CN1134398C - 低级脂肪醇的羰基化方法 - Google Patents

低级脂肪醇的羰基化方法 Download PDF

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Publication number
CN1134398C
CN1134398C CNB998161624A CN99816162A CN1134398C CN 1134398 C CN1134398 C CN 1134398C CN B998161624 A CNB998161624 A CN B998161624A CN 99816162 A CN99816162 A CN 99816162A CN 1134398 C CN1134398 C CN 1134398C
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China
Prior art keywords
catalyzer
weight
metal
carbonylation
methyl
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Expired - Fee Related
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CNB998161624A
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English (en)
Chinese (zh)
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CN1334789A (zh
Inventor
�ź㴫
J·R·策勒
A·H·辛莱顿
̹��
G·C·图斯丁
D·L·卡维尔
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Eastman Chemical Co
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Eastman Chemical Co
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB998161624A 1999-02-16 1999-12-30 低级脂肪醇的羰基化方法 Expired - Fee Related CN1134398C (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/250666 1999-02-16
US09/250,666 1999-02-16
US09/250,666 US6137000A (en) 1999-02-16 1999-02-16 Method for carbonylation of lower aliphatic alcohols using a supported iridium and lanthanide series catalyst

Publications (2)

Publication Number Publication Date
CN1334789A CN1334789A (zh) 2002-02-06
CN1134398C true CN1134398C (zh) 2004-01-14

Family

ID=22948679

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB998161624A Expired - Fee Related CN1134398C (zh) 1999-02-16 1999-12-30 低级脂肪醇的羰基化方法

Country Status (6)

Country Link
US (1) US6137000A (de)
EP (1) EP1153009B1 (de)
JP (1) JP2002537278A (de)
CN (1) CN1134398C (de)
DE (1) DE69915886T2 (de)
WO (1) WO2000048978A1 (de)

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US6159896A (en) * 1999-02-16 2000-12-12 Eastman Chemical Company Iridium catalyst for carbonylation of lower aliphatic alcohols
US6160155A (en) * 1999-04-29 2000-12-12 General Electric Company Method and catalyst system for producing aromatic carbonates
US7465823B2 (en) * 2004-03-17 2008-12-16 Celanese International Corporation Utilization of acetic acid reaction heat in other process plants
WO2011159268A1 (en) * 2010-06-14 2011-12-22 Celanese Internaltional Corporation Carbonylation process
CN103084214B (zh) * 2011-11-02 2014-11-05 中国石油化工股份有限公司 一种铱催化剂体系
CN103086868B (zh) * 2011-11-02 2015-06-17 中国石油化工股份有限公司 一种羰基化反应制备乙酸的方法
US9421522B2 (en) 2011-12-28 2016-08-23 Eastman Chemical Company Iridium catalysts for carbonylation
CN106140156A (zh) * 2015-04-20 2016-11-23 中国科学院大连化学物理研究所 一种活性炭负载的铑基催化剂及其制备方法和应用
CN106807367A (zh) * 2015-12-02 2017-06-09 中国科学院大连化学物理研究所 一种碳基材料负载的铱基催化剂及其制备方法和应用
CN106807368A (zh) * 2015-12-02 2017-06-09 中国科学院大连化学物理研究所 一种活性炭负载的铱基催化剂及其制备方法和应用
CN109759055B (zh) * 2017-11-09 2022-04-15 中国科学院大连化学物理研究所 一种活性炭负载的含硫铱基催化剂及其制备与应用
CN109759090B (zh) * 2017-11-09 2021-11-23 中国科学院大连化学物理研究所 活性炭负载的含硫化铁镍的铱基催化剂及其制备与应用
CN109759085B (zh) * 2017-11-09 2021-11-30 中国科学院大连化学物理研究所 一种活性炭负载的硫化铁基催化剂及其制备与应用
CN109759086B (zh) * 2017-11-09 2021-11-30 中国科学院大连化学物理研究所 含有助剂的活性炭负载的硫化铁基催化剂及其制备与应用
BR112021023959A2 (pt) * 2019-05-28 2022-02-01 Enerkem Inc Catalisador de carbonilação de metanol em fase de vapor
CN113893881B (zh) * 2021-10-12 2024-04-09 江苏索普化工股份有限公司 一种制备铱基催化剂的方法及其在催化甲醇羰基化上的应用

