CN113135803A - Disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer - Google Patents

Disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer Download PDF

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Publication number
CN113135803A
CN113135803A CN202110638296.XA CN202110638296A CN113135803A CN 113135803 A CN113135803 A CN 113135803A CN 202110638296 A CN202110638296 A CN 202110638296A CN 113135803 A CN113135803 A CN 113135803A
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parts
preventing
disease
insect
fertilizer
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师进
肖璐
倪宝龙
杨义刚
杨姗姗
潘耀明
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Shenzhen Green Agricultural Biotechnology Co ltd
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Shenzhen Green Agricultural Biotechnology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C11/00Other nitrogenous fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Sciences (AREA)
  • Plant Pathology (AREA)
  • Fertilizers (AREA)

Abstract

The invention provides a disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer, and belongs to the technical field of agricultural fertilizers. The invention is prepared by taking microbial flora, a nitrogen source, a carbon source, trace elements, sugar alcohol silicon, citric acid, compound amino acid, mineral potassium fulvate, a coupling agent, protamine, alkaloid, tea saponin and purified water as raw materials. The product obtained by the invention has high bacteria content, nitrogen fixation, phosphorus and potassium dissolution, growth promotion and obvious effect, and can provide nutrition for plants, improve soil, prevent diseases and prevent insects. The product of the invention can be applied to the water and fertilizer integrated sprinkling irrigation, drip irrigation, irrigation and spraying of modern agriculture, has obvious effects of soil improvement, growth promotion, disease prevention and insect prevention, can prevent insect pests or kill larvae when the larvae are produced, can achieve the effect of getting twice the result with half the effort with extremely small dosage, and is the best choice for producing green, environment-friendly and organic agricultural products.

