聚醚改性硅油，亲水性增加，能使织物柔软且吸湿性良好；借助异构醇聚氧乙烯醚对聚醚改性硅油进行乳化；薄荷香料不仅提供冰感且能提供清香感；非离子乳化剂中采用2-5个环氧乙烷，使其更有利于与薄荷香料相容；采用长链季铵盐阳离子表面活性剂以实现慢溶、增稠的目的，更有利于对薄荷香料相容；阳离子乳化剂一端亲水，其另一端能促进薄荷香料的乳化；脂肪酰胺的引入进一步促进薄荷香料在体系中相容。总之，通过非离子乳化剂、长链季铵盐阳离子表面活性剂、阳离子乳化剂、脂肪酰胺复配很好的将薄荷香料溶于乳化后的聚醚改性硅油中，以实现该薄荷冰感硅油复合物既能给人冰凉感还能给人清香感，同时还引入固化剂，可对各分子进行包覆，使其香味不易挥发，实现清香持久。
较佳地，所述聚醚改性硅油的分子量为8000-10000。
较佳地，所述异构醇聚氧乙烯醚选自异构十醇聚氧乙烯醚、异构十一醇聚氧乙烯醚、异构十三醇聚氧乙烯醚中的至少一种。
较佳地，非离子乳化剂选自十二醇聚氧乙烯醚且含2个环氧乙烷(简称C12E2)，十二醇聚氧乙烯醚且含3个环氧乙烷(简称C12E3)，十二醇聚氧乙烯醚且含4个环氧乙烷(简称C12E4)，十二醇聚氧乙烯醚且含5个环氧乙烷(简称C12E5)，十三醇聚氧乙烯醚且含3个环氧乙烷(简称C13E3)，十五醇聚氧乙烯醚且含3个环氧乙烷(简称C15E3)中的至少一种。
较佳地，所述长链季铵盐阳离子表面活性剂选自十八烷基三甲基溴化铵、十六烷基三甲基溴化铵、十四烷基三甲基溴化铵、双十八烷基二甲基氯化铵、双十六烷基二甲基氯化铵、十八烷基三甲基氯化铵、十六烷基三甲基氯化铵、十四烷基三甲基氯化铵、十四烷基二甲基吡啶溴化铵中的至少一种。
较佳地，所述阳离子乳化剂选自苯扎溴铵或苯扎氯铵。
较佳地，所述固化剂选自聚氨酯类固化剂、苯乙酸类固化剂，比如但不限于固化剂JX-516(江兴实业)、固化剂JX-615H(江兴实业)。
较佳地，制备原料包括10-40份聚醚改性硅油、5-15份异构醇聚氧乙烯醚、1-10份薄荷香料、1-20份非离子乳化剂、1-20份长链季铵盐阳离子表面活性剂、1-20份阳离子乳化剂、1-10份脂肪酰胺、0.5-5份固化剂和10-50份水。其中，聚醚改性硅油的含量可为但不限于10份、15份、20份、25份、30份、35份、40份；异构醇聚氧乙烯醚的含量可为但不限于5份、10份、15份；薄荷香料的含量可为但不限于1份、2份、3份、4份、5份、6份、7份、8份、9份、10份；非离子乳化剂的含量可为但不限于1份、3份、5份、10份、15份、20份；长链季铵盐阳离子表面活性剂的含量可为但不限于1份、3份、5份、10份、15份、20份；阳离子乳化剂的含量可为但不限于1份、3份、5份、10份、15份、20份；脂肪酰胺的含量可为但不限于1份、2份、3份、4份、5份、6份、7份、8份、9份、10份；固化剂的含量可为但不限于0.5份、1份、2份、3份、4份、5份；水的含量可为但不限于10份、15份、20份、25份、30份、35份、40份、45份、50份。
相应地，本发明还提供一种薄荷冰感硅油复合物的制备方法，包括步骤：
采用异构醇聚氧乙烯醚乳化聚醚改性硅油，得到混合物A；
采用水将长链季铵盐阳离子表面活性剂和脂肪酰胺进行溶解，得到分散体；
采用分散体、阳离子乳化剂和非离子乳化剂对薄荷香料进行乳化，得到混合物B；
将混合物A和混合物B搅拌均匀得到半成品；
将固化剂与半成品搅拌均匀制得薄荷冰感硅油复合物。
较佳地，聚醚胺和端环氧基聚醚在溶剂的条件下聚合生成聚醚改性硅油，
其中，聚醚胺选自ED900、ED1200、EA1200。
具体实施方式
以下实施例旨在说明本发明内容，而不是限制本发明的权利要求的保护范围。
实施例1
一种薄荷冰感硅油复合物，制备原料包括20份分子量为8000的聚醚改性硅油、5份异构十醇聚氧乙烯醚、2份薄荷香料、10份C12E5、5份十六烷基三甲基溴化铵、5份苯扎溴铵、2份脂肪酰胺、1份固化剂JX-516和50份水。
该薄荷冰感硅油复合物的制备方法如下：
(1)制备聚醚改性硅油：以聚醚胺ED900和端环氧基聚醚为材料，在异丙醇为溶剂的条件下聚合生成聚醚改性硅油，控制其分子量为8000；
(2)采用异构十醇聚氧乙烯醚乳化聚醚改性硅油，得到混合物A；
(3)采用水将十六烷基三甲基溴化铵和脂肪酰胺进行溶解，得到分散体；
(4)采用分散体、苯扎溴铵和C12E5对薄荷香料进行乳化，得到混合物B；
(5)将混合物A和混合物B搅拌均匀得到半成品；
(6)将固化剂JX-516与半成品搅拌均匀制得薄荷冰感硅油复合物。
实施例2
一种薄荷冰感硅油复合物，制备原料包括30份分子量为10000的聚醚改性硅油、10份异构十三醇聚氧乙烯醚、5份薄荷香料、5份C12E3、10份十八烷基三甲基氯化铵、10份苯扎氯铵、6份脂肪酰胺、2份固化剂JX-615H和40份水。
