CN113791064B - 一种喹硫磷农药残留的快速检测方法 - Google Patents
一种喹硫磷农药残留的快速检测方法 Download PDFInfo
- Publication number
- CN113791064B CN113791064B CN202111048410.XA CN202111048410A CN113791064B CN 113791064 B CN113791064 B CN 113791064B CN 202111048410 A CN202111048410 A CN 202111048410A CN 113791064 B CN113791064 B CN 113791064B
- Authority
- CN
- China
- Prior art keywords
- quinfos
- concentration
- parts
- pesticide residue
- pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000001514 detection method Methods 0.000 title claims abstract description 31
- 239000000447 pesticide residue Substances 0.000 title claims abstract description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 37
- 239000003153 chemical reaction reagent Substances 0.000 claims description 36
- 239000013310 covalent-organic framework Substances 0.000 claims description 28
- 238000006243 chemical reaction Methods 0.000 claims description 26
- 238000012360 testing method Methods 0.000 claims description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 24
- 239000000243 solution Substances 0.000 claims description 24
- 238000005406 washing Methods 0.000 claims description 23
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical group CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 22
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 22
- 239000000575 pesticide Substances 0.000 claims description 22
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 19
- JYQUHIFYBATCCY-UHFFFAOYSA-N quinalphos Chemical compound C1=CC=CC2=NC(OP(=S)(OCC)OCC)=CN=C21 JYQUHIFYBATCCY-UHFFFAOYSA-N 0.000 claims description 18
- 239000003960 organic solvent Substances 0.000 claims description 17
- 239000000696 magnetic material Substances 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 14
- URKOMYMAXPYINW-UHFFFAOYSA-N quetiapine Chemical compound C1CN(CCOCCO)CCN1C1=NC2=CC=CC=C2SC2=CC=CC=C12 URKOMYMAXPYINW-UHFFFAOYSA-N 0.000 claims description 14
- 229960004431 quetiapine Drugs 0.000 claims description 14
- 239000012265 solid product Substances 0.000 claims description 14
- 239000007864 aqueous solution Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 11
- 239000011259 mixed solution Substances 0.000 claims description 11
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 10
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 10
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 10
- 238000012417 linear regression Methods 0.000 claims description 10
- 239000002122 magnetic nanoparticle Substances 0.000 claims description 10
- 239000008055 phosphate buffer solution Substances 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- UBIJTWDKTYCPMQ-UHFFFAOYSA-N hexachlorophosphazene Chemical compound ClP1(Cl)=NP(Cl)(Cl)=NP(Cl)(Cl)=N1 UBIJTWDKTYCPMQ-UHFFFAOYSA-N 0.000 claims description 9
- 238000000265 homogenisation Methods 0.000 claims description 9
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 9
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 claims description 9
- 229920000877 Melamine resin Polymers 0.000 claims description 8
- 235000013311 vegetables Nutrition 0.000 claims description 8
- 238000009210 therapy by ultrasound Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 238000004401 flow injection analysis Methods 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 6
