CN113169343B - 用作催化剂的碳纳米材料 - Google Patents
用作催化剂的碳纳米材料 Download PDFInfo
- Publication number
- CN113169343B CN113169343B CN201980076336.7A CN201980076336A CN113169343B CN 113169343 B CN113169343 B CN 113169343B CN 201980076336 A CN201980076336 A CN 201980076336A CN 113169343 B CN113169343 B CN 113169343B
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- precursor
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- heating
- nitrogen
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- 239000003054 catalyst Substances 0.000 title claims abstract description 67
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 33
- 239000002086 nanomaterial Substances 0.000 title claims abstract description 12
- 238000010438 heat treatment Methods 0.000 claims abstract description 28
- 239000002243 precursor Substances 0.000 claims abstract description 27
- 230000004913 activation Effects 0.000 claims abstract description 15
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 10
- 229920005610 lignin Polymers 0.000 claims abstract description 9
- 239000012670 alkaline solution Substances 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 32
- 239000000446 fuel Substances 0.000 claims description 14
- 239000000243 solution Substances 0.000 claims description 14
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 12
- 241000219495 Betulaceae Species 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 5
- 239000012298 atmosphere Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- 238000003801 milling Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 64
- 229910052757 nitrogen Inorganic materials 0.000 description 35
- 239000000463 material Substances 0.000 description 29
- 239000002023 wood Substances 0.000 description 21
- 230000000694 effects Effects 0.000 description 17
- 238000006722 reduction reaction Methods 0.000 description 16
- 238000001994 activation Methods 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
- 239000001301 oxygen Substances 0.000 description 12
- 229910052760 oxygen Inorganic materials 0.000 description 12
- 230000009467 reduction Effects 0.000 description 12
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 10
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 9
- 239000002028 Biomass Substances 0.000 description 7
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 7
- 239000003575 carbonaceous material Substances 0.000 description 7
- 238000002848 electrochemical method Methods 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 239000011148 porous material Substances 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 238000000197 pyrolysis Methods 0.000 description 6
- 238000001228 spectrum Methods 0.000 description 6
- 238000001237 Raman spectrum Methods 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000000976 ink Substances 0.000 description 5
- 230000010287 polarization Effects 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 238000001069 Raman spectroscopy Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000003610 charcoal Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000010411 electrocatalyst Substances 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 3
- 230000005284 excitation Effects 0.000 description 3
- 229910021389 graphene Inorganic materials 0.000 description 3
- 230000033001 locomotion Effects 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000012300 argon atmosphere Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000004146 energy storage Methods 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 2
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 2
- 229920000554 ionomer Polymers 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910021392 nanocarbon Inorganic materials 0.000 description 2
- 239000002077 nanosphere Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000013112 stability test Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000004627 transmission electron microscopy Methods 0.000 description 2
- 238000001075 voltammogram Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000219497 Alnus incana Species 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 239000012901 Milli-Q water Substances 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000002717 carbon nanostructure Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910021397 glassy carbon Inorganic materials 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000002064 nanoplatelet Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- ILVXOBCQQYKLDS-UHFFFAOYSA-N pyridine N-oxide Chemical compound [O-][N+]1=CC=CC=C1 ILVXOBCQQYKLDS-UHFFFAOYSA-N 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000012430 stability testing Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000009210 therapy by ultrasound Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- -1 transition metal salt Chemical class 0.000 description 1
- 238000004832 voltammetry Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/96—Carbon-based electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
- H01M4/9083—Catalytic material supported on carriers, e.g. powder carriers on carbon or graphite
