CN113423497A - 用于锂离子电池的锂过渡金属氧化物的等离子体处理 - Google Patents
用于锂离子电池的锂过渡金属氧化物的等离子体处理 Download PDFInfo
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- CN113423497A CN113423497A CN201980092525.3A CN201980092525A CN113423497A CN 113423497 A CN113423497 A CN 113423497A CN 201980092525 A CN201980092525 A CN 201980092525A CN 113423497 A CN113423497 A CN 113423497A
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- lithium
- nmc
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- lithium ion
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- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 69
- 238000009832 plasma treatment Methods 0.000 title claims abstract description 60
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title abstract description 52
- 229910021437 lithium-transition metal oxide Inorganic materials 0.000 title description 5
- 238000000034 method Methods 0.000 claims abstract description 255
- 239000000843 powder Substances 0.000 claims abstract description 98
- 239000000463 material Substances 0.000 claims description 211
- 239000002245 particle Substances 0.000 claims description 150
- 239000002243 precursor Substances 0.000 claims description 130
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 87
- 229910052744 lithium Inorganic materials 0.000 claims description 87
- 239000007787 solid Substances 0.000 claims description 76
- 239000002019 doping agent Substances 0.000 claims description 64
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 60
- 150000003839 salts Chemical class 0.000 claims description 51
- 238000001354 calcination Methods 0.000 claims description 42
- 229910052751 metal Inorganic materials 0.000 claims description 39
- 239000002184 metal Substances 0.000 claims description 38
- 239000000203 mixture Substances 0.000 claims description 36
- 238000000975 co-precipitation Methods 0.000 claims description 30
- 239000002904 solvent Substances 0.000 claims description 30
- 229910052759 nickel Inorganic materials 0.000 claims description 29
- 239000002994 raw material Substances 0.000 claims description 28
- 229910052782 aluminium Inorganic materials 0.000 claims description 27
- 239000010941 cobalt Substances 0.000 claims description 23
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 23
- 229910017052 cobalt Inorganic materials 0.000 claims description 22
- 239000007788 liquid Substances 0.000 claims description 21
- 238000011282 treatment Methods 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 20
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 19
- 229910052719 titanium Inorganic materials 0.000 claims description 18
- 229910052726 zirconium Inorganic materials 0.000 claims description 18
- 150000002823 nitrates Chemical class 0.000 claims description 16
- 239000002002 slurry Substances 0.000 claims description 16
- 150000001242 acetic acid derivatives Chemical class 0.000 claims description 15
- 229910052749 magnesium Inorganic materials 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
- 239000000470 constituent Substances 0.000 claims description 12
- 238000001694 spray drying Methods 0.000 claims description 12
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 12
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 11
- 229910052804 chromium Inorganic materials 0.000 claims description 11
- 150000004679 hydroxides Chemical class 0.000 claims description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims description 11
- 229910052720 vanadium Inorganic materials 0.000 claims description 11
- 229910052725 zinc Inorganic materials 0.000 claims description 11
- 239000002105 nanoparticle Substances 0.000 claims description 9
- 229910052758 niobium Inorganic materials 0.000 claims description 9
- 229910052700 potassium Inorganic materials 0.000 claims description 9
- 229910052731 fluorine Inorganic materials 0.000 claims description 8
- 150000003841 chloride salts Chemical class 0.000 claims 4
- 238000004519 manufacturing process Methods 0.000 abstract description 26
- 238000012545 processing Methods 0.000 abstract description 21
- 239000006227 byproduct Substances 0.000 abstract description 4
- 230000002939 deleterious effect Effects 0.000 abstract 1
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- 239000000047 product Substances 0.000 description 36
- 210000004027 cell Anatomy 0.000 description 24
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- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 22
- 239000007789 gas Substances 0.000 description 21