该薄荷冰感硅油复合物的制备方法与实施例1相同，不同在于该实施例中聚醚胺选自ED1200，在此不详细阐述。
实施例3
一种薄荷冰感硅油复合物，制备原料包括10份分子量为9000的聚醚改性硅油、10份异构十醇聚氧乙烯醚、10份薄荷香料、15份C12E3、5份十八烷基三甲基氯化铵、5份苯扎氯铵、10份脂肪酰胺、5份固化剂JX-516和50份水。
该薄荷冰感硅油复合物的制备方法与实施例1相同，不同在于该实施例中聚醚胺选自EA1200，在此不详细阐述。
对比例1
对比例1中薄荷冰感硅油复合物的制备原料与实施例1基本相同，不同在于对比例1中不含固化剂，而实施例1含有固化剂。
其薄荷冰感硅油复合物的制备方法与实施例1相同，在此不详细阐述。
对比例2
对比例2中薄荷冰感硅油复合物的制备原料与实施例1基本相同，不同在于对比例2中不含C12E5，而实施例1含有C12E5。
其薄荷冰感硅油复合物的制备方法与实施例1相同，在此不详细阐述。
对比例3
对比例3中薄荷冰感硅油复合物的制备原料与实施例1基本相同，不同在于对比例3中不含十六烷基三甲基溴化铵，而实施例1含有十六烷基三甲基溴化铵。
其薄荷冰感硅油复合物的制备方法与实施例1相同，在此不详细阐述。
对比例4
对比例4中薄荷冰感硅油复合物的制备原料与实施例1基本相同，不同在于对比例4中不含苯扎溴铵，而实施例1含有苯扎溴铵。
其薄荷冰感硅油复合物的制备方法与实施例1相同，在此不详细阐述。
对比例5
对比例5中薄荷冰感硅油复合物的制备原料与实施例1基本相同，不同在于对比例5中不含脂肪酰胺，而实施例1含有脂肪酰胺。
其薄荷冰感硅油复合物的制备方法与实施例1相同，在此不详细阐述。
对实施例1～3和对比例1-5制得的薄荷冰感硅油复合物进行性能测试和应用测试，结果见表1。
性能测试项目和方法有：
稳定性：在室温条件下，静置10天、30天、90天，观察其是否分层；
水溶性：将其溶于水中，观察其分散均匀的时间。
应用测试项目和方法有：
将薄荷冰感硅油复合物配成水溶液对锦纶纤维织物进行后整理，并进行手感测试和香味持久性测试：
手感测性：采用实物手感评定法，以5个具有行业素养的人员组成一个专业小组评估织物手感。通过多人手感测评，100分制，取平均值，分值越大越柔软，手感越好。
香味持久性测试：鼻子闻香，记录香味残留时间。
表1试验测试结果
从实施例1～3和对比例1～5的测试结果可知，通过本申请的薄荷冰感硅油复合物对织物进行后整理，该织物产品不仅手感优良，且给人冰凉感及清香感，且清香感持久，让人清爽，既满足触觉又满足味觉，大大地提高了用户的体验度。
从实施例1与对比例1的比较可知，当技术方案中无固化剂时，香味残留时间大大降低。
从实施例1与对比例2-5的比较可知，通过非离子乳化剂、长链季铵盐阳离子表面活性剂、阳离子乳化剂、脂肪酰胺复配可以实现产品的最优性能，当缺少其中一种时，稳定性和水溶性均有所下降。
以上所述仅是本发明的较佳实施例而已，并非对本发明做任何形式上的限制，虽然本发明已以较佳实施例揭露如上，然而并非用以限定本发明，任何所属技术领域中具有通常知识者，在不脱离本发明技术方案的范围内，当可利用上述揭示的技术内容作出些许更动或修饰为等同变化的等效实施例，但凡是未脱离本发明技术方案的内容，依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与修饰，均仍属于本发明技术方案的范围内。
Claims (6)
1.一种薄荷冰感硅油复合物，其特征在于，制备原料包括10-40份聚醚改性硅油、5-15份异构醇聚氧乙烯醚、1-10份薄荷香料、1-20份非离子乳化剂、1-20份长链季铵盐阳离子表面活性剂、1-20份阳离子乳化剂、1-10份脂肪酰胺、0.5-5份固化剂和10-50份水；
所述长链季铵盐阳离子表面活性剂的碳链个数为14-18；
所述非离子乳化剂选自含12-15个碳链及2-5个环氧乙烷的脂肪醇聚氧乙烯醚；
所述阳离子乳化剂选自苯扎溴铵或苯扎氯铵；
所述固化剂选自聚氨酯类固化剂或苯乙酸类固化剂。
2.如权利要求1所述的薄荷冰感硅油复合物，其特征在于，所述聚醚改性硅油的分子量为8000-10000。
3.如权利要求1所述的薄荷冰感硅油复合物，其特征在于，所述异构醇聚氧乙烯醚选自异构十醇聚氧乙烯醚、异构十一醇聚氧乙烯醚、异构十三醇聚氧乙烯醚中的至少一种。
4.如权利要求1所述的薄荷冰感硅油复合物，其特征在于，所述非离子乳化剂选自十二醇聚氧乙烯醚且含2个环氧乙烷、十二醇聚氧乙烯醚且含3个环氧乙烷、十二醇聚氧乙烯醚且含4个环氧乙烷、十二醇聚氧乙烯醚且含5个环氧乙烷、十三醇聚氧乙烯醚且含3个环氧乙烷、十五醇聚氧乙烯醚且含3个环氧乙烷中的至少一种。
