CN1136259C - 含有改性沸石稳定剂的含卤聚合物混合物及其制备方法 - Google Patents
含有改性沸石稳定剂的含卤聚合物混合物及其制备方法 Download PDFInfo
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- CN1136259C CN1136259C CNB998107956A CN99810795A CN1136259C CN 1136259 C CN1136259 C CN 1136259C CN B998107956 A CNB998107956 A CN B998107956A CN 99810795 A CN99810795 A CN 99810795A CN 1136259 C CN1136259 C CN 1136259C
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- Prior art keywords
- zeolite
- mixture
- halogen
- containing polymers
- vinyl
- Prior art date
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 259
- 229910052736 halogen Inorganic materials 0.000 title claims abstract description 79
- 150000002367 halogens Chemical class 0.000 title claims abstract description 79
- 229920000642 polymer Polymers 0.000 title claims abstract description 58
- 150000001875 compounds Chemical class 0.000 title claims abstract description 28
- 239000003381 stabilizer Substances 0.000 title abstract description 36
- 239000002245 particle Substances 0.000 claims abstract description 64
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 57
- 238000000034 method Methods 0.000 claims abstract description 53
- 238000000576 coating method Methods 0.000 claims abstract description 21
- 239000011248 coating agent Substances 0.000 claims abstract description 20
- 239000010457 zeolite Substances 0.000 claims description 202
- 229910021536 Zeolite Inorganic materials 0.000 claims description 188
- 239000000203 mixture Substances 0.000 claims description 134
- 239000004801 Chlorinated PVC Substances 0.000 claims description 76
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 claims description 76
- -1 alkyl methacrylate Chemical compound 0.000 claims description 44
- 238000007669 thermal treatment Methods 0.000 claims description 28
- 239000004800 polyvinyl chloride Substances 0.000 claims description 22
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 20
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 18
- 238000012360 testing method Methods 0.000 claims description 16
- 239000011734 sodium Substances 0.000 claims description 15
- 239000000460 chlorine Substances 0.000 claims description 11
- 229910052801 chlorine Inorganic materials 0.000 claims description 11
- 238000007334 copolymerization reaction Methods 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- 239000004411 aluminium Substances 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 6
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 6
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Natural products OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 5
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 5
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000001530 fumaric acid Substances 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
- 239000004812 Fluorinated ethylene propylene Substances 0.000 claims description 3
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 3
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 claims description 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 3