- 239000011572 manganese Substances 0.000 description 19
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- 239000001301 oxygen Substances 0.000 description 14
- 229910052760 oxygen Inorganic materials 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 239000010936 titanium Substances 0.000 description 12
- 230000008901 benefit Effects 0.000 description 11
- 239000012071 phase Substances 0.000 description 11
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 10
- 229910052748 manganese Inorganic materials 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 229910002651 NO3 Inorganic materials 0.000 description 9
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 125000002091 cationic group Chemical group 0.000 description 9
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt(II) nitrate Inorganic materials [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 9
- 239000011777 magnesium Substances 0.000 description 9
- 239000002244 precipitate Substances 0.000 description 9
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- 239000010406 cathode material Substances 0.000 description 8
- 239000011651 chromium Substances 0.000 description 8
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 8
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 8
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 8
- 238000010791 quenching Methods 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 7
- 150000001805 chlorine compounds Chemical class 0.000 description 7
- 150000001868 cobalt Chemical class 0.000 description 7
- 229910052734 helium Inorganic materials 0.000 description 7
- 239000001307 helium Substances 0.000 description 7
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 7
- 229910003002 lithium salt Inorganic materials 0.000 description 7
- 159000000002 lithium salts Chemical class 0.000 description 7
- 150000002696 manganese Chemical class 0.000 description 7
- 230000000171 quenching effect Effects 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 229910001868 water Inorganic materials 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910013710 LiNixMnyCozO2 Inorganic materials 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
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- 150000002815 nickel Chemical class 0.000 description 6
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- 238000007873 sieving Methods 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 229910013410 LiNixCoyAlzO2 Inorganic materials 0.000 description 5
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 5
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- 229910014422 LiNi1/3Mn1/3Co1/3O2 Inorganic materials 0.000 description 3
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- 150000007942 carboxylates Chemical class 0.000 description 2
- ZBYYWKJVSFHYJL-UHFFFAOYSA-L cobalt(2+);diacetate;tetrahydrate Chemical compound O.O.O.O.[Co+2].CC([O-])=O.CC([O-])=O ZBYYWKJVSFHYJL-UHFFFAOYSA-L 0.000 description 2
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- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
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- C01G53/40—Complex oxides containing nickel and at least one other metal element
- C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
- C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
- C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
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- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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| PCT/US2019/067637 WO2020132343A1 (en) | 2018-12-20 | 2019-12-19 | Plasma processing of lithium transition metal oxides for lithium ion batteries |
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| US10987735B2 (en) | 2015-12-16 | 2021-04-27 | 6K Inc. | Spheroidal titanium metallic powders with custom microstructures |
| HUE065423T2 (hu) | 2015-12-16 | 2024-05-28 | 6K Inc | Eljárás szferoidális dehidrogénezett titánötvözet részecskék elõállítására |
| AU2019290663B2 (en) | 2018-06-19 | 2023-05-04 | 6K Inc. | Process for producing spheroidized powder from feedstock materials |
| CN112909238B (zh) | 2018-12-29 | 2022-04-22 | 宁德时代新能源科技股份有限公司 | 正极活性材料、正极极片及电化学储能装置 |
| CN110233247B (zh) * | 2018-12-29 | 2021-01-01 | 宁德时代新能源科技股份有限公司 | 正极活性材料、正极极片及电化学储能装置 |
| KR20240036705A (ko) | 2019-04-30 | 2024-03-20 | 6케이 인크. | 리튬 란타넘 지르코늄 산화물(llzo) 분말 |
| CA3134573A1 (en) | 2019-04-30 | 2020-11-05 | Sunil Bhalchandra BADWE | Mechanically alloyed powder feedstock |