5.如权利要求1所述的薄荷冰感硅油复合物，其特征在于，所述长链季铵盐阳离子表面活性剂选自十八烷基三甲基溴化铵、十六烷基三甲基溴化铵、十四烷基三甲基溴化铵、双十八烷基二甲基氯化铵、双十六烷基二甲基氯化铵、十八烷基三甲基氯化铵、十六烷基三甲基氯化铵、十四烷基三甲基氯化铵、十四烷基二甲基吡啶溴化铵中的至少一种。
6.一种如权利要求1-5任一项所述的薄荷冰感硅油复合物的制备方法，其特征在于，包括步骤：
采用异构醇聚氧乙烯醚乳化聚醚改性硅油，得到混合物A；
采用水将长链季铵盐阳离子表面活性剂和脂肪酰胺进行溶解，得到分散体；
采用分散体、阳离子乳化剂和非离子乳化剂对薄荷香料进行乳化，得到混合物B；
将混合物A和混合物B搅拌均匀得到半成品；
将固化剂与半成品搅拌均匀制得薄荷冰感硅油复合物。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111230083.XA CN113818252B (zh) | 2021-10-20 | 2021-10-20 | 一种薄荷冰感硅油复合物及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111230083.XA CN113818252B (zh) | 2021-10-20 | 2021-10-20 | 一种薄荷冰感硅油复合物及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113818252A CN113818252A (zh) | 2021-12-21 |
| CN113818252B true CN113818252B (zh) | 2024-03-29 |
Family
ID=78917114
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111230083.XA Active CN113818252B (zh) | 2021-10-20 | 2021-10-20 | 一种薄荷冰感硅油复合物及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113818252B (zh) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1056808A (en) * | 1964-12-01 | 1967-02-01 | Boehme Fettchemie Gmbh | Aqueous emulsions of silicones |
| JP2000169705A (ja) * | 1998-12-11 | 2000-06-20 | Dow Corning Toray Silicone Co Ltd | シリコーンオイルエマルジョン、およびその製造方法 |
| KR20050073079A (ko) * | 2004-01-08 | 2005-07-13 | 주식회사 엘지생활건강 | 섬유유연제 조성물 |
| JP2012072539A (ja) * | 2010-09-02 | 2012-04-12 | Lion Corp | 繊維製品用処理剤組成物 |
| CN112593410A (zh) * | 2020-12-10 | 2021-04-02 | 辽宁恒星精细化工有限公司 | 一种水性仿涂层高弹挺括整理剂及制备方法 |
-
2021
- 2021-10-20 CN CN202111230083.XA patent/CN113818252B/zh active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1056808A (en) * | 1964-12-01 | 1967-02-01 | Boehme Fettchemie Gmbh | Aqueous emulsions of silicones |
| JP2000169705A (ja) * | 1998-12-11 | 2000-06-20 | Dow Corning Toray Silicone Co Ltd | シリコーンオイルエマルジョン、およびその製造方法 |
| KR20050073079A (ko) * | 2004-01-08 | 2005-07-13 | 주식회사 엘지생활건강 | 섬유유연제 조성물 |
| JP2012072539A (ja) * | 2010-09-02 | 2012-04-12 | Lion Corp | 繊維製品用処理剤組成物 |
| CN112593410A (zh) * | 2020-12-10 | 2021-04-02 | 辽宁恒星精细化工有限公司 | 一种水性仿涂层高弹挺括整理剂及制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113818252A (zh) | 2021-12-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69926456T2 (de) | Aminofunktionelle Siliconemulsion | |