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US3717670A (en) * 1968-08-02 1973-02-20 Monsanto Co Production of carboxylic acids and esters
US3772380A (en) * 1970-03-12 1973-11-13 Monsanto Co Production of carboxylic acids and esters
US3689533A (en) * 1971-03-15 1972-09-05 Monsanto Co Production of carboxylic acids and esters
US5138093A (en) * 1975-03-10 1992-08-11 Eastman Kodak Company Process for preparing ethylidene diacetate
US4024052A (en) * 1975-11-20 1977-05-17 Uop Inc. Hydrocarbon conversion with an acidic multimetallic catalytic composite
FR2484404A1 (fr) * 1980-05-06 1981-12-18 Rhone Poulenc Ind Preparation d'acides carboxyliques par carbonylation
US4417077A (en) * 1980-10-01 1983-11-22 University Of Illinois Foundation Heterogeneous anionic transition metal catalysts
FR2507597B1 (fr) * 1981-06-12 1985-12-13 Rhone Poulenc Chim Base Procede de carbonylation de l'acetate de methyle
US4612387A (en) * 1982-01-04 1986-09-16 Air Products And Chemicals, Inc. Production of carboxylic acids and esters
EP0120631B1 (de) * 1983-03-25 1987-04-22 Texaco Development Corporation Verfahren zur Herstellung von Carbonsäuren durch Carbonylierung in Gegenwart eines Aktivkohlenkatalysators
US4625050A (en) * 1983-06-23 1986-11-25 Chevron Research Company Ether homologation to esters and alcohols using a heterogeneous sulfided catalyst
DE3323654A1 (de) * 1983-07-01 1985-01-03 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von essigsaeure und methylacetat
US5144068A (en) * 1984-05-03 1992-09-01 Hoechst Celanese Corporation Methanol carbonylation process
US4790963A (en) * 1984-08-20 1988-12-13 The Standard Oil Company Process for synthesis of esters from gaseous reactants containing organic hydroxy compounds and mixtures of hydrogen and carbon monoxide
EP0203286B1 (de) * 1985-03-27 1988-09-14 Hoechst Aktiengesellschaft Trägerkatalysator und Verfahren zur Herstellung von Monocarbonsäureanhydriden
DE3643894A1 (de) * 1986-12-22 1988-06-23 Degussa Rhodium-haltige organopolysiloxan-ammoniumverbindungen, verfahren zu ihrer herstellung und verwendung
US5185462A (en) * 1987-01-08 1993-02-09 Bp Chemicals Limited Production of carboxylic acids and esters thereof
GB8807284D0 (en) * 1988-03-26 1988-04-27 Bp Chem Int Ltd Chemical process
US5218140A (en) * 1988-08-02 1993-06-08 Union Carbide Chemicals & Plastics Technology Corporation Carbonylation reaction and catalyst therefor
GB9013116D0 (en) * 1990-06-12 1990-08-01 British Petroleum Co Plc Carbonylation of methanol
US5488143A (en) * 1992-06-30 1996-01-30 Korea Institute Of Science And Technology Processes for the carbonylation of methanol to form acetic acid, methyl acetate and acetic anhydride
GB9223170D0 (en) * 1992-11-05 1992-12-16 British Petroleum Co Plc Process for preparing carboxylic acids
US5510524A (en) * 1995-02-21 1996-04-23 Bp Chemicals Limited Process for the production of a carboxylic acid
US5696284A (en) * 1995-06-21 1997-12-09 Bp Chemicals Limited Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof
GB9517184D0 (en) * 1995-08-22 1995-10-25 Bp Chem Int Ltd Process
GB9521501D0 (en) * 1995-10-20 1995-12-20 Bp Chem Int Ltd Process
GB9626429D0 (en) * 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
US5900505A (en) * 1997-02-04 1999-05-04 Eastman Chemical Company Heterogeneous vapor phase carbonylation process
DE19824532A1 (de) * 1998-06-03 1999-12-09 Basf Ag Verfahren zur Herstellung von Schalenkatalysatoren für die katalytische Gasphasenoxidation von aromatischen Kohlenwasserstoffen und so erhältliche Katalysatoren

Also Published As

Publication number Publication date
EP1153009A1 (de) 2001-11-14
EP1153009B1 (de) 2004-03-24
WO2000048978A1 (en) 2000-08-24
US6137000A (en) 2000-10-24
DE69915886D1 (de) 2004-04-29
DE69915886T2 (de) 2005-01-27
JP2002537278A (ja) 2002-11-05
CN1334789A (zh) 2002-02-06

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Termination date: 20171230