| US12183912B2 (en) * | 2019-05-09 | 2024-12-31 | A123 Systems Llc | Methods and systems for dry surface doping of cathode materials |
| CN112786949B (zh) * | 2019-11-06 | 2022-06-07 | 宁德时代新能源科技股份有限公司 | 二次电池及含有该二次电池的电池模组、电池包、装置 |
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| US12469838B2 (en) | 2020-05-03 | 2025-11-11 | Sparkz Inc. | Systems and methods involving use of nitrogen-containing plasma to treat lithium iron phosphate cathodes |
| US12015142B2 (en) * | 2020-05-03 | 2024-06-18 | Venkatraman Prabhakar | Methods involving use of nitrogen-containing plasma to treat liquid electrolyte lithium-ion cathode materials |
| AU2021297476A1 (en) | 2020-06-25 | 2022-12-15 | 6K Inc. | Microcomposite alloy structure |
| AU2021349358A1 (en) | 2020-09-24 | 2023-02-09 | 6K Inc. | Systems, devices, and methods for starting plasma |
| EP4237174A1 (en) | 2020-10-30 | 2023-09-06 | 6K Inc. | Systems and methods for synthesis of spheroidized metal powders |
| EP4275239A4 (en) * | 2021-01-11 | 2024-12-18 | 6K Inc. | METHODS AND SYSTEMS FOR RECLAIMING LI-ION CATHODE MATERIALS USING MICROWAVE PLASMA TREATMENT |
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| AU2022246797A1 (en) | 2021-03-31 | 2023-10-05 | 6K Inc. | Systems and methods for additive manufacturing of metal nitride ceramics |
| WO2022269429A1 (en) * | 2021-06-25 | 2022-12-29 | Advanced Potash Technologies, Ltd. | Multi-step methods of making a high temperature multi-phase material and related materials, compositions and methods of use |
| WO2023229928A1 (en) | 2022-05-23 | 2023-11-30 | 6K Inc. | Microwave plasma apparatus and methods for processing materials using an interior liner |
| US12040162B2 (en) | 2022-06-09 | 2024-07-16 | 6K Inc. | Plasma apparatus and methods for processing feed material utilizing an upstream swirl module and composite gas flows |
| WO2024044498A1 (en) | 2022-08-25 | 2024-02-29 | 6K Inc. | Plasma apparatus and methods for processing feed material utilizing a powder ingress preventor (pip) |
| EP4608776A1 (en) * | 2022-10-28 | 2025-09-03 | The Regents of the University of California | Solid-state microwave route to cation-disordered rocksalt oxide and oxyfluoride cathodes |
| US12195338B2 (en) | 2022-12-15 | 2025-01-14 | 6K Inc. | Systems, methods, and device for pyrolysis of methane in a microwave plasma for hydrogen and structured carbon powder production |
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|---|---|---|---|---|
| US838072A (en) * | 1905-04-19 | 1906-12-11 | Benner Mfg Company | Baby-jumper. |
| JPH10172564A (ja) * | 1996-12-04 | 1998-06-26 | Mitsubishi Electric Corp | 活物質及びその製造方法並びにその活物質を用いたリチウムイオン二次電池 |
| JP2007238402A (ja) * | 2006-03-10 | 2007-09-20 | Chugai Ro Co Ltd | 粉体製造装置および粉体製造方法 |
| CN102782176B (zh) * | 2009-08-24 | 2014-10-15 | 应用材料公司 | 通过热喷涂原位沉积电池活性锂材料 |
| ES2599646T3 (es) * | 2010-02-23 | 2017-02-02 | Toda Kogyo Corporation | Polvo de partículas precursoras de sustancia activa para un electrodo activo, polvo en partículas de sustancia activa para un electrodo positivo y batería secundaria de electrolito no acuoso |
| US9899674B2 (en) * | 2013-02-28 | 2018-02-20 | Nissan Motor Co., Ltd. | Positive electrode active substance, positive electrode material, positive electrode, and non-aqueous electrolyte secondary battery |
| HUE056425T2 (hu) * | 2016-06-23 | 2022-02-28 | 6K Inc | Lítium-ion akkumulátor anyagok |
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2019
- 2019-12-19 US US16/720,926 patent/US20200203706A1/en not_active Abandoned
- 2019-12-19 EP EP19897917.1A patent/EP3897963A4/en active Pending
- 2019-12-19 JP JP2021535974A patent/JP2022514676A/ja active Pending
- 2019-12-19 CN CN201980092525.3A patent/CN113423497A/zh active Pending
- 2019-12-19 AU AU2019405960A patent/AU2019405960A1/en not_active Abandoned
- 2019-12-19 CA CA3122582A patent/CA3122582A1/en active Pending
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- 2019-12-19 WO PCT/US2019/067637 patent/WO2020132343A1/en not_active Ceased
- 2019-12-20 TW TW108147074A patent/TW202031596A/zh unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024026984A1 (zh) * | 2022-08-04 | 2024-02-08 | 广东邦普循环科技有限公司 | 一种正极材料的制备方法及其应用 |
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| TW202031596A (zh) | 2020-09-01 |
| EP3897963A4 (en) | 2022-09-14 |
| KR20210102427A (ko) | 2021-08-19 |
| WO2020132343A1 (en) | 2020-06-25 |
| EP3897963A1 (en) | 2021-10-27 |
| JP2022514676A (ja) | 2022-02-14 |
| AU2019405960A1 (en) | 2021-06-24 |
| US20200203706A1 (en) | 2020-06-25 |
| CA3122582A1 (en) | 2020-06-25 |
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