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 claims description 3
- UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical class C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 claims description 3
- 229920009441 perflouroethylene propylene Polymers 0.000 claims description 3
- 239000005033 polyvinylidene chloride Substances 0.000 claims description 3
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 claims description 3
- 239000003469 silicate cement Substances 0.000 claims 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 238000009826 distribution Methods 0.000 abstract description 10
- 230000035939 shock Effects 0.000 abstract description 3
- 238000000137 annealing Methods 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 57
- 239000000243 solution Substances 0.000 description 52
- 229920005989 resin Polymers 0.000 description 28
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- 238000012545 processing Methods 0.000 description 16
- 208000005156 Dehydration Diseases 0.000 description 15
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 15
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 15
- 230000018044 dehydration Effects 0.000 description 15
- 238000006297 dehydration reaction Methods 0.000 description 15
- 229910052751 metal Inorganic materials 0.000 description 15
- 229910001388 sodium aluminate Inorganic materials 0.000 description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 14
- 229910000323 aluminium silicate Inorganic materials 0.000 description 14
- 239000002184 metal Substances 0.000 description 14
- 238000002360 preparation method Methods 0.000 description 14
- 229920006385 Geon Polymers 0.000 description 13
- 239000004115 Sodium Silicate Substances 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 13
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 13
- 229910052911 sodium silicate Inorganic materials 0.000 description 13
- 239000004709 Chlorinated polyethylene Substances 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000004698 Polyethylene Substances 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- 229920000573 polyethylene Polymers 0.000 description 10
- 239000000654 additive Substances 0.000 description 9
- 238000000465 moulding Methods 0.000 description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 8
- 239000006057 Non-nutritive feed additive Substances 0.000 description 8
- 230000008859 change Effects 0.000 description 8
- 239000012188 paraffin wax Substances 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 7
- 238000013019 agitation Methods 0.000 description 7
- 229910052788 barium Inorganic materials 0.000 description 7
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 7
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
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- 239000004408 titanium dioxide Substances 0.000 description 6
- 206010013786 Dry skin Diseases 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 5
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 5
