CN113713753A - 一种草酸镁微球的制备方法及其应用 - Google Patents
一种草酸镁微球的制备方法及其应用 Download PDFInfo
- Publication number
- CN113713753A CN113713753A CN202111040135.7A CN202111040135A CN113713753A CN 113713753 A CN113713753 A CN 113713753A CN 202111040135 A CN202111040135 A CN 202111040135A CN 113713753 A CN113713753 A CN 113713753A
- Authority
- CN
- China
- Prior art keywords
- microspheres
- magnesium oxalate
- oxalic acid
- oxalate
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004005 microsphere Substances 0.000 title claims abstract description 65
- UHNWOJJPXCYKCG-UHFFFAOYSA-L magnesium oxalate Chemical compound [Mg+2].[O-]C(=O)C([O-])=O UHNWOJJPXCYKCG-UHFFFAOYSA-L 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title abstract description 11
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000002351 wastewater Substances 0.000 claims abstract description 18
- 229940072172 tetracycline antibiotic Drugs 0.000 claims abstract description 16
- 238000001035 drying Methods 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011812 mixed powder Substances 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 10
- 229920002545 silicone oil Polymers 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 10
- 239000011259 mixed solution Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 8
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000000227 grinding Methods 0.000 claims abstract description 6
- 239000002244 precipitate Substances 0.000 claims abstract description 6
- 238000005406 washing Methods 0.000 claims abstract description 6
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 3
- 238000001914 filtration Methods 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 7
- 229910021538 borax Inorganic materials 0.000 claims description 5
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 5
- 239000004328 sodium tetraborate Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 2
- 239000003463 adsorbent Substances 0.000 abstract description 7
- 230000003115 biocidal effect Effects 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 6
- 238000001179 sorption measurement Methods 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 238000009776 industrial production Methods 0.000 abstract description 2
- OGQYJDHTHFAPRN-UHFFFAOYSA-N 2-fluoro-6-(trifluoromethyl)benzonitrile Chemical compound FC1=CC=CC(C(F)(F)F)=C1C#N OGQYJDHTHFAPRN-UHFFFAOYSA-N 0.000 description 9
- 229960003185 chlortetracycline hydrochloride Drugs 0.000 description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 229910052710 silicon Inorganic materials 0.000 description 8
- 239000010703 silicon Substances 0.000 description 8
- 239000003242 anti bacterial agent Substances 0.000 description 7
- 229940088710 antibiotic agent Drugs 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- QYAPHLRPFNSDNH-MRFRVZCGSA-N (4s,4as,5as,6s,12ar)-7-chloro-4-(dimethylamino)-1,6,10,11,12a-pentahydroxy-6-methyl-3,12-dioxo-4,4a,5,5a-tetrahydrotetracene-2-carboxamide;hydrochloride Chemical compound Cl.C1=CC(Cl)=C2[C@](O)(C)[C@H]3C[C@H]4[C@H](N(C)C)C(=O)C(C(N)=O)=C(O)[C@@]4(O)C(=O)C3=C(O)C2=C1O QYAPHLRPFNSDNH-MRFRVZCGSA-N 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 4
- 239000004100 Oxytetracycline Substances 0.000 description 4
- 229960000625 oxytetracycline Drugs 0.000 description 4
- IWVCMVBTMGNXQD-PXOLEDIWSA-N oxytetracycline Chemical compound C1=CC=C2[C@](O)(C)[C@H]3[C@H](O)[C@H]4[C@H](N(C)C)C(O)=C(C(N)=O)C(=O)[C@@]4(O)C(O)=C3C(=O)C2=C1O IWVCMVBTMGNXQD-PXOLEDIWSA-N 0.000 description 4