- HWYHZTIRURJOHG-UHFFFAOYSA-N luminol Chemical group O=C1NNC(=O)C2=C1C(N)=CC=C2 HWYHZTIRURJOHG-UHFFFAOYSA-N 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 5
- 238000007664 blowing Methods 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 230000035484 reaction time Effects 0.000 claims description 5
- 238000010992 reflux Methods 0.000 claims description 5
- 239000001632 sodium acetate Substances 0.000 claims description 5
- 235000017281 sodium acetate Nutrition 0.000 claims description 5
- 239000006228 supernatant Substances 0.000 claims description 5
- 238000005520 cutting process Methods 0.000 claims description 3
- 238000004090 dissolution Methods 0.000 claims description 3
- 238000004020 luminiscence type Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 10
- 238000004458 analytical method Methods 0.000 abstract description 4
- 238000013178 mathematical model Methods 0.000 abstract description 2
- WTHRRGMBUAHGNI-LCYNINFDSA-N quinupristin Chemical compound N([C@@H]1C(=O)N[C@@H](C(N2CCC[C@H]2C(=O)N(C)[C@@H](CC=2C=CC(=CC=2)N(C)C)C(=O)N2C[C@@H](CS[C@H]3C4CCN(CC4)C3)C(=O)C[C@H]2C(=O)N[C@H](C(=O)O[C@@H]1C)C=1C=CC=CC=1)=O)CC)C(=O)C1=NC=CC=C1O WTHRRGMBUAHGNI-LCYNINFDSA-N 0.000 abstract 3
- 238000004364 calculation method Methods 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 239000002131 composite material Substances 0.000 description 13
- 229910052802 copper Inorganic materials 0.000 description 13
- 239000010949 copper Substances 0.000 description 13
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 12
- 239000013384 organic framework Substances 0.000 description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 5
- 229910001431 copper ion Inorganic materials 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000001509 sodium citrate Substances 0.000 description 4
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- -1 alcoholysis Chemical class 0.000 description 2
- UBRBTUQHTMHTMU-UHFFFAOYSA-N bis(ethylperoxy)-hydroxy-sulfanylidene-$l^{5}-phosphane Chemical compound CCOOP(O)(=S)OOCC UBRBTUQHTMHTMU-UHFFFAOYSA-N 0.000 description 2
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000002329 infrared spectrum Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical compound Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 238000002965 ELISA Methods 0.000 description 1
- 238000008157 ELISA kit Methods 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- ROBVLQBZPQQRTQ-UHFFFAOYSA-N [N].C1=CN=NN=C1 Chemical compound [N].C1=CN=NN=C1 ROBVLQBZPQQRTQ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- 238000005915 ammonolysis reaction Methods 0.000 description 1
- 239000000427 antigen Substances 0.000 description 1
- 102000036639 antigens Human genes 0.000 description 1
- 108091007433 antigens Proteins 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000003169 central nervous system Anatomy 0.000 description 1
- 239000013064 chemical raw material Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000037406 food intake Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004434 industrial solvent Substances 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical class CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003987 organophosphate pesticide Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000037384 skin absorption Effects 0.000 description 1
- 231100000274 skin absorption Toxicity 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 235000019605 sweet taste sensations Nutrition 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/76—Chemiluminescence; Bioluminescence
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
- G01N21/64—Fluorescence; Phosphorescence
- G01N21/6428—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes"
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
- G01N21/64—Fluorescence; Phosphorescence
- G01N21/6428—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes"
- G01N2021/6432—Quenching
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
- G01N21/64—Fluorescence; Phosphorescence
- G01N21/6428—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes"
- G01N2021/6439—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes" with indicators, stains, dyes, tags, labels, marks
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plasma & Fusion (AREA)
- Engineering & Computer Science (AREA)
- Optics & Photonics (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
Abstract
Description
名称 | 比表面积(m2/g) |
实施例1 | 612 |
实施例2 | 897 |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111048410.XA CN113791064B (zh) | 2021-09-08 | 2021-09-08 | 一种喹硫磷农药残留的快速检测方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111048410.XA CN113791064B (zh) | 2021-09-08 | 2021-09-08 | 一种喹硫磷农药残留的快速检测方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN113791064A CN113791064A (zh) | 2021-12-14 |
CN113791064B true CN113791064B (zh) | 2024-03-12 |
Family
ID=79182916
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202111048410.XA Active CN113791064B (zh) | 2021-09-08 | 2021-09-08 | 一种喹硫磷农药残留的快速检测方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN113791064B (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115888654B (zh) * | 2022-11-09 | 2024-03-26 | 昆明理工大学 | 一种磁性cof吸附剂及其制备方法与应用 |
Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005064331A1 (en) * | 2003-12-31 | 2005-07-14 | Council Of Scientific And Industrial Research | Method and kit for pesticide analysis |
CN1664567A (zh) * | 2005-03-14 | 2005-09-07 | 陕西师范大学 | 化学发光有机磷农药残留分析仪及其检测方法 |
CN102221529A (zh) * | 2011-03-31 | 2011-10-19 | 吉林大学 | 金纳米粒子比色法快速检测蔬菜中有机磷农药残留的方法 |
CN102590192A (zh) * | 2012-02-17 | 2012-07-18 | 中国科学院合肥物质科学研究院 | 一种化学发光增强型检测农药残留的方法 |
CN104007104A (zh) * | 2014-05-22 | 2014-08-27 | 上海交通大学 | 快速检测有机磷农药残留的试剂盒及其使用方法 |
CN104399535A (zh) * | 2014-10-09 | 2015-03-11 | 济南大学 | 一种磁性配合物基催化剂的制备方法和应用 |
CN104597039A (zh) * | 2014-12-28 | 2015-05-06 | 福建医科大学 | 一种有机磷农药残留化学发光传感检测方法及用途 |
CN108593925A (zh) * | 2017-12-28 | 2018-09-28 | 华南农业大学 | 一种基于纳米抗体检测二乙氧基有机磷农药的酶联免疫试剂盒及其使用方法 |
CN109164100A (zh) * | 2018-10-30 | 2019-01-08 | 青岛农业大学 | 一种快速检测农药的试纸条 |
CN109765220A (zh) * | 2019-01-15 | 2019-05-17 | 安徽师范大学 | 利用钴基金属有机凝胶催化鲁米诺-过氧化氢发光定量检测对苯二酚的方法 |
CN110487778A (zh) * | 2019-08-07 | 2019-11-22 | 东南大学 | 基于水凝胶构建的辉光型化学发光传感器及其制备方法和应用 |
CN111318310A (zh) * | 2020-03-17 | 2020-06-23 | 山东师范大学 | 一种装载FePc的金属有机框架复合纳米材料及其制备方法和化学发光检测的应用 |
CN111330643A (zh) * | 2020-02-25 | 2020-06-26 | 青岛农业大学 | 一种不同单金属、双金属二维MOFs纳米酶的超声合成法及其应用 |
-
2021
- 2021-09-08 CN CN202111048410.XA patent/CN113791064B/zh active Active
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005064331A1 (en) * | 2003-12-31 | 2005-07-14 | Council Of Scientific And Industrial Research | Method and kit for pesticide analysis |
CN1664567A (zh) * | 2005-03-14 | 2005-09-07 | 陕西师范大学 | 化学发光有机磷农药残留分析仪及其检测方法 |
CN102221529A (zh) * | 2011-03-31 | 2011-10-19 | 吉林大学 | 金纳米粒子比色法快速检测蔬菜中有机磷农药残留的方法 |
CN102590192A (zh) * | 2012-02-17 | 2012-07-18 | 中国科学院合肥物质科学研究院 | 一种化学发光增强型检测农药残留的方法 |
CN104007104A (zh) * | 2014-05-22 | 2014-08-27 | 上海交通大学 | 快速检测有机磷农药残留的试剂盒及其使用方法 |
CN104399535A (zh) * | 2014-10-09 | 2015-03-11 | 济南大学 | 一种磁性配合物基催化剂的制备方法和应用 |
CN104597039A (zh) * | 2014-12-28 | 2015-05-06 | 福建医科大学 | 一种有机磷农药残留化学发光传感检测方法及用途 |
CN108593925A (zh) * | 2017-12-28 | 2018-09-28 | 华南农业大学 | 一种基于纳米抗体检测二乙氧基有机磷农药的酶联免疫试剂盒及其使用方法 |
CN109164100A (zh) * | 2018-10-30 | 2019-01-08 | 青岛农业大学 | 一种快速检测农药的试纸条 |
CN109765220A (zh) * | 2019-01-15 | 2019-05-17 | 安徽师范大学 | 利用钴基金属有机凝胶催化鲁米诺-过氧化氢发光定量检测对苯二酚的方法 |
CN110487778A (zh) * | 2019-08-07 | 2019-11-22 | 东南大学 | 基于水凝胶构建的辉光型化学发光传感器及其制备方法和应用 |
CN111330643A (zh) * | 2020-02-25 | 2020-06-26 | 青岛农业大学 | 一种不同单金属、双金属二维MOFs纳米酶的超声合成法及其应用 |
CN111318310A (zh) * | 2020-03-17 | 2020-06-23 | 山东师范大学 | 一种装载FePc的金属有机框架复合纳米材料及其制备方法和化学发光检测的应用 |
Non-Patent Citations (1)
Title |
---|
化学发光生物传感器法测定食品中有机磷与氨基甲酸酯类农药残留;王晓朋;曾梅;万德慧;唐晗;赵彬媛;周雅倩;刘晓宇;;食品安全质量检测学报(第12期);全文 * |
Also Published As
Publication number | Publication date |
---|---|
CN113791064A (zh) | 2021-12-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106338568B (zh) | 一种检测汽车及汽车内饰气味物质的方法 | |
Zhang et al. | Nitration of particle-associated PAHs and their derivatives (nitro-, oxy-, and hydroxy-PAHs) with NO3 radicals | |
CN113791064B (zh) | 一种喹硫磷农药残留的快速检测方法 | |
Shepson et al. | Mutagenic activity of irradiated toluene nitrogen oxide (NOx)/water/air mixtures | |
CN113234068B (zh) | 一种近红外花菁类比色荧光探针及其制备方法和应用 | |
CN108570062B (zh) | 一种多孔金属有机配合物及其制备方法和在检测氨气、氨水中的应用 | |
Liu et al. | Discovery of a novel camphor-based fluorescent probe for Co2+ in fresh vegetables with high selectivity and sensitivity | |
CN111393461A (zh) | 一种基于bodipy的钯离子荧光探针化合物及其合成方法 | |
CN108279276A (zh) | 一种海绵文胸中甲苯二异氰酸酯残留量的测定方法 | |
CN109239035A (zh) | 一种基于十元瓜环的超分子框架材料在甲醛检测中的应用 | |
CN113698307A (zh) | 一种同位素化合物及其制备方法和用途 | |
CN111363161B (zh) | 一种基于铽-有机框架材料的钍离子荧光探针及制备方法 | |
CN110878100B (zh) | 一种可裸眼识别的氰根离子探针及其制备方法和在含水体系中检测氰根离子的应用 | |
CN109053626B (zh) | 一种荧光探针及其制备方法和其在二价钯检测中的应用 | |
CN115073338B (zh) | 一种高选择性识别汞离子荧光探针、制备方法与应用 | |
CN114814054B (zh) | 一种检测海洋沉积物中10种卤代咔唑类化合物的方法 | |
CN108226345B (zh) | 一种检测环境中bnst类污染物的方法 | |
CN103123346A (zh) | 一种食品中玉米赤霉烯酮快速仪器分析方法 | |
CN113419018B (zh) | 一种燃香样品的前处理方法及对燃香烟气中多种大麻素类化合物进行检测的方法 | |
CN115015404A (zh) | 一种基于同位素示踪的“烃-水-岩”相互作用热模拟实验方法 | |
CN114354790A (zh) | 一种检测水产品中7种卤代咔唑类化合物的方法 | |
CN107290469A (zh) | 虾夷扇贝中微囊藻毒素检测方法 | |
CN113736091A (zh) | 一种荧光微米探针检测槲皮素的方法和应用 | |
CN104297195A (zh) | 一种味精中铅的快速检测方法 | |
CN111218271A (zh) | 一种基于聚集诱导发光性质的汞离子检测材料的制备和使用方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240407 Address after: Room 4-1, 2nd Floor, Building 3, No. 103 Beiqing Road, Haidian District, Beijing, 100089 Patentee after: Beijing kemia Technology Co.,Ltd. Country or region after: China Address before: 430056 room 2256, 2266-61, 2f, building e, Cyberport, Dongxin Road, Donghu New Technology Development Zone, Wuhan City, Hubei Province Patentee before: WUHAN PUXIN ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. Country or region before: China |
|
TR01 | Transfer of patent right |