Description

Disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer
Technical Field
The invention belongs to the technical field of agricultural fertilizers, relates to a water-soluble fertilizer, and particularly relates to a disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer.
Background
The water-soluble fertilizer is widely used in agricultural production, and is an indispensable agricultural preparation in modern agricultural sprinkling irrigation, drip irrigation and micro-irrigation systems, the existing water-soluble fertilizer mainly contains chemical water-soluble fertilizers of nitrogen, phosphorus, potassium and trace elements, the chemical fertilizer is used, the yield of agricultural production is improved, the normal life of people is met, and the contribution of non-wear and non-extinguishment is made for eating, but soil hardening, serious pollution, aggravation of plant diseases and insect pests, reduction of quality of agricultural products, fragrance of grains, sweetness of fruits and insecurity of eating are caused by overuse of the chemical fertilizer, so that the country makes a decision for realizing zero increase of the fertilizer in 2020, realizes green planting, organic planting, reduces the consumption of pesticides and fertilizers and improves food safety, and is a major subject in front of agricultural science and technology personnel.
Chinese patent CN201911268862.1 discloses a compound microorganism organic water-soluble fertilizer and a preparation method thereof, wherein the selected bacillus subtilis, trichoderma harzianum and bacillus polymyxa have obvious effects of preventing and treating crop diseases, but the insect prevention and insect expelling effects are not obvious; chinese patent CN201810538802.6 discloses an organic water-soluble fertilizer with insect-expelling function and a preparation method thereof, which also takes chemical fertilizers of ammonium nitrate, urea, monopotassium phosphate and potassium hydroxide as main raw materials, and no microbial preparation participates, so that the organic water-soluble fertilizer improves soil and has insignificant yield-increasing effect; CN201610765608.2 discloses an organic water-soluble fertilizer and a preparation method thereof, which has certain effects of improving soil and preventing and treating plant diseases, but the insect prevention and expelling effect is not obvious; CN201210016659.7 discloses an amino acid microorganism organic water-soluble fertilizer and a preparation method thereof, the patent adopts mycelium of trametes hirsuta, mycelium of poplar, mycelium of Clontopodium hybridum, mycelium of sulfur bacteria, calcium sulfate, chitin and leaf humus as main raw materials, and secondary soaking extraction is adopted, so that the fertilizer has good environmental protection ecological effect, but has poor effects of preventing plant diseases and insect pests, promoting plant growth, improving crop yield and great popularization difficulty.
The disclosed technologies provide a new idea for the development of water-soluble fertilizers, but some have the effect of promoting yield increase, but have no environmental protection and insect prevention effect, some have the effect of expelling insects, but the effect of promoting yield increase is not obvious, some have the effect of environmental protection, but the effect of expelling insects and increasing yield is not obvious, and the technologies need to be continuously improved and continuously innovated.
Disclosure of Invention
The invention aims to provide a disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer. On the basis of the prior art, the invention provides a novel water-soluble fertilizer which can provide nutrition for plants, improve soil, prevent diseases and prevent insects, mainly changes the treatment as the main treatment in the past and the prevention as the main treatment, can eliminate the diseases and the insects in a bud state with the least dosage, can reduce labor cost, improve the agricultural production benefit, and realize the yield increase, the income increase, the environmental protection and the sustainable development of the agricultural production.
The invention provides a disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer which is prepared from the following raw materials by the process:
the raw materials are proportioned according to parts by weight:
2-5 parts of microbial flora; 1-10 parts of a nitrogen source; 1-10 parts of a carbon source; 1-2 parts of trace elements; 1-5 parts of sugar alcohol silicon; 2-5 parts of citric acid; 5-10 parts of compound amino acid; 5-10 parts of mineral source potassium fulvate; 2-5 parts of a coupling agent; 3-5 parts of protamine; 0.5-2 parts of alkaloid; 0.5-2 parts of tea saponin; 50-60 parts of purified water.
The microbial flora is at least two of bacillus natto, bacillus subtilis, bacillus mucilaginosus, bacillus megaterium, bacillus licheniformis and bacillus polymyxa.
The nitrogen source is a chelated liquid nitrogen fertilizer.
The carbon source is at least one of white sugar, brown sugar and glucose.
The trace elements are at least one of zinc-iron-boron-manganese fertilizer, copper sulfate and ammonium molybdate.
The coupling agent is at least one of chitosan oligosaccharide and alginic acid.
The alkaloid is at least one of nicotine, berberine and matrine.
The preparation process comprises the following steps: adding microbial flora, a nitrogen source, a carbon source, trace elements, sugar alcohol silicon, compound amino acid, mineral source potassium fulvate, a coupling agent and protamine into purified water, then adding the purified water into an aerobic fermentation tank, adjusting the pH value to 5-6.5 by using citric acid, keeping the temperature to be 35-38 ℃, injecting aerobic compressed air, carrying out gas stirring, fermenting for 25-30 days, then adding alkaloid and tea saponin, and homogenizing by using a high-speed homogenizer to obtain the disease-preventing and insect-preventing environment-friendly microbial water-soluble fertilizer.