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- VNPRJHMMOKDEDZ-UHFFFAOYSA-L 6-methylheptyl 2-[dibutyl-[2-(6-methylheptoxy)-2-oxoethyl]sulfanylstannyl]sulfanylacetate Chemical compound CC(C)CCCCCOC(=O)CS[Sn](CCCC)(CCCC)SCC(=O)OCCCCCC(C)C VNPRJHMMOKDEDZ-UHFFFAOYSA-L 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
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- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
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- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229910017090 AlO 2 Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 241000557626 Corvus corax Species 0.000 description 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical class OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 229910000003 Lead carbonate Inorganic materials 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- SUAKHGWARZSWIH-UHFFFAOYSA-N N,N‐diethylformamide Chemical compound CCN(CC)C=O SUAKHGWARZSWIH-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- HXRIYHZUZSPCBJ-UHFFFAOYSA-H S(=O)(=O)([O-])[O-].[Pb+2].[Si+4].S(=O)(=O)([O-])[O-].S(=O)(=O)([O-])[O-] Chemical compound S(=O)(=O)([O-])[O-].[Pb+2].[Si+4].S(=O)(=O)([O-])[O-].S(=O)(=O)([O-])[O-] HXRIYHZUZSPCBJ-UHFFFAOYSA-H 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- LUZSPGQEISANPO-UHFFFAOYSA-N butyltin Chemical compound CCCC[Sn] LUZSPGQEISANPO-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 230000021523 carboxylation Effects 0.000 description 1
- 238000006473 carboxylation reaction Methods 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- 125000004119 disulfanediyl group Chemical group *SS* 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- NHOGGUYTANYCGQ-UHFFFAOYSA-N ethenoxybenzene Chemical compound C=COC1=CC=CC=C1 NHOGGUYTANYCGQ-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- UACSZOWTRIJIFU-UHFFFAOYSA-N hydroxymethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCO UACSZOWTRIJIFU-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- LGRLWUINFJPLSH-UHFFFAOYSA-N methanide Chemical compound [CH3-] LGRLWUINFJPLSH-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- CSHCPECZJIEGJF-UHFFFAOYSA-N methyltin Chemical compound [Sn]C CSHCPECZJIEGJF-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- 229910052674 natrolite Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 238000009704 powder extrusion Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 238000007613 slurry method Methods 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 235000015870 tripotassium citrate Nutrition 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000012056 up-stream process Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229960000834 vinyl ether Drugs 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
Description
表I | ||||||
实施例 | 冷却剂 | 温度(℃) | 时间(分钟) | 吸水(%) | DTS(分钟) | %DTS增加 |
4 | 空气 | 840 | 15 | 0.8 | 30.5 | 118% |
5 | 空气 | 840 | 15 | 1.0 | 33.6 | 140% |
6 | 空气 | 790 | 20 | 1.1 | 28.0 | 100% |
7 | 空气 | 830 | 15 | 1.1 | 33.4 | 139% |
8 | 空气 | 785 | 20 | 1.2 | 30.5 | 118% |
9 | 空气 | 810 | 15 | 1.5 | 33.3 | 138% |
