CN113018515A - 一种可降解锌基合金骨骼固定系统材料及其制备方法 - Google Patents
一种可降解锌基合金骨骼固定系统材料及其制备方法 Download PDFInfo
- Publication number
- CN113018515A CN113018515A CN202110242100.5A CN202110242100A CN113018515A CN 113018515 A CN113018515 A CN 113018515A CN 202110242100 A CN202110242100 A CN 202110242100A CN 113018515 A CN113018515 A CN 113018515A
- Authority
- CN
- China
- Prior art keywords
- zinc
- based alloy
- plate
- casting
- fixing system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011701 zinc Substances 0.000 title claims abstract description 65
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 61
- 239000000956 alloy Substances 0.000 title claims abstract description 59
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 55
- 239000000463 material Substances 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 210000000988 bone and bone Anatomy 0.000 title abstract description 15
- 238000005266 casting Methods 0.000 claims abstract description 44
- 238000010438 heat treatment Methods 0.000 claims abstract description 33
- 239000002994 raw material Substances 0.000 claims abstract description 29
- 238000000265 homogenisation Methods 0.000 claims abstract description 20
- 238000005242 forging Methods 0.000 claims abstract description 19
- 238000004140 cleaning Methods 0.000 claims abstract description 18
- 238000002844 melting Methods 0.000 claims abstract description 10
- 230000008018 melting Effects 0.000 claims abstract description 10
- 238000005096 rolling process Methods 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims description 21
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- 229910002804 graphite Inorganic materials 0.000 claims description 10
- 239000010439 graphite Substances 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000004519 grease Substances 0.000 claims description 8
- 229910052786 argon Inorganic materials 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 4
- 239000010410 layer Substances 0.000 claims description 4
- 238000003801 milling Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000011282 treatment Methods 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 2
- 238000009497 press forging Methods 0.000 claims description 2
- 239000002344 surface layer Substances 0.000 claims description 2
- 230000015556 catabolic process Effects 0.000 abstract description 3
- 238000006731 degradation reaction Methods 0.000 abstract description 3
- 208000010392 Bone Fractures Diseases 0.000 abstract 1
- 238000003723 Smelting Methods 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 229910052749 magnesium Inorganic materials 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000010949 copper Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- PGTXKIZLOWULDJ-UHFFFAOYSA-N [Mg].[Zn] Chemical compound [Mg].[Zn] PGTXKIZLOWULDJ-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 230000006698 induction Effects 0.000 description 4
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 208000027418 Wounds and injury Diseases 0.000 description 3
- 229910001297 Zn alloy Inorganic materials 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 229910001069 Ti alloy Inorganic materials 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000007857 degradation product Substances 0.000 description 2
- 238000004033 diameter control Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000001727 in vivo Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 206010002198 Anaphylactic reaction Diseases 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 230000036783 anaphylactic response Effects 0.000 description 1
- 208000003455 anaphylaxis Diseases 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/02—Inorganic materials
- A61L31/022—Metals or alloys
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/14—Materials characterised by their function or physical properties, e.g. injectable or lubricating compositions, shape-memory materials, surface modified materials
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C18/00—Alloys based on zinc
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
- C22F1/165—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon of zinc or cadmium or alloys based thereon
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Vascular Medicine (AREA)
- Surgery (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- Heart & Thoracic Surgery (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials For Medical Uses (AREA)
- Forging (AREA)
Abstract
Description
组别 | 抗拉强度/MPa | 延伸率/% | 组别 | 抗拉强度/MPa | 延伸率/% |
实施例1 | 386.7 | 39% | 对比例1 | 367.3 | 40% |
实施例2 | 403.3 | 33% | 对比例2 | 384.0 | 32% |
实施例3 | 407.0 | 35% | 对比例3 | 382.3 | 27% |
实施例4 | 416.3 | 36% | 对比例4 | 378.3 | 25% |
Claims (10)
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CN202110242100.5A CN113018515B (zh) | 2021-03-04 | 2021-03-04 | 一种可降解锌基合金骨骼固定系统材料及其制备方法 |
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CN202110242100.5A CN113018515B (zh) | 2021-03-04 | 2021-03-04 | 一种可降解锌基合金骨骼固定系统材料及其制备方法 |
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CN113018515A true CN113018515A (zh) | 2021-06-25 |
CN113018515B CN113018515B (zh) | 2022-09-13 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114045409A (zh) * | 2021-11-16 | 2022-02-15 | 湖南华耀百奥医疗科技有限公司 | 一种骨科修复植入物及其制备方法 |
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CN104328312A (zh) * | 2014-10-20 | 2015-02-04 | 东北大学 | 一种医用生物可降解锌合金及其制备方法 |
CN105925848A (zh) * | 2016-06-28 | 2016-09-07 | 东北大学 | 一种生物医用可降解锌合金内植入材料及其板材制备方法 |
CN107177754A (zh) * | 2017-05-22 | 2017-09-19 | 北京科技大学 | 一种高塑性和可生物降解Zn‑Mn系锌合金及其制备方法 |
CN108277386A (zh) * | 2018-03-23 | 2018-07-13 | 北京大学 | 一种Zn-Li-Mg系锌合金及其制备方法与应用 |
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US20190083685A1 (en) * | 2016-03-10 | 2019-03-21 | Shandong Rientech Medical Tech Co., Ltd. | Degradable zinc base alloy implant material and preparation method and use thereof |
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CN112371983A (zh) * | 2020-10-16 | 2021-02-19 | 珠海中科先进技术研究院有限公司 | 具有抗菌性、强韧性的合金材料及其制备方法和应用 |
CN114045409A (zh) * | 2021-11-16 | 2022-02-15 | 湖南华耀百奥医疗科技有限公司 | 一种骨科修复植入物及其制备方法 |
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2021
- 2021-03-04 CN CN202110242100.5A patent/CN113018515B/zh active Active
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WO2007110611A1 (en) * | 2006-03-24 | 2007-10-04 | Smith & Nephew, Plc | Composite material |
CN104195368A (zh) * | 2014-08-21 | 2014-12-10 | 北京大学 | 一种Zn-Sr系锌合金及其制备方法与应用 |
CN104328312A (zh) * | 2014-10-20 | 2015-02-04 | 东北大学 | 一种医用生物可降解锌合金及其制备方法 |
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CN107177754A (zh) * | 2017-05-22 | 2017-09-19 | 北京科技大学 | 一种高塑性和可生物降解Zn‑Mn系锌合金及其制备方法 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114045409A (zh) * | 2021-11-16 | 2022-02-15 | 湖南华耀百奥医疗科技有限公司 | 一种骨科修复植入物及其制备方法 |
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Address after: No. 58 Jinshui West Road, Ningxiang High tech Industrial Park, Changsha City, Hunan Province, 410604 Patentee after: Hunan Huarui Technology Group Co.,Ltd. Country or region after: China Address before: No. 40601-40610, Zhongchuang space, 4 / F, comprehensive building, science and Technology Industrial Park, Hunan University, No. 001, Jinzhou North Road, Ningxiang high tech Industrial Park, Changsha City, Hunan Province, 410600 Patentee before: Hunan Huarui Technology Group Co.,Ltd. Country or region before: China |