| CN105648127A (zh) | 一种环保型抗菌裘皮后整理剂及其制备方法 | |
| DE3723697A1 (de) | Waessrige, feinteilige bis optisch klare, thermisch und mechanisch stabile silikonemulsionen, verfahren zu deren herstellung und deren verwendung | |
| CN113818252B (zh) | 一种薄荷冰感硅油复合物及其制备方法 | |
| CN103668999A (zh) | 一种香味家纺面料的制作方法 | |
| EP1892327B1 (de) | Verwendung von polyethermodifizierten Siloxanblockcopolymeren als hydrophile silikonhaltige Weichmacher für Gewebe, Non-wovens und/oder Fasern aus natürlichen und/oder synthetischen Rohstoffen | |
| CN106714774A (zh) | 包含聚二甲基硅氧烷聚合物乳液的毛发护理组合物 | |
| DE4332607A1 (de) | Wäßrige Wachs- und Silicon-Dispersionen, deren Herstellung und Verwendung | |
| EP1576056B1 (de) | Hochkonzentrierte, selbstemulgierende zubereitungen, enthaltend organopolysiloxane und alkylammoniumverbindungen und deren verwendung in wässrigen systemen | |
| EP0110290B1 (de) | Wässrige Silicondispersionen, Verfahren zu deren Herstellung und Verwendung als Textilbehandlungsmittel | |
| KR101961487B1 (ko) | 고기능성 실리콘 에멀젼 조성물 및 제조 방법 | |
| CN106480739A (zh) | 一种防蚊虫纺织品织物及其制备方法 | |
| CN111821220A (zh) | 头发护理组合物、修护发膜及其制备方法 | |
| DE60111383T2 (de) | Mischungen von polysiloxanemulsionen | |
| CN113802376B (zh) | 一种化纤织物用棉感剂及其制备方法 | |
| CN105064046A (zh) | 棉织物用香精微胶囊复合有机硅柔顺剂的制备方法与应用 | |
| DE3926005A1 (de) | Zusammensetzung in form einer waessrigen dispersion und verfahren zur behandlung von fasermaterialien | |
| DE2922376A1 (de) | Verwendung von alkoxylierungsprodukten als textilbehandlungsmittel | |
| CN115369649A (zh) | 热湿舒适性聚酯纤维低油烟高速纺专用油剂及其制备工艺 | |
| JP5596743B2 (ja) | 中綿用セルロース繊維及びその製造方法 | |
| JP3721311B2 (ja) | 機能化繊維材料とその製造方法 | |
| JP2012097377A (ja) | 繊維処理剤及びその製造方法 | |
| JP2693803B2 (ja) | 濃縮型衣料用柔軟仕上剤 | |
| CN117306263B (zh) | 一种远红外负离子抗菌多功能健康被及其制备方法 | |
| DE4024403A1 (de) | Waessrige dispersion auf basis von silikonen, deren herstellung und verwendung |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |