CN113800879B - 一种透光石陶瓷板及其制备方法 - Google Patents
一种透光石陶瓷板及其制备方法 Download PDFInfo
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- 239000004575 stone Substances 0.000 title claims abstract description 144
- 239000000919 ceramic Substances 0.000 title claims abstract description 62
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000005498 polishing Methods 0.000 claims abstract description 46
- 238000010304 firing Methods 0.000 claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 13
- 238000007639 printing Methods 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 38
- 239000005995 Aluminium silicate Substances 0.000 claims description 34
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims description 34
- 235000012211 aluminium silicate Nutrition 0.000 claims description 34
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 32
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 29
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 26
- 239000011734 sodium Substances 0.000 claims description 22
- 229910052742 iron Inorganic materials 0.000 claims description 21
- 238000002834 transmittance Methods 0.000 claims description 21
- 229910052700 potassium Inorganic materials 0.000 claims description 19
- 229910052708 sodium Inorganic materials 0.000 claims description 18
- 239000000126 substance Substances 0.000 claims description 16
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 15
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 15
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 14
- 239000011787 zinc oxide Substances 0.000 claims description 13
- AYJRCSIUFZENHW-UHFFFAOYSA-L Barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 12
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 12
- 239000000454 talc Substances 0.000 claims description 12
- 229910052623 talc Inorganic materials 0.000 claims description 12
- 238000005406 washing Methods 0.000 claims description 12
- 229910052656 albite Inorganic materials 0.000 claims description 11
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- HWKQNAWCHQMZHK-UHFFFAOYSA-N Trolnitrate Chemical compound [O-][N+](=O)OCCN(CCO[N+]([O-])=O)CCO[N+]([O-])=O HWKQNAWCHQMZHK-UHFFFAOYSA-N 0.000 claims description 9
- 239000000440 bentonite Substances 0.000 claims description 9
- 229910000278 bentonite Inorganic materials 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 9
- 239000010456 wollastonite Substances 0.000 claims description 9
- 229910052882 wollastonite Inorganic materials 0.000 claims description 9
- 238000005507 spraying Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 229910052661 anorthite Inorganic materials 0.000 claims description 7
- 239000004576 sand Substances 0.000 claims description 7
- 229910052593 corundum Inorganic materials 0.000 claims description 6
- 239000010431 corundum Substances 0.000 claims description 6
- 239000010459 dolomite Substances 0.000 claims description 6
- 229910000514 dolomite Inorganic materials 0.000 claims description 6
- 239000005350 fused silica glass Substances 0.000 claims description 6
- 230000005484 gravity Effects 0.000 claims description 6
- 229910052863 mullite Inorganic materials 0.000 claims description 6
- -1 potassium sodium Chemical compound 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000010453 quartz Substances 0.000 claims description 4
- 229910052904 quartz Inorganic materials 0.000 claims description 4
- 238000005034 decoration Methods 0.000 abstract description 3
- 238000010923 batch production Methods 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 26
- 238000001035 drying Methods 0.000 description 14
- 229910052500 inorganic mineral Inorganic materials 0.000 description 13
- 239000011707 mineral Substances 0.000 description 13
- 235000010755 mineral Nutrition 0.000 description 13
- 239000011521 glass Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 9
- 238000005245 sintering Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 230000005540 biological transmission Effects 0.000 description 6
- 239000012535 impurity Substances 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 238000007688 edging Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000010433 feldspar Substances 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 4
- 238000004018 waxing Methods 0.000 description 4
- 229910004261 CaF 2 Inorganic materials 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052788 barium Inorganic materials 0.000 description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium(0) Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 3
- 229940072033 potash Drugs 0.000 description 3
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 3
- 235000015320 potassium carbonate Nutrition 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- 241001448624 Miliaria Species 0.000 description 2
- NOTVAPJNGZMVSD-UHFFFAOYSA-N Potassium oxide Chemical compound [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000005712 crystallization Effects 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 229910052622 kaolinite Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000006060 molten glass Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910001950 potassium oxide Inorganic materials 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 230000001737 promoting Effects 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 2
- 229920000160 (ribonucleotides)n+m Polymers 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N Iron(III) oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910014142 Na—O Inorganic materials 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000010427 ball clay Substances 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 238000011030 bottleneck Methods 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000002349 favourable Effects 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 229910000460 iron oxide Inorganic materials 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 230000004301 light adaptation Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
-
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- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
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- C04B2235/3427—Silicates other than clay, e.g. water glass
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- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
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Abstract
本发明公开一种透光石陶瓷板及其制备方法。所述制备方法包括以下步骤:使用透光石坯体粉料制备透光石坯体;在透光石坯体上喷墨打印图案;在喷墨打印图案后的透光石坯体上施透光石抛釉;将施透光石抛釉后的坯体烧成获得透光石陶瓷板。所述制备方法通过在透光石坯体上喷墨打印设计图案然后施透光石抛釉,实现透光石陶瓷板系列产品的定制批量性生产,获得具有纹理图案装饰的透光石陶瓷板。
Description
技术领域
本发明涉及透光石陶瓷板及其制备方法,属于陶瓷砖生产制造技术领域。
背景技术
当前传统陶瓷板的发展已经陷入瓶颈。面对同类产品的市场冲击以及自身同质化的生产方式,吸取其他材料的优势以进一步优化陶瓷板的性能是重要途径。普通陶瓷板仅对光具有反射作用而不具有透光性。透光陶瓷板在保持同类陶瓷产品性能的同时还兼具透光特性。透光陶瓷板在艺术灯光或自然光线照射下将灯光从陶瓷板内部透出,给人以一种幽雅、朦胧、明快、清新的感觉,充分展示出透光陶瓷板的图案颜色、纹理和质感,显著提升了透光陶瓷板的视觉效果和装饰效果。洁白光润、透光度高的透光陶瓷板给人以玲珑剔透之感,可以比拟珍贵的玉石。透光陶瓷板特有的视觉及装饰效果为建筑设计提供新的、更为广泛的创作空间。将透光和陶瓷板两者巧妙结合,可创造出透光陶瓷板的装饰新天地。
发明内容
本发明提供一种透光石陶瓷板及其制备方法,所述制备方法通过在透光石坯体上喷墨打印设计图案然后施透光石抛釉,实现透光石陶瓷板系列产品的定制批量性生产,获得具有纹理图案装饰的透光石陶瓷板。该系列产品具有质感滋润、细腻柔和、耐磨度高、硬度高、耐污染性能佳、切割加工性能优异、经久耐用的特点,可长期呈现透光石特有的高档装饰效果,能够用于拓宽建筑陶瓷产品的应用空间。
第一方面,本发明提供一种透光石陶瓷板的制备方法。所述制备方法包括以下步骤:使用透光石坯体粉料制备透光石坯体;
在透光石坯体上喷墨打印图案;
在喷墨打印图案后的透光石坯体上施透光石抛釉;
将施透光石抛釉后的坯体烧成获得透光石陶瓷板。
较佳地,所述透光石坯体的化学组成包括:以质量百分比计,烧失:4.5~5.5%、SiO2:65~68%、Al2O3:18.5~20.5%、Fe2O3:0~0.1%、TiO2:0~0.1%、CaO:2.0~3.5%、MgO:1.0~2.0%、K2O:2.5~3.5%、Na2O:0.5~1.5%。
较佳地,所述透光石坯体的矿物组成包括:以质量百分比计,水磨钾钠砂:25~35%、水磨钾长石:4~14%、烧滑石:2~6%、硅灰石:5~9%、超白膨润土:3~7%、原矿高岭土:23~33%、水洗高岭土:10~24%。
较佳地,所述透光石坯体粉料的颗粒级配包括:以质量百分比计,30目以上:5-10%,30~60目:≥78%,60~80目:≤8%,80目以下:≤6%。其中,“30目以上”指的是使用30目筛过粉料时残留在筛网以上的粉料颗粒,“80目以下”指的是使用80目筛过粉料时通过筛网的粉料颗粒。
较佳地,所述透光石坯体烧成后的物相组成包括:以质量百分比计,拉长石:10~15%、莫来石:15~20%、石英:15~25%,非晶相:45~55%。
较佳地,所述透光石抛釉的化学组成包括:以质量百分比计,烧失:7.5~9.5%、SiO2:45.0~50.0%、Al2O3:12.5~16.5%、Fe2O3:0~0.1%、TiO2:0~0.1%、CaO:7.0~10.0%、MgO:3.0~5.0%、K2O:3.0~5.0%、Na2O:1.0~3.0%、BaO:6.0~10.0%、ZnO:3.0~5.0%。
较佳地,所述透光石抛釉的矿物组成包括:以质量百分比计,透光钾长石:35~45%,钠长石:0~10%,透光高岭土:6~10%、熔融石英:2~6%,刚玉:2~6%,方解石:11~15%,白云石:0~4%,烧滑石:8~12%,碳酸钡:8~12%,氧化锌:3~5%。
较佳地,所述透光石抛釉的施加方式为喷釉,比重为1.55~1.60g/cm3,施加量为240~280g/m2。
第二方面,本发明还提供上述任一项所述的制备方法获得的透光石陶瓷板。所述透光石陶瓷板的可见光透射率为20.0~30.0%。
具体实施方式
通过下述实施方式进一步说明本发明,应理解,下述实施方式仅用于说明本发明,而非限制本发明。在没有特殊说明的情况下,各百分含量指质量百分含量。
以下示例性说明本发明所述透光石陶瓷板的制备方法。
制备透光石坯体。所述透光石坯体中氧化铁的含量在0.1wt%以下。作为优选,所述透光石坯体的化学组成包括:以质量百分比计,烧失:4.5~5.5%、SiO2:65~68%、Al2O3:18.5~20.5%、Fe2O3:0~0.1%、TiO2:0~0.1%、CaO:2.0~3.5%、MgO:1.0~2.0%、K2O:2.5~3.5%、Na2O:0.5~1.5%。一些实施方式中,所述透光石坯体的化学组成包括:以质量百分比计,烧失:4.82%、SiO2:66.43%、Al2O3:20.19%、Fe2O3:0.09%、TiO2:0.05%、CaO:2.81%、MgO:1.48%、K2O:2.98%、Na2O:1.15%。
所述透光石坯体中氧化钾的含量高于氧化钠,这有利于玻璃相的生成,提高坯体的透光度。对玻璃相而言,玻璃相的K+离子的折光率值明显高于Na+离子的折光率(RK+=8.25,RNa+=4.75),故K2O更有利于提高坯体的透光度。同时,K+离子半径(133pm)比Na+离子半径(97pm)大,K-O键比Na-O键强弱,因而K+离子相对于Na+离子对Si-O键的键强度影响较小,对玻璃网络结构的变化影响也较弱。因此,所述透光石坯体引入较多的K2O来促进玻璃相的形成,抑制分相与析晶,便于获得透明度高的坯体。同时采用高钾低钠的思路,烧成后促进形成拉长石晶体,减少玻璃相含量,在降低膨胀系数的同时有效解决烧成过程中的变形缺陷,同时也促进坯体快速烧结。
普通瓷质砖坯体中的CaO含量通常在0.5wt%以下,这不利于获得高透明性。普通坯体中CaO含量过高易导致烧成后变形,也易造成釉面痱子、针孔等缺陷。本发明在透光石坯体中引入硅灰石,与高岭石类粘土原料在高温下反应生成钙长石,钙长石与钠长石固溶成拉长石晶相,降低该坯体的烧成温度,以及和高钾低钠的设计相结合,拓宽坯体烧成温度范围,减少高温烧成变形,避免痱子、针孔等釉面缺陷的产生。
一些实施方式中,所述透光石坯体的矿物组成包括:以质量百分比计,水磨钾钠砂:25~35%、水磨钾长石:4~14%、烧滑石:2~6%、硅灰石:5~9%、超白膨润土:3~7%、原矿高岭土:23~33%、水洗高岭土:10~24%。透光石坯体中引入钾长石以提供合适含量的氧化钾。同时钾长石融化玻璃相的粘度是钠长石融化玻璃相粘度的5倍,而且随着温度升高,钾长石玻璃相粘度降低的幅度远小于钠长石玻璃相,即含钾长石的陶瓷坯体的抗变形能力远大于含钠长石的陶瓷坯体。原矿高岭土指的是未经处理的天然高岭土原料。在透光石坯体的矿物组成中使用原矿高岭土可提高坯体的可塑性,可满足半干压成形需求。水洗高岭土指的是将天然高岭石原料经球磨加工水洗除铁而成。引入去除铁、钛杂质的水洗高岭土可提高坯体烧后的透光性能。
本发明所述透光石坯体属于Al2O3-SiO2-K2O-Na2O-CaO-MgO配方体系。坯体的透明度与坯体中玻璃相的含量有关,坯体中的玻璃相越多透明度越高。但玻璃相过量会导致烧成过程中坯体发生严重变形。本发明在透光石坯体中引入硅灰石以在烧后形成拉长石晶相,在降低膨胀系数的同时,可有效解决烧成过程中的变形缺陷,同时也可促进坯体快速烧结。而且,坯体的透明度还和坯体的晶相与玻璃相折光率之间的差值有关。上述差值越小坯体的透明度越高。透光石坯体中引入硅灰石,烧成后形成的拉长石晶相与玻璃相折射率较接近,可明显提高坯体的透明度。
此外,在透光石坯体中还使用可塑性好的原矿高岭土、水洗高岭土和超白膨润土以满足干压成形的要求,也可保证半成品砖坯(生坯)具有较高的干坯强度,在釉线运行过程中无破损。原矿高岭土、水洗高岭土和超白膨润土的杂质较少,铁、钛含量较低,引入坯体后可增加坯体的透光性,烧成后呈现晶莹剔透的透光效果。
可将透光石坯体粉料压制成型以得到透光石坯体。按照透光石坯体的矿物组成称量各原料,混合均匀后球磨过筛,干燥即可得到透光石坯体粉料。所述透光石坯体粉料的水分含量控制在7.0~8.0wt%为宜。一些实施方式中,所述透光石坯体粉料的颗粒级配包括:以质量百分比计,30目以上:5-10%,30~60目:≥78%,60~80目:≤8%,80目以下:≤6%。采用该颗粒级配可满足半干压成形的要求,同时也保证烧后的坯面平整度较佳,促进提高坯体的透光性。
一些实施方式中,所述透光石坯体在600℃的热膨胀系数为8.0~8.5×10-7/℃。
所述透光石坯体烧成后具有拉长石、莫来石、石英等多元晶相。一些实施方式中,所述透光石坯体烧成后的物相组成包括:以质量百分比计,拉长石:10~15%、莫来石:15~20%、石英:15~25%,非晶相:45~55%。
将透光石坯体干燥。干燥温度可为100~160℃。干燥时间可为30~60min。干燥后透光石坯体的水分含量控制在0.5wt%以内为宜。
在干燥后的透光石坯体上喷墨打印图案。喷墨打印图案的内容和颜色根据版面设计作适应性变化。
在喷墨打印图案后的透光石坯体上施透光石抛釉,既充分呈现出喷墨图案纹理的效果,也可促进透光石的透光性能。
所述透光石抛釉的化学组成包括:以质量百分比计,烧失:7.5~9.5%、SiO2:45.0~50.0%、Al2O3:12.5~16.5%、Fe2O3:0~0.1%、TiO2:0~0.1%、CaO:7.0~10.0%、MgO:3.0~5.0%、K2O:3.0~5.0%、Na2O:1.0~3.0%、BaO:6.0~10.0%、ZnO:3.0~5.0%。作为示例,所述透光石抛釉的化学组成包括:以质量百分比计,烧失:8.78%、SiO2:45.91%、Al2O3:14.35%、Fe2O3:0.09%、TiO2:0.05%、CaO:8.26%、MgO:3.83%、K2O:4.06%、Na2O:1.89%、BaO:8.57%、ZnO:3.73%。透光石抛釉采用低铝高钡、高钾低钠的思路,可促进透光效果。
为保证透光石抛釉的透光性能,透光石抛釉的矿物组成中尽可能引入低铁钛的原料,用熔融石英、刚玉取代铁钛杂质多、富含莫来石的煅烧高岭土,用透光高岭土取代铁钛杂质多的高岭土,同时尽可能采用高钾低钠、低铝高钡的思路。一些实施方式中,所述透光石抛釉在600℃的热膨胀系数为7.0~7.5×10-7/℃。
上述透光石抛釉的矿物组成包括:以质量百分比计,,透光钾长石:35~45%,钠长石:0~10%,透光高岭土:6~10%、熔融石英:2~6%,刚玉:2~6%,方解石:11~15%,白云石:0~4%,烧滑石:8~12%,碳酸钡:8~12%,氧化锌:3~5%。
将透光石抛釉制备成釉浆。例如,按照透光石抛釉的矿物组成称量各原料,加入水和其他助剂(例如羧甲基纤维素钠和三聚磷酸钠等),混合均匀后过筛,制成釉浆。透光石抛釉的325目筛余为0.5~0.8wt%。
所述透光石抛釉的施加方式为喷釉。与淋釉相比,喷釉可减少透光石抛釉的施釉量,减少抛釉析晶效果从而促进透光性能。
一些实施方式中,所述透光石抛釉的施加方式为喷釉,比重为1.55~1.60g/cm3,施加量为240~280g/m2。
本发明采用透光石坯体结合透光石抛釉,可促进透光性能最佳。若使用透光石坯体,不使用透光石抛釉而使用普通抛釉,会降低透光性能。若使用透光石抛釉,不使用透光石坯体而使用普通坯体,也会大幅度降低透光性能,使可见光透射率几乎为零。
将施透光石抛釉后的坯体高温干燥。干燥温度可为100~160℃。干燥时间可为30~60min。
将干燥后的坯体烧成获得透光石陶瓷板。可在辊道窑快速烧成。一些实施方式中,最高烧成温度1180~1220℃,烧成周期60~120min。
所述透光石陶瓷板的厚度可为3~8mm。一些实施方式中,所述透光石陶瓷板的规格为长800~1800mm×宽1400~3600mm×厚3~8mm。
现有技术中通过引入富含BaO、Li2O、CaF2、P2O5等组分并经1530℃熔制水淬形成析晶熔块来提高陶瓷产品的透明性能,但是这会导致坯体化学组成中存在较多的BaO、Li2O、CaF2、P2O5等组分,该透光陶瓷产品的玻璃相含量仅18~45wt%,可见光透射率仅2.5~4.6%。本发明所述透光石坯体未引入BaO、Li2O、CaF2、P2O5等组分,烧后的非晶相在45~55%,透光石陶瓷板的可见光透射率高达20~30%。
本发明所述制备方法获得的透光石陶瓷板质感滋润细腻,透光性极高,膨胀系数小,耐污染性能优异,具有高硬度和高耐磨度性,经久耐用。该透光石陶瓷板在灯光照射下晶莹剔透,给人以一种高档、奢华的感觉。将交替变化的不同颜色灯光从透光石陶瓷板内部透出将出现交替变化的不同颜色,呈现动态的装饰效果,具有很强的视角冲击力,给人无限的遐想空间,可满足人们对美学的不断追求。
还可以对烧成后得到的透光石陶瓷板采用柔性抛光技术进行抛光处理,抛后光泽度在40~50度,可减少陶瓷板光污染现象。
打蜡磨边,分级打包进仓。
下面进一步例举实施例以详细说明本发明。同样应理解,以下实施例只用于对本发明进行进一步说明,不能理解为对本发明保护范围的限制,本领域的技术人员根据本发明的上述内容作出的一些非本质的改进和调整均属于本发明的保护范围。下述示例具体的工艺参数等也仅是合适范围中的一个示例,即本领域技术人员可以通过本文的说明做合适的范围内选择,而并非要限定于下文示例的具体数值。
实施例1
透光石陶瓷板的制备方法包括以下步骤:
步骤一:按照配比制备透光石坯体;所述透光石的矿物组成包括:以质量百分比计,水磨钾钠砂:30%、水磨钾长石:9%、烧滑石:4%、硅灰石:7%、超白膨润土:5%、原矿高岭土:28%、水洗高岭土:17%;所述透光石坯体的化学组成包括:以质量百分比计,烧失:4.82%、SiO2:66.43%、Al2O3:20.19%、Fe2O3:0.09%、TiO2:0.05%、CaO:2.81%、MgO:1.48%、K2O:2.98%、Na2O:1.15%;
步骤二:将透光石坯体干燥,干燥后的坯体水分控制在0.5wt%以内;
步骤三:在干燥后的透光石坯体表面用喷墨机喷墨打印图案;
步骤四:在喷墨打印图案后的透光石坯体上施透光石抛釉;所述透光石抛釉的矿物组成包括:以质量百分比计,透光钾长石:40%,钠长石:5%,透光高岭土:8%、熔融石英:4%,刚玉:4%,方解石:13%,白云石:2%,烧滑石:10%,碳酸钡:10%,氧化锌:4%;透光石抛釉化学组成包括:以质量百分比计,烧失:8.78%、SiO2:45.91%、Al2O3:14.35%、Fe2O3:0.09%、TiO2:0.05%、CaO:8.26%、MgO:3.83%、K2O:4.06%、Na2O:1.89%、BaO:8.57%、ZnO:3.73%;
步骤五:采用摆臂式喷釉机在打印喷墨图案后的坯体表面施透光石抛釉;所述透光石抛釉的比重为1.55g/cm3,施加量为280g/m2;
步骤六:将施透光石抛釉的坯体高温干燥后在辊道窑快速烧成;最高烧成温度1180℃,烧成周期80min;
步骤七:将烧成后的透光石陶瓷板采用柔性抛光技术进行抛坯处理;
步骤八:打蜡磨边,分级打包进仓。
将实施例1的透光石陶瓷板根据GB/T 2680-1994《建筑玻璃可见光透射比、太阳光直接投射比、太阳能总透射比、紫外线透射比及有关窗玻璃参数的测定》进行测试。所述透光石陶瓷板的可见光透射率为25.6%。
对比例1
陶瓷板的制备方法包括以下步骤:
步骤一:按照配比制备普通坯体;所述普通坯体的矿物组成包括:以质量百分比计,钠长石:21%、黑滑石:2%、高白钾砂:20%、钾铝砂:20%、煅烧铝矾土:6%、水洗球土:29%,膨润土:2%;所述普通坯体的化学组成包括:以质量百分比计,烧失:5.43%、SiO2:63.0%、Al2O3:24.02%、Fe2O3:0.81%、TiO2:0.23%、CaO:0.37%、MgO:0.69%、K2O:2.57%、Na2O:2.88%;
步骤二:将普通坯体干燥,干燥后的坯体水分控制在0.5wt%以内;
步骤三:在干燥后的普通坯体表面用喷墨机喷墨打印图案;
步骤四:在喷墨打印图案后的普通坯体上施透光石抛釉;所述透光石抛釉的矿物组成包括:以质量百分比计,透光钾长石:40%,钠长石:5%,透光高岭土:8%、熔融石英:4%,刚玉:4%,方解石:13%,白云石:2%,烧滑石:10%,碳酸钡:10%,氧化锌:4%;透光石抛釉化学组成包括:以质量百分比计,烧失:8.78%、SiO2:45.91%、Al2O3:14.35%、Fe2O3:0.09%、TiO2:0.05%、CaO:8.26%、MgO:3.83%、K2O:4.06%、Na2O:1.89%、BaO:8.57%、ZnO:3.73%;
步骤五:采用摆臂式喷釉机在打印喷墨图案后的坯体表面施透光石抛釉;所述透光石抛釉的比重为1.55g/cm3,施加量为280g/m2;
步骤六:将施透光石抛釉的坯体高温干燥后在辊道窑快速烧成;最高烧成温度1220℃,烧成周期120min;
步骤七:将烧成后的陶瓷板采用柔性抛光技术进行抛坯处理;
步骤八:打蜡磨边,分级打包进仓。
将对比例1的陶瓷板根据GB/T 2680-1994《建筑玻璃可见光透射比、太阳光直接投射比、太阳能总透射比、紫外线透射比及有关窗玻璃参数的测定》进行测试。所述陶瓷板的可见光透射率为0.3%。这是因为:对比例1的普通坯体化学组成中影响透光性的Fe2O3杂质含量高达0.81%、TiO2高达0.23%,会明显降低坯体的透光性能;同时普通坯体未引入硅灰石形成拉长石相,而是形成大量的莫来石相,这也会降低透光性能。基于以上两点原因,对比例1的陶瓷板的可见光透射率趋向于接近零。
对比例2
陶瓷板的制备方法包括以下步骤:
步骤一:按照配比制备透光石坯体;所述透光石的原料组成包括:以质量百分比计,水磨钾钠砂:30%、水磨钾长石:9%、烧滑石:4%、硅灰石:7%、超白膨润土:5%、高岭土:28%、水洗高岭土:17%;所述透光石坯体的化学组成包括:以质量百分比计,烧失:4.82%、SiO2:66.43%、Al2O3:20.19%、Fe2O3:0.09%、TiO2:0.05%、CaO:2.81%、MgO:1.48%、K2O:2.98%、Na2O:1.15%;
步骤二:将透光石坯体干燥,干燥后的坯体水分控制在0.5wt%以内;
步骤三:在干燥后的透光石坯体表面用喷墨机喷墨打印图案;
步骤四:在喷墨打印图案后的透光石坯体上施普通抛釉;所述普通抛釉的矿物组成包括:以质量百分比计,钾长石:30%,钠长石:13%,高岭土:15%、煅烧高岭土:15%,方解石:10%,白云石:2%,烧滑石:5%,硅灰石:5%,碳酸钡:1%,氧化锌:4%;所述普通抛釉的化学组成包括:以质量百分比计,烧失:7.80%、SiO2:51.21%、Al2O3:19.42%、Fe2O3:0.30%、TiO2:0.12%、CaO:8.77%、MgO:2.23%、K2O:3.33%、Na2O:1.86%、BaO:0.78%、ZnO:3.97%;
步骤五:采用摆臂式喷釉机在打印喷墨图案后的坯体表面施普通抛釉;所述普通抛釉的比重为1.60g/cm3,施加量为240g/m2;
步骤六:将施普通抛釉的坯体高温干燥后在辊道窑快速烧成;最高烧成温度1200℃,烧成周期80min;
步骤七:将烧成后的陶瓷板采用柔性抛光技术进行抛坯处理;
步骤八:打蜡磨边,分级打包进仓。
将对比例2的陶瓷板根据GB/T 2680-1994《建筑玻璃可见光透射比、太阳光直接投射比、太阳能总透射比、紫外线透射比及有关窗玻璃参数的测定》进行测试。所述陶瓷板的可见光透射率为13.1%。这是因为:对比例2的普通抛釉中使用普通的高岭土及煅烧高岭土,引入较多的铁、钛杂质,会降低透光性能;同时普通抛釉采用高铝低钡的思路,也会降低透光性能。基于以上两点原因,导致对比例2采用普通抛釉的透光率会明显下降。
Claims (6)
1.一种透光石陶瓷板的制备方法,其特征在于,所述制备方法包括以下步骤:
使用透光石坯体粉料制备透光石坯体;所述透光石坯体的原料组成包括:以质量百分比计,水磨钾钠砂:25~35%、水磨钾长石:4~14%、烧滑石:2~6%、硅灰石:5~9%、超白膨润土:3~7%、原矿高岭土:23~33%、水洗高岭土:10~24%;所述透光石坯体烧成后的物相组成包括:以质量百分比计,拉长石:10~15%、莫来石:15~20%、石英:15~25%,非晶相:45~55%;
在透光石坯体上喷墨打印图案;
在喷墨打印图案后的透光石坯体上施透光石抛釉;所述透光石抛釉的原料组成包括:以质量百分比计,透光钾长石:35~45%,钠长石:0~10%,透光高岭土:6~10%、熔融石英:2~6%,刚玉:2~6%,方解石:11~15%,白云石:0~4%,烧滑石:8~12%,碳酸钡:8~12%,氧化锌:3~5%;
将施透光石抛釉后的坯体烧成获得透光石陶瓷板。
2.根据权利要求1所述的制备方法,其特征在于,所述透光石坯体的化学组成包括:以质量百分比计,烧失:4.5~5.5%、SiO2:65~68%、Al2O3:18.5~20.5%、Fe2O3:0~0.1%、TiO2:0~0.1%、CaO:2.0~3.5%、MgO:1.0~2.0%、K2O:2.5~3.5%、Na2O:0.5~1.5%。
3.根据权利要求1所述的制备方法,其特征在于,所述透光石坯体粉料的颗粒级配包括:以质量百分比计,30目以上:5-10%,30~60目:≥78%,60~80目:≤8%,80目以下:≤6%。
4.根据权利要求1所述的制备方法,其特征在于,所述透光石抛釉的化学组成包括:以质量百分比计,烧失:7.5~9.5%、SiO2:45.0~50.0%、Al2O3:12.5~16.5%、Fe2O3:0~0.1%、TiO2:0~0.1%、CaO:7.0~10.0%、MgO:3.0~5.0%、K2O:3.0~5.0%、Na2O:1.0~3.0%、BaO:6.0~10.0%、ZnO:3.0~5.0%。
5.根据权利要求1所述的制备方法,其特征在于,所述透光石抛釉的施加方式为喷釉,比重为1.55~1.60g/cm3,施加量为240~280g/m2。
6.根据权利要求1至5中任一项所述的制备方法获得的透光石陶瓷板,其特征在于,所述透光石陶瓷板的可见光透射率为20.0~30.0%。
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