- 235000019366 oxytetracycline Nutrition 0.000 description 4
- IWVCMVBTMGNXQD-UHFFFAOYSA-N terramycin dehydrate Natural products C1=CC=C2C(O)(C)C3C(O)C4C(N(C)C)C(O)=C(C(N)=O)C(=O)C4(O)C(O)=C3C(=O)C2=C1O IWVCMVBTMGNXQD-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- 230000010355 oscillation Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 241000282412 Homo Species 0.000 description 2
- 241000282414 Homo sapiens Species 0.000 description 2
- 239000004098 Tetracycline Substances 0.000 description 2
- CYDMQBQPVICBEU-UHFFFAOYSA-N chlorotetracycline Natural products C1=CC(Cl)=C2C(O)(C)C3CC4C(N(C)C)C(O)=C(C(N)=O)C(=O)C4(O)C(O)=C3C(=O)C2=C1O CYDMQBQPVICBEU-UHFFFAOYSA-N 0.000 description 2
- 229960004475 chlortetracycline Drugs 0.000 description 2
- 235000019365 chlortetracycline Nutrition 0.000 description 2
- CYDMQBQPVICBEU-XRNKAMNCSA-N chlortetracycline Chemical compound C1=CC(Cl)=C2[C@](O)(C)[C@H]3C[C@H]4[C@H](N(C)C)C(O)=C(C(N)=O)C(=O)[C@@]4(O)C(O)=C3C(=O)C2=C1O CYDMQBQPVICBEU-XRNKAMNCSA-N 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229960002180 tetracycline Drugs 0.000 description 2
- 235000019364 tetracycline Nutrition 0.000 description 2
- 229930101283 tetracycline Natural products 0.000 description 2
- 150000003522 tetracyclines Chemical class 0.000 description 2
- KIPLYOUQVMMOHB-MXWBXKMOSA-L [Ca++].CN(C)[C@H]1[C@@H]2[C@@H](O)[C@H]3C(=C([O-])[C@]2(O)C(=O)C(C(N)=O)=C1O)C(=O)c1c(O)cccc1[C@@]3(C)O.CN(C)[C@H]1[C@@H]2[C@@H](O)[C@H]3C(=C([O-])[C@]2(O)C(=O)C(C(N)=O)=C1O)C(=O)c1c(O)cccc1[C@@]3(C)O Chemical compound [Ca++].CN(C)[C@H]1[C@@H]2[C@@H](O)[C@H]3C(=C([O-])[C@]2(O)C(=O)C(C(N)=O)=C1O)C(=O)c1c(O)cccc1[C@@]3(C)O.CN(C)[C@H]1[C@@H]2[C@@H](O)[C@H]3C(=C([O-])[C@]2(O)C(=O)C(C(N)=O)=C1O)C(=O)c1c(O)cccc1[C@@]3(C)O KIPLYOUQVMMOHB-MXWBXKMOSA-L 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229940063650 terramycin Drugs 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28016—Particle form
- B01J20/28019—Spherical, ellipsoidal or cylindrical
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Water Treatment By Sorption (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111040135.7A CN113713753B (zh) | 2021-09-06 | 2021-09-06 | 一种草酸镁微球的制备方法及其应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111040135.7A CN113713753B (zh) | 2021-09-06 | 2021-09-06 | 一种草酸镁微球的制备方法及其应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN113713753A true CN113713753A (zh) | 2021-11-30 |
CN113713753B CN113713753B (zh) | 2023-07-14 |
Family
ID=78681963
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202111040135.7A Active CN113713753B (zh) | 2021-09-06 | 2021-09-06 | 一种草酸镁微球的制备方法及其应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN113713753B (zh) |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040121008A1 (en) * | 2001-03-16 | 2004-06-24 | Keiko Shiraishi | Process for producing sustained release preparation |
US20100258494A1 (en) * | 2005-09-12 | 2010-10-14 | Martin Freudenschuss | Packing Material for a Micro-Adsorption Column for Drying and/or Purification of Dissolved Organic or Biological Analytes and Micro-Adsorption Column and use thereof |
CN106045351A (zh) * | 2016-05-30 | 2016-10-26 | 昆明理工大学 | 一种水渣基草酸盐化学键合材料及其用途 |
CN107098612A (zh) * | 2017-04-19 | 2017-08-29 | 昆明理工大学 | 一种镁系草酸盐水泥 |
CN107159112A (zh) * | 2017-05-26 | 2017-09-15 | 湖南农业大学 | 磁性复合吸附剂去除废水中四环素的方法 |
US20170369333A1 (en) * | 2016-06-23 | 2017-12-28 | Southern Methodist University | Graphene Oxide/Magnesium Oxide Nanocomposites as Superior Sorbents for Methylene Blue Removal from Aqueous Solutions |
CN108379666A (zh) * | 2018-03-05 | 2018-08-10 | 武汉理工大学 | 一种明胶微球/磷酸镁基骨水泥药物缓释载体及其制备方法 |
CN108793288A (zh) * | 2018-07-10 | 2018-11-13 | 韩瑞 | 一种可重复使用的污水处理材料 |
CN113244879A (zh) * | 2021-06-10 | 2021-08-13 | 昆明理工大学 | 铁质磷酸盐微球在处理含亚甲基蓝废水中的应用 |
-
2021
- 2021-09-06 CN CN202111040135.7A patent/CN113713753B/zh active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040121008A1 (en) * | 2001-03-16 | 2004-06-24 | Keiko Shiraishi | Process for producing sustained release preparation |
US20100258494A1 (en) * | 2005-09-12 | 2010-10-14 | Martin Freudenschuss | Packing Material for a Micro-Adsorption Column for Drying and/or Purification of Dissolved Organic or Biological Analytes and Micro-Adsorption Column and use thereof |
CN106045351A (zh) * | 2016-05-30 | 2016-10-26 | 昆明理工大学 | 一种水渣基草酸盐化学键合材料及其用途 |
US20170369333A1 (en) * | 2016-06-23 | 2017-12-28 | Southern Methodist University | Graphene Oxide/Magnesium Oxide Nanocomposites as Superior Sorbents for Methylene Blue Removal from Aqueous Solutions |
CN107098612A (zh) * | 2017-04-19 | 2017-08-29 | 昆明理工大学 | 一种镁系草酸盐水泥 |
CN107159112A (zh) * | 2017-05-26 | 2017-09-15 | 湖南农业大学 | 磁性复合吸附剂去除废水中四环素的方法 |
CN108379666A (zh) * | 2018-03-05 | 2018-08-10 | 武汉理工大学 | 一种明胶微球/磷酸镁基骨水泥药物缓释载体及其制备方法 |
CN108793288A (zh) * | 2018-07-10 | 2018-11-13 | 韩瑞 | 一种可重复使用的污水处理材料 |
CN113244879A (zh) * | 2021-06-10 | 2021-08-13 | 昆明理工大学 | 铁质磷酸盐微球在处理含亚甲基蓝废水中的应用 |
Also Published As
Publication number | Publication date |
---|---|
CN113713753B (zh) | 2023-07-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106423051A (zh) | 一种磁性活化水热生物炭微球的制备方法与应用 | |
CN104959151B (zh) | 一种硫化铟催化剂及其制备方法和应用 | |
CN107694523A (zh) | 一种高岭土复合材料及其制备方法 | |
CN106423103B (zh) | 一种具有吸附-催化降解抗生素功能的复合水凝胶的制备和应用 | |
CN106179215A (zh) | 水生植物生物炭‑碳纳米管复合材料的制备方法与应用 | |
CN109046466A (zh) | 一种ZIF-8衍生碳基材料负载CdS的光催化剂及其制备方法和应用 | |
CN108927172B (zh) | 一种负载金纳米粒子的磁性生物质碳材料的制备及其应用 | |
CN108543542A (zh) | 一种三维多孔复合光催化剂的制备方法及应用 | |
CN108203142A (zh) | 一种光催化复合电极及其制备方法、和在废水处理中的应用 | |
CN110316785A (zh) | 用于控制蓝藻水华的水体修复剂及其制备方法和富营养化水体修复方法 | |
CN113713753B (zh) | 一种草酸镁微球的制备方法及其应用 | |
CN106984306A (zh) | 一种具有抗菌及光催化双功能环境净化材料及其制备方法 | |
CN109692665A (zh) | 一种氮掺杂多孔炭去除抗生素吸附剂的制备方法 | |
CN109663590B (zh) | 一种以鸡蛋壳为反应器的光催化材料及其制备方法与应用 | |
CN102060371B (zh) | 一种用于污水处理的复合材料 | |
CN115739103A (zh) | 一种可见光光催化材料CuOx@BiVO4及其制备方法和应用 | |
CN110404521A (zh) | 选择性吸附亚甲基蓝的吸附剂及其制备方法和应用 | |
CN109926016A (zh) | 一种吸附材料、其制备方法及其应用 | |
CN109046241A (zh) | 一种基于蟹壳生物质炭油污吸附剂的制备方法 | |
CN114106838A (zh) | 一种以钙基膨润土为基底的大颗粒镉钝化材料及制备方法 | |
CN105642241A (zh) | 一种用于除去水中有害阴离子的生物质基吸附材料及其制备方法 | |
CN108745415B (zh) | 一种聚邻苯二胺修饰AgCl/g-C3N4复合光催化剂及其制备与应用 | |
CN108249584A (zh) | 污水处理剂及其制备方法 | |
CN109794291B (zh) | 一种Ti@BiOI-pDA@CA自清洁膜的仿生构建方法及其用途 | |
CN115318293B (zh) | 一种鸡粪无害化加工制备水处理催化剂的方法与应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Zhou Xintao Inventor after: Lan Xiong Inventor after: Luo Zhongqiu Inventor after: Luo Yunlong Inventor after: Zhao Xiaoteng Inventor after: Liu Qin Inventor after: Wei Yu Inventor before: Lan Xiong Inventor before: Zhou Xintao Inventor before: Luo Zhongqiu Inventor before: Luo Yunlong Inventor before: Zhao Xiaoteng Inventor before: Liu Qin Inventor before: Wei Yu |
|
GR01 | Patent grant | ||
GR01 | Patent grant |