10 | CO2(s) | 840 | 15 | 0.4 | 29.4 | 110% |
11 | CO2(s) | 820 | 15 | 0.8 | 33.6 | 140% |
12 | CO2(s) | 830 | 15 | 0.9 | 33.0 | 136% |
13 | CO2(s) | 810 | 15 | 1.1 | 31.9 | 128% |
14 | CO2(s) | 820 | 15 | 1.5 | 34.0 | 143% |
15 | CO2(s) | 800 | 15 | 3.9 | 31.4 | 124% |
16 | CO2(s) | 840 | 10 | 4.4 | 33.3 | 138% |
17 | CO2(s) | 790 | 15 | 5.7 | 32.5 | 132% |
18 | CO2(s) | 820 | 10 | 6.7 | 31.0 | 121% |
19 | CO2(s) | 750 | 15 | 8.0 | 34.0 | 143% |
20 | CO2(s) | 770 | 15 | 10.5 | 34.5 | 146% |
表II | |||||||||
实施例# | 加入ZnCl2 | 加入C11H23COOH | 急骤热处理 | 粒径 | DTS分钟 | %DTS增加 | %吸水(48小时) | ||
平均直径(微米) | 中等直径(微米) | <90%(微米) | |||||||
21 | 是 | 是 | 是 | 1.4 | 1.1 | 2.9 | 28 | 100% | 0.6% |
22 | 是 | 是 | 不 | 1.7 | 1.2 | 2.5 | 38 | 171% | 12.3% |
23 | 是 | 不 | 是 | 1.5 | 1.1 | 2.6 | 27 | 93% | 1.0% |
24 | 是 | 不 | 不 | 1.4 | 1.1 | 2.5 | 35 | 150% | 14.1% |
25 | 不 | 是 | 是 | 2.1 | 1.4 | 5.6 | 25 | 79% | 0.5% |
26 | 不 | 是 | 不 | 1.9 | 1.6 | 4.1 | 32 | 129% | 10.9% |
27 | 不 | 不 | 是 | 11.8 | 6.9 | 5.6 | 27 | 93% | 0.8% |
28 | 不 | 不 | 不 | 27.3 | 14.9 | 91.9 | 30 | 114% | 2.1% |
29 | 是 | 是 | 是 | 1.4 | 1.1 | 2.2 | 27 | 93% | 1.0% |
30 | 不 | 不 | 不 | 1.9 | 1.5 | 4.7 | 31 | 121% | 12.0% |
31 | 商品沸石 | 商品沸石 | 是 | 4.3 | 4.0 | 7.1 | 22 | 57% | 2.8% |
32 | 商品沸石 | 商品沸石 | 不 | 3.9 | 3.6 | 6.5 | 34 | 143% | 16.2% |
表III | |||
混合物编号 | |||
描述 | 1a对比-TempRite3210化合物 | 1b含沸石13X的TempRite3210CPVC | 1c含沸石4A的TempRite3210CPVC |
沸石的添加量(phr) | 0.0 | 1.5 | 1.5 |
平均粒径(微米) | -- | 1.5 | 1.7 |
215℃时的DTS(分钟) | 10 | 21 | 20 |
刚果红试验(分钟) | 35 | 52 | 56 |
热变形温度(℃) | 104 | 105 | 104 |
切口悬臂梁冲击值(ft.lb./in.) | 2.9±0.2 | 2.0±0.4 | 2.7±0.2 |
拉伸强度(psi) | 8320 | 8370 | 8560 |
拉伸模量(Kpsi) | 340 | 362 | 368 |
拉伸伸长率(%) | 15 | 12 | 21 |
表IV | ||
混合物 | 对比样品 | 混合物1 |
沸石浓度(phr) | 0 | 2 |
<90%粒径(微米) | -- | 0.7 |
平均粒径(微米) | -- | 0.47 |
含水量(%) | -- | 8.5 |
切口悬臂梁冲击值(ft.lb./in.) | 2.2±0.2 | 1.6±0.1 |
拉伸强度(psi) | 8590±69 | 8700±43 |
拉伸模量(Kpsi) | 396±13 | 407±11 |
拉伸伸长率(%) | 13 | 13 |
HDT(℃) | 111±2 | 114±3 |
表V | |||||
混合物 | 2a | 2b | 2c | 2d | 2e |
沸石浓度(phr) | 0 | 1.5 | 1.5 | 3 | 1.5 |
<90%粒径(微米) | -- | 3.2 | 3.2 | 3.2 | 5.7 |
平均粒径(微米) | -- | 1.2 | 1 | 1 | 3.2 |
评价 | -- | 4-8微米的聚集物 | 4-10微米的聚集物 | 4微米的聚集物 | 未聚集 |
含水量(%) | 0.5 | 0.5 | 0.5 | 18% | |
切口悬臂梁冲击值(ft.lb./in.) | 1.8 | 1.2 | 1.2 | 0.9 | 0.8 |
拉伸强度(psi) | 8640 | 8800 | 8940 | 8960 | 8950 |
拉伸模量(Kpsi) | 408 | 416 | 426 | 427 | 409 |
拉伸伸长率(%) | 15 | 12.7 | 11.2 | 12 | 15 |
HDT(℃) | 117±0 | 119±0 | 118.5±5 | 120±0 | 117.5±5 |
刚果红试验(分钟) | 21.5 | 40.1 | 35.4 | 57.7 | 43.7 |
目测外观(3/4”两个) | 燃烧 | 好 | 好 | 好 | 表面潮湿 |
表VI | ||||
对比 | 1 | 2 | 3 | |
TempRite3107 CPVC(phr) | 100 | 100 | 100 | 100 |
沸石添加量(phr) | 0 | 2 | 2 | 2 |
<90%沸石粒径(微米) | -- | 0.6 | 0.6 | 0.6 |
沸石平均粒径(微米) | -- | 0.4 | 0.4 | 0.4 |
涂料 | -- | Mark 29233重量% | SF10037重量% | 无 |
沸石的含水量(%) | -- | 1.8 | 1.8 | 0 |
切口悬臂梁冲击值(ft.lb/in) | 9.5±0.8 | 9.6±0.9 | 10.5±0.2 | 10.2±0.5 |
拉伸强度(psi) | 7720±52 | 7430±18 | 6650±177 | 7510±62 |
拉伸模量(Kpsi) | 335±21 | 355±21 | 337±17 | 338±10 |
拉伸伸长率(%) | 5.2±0.2 | 4.7±0.1 | 4.7±0.1 | 5.1±0.2 |
HDT(℃) | 102 | 100 | 108 | 108 |
表VII | ||||||
对比 | 1 | 2 | 3 | 4 | 5 | |