The pest and disease prevention environment-friendly microbial water-soluble fertilizer provided by the invention provides sufficient nitrogen sources, carbon sources and required nutrients for microbial flora, the propagation time is long, the obtained product has high bacterial content, the microbial flora mainly comprises bacillus natto, bacillus subtilis, bacillus mucilaginosus, bacillus megaterium and bacillus licheniformis, the nitrogen fixation, phosphorus removal, potassium removal and growth promotion effects are obvious, and a large amount of compound amino acid can be generated through full fermentation, so that the fertilizer efficiency of the product is improved. The invention adds certain microelements and sugar alcohol silicon, and can also prevent and treat diseases of crops. The added compound amino acid, chitosan oligosaccharide and alginic acid are not only coupling agents, but also high-efficiency organic fertilizers, and can also improve the fertilizer efficiency of the products. The product of the invention can be applied to the water and fertilizer integrated sprinkling irrigation, drip irrigation, irrigation and spraying of modern agriculture, has obvious effects of soil improvement, growth promotion, disease prevention and insect prevention, can prevent insect pests or kill larvae when the larvae are produced, can achieve the effect of getting twice the result with half the effort with extremely small dosage, and is the best choice for producing green, environment-friendly and organic agricultural products.
Detailed Description
The invention further discloses a disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer by specific examples.
Example one
1 part of bacillus subtilis, 1 part of bacillus mucilaginosus, 1 part of chelated liquid nitrogen fertilizer, 5 parts of white sugar, 5 parts of brown sugar, 2 parts of zinc-iron-boron-manganese fertilizer, 10 parts of compound amino acid, 10 parts of mineral potassium fulvate, 2 parts of chitosan oligosaccharide, 3 parts of alginic acid and 5 parts of protamine are added into 50 parts of purified water, then the mixture is added into an aerobic fermentation tank, the pH value is adjusted to be 5-6.5 by citric acid, the temperature is kept to be 35-38 ℃, aerobic compressed air is injected from the bottom, gas stirring is carried out, fermentation is carried out for 25 days, then 0.5 part of nicotine and 0.5 part of tea saponin are added, and the disease-preventing, insect-preventing and environment-friendly microbial water-soluble fertilizer is obtained after homogenization by a high-speed homogenizer.
Example two
2 parts of bacillus natto, 3 parts of bacillus megatherium, 10 parts of chelated liquid nitrogen fertilizer, 0.5 part of glucose, 0.5 part of brown sugar, 1 part of zinc-iron-boron-manganese fertilizer, 1 part of copper sulfate, 5 parts of sugar alcohol silicon, 5 parts of compound amino acid, 15 parts of mineral potassium fulvate, 2 parts of chitosan oligosaccharide and 3 parts of protamine are added into 60 parts of purified water, then the mixture is added into an aerobic fermentation tank, the pH value is adjusted to be 5-6.5 by citric acid, the temperature is kept to be 35-38 ℃, aerobic compressed air is injected from the bottom for gas stirring and fermentation for 30 days, then 2 parts of nicotine and 2 parts of tea saponin are added, and the disease-preventing, environment-friendly and insect-preventing microbial water-soluble fertilizer is obtained after homogenization by a high-speed homogenizer.
EXAMPLE III
1 part of bacillus mucilaginosus, 1.5 parts of bacillus megaterium, 5 parts of chelated liquid nitrogen fertilizer, 5 parts of brown sugar, 1 part of zinc-iron-boron-manganese fertilizer, 1 part of ammonium molybdate, 2.5 parts of sugar alcohol silicon, 7 parts of compound amino acid, 7 parts of mineral potassium fulvate, 2.5 parts of chitosan oligosaccharide and 4 parts of protamine are added into 60 parts of purified water and then added into an aerobic fermentation tank, the pH value is adjusted to be 5-6.5 by citric acid, the temperature is kept to be 35-38 ℃, aerobic compressed air is injected from the bottom for gas stirring and fermentation for 28 days, then 1 part of nicotine and 1 part of tea saponin are added, and the disease-preventing, environment-friendly and insect-preventing microbial water-soluble fertilizer is obtained after homogenization by a high-speed homogenizer.
Example four
1 part of bacillus subtilis, 1 part of bacillus licheniformis, 5 parts of chelated liquid nitrogen fertilizer, 8 parts of brown sugar, 2 parts of zinc-iron-boron-manganese fertilizer, 3 parts of sugar alcohol silicon, 8 parts of compound amino acid, 8 parts of mineral potassium fulvate, 2 parts of alginic acid and 3 parts of protamine are added into 55 parts of purified water, then the mixture is added into an aerobic fermentation tank, the pH value is adjusted to be 5-6.5 by citric acid, the temperature is kept to be 35-38 ℃, aerobic compressed air is injected from the bottom for gas stirring, the mixture is fermented for 26 days, then 1.5 parts of nicotine and 1.5 parts of tea saponin are added, and the mixture is homogenized by a high-speed homogenizer to obtain the disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer.
EXAMPLE five
Adding 2 parts of bacillus amyloliquefaciens, 2 parts of bacillus licheniformis, 8 parts of chelating liquid nitrogen fertilizer, 2 parts of brown sugar, 2 parts of glucose, 1 part of zinc-iron-boron-manganese fertilizer, 1 part of ammonium molybdate, 4 parts of sugar alcohol silicon, 7 parts of compound amino acid, 6 parts of mineral potassium fulvate, 4 parts of chitosan oligosaccharide and 5 parts of protamine into 52 parts of purified water, adding the mixture into an aerobic fermentation tank, adjusting the pH value to 5-6.5 by using citric acid, keeping the temperature to 35-38 ℃, injecting aerobic compressed air from the bottom, carrying out gas stirring, fermenting for 27 days, adding 1 part of berberine and 1.5 parts of tea saponin, and homogenizing by a high-speed homogenizer to obtain the disease-preventing environment-friendly insect-preventing microbial water-soluble fertilizer.
EXAMPLE six
2 parts of bacillus megatherium, 3 parts of bacillus polymyxa, 2 parts of chelating liquid nitrogen fertilizer, 5 parts of brown sugar, 4 parts of glucose, 1 part of ammonium molybdate, 1 part of copper sulfate, 2 parts of sugar alcohol silicon, 6 parts of compound amino acid, 6 parts of mineral potassium fulvate, 3 parts of chitosan oligosaccharide and 3 parts of protamine are added into 58 parts of purified water, then the mixture is added into an aerobic fermentation tank, the pH value is adjusted to be 5-6.5 by citric acid, the temperature is kept to be 35-38 ℃, aerobic compressed air is injected from the bottom for gas stirring and fermentation for 28 days, then 1 part of nicotine, 1 part of matrine and 1 part of tea saponin are added, and the mixture is homogenized by a high-speed homogenizer to obtain the disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer.
EXAMPLE seven
Adding 3 parts of bacillus megatherium, 2 parts of bacillus subtilis, 5 parts of chelating liquid nitrogen fertilizer, 1 part of brown sugar, 2 parts of glucose, 0.5 part of calcium magnesium zinc iron boron manganese fertilizer, 0.5 part of ammonium molybdate, 1 part of copper sulfate, 5 parts of sugar alcohol silicon, 10 parts of compound amino acid, 6 parts of mineral source potassium fulvate, 5 parts of alginic acid and 4 parts of protamine into 60 parts of purified water, adding the mixture into an aerobic fermentation tank, adjusting the pH value to be 5-6.5 by using citric acid, keeping the temperature to be 35-38 ℃, injecting aerobic compressed air from the bottom, carrying out gas stirring, fermenting for 28 days, adding 1.5 parts of matrine and 1 part of tea saponin, and homogenizing by a high-speed homogenizer to obtain the disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer.
Example eight
Adding 1 part of bacillus amyloliquefaciens, 1 part of bacillus subtilis, 5 parts of chelating liquid nitrogen fertilizer, 2 parts of brown sugar, 3 parts of glucose, 1 part of calcium-magnesium-zinc-iron-boron-manganese fertilizer, 0.5 part of ammonium molybdate, 0.5 part of copper sulfate, 3 parts of sugar alcohol silicon, 5 parts of compound amino acid, 8 parts of mineral source potassium fulvate, 4 parts of alginic acid and 5 parts of protamine into 50 parts of purified water, adding the mixture into an aerobic fermentation tank, adjusting the pH value to be 5-6.5 by using citric acid, keeping the temperature to be 35-38 ℃, injecting aerobic compressed air from the bottom, carrying out gas stirring, fermenting for 25 days, then adding 1 part of nicotine and 2 parts of tea saponin, and homogenizing by a high-speed homogenizer to obtain the disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer.
The using effect of the product prepared by the embodiment is as follows:
six treatments are carried out on the prepared disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer in greenhouse cucumbers in Guanying town Lijiazhuang village in Ming district of Deng city, Gansu province, and three repeated drip irrigation tests (contrast is Strobile major element water-soluble fertilizer N + K)2O+P2O5≧ 60), the fertilizer applied includes base fertilizer and additional fertilizer of whole production cycle, and its statistical effect is as follows:
Figure DEST_PATH_IMAGE002
the prepared disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer is subjected to six treatments and three repeated drip irrigation tests (contrast is major element water-soluble fertilizer N + K of Strobilanty Studiana) on greenhouse eggplants in gardens and villages of Shahe towns in Yangzu city of Zhangye city in Gansu province2O+P2O5≧ 60), the fertilizer applied includes base fertilizer and additional fertilizer of whole production cycle, and its statistical effect is as follows:
Figure DEST_PATH_IMAGE004
the prepared disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer is subjected to six treatments and three repeated drip irrigation tests (contrast is major element water-soluble fertilizer N + K of Strobilantic acid of Strongan town of Shubizhou province in Zhangye city of Gansu province)2O+P2O5≧ 60), the fertilizer applied includes base fertilizer and additional fertilizer of whole production cycle, and its statistical effect is as follows:
Figure 456249DEST_PATH_IMAGE006
the prepared disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer is subjected to six treatments and three repeated drip irrigation tests (contrast is major element water-soluble fertilizer N + K of Strobile)2O+P2O5≧ 60), the fertilizer applied includes base fertilizer and additional fertilizer of whole production cycle, and its statistical effect is as follows:
Figure DEST_PATH_IMAGE008
the prepared disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer is subjected to six treatments and three repeated drip irrigation tests (contrast is Stricty major element water-soluble fertilizer N + K) on field tomatoes in village of Mojia village three society of Shanzhai province in Gansu province, Zhangye city2O+P2O5≧ 60), the fertilizer applied includes base fertilizer and additional fertilizer of whole production cycle, and its statistical effect is as follows:
Figure DEST_PATH_IMAGE010
six treatments are carried out on the prepared disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer on the sweet melon in the greenhouse of Gaoqiaomi village in Luoman town of Tianshui city, Gansu province, three repeated drip irrigation tests (the contrast is N18; K18; P18, and a compound fertilizer with 54 percent of total nutrient content), the applied fertilizer comprises base fertilizer and additional fertilizer in the whole production period, and the statistical effect is as follows:
Figure DEST_PATH_IMAGE012
the prepared disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer is subjected to six treatments and three repeated drip irrigation tests (contrast is major element water-soluble fertilizer N + K of Shidanli, N + K) on greenhouse peppers in Mengdankang village in Lumen county of Wushan city of Tianshui city, Gansu province2O+P2O5≧ 60), the fertilizer applied includes base fertilizer and additional fertilizer of whole production cycle, and its statistical effect is as follows:
Figure DEST_PATH_IMAGE014

Claims (7)

1. the disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer is prepared from the following raw materials by the process:
the raw materials are proportioned according to parts by weight:
2-5 parts of microbial flora; 1-10 parts of a nitrogen source; 1-10 parts of a carbon source; 1-2 parts of trace elements; 1-5 parts of sugar alcohol silicon; 2-5 parts of citric acid; 5-10 parts of compound amino acid; 5-10 parts of mineral source potassium fulvate; 2-5 parts of a coupling agent; 3-5 parts of protamine; 0.5-2 parts of alkaloid; 0.5-2 parts of tea saponin; 50-60 parts of purified water;
the preparation process comprises the following steps: adding microbial flora, a nitrogen source, a carbon source, trace elements, sugar alcohol silicon, compound amino acid, mineral source potassium fulvate, a coupling agent and protamine into purified water, then adding the purified water into an aerobic fermentation tank, adjusting the pH value to 5-6.5 by using citric acid, keeping the temperature to be 35-38 ℃, injecting aerobic compressed air, carrying out gas stirring, fermenting for 25-30 days, then adding alkaloid and tea saponin, and homogenizing by using a high-speed homogenizer to obtain the disease-preventing and insect-preventing environment-friendly microbial water-soluble fertilizer.
2. The disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer as claimed in claim 1, which is characterized in that: the microbial flora is at least two of bacillus natto, bacillus subtilis, bacillus mucilaginosus, bacillus megaterium, bacillus licheniformis and bacillus polymyxa.
3. The disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer as claimed in claim 1, which is characterized in that: the nitrogen source is a chelated liquid nitrogen fertilizer.
4. The disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer as claimed in claim 1, which is characterized in that: the carbon source is at least one of white sugar, brown sugar and glucose.
5. The disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer as claimed in claim 1, which is characterized in that: the trace elements are at least one of zinc-iron-boron-manganese fertilizer, copper sulfate and ammonium molybdate.
6. The disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer as claimed in claim 1, which is characterized in that: the coupling agent is at least one of chitosan oligosaccharide and alginic acid.
7. The disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer as claimed in claim 1, which is characterized in that: the alkaloid is at least one of nicotine, berberine and matrine.
CN202110638296.XA 2021-06-08 2021-06-08 Disease-preventing insect-preventing environment-friendly microbial water-soluble fertilizer Pending CN113135803A (en)

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CN113773154A (en) * 2021-09-14 2021-12-10 深圳市绿色农业生物科技有限公司 Disease-preventing insect-preventing environment-friendly microbial organic water-soluble fertilizer
CN113773151A (en) * 2021-09-14 2021-12-10 深圳市绿色农业生物科技有限公司 Alginic acid and humic acid combined disease-preventing insect-preventing biological organic-inorganic compound fertilizer
CN113773138A (en) * 2021-09-14 2021-12-10 深圳市绿色农业生物科技有限公司 Disease-preventing and insect-preventing compound microbial agent combining amino acid and humic acid

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