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
- H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/82—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/85—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8892—Impregnation or coating of the catalyst layer, e.g. by an ionomer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Catalysts (AREA)
- Carbon And Carbon Compounds (AREA)
- Inert Electrodes (AREA)
Abstract
Description
S,m2/g | V总,cm3/g | L,nm | |
ERT-01 | 2435 | 1.27 | 1.36 |
ERT-01(二次热解后) | 2245 | 1.34 | 1.63 |
Claims (15)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB1819118.9A GB201819118D0 (en) | 2018-11-23 | 2018-11-23 | Carbon nanomaterial for use as a catalyst |
GB1819118.9 | 2018-11-23 | ||
PCT/EP2019/082243 WO2020104663A1 (en) | 2018-11-23 | 2019-11-22 | Carbon nanomaterial for use as a catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
CN113169343A CN113169343A (zh) | 2021-07-23 |
CN113169343B true CN113169343B (zh) | 2024-05-10 |
Family
ID=65024648
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201980076336.7A Active CN113169343B (zh) | 2018-11-23 | 2019-11-22 | 用作催化剂的碳纳米材料 |
Country Status (13)
Country | Link |
---|---|
US (1) | US20220017367A1 (zh) |
EP (1) | EP3867966B1 (zh) |
JP (1) | JP7397510B2 (zh) |
KR (1) | KR20210093999A (zh) |
CN (1) | CN113169343B (zh) |
BR (1) | BR112021009713A8 (zh) |
CA (1) | CA3120741A1 (zh) |
ES (1) | ES2949022T3 (zh) |
GB (1) | GB201819118D0 (zh) |
HR (1) | HRP20230817T1 (zh) |
PL (1) | PL3867966T3 (zh) |
WO (1) | WO2020104663A1 (zh) |
ZA (1) | ZA202104193B (zh) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113271758B (zh) * | 2021-04-19 | 2022-08-23 | 杭州电子科技大学 | 一种电磁波屏蔽透气多孔碳复合材料及其制备方法、应用 |
CN114984995B (zh) * | 2022-06-21 | 2023-11-21 | 长沙理工大学 | 通过表界面反应将木质素转化为多种异原子掺杂纳米碳基复合非金属催化剂的制备方法 |
CN115548357A (zh) * | 2022-10-17 | 2022-12-30 | 河南农业大学 | 一种锌空气电池空气电极催化剂及其制备方法和应用 |
Citations (8)
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JP2006331689A (ja) * | 2005-05-23 | 2006-12-07 | Gunma Univ | 炭素系燃料電池用触媒及びその製造方法並びに該触媒を用いた燃料電池 |
JP2010287316A (ja) * | 2009-06-09 | 2010-12-24 | Kyoto Univ | 燃料電池用電極触媒の製造方法 |
CN102639236A (zh) * | 2009-11-05 | 2012-08-15 | 国立大学法人群马大学 | 碳催化剂、其制备方法以及使用所述碳催化剂的电极和电池 |
CN102648050A (zh) * | 2009-12-07 | 2012-08-22 | 日清纺控股株式会社 | 用于负载催化剂的载体、负载有催化剂的负载体、电极和电池 |
JP2015220036A (ja) * | 2014-05-15 | 2015-12-07 | 国立大学法人 名古屋工業大学 | 空気極、金属空気電池、並びに窒素がドープされたカーボンナノチューブ及び空気極の製造方法 |
CN106564874A (zh) * | 2016-10-18 | 2017-04-19 | 宁波工程学院 | 一种木质素基二维碳纳米材料及其制备方法和应用 |
CN107046139A (zh) * | 2017-02-07 | 2017-08-15 | 辽宁大学 | 一种基于金属有机骨架的掺氮碳材料及其制备方法和应用 |
CN107583665A (zh) * | 2017-10-20 | 2018-01-16 | 南京大学 | 一种二维多孔氮掺杂碳纳米片的制法及其用途 |
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CN105449228B (zh) * | 2011-01-14 | 2018-02-16 | 昭和电工株式会社 | 燃料电池用电极催化剂的制造方法、燃料电池用电极催化剂和其用途 |
JP5931069B2 (ja) * | 2011-08-08 | 2016-06-08 | 昭和電工株式会社 | 酸素還元触媒の製造方法ならびにその用途 |
US9190222B1 (en) * | 2012-06-07 | 2015-11-17 | North Carolina Agricultural And Technical State University | Production of carbonaceous nano-fibrous materials with ultra-high specific surface area from alkali (Kraft) lignin |
JP6406540B2 (ja) | 2014-07-23 | 2018-10-17 | 大王製紙株式会社 | 炭素微粒子の製造方法 |
CN105728009B (zh) * | 2014-12-12 | 2018-06-26 | 中国科学院大连化学物理研究所 | 一种金属/氮/碳的分级多孔电催化剂及其制备和应用 |
CN108136453A (zh) | 2015-09-16 | 2018-06-08 | 斯威特沃特能源公司 | 衍生自经预处理的生物质的专用活性碳 |
CN106207197A (zh) * | 2016-07-08 | 2016-12-07 | 北京化工大学 | 一种采用头发制备双功能电催化剂的方法 |
JP7156598B2 (ja) | 2018-04-26 | 2022-10-19 | 株式会社名城ナノカーボン | カーボン材料 |
CN109012590B (zh) | 2018-08-24 | 2020-04-07 | 华南理工大学 | 一种木质素基过渡金属-氮掺杂碳材料及其制备和应用 |
-
2018
- 2018-11-23 GB GBGB1819118.9A patent/GB201819118D0/en not_active Ceased
-
2019
- 2019-11-22 CN CN201980076336.7A patent/CN113169343B/zh active Active
- 2019-11-22 KR KR1020217018984A patent/KR20210093999A/ko unknown
- 2019-11-22 US US17/295,663 patent/US20220017367A1/en active Pending
- 2019-11-22 JP JP2021529140A patent/JP7397510B2/ja active Active
- 2019-11-22 HR HRP20230817TT patent/HRP20230817T1/hr unknown
- 2019-11-22 BR BR112021009713A patent/BR112021009713A8/pt unknown
- 2019-11-22 EP EP19817161.3A patent/EP3867966B1/en active Active
- 2019-11-22 ES ES19817161T patent/ES2949022T3/es active Active
- 2019-11-22 CA CA3120741A patent/CA3120741A1/en active Pending
- 2019-11-22 PL PL19817161.3T patent/PL3867966T3/pl unknown
- 2019-11-22 WO PCT/EP2019/082243 patent/WO2020104663A1/en unknown
-
2021
- 2021-06-18 ZA ZA2021/04193A patent/ZA202104193B/en unknown
Patent Citations (8)
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KR20210093999A (ko) | 2021-07-28 |
ES2949022T3 (es) | 2023-09-25 |
CA3120741A1 (en) | 2020-05-28 |
HRP20230817T1 (hr) | 2023-11-10 |
EP3867966A1 (en) | 2021-08-25 |
BR112021009713A2 (pt) | 2021-08-17 |
PL3867966T3 (pl) | 2024-04-22 |
US20220017367A1 (en) | 2022-01-20 |
WO2020104663A1 (en) | 2020-05-28 |
JP2022509166A (ja) | 2022-01-20 |
EP3867966C0 (en) | 2023-06-28 |
GB201819118D0 (en) | 2019-01-09 |
CN113169343A (zh) | 2021-07-23 |
BR112021009713A8 (pt) | 2023-04-11 |
ZA202104193B (en) | 2022-08-31 |
JP7397510B2 (ja) | 2023-12-13 |
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