TempRite3107CPVC(phr) | 100 | 100 | 100 | 100 | 100 | 100 |
沸石添加量(phr) | 0 | 2 | 2 | 2 | 2 | 2 |
<90%沸石粒径(微米) | -- | 0.6 | 0.6 | 4.6 | 4.6 | 4.6 |
沸石平均粒径(微米) | -- | 0.4 | 0.4 | 2.5 | 2.5 | 2.5 |
涂料 | -- | Mark29233重量% | 无 | 无 | SF10033重量% | Mark29233重量% |
沸石的含水量(%) | -- | 1.8 | 0 | 18 | 2.4 | 2.4 |
切口悬臂梁冲击值(ft.lb.in) | 6.9±0.9 | 7.4±0.5 | 7.3±0.5 | 2.5±0.2 | 2.7±0.1 | 2.1±0.1 |
DTS(%对比增加) | -- | 55% | 55% | 55% | 95% | 66% |
表VIII | ||
对比 | 混合物1 | |
沸石含量 | 0 | 4 |
<90%沸石粒径(微米) | -- | 5.7 |
平均粒径(微米) | -- | 3.2 |
含水量(%) | -- | 0 |
切口悬臂梁冲击值(ft.lb/in) | 2.6±0.1 | 1.8±0.4 |
VIIIT冲击值(in.lb/in) | 2.1±0.1 | 1.85±0.1 |
表IX | ||
对比 | 混合物1 | |
沸石含量 | 0 | 2 |
<90%沸石粒径(微米) | -- | 0.6 |
平均粒径(微米) | -- | 0.35 |
含水量(%) | -- | 0 |
VHIT冲击值(in.lb/in) | 2.43±0.18 | 2.45±0.13 |
表X | ||
材料 | 生产者 | 份数 |
PVC树脂(IV=0.92,Geon 130 EPF 76-TR) | Geon公司 | 100.0 |
硬脂酸钙 | Witco | 1.3 |
石蜡 | Witco | 1.0 |
氧化聚乙烯,AC 629 | 联合Signal | 0.1 |
丙烯酸类加工助剂,Paraloid K-120ND | Rohm & Hass | 1.25 |
丙烯酸类增强剂 | Rohm & Hass | 6.0 |
二氧化钛,Tioxide RFC-6 | Tioxide | 10.0 |
甲基(硫代乙醇酸)锡(IV)-基稳定剂,Mark 1900 | Witco | 0.5或1.5 |
急骤热处理沸石 | 实施例IV | 0.0、2.0或4.0 |
表XI | |
滚筒设置(温度) | 170℃ |
旋转速率(RPM) | 60 |
预热时间 | 3分钟(在5-10rpm下) |
混合物负荷 | 67克 |
表XII | |||||
实施例 | 锡稳定剂(份) | 急骤热处理的沸石(份) | DTS时间(分钟) | %DTS增加 | 转子状况 |
A | 0.5 | 0.0 | 14 | 0% | 干净 |
B | 0.5 | 2.0 | 24 | 71% | 干净 |
C | 0.5 | 4.0 | 29 | 107% | 干净 |
D | 1.5 | 0.0 | 29 | 0% | 干净 |
E | 1.5 | 2.0 | 43 | 48% | 干净 |
F | 1.5 | 4.0 | 60 | 107% | 干净 |
表XIII | ||
材料 | 生产者 | 份数 |
PVC树脂(IV=0.72) | Geon公司 | 100.0 |
硬脂酸钙 | Witco | 0.8 |
石蜡 | Witco | 0.8 |
氧化聚乙烯 | 联合Signal | 0.1 |
丙烯酸类加工助剂 | Rohm & Hass | 1.0 |
MBS增强剂 | Rohm & Hass | 5.0 |
二氧化钛 | Tioxide | 1.0 |
碳酸钙 | Pfizer | 3.0 |
甲基(硫代乙醇酸)锡(IV)-基稳定剂 | Witco | 0.5或1.0 |
急骤热处理的沸石(实施例IV) | 实施例IV | 0.0、2.0或4.0 |
表XIV | |
滚筒设置(温度) | 170℃ |
旋转速率(RPM) | 60 |
预热时间 | 3分钟(在5-10rpm下) |
混合物负荷 | 67克 |
表XV | |||||
实施例 | 锡稳定剂(份) | 急骤热处理的沸石(份) | DTS时间(分钟) | %DTS增加 | 转子状况 |
G | 0.5 | 0.0 | 17 | 0% | 发粘 |
H | 0.5 | 2.0 | 20 | 18% | 干净 |
I | 0.5 | 4.0 | 22 | 29% | 干净 |
J | 1.0 | 0.0 | 24 | 0% | 发粘 |
K | 1.0 | 2.0 | 25 | 4% | 干净 |
L | 1.0 | 4.0 | 31 | 29% | 干净 |
表XVI | |||
对比 | 1 | 2 | |
TempRite3104 CPVC | 100 | 100 | 100 |
沸石4A | -- | 3 | 3 |
%DTS增加 | 118% | 118% | |
梯段降落冲击值,于73°F(ft.lb) | 40± | 11±1 | 20±4 |
梯段降落冲击值,于32°F(ft.lb) | 10+1 | <6 | <6 |
轧钳压碎通道 | 3/3 | 3/3 | 3/3 |
压缩60%全部 | 3/3 | 2/3 | 3/3 |
管材外观 | 好 | 很差(有小突起) | 差 |
表XVII | |||
对比 | 含沸石13X的混合物 | ||
1/4”切口悬臂梁冲击值,23℃(ft.lb./in.) | 1.77 | 0.72 | |
1/8”拉伸强度,23℃(psi) | 7810 | 7460 | |
DTS-210℃35rpm,82克立方体 | DTS最小转矩(m-gm) | 2330 | 2330 |
DTS最小时间(分钟) | 6.4 | 12.8 | |
DTS温度(℃) | 231 | 233 |
Claims (23)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US09/151,407 US6306945B1 (en) | 1998-09-10 | 1998-09-10 | Halogen containing polymer compounds containing modified zeolite stabilizers |
US09/151,407 | 1998-09-10 |
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CN1317034A CN1317034A (zh) | 2001-10-10 |
CN1136259C true CN1136259C (zh) | 2004-01-28 |
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US (1) | US6306945B1 (zh) |
EP (1) | EP1115787B1 (zh) |
JP (1) | JP2002524642A (zh) |
CN (1) | CN1136259C (zh) |
AT (1) | ATE283313T1 (zh) |
AU (1) | AU761222B2 (zh) |
CA (1) | CA2341731C (zh) |
DE (1) | DE69922227T2 (zh) |
HK (1) | HK1043805B (zh) |
MX (1) | MXPA01002106A (zh) |
TW (1) | TWI224609B (zh) |
WO (1) | WO2000015709A1 (zh) |
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US6357678B1 (en) | 1999-10-29 | 2002-03-19 | Albermarle Corporation | Process for producing ultra finely-divided zeolite powder |
US6432380B1 (en) | 2000-09-08 | 2002-08-13 | Albemarle Corporation | Synthesis of aluminosilicates via cofeeding an alkali metal aluminate and sodium silicate and cofeeding apparatus therefor |
GB0221430D0 (en) * | 2002-09-16 | 2002-10-23 | Ineos Silicas Ltd | Powder coating compositions |
US20050112311A1 (en) * | 2003-11-26 | 2005-05-26 | Dalal Girish T. | CPVC compositions having good impact strength and heat stability, and smooth surfaces |
CA2611255A1 (en) * | 2005-06-09 | 2006-12-14 | Uponor Innovation Ab | An improved multilayer pipe |
US20090022462A1 (en) * | 2007-07-20 | 2009-01-22 | Polymer Products Company, Inc. | Fire resistant jacket composition for electrical coaxial and fiber optic cable |
CN112321977A (zh) * | 2020-10-12 | 2021-02-05 | 新疆兵团现代绿色氯碱化工工程研究中心(有限公司) | 一种高热稳定性cpvc组合物的制备方法 |
CN112794934B (zh) * | 2020-12-14 | 2023-06-09 | 中广核拓普(四川)新材料有限公司 | 低分子量聚氯乙烯、制备方法及护套料、制备方法 |
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- 1998-09-10 US US09/151,407 patent/US6306945B1/en not_active Expired - Lifetime
-
1999
- 1999-06-30 AT AT99932039T patent/ATE283313T1/de not_active IP Right Cessation
- 1999-06-30 AU AU48433/99A patent/AU761222B2/en not_active Ceased
- 1999-06-30 CN CNB998107956A patent/CN1136259C/zh not_active Expired - Fee Related
- 1999-06-30 MX MXPA01002106A patent/MXPA01002106A/es active IP Right Grant
- 1999-06-30 JP JP2000570242A patent/JP2002524642A/ja active Pending
- 1999-06-30 CA CA002341731A patent/CA2341731C/en not_active Expired - Fee Related
- 1999-06-30 DE DE69922227T patent/DE69922227T2/de not_active Expired - Lifetime
- 1999-06-30 WO PCT/US1999/014697 patent/WO2000015709A1/en active IP Right Grant
- 1999-06-30 EP EP99932039A patent/EP1115787B1/en not_active Expired - Lifetime
- 1999-07-26 TW TW088112613A patent/TWI224609B/zh not_active IP Right Cessation
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2002
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Also Published As
Publication number | Publication date |
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EP1115787B1 (en) | 2004-11-24 |
DE69922227D1 (de) | 2004-12-30 |
HK1043805B (zh) | 2004-12-10 |
ATE283313T1 (de) | 2004-12-15 |
MXPA01002106A (es) | 2002-08-20 |
CA2341731C (en) | 2009-08-25 |
AU4843399A (en) | 2000-04-03 |
WO2000015709A1 (en) | 2000-03-23 |
HK1043805A1 (en) | 2002-09-27 |
CN1317034A (zh) | 2001-10-10 |
US6306945B1 (en) | 2001-10-23 |
DE69922227T2 (de) | 2005-12-01 |
JP2002524642A (ja) | 2002-08-06 |
AU761222B2 (en) | 2003-05-29 |
CA2341731A1 (en) | 2000-03-23 |
TWI224609B (en) | 2004-12-01 |
EP1115787A1 (en) | 2001-07-18 |
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