CN112794954A - 耐热玻璃钢材料 - Google Patents

耐热玻璃钢材料 Download PDF

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CN112794954A
CN112794954A CN201911110689.2A CN201911110689A CN112794954A CN 112794954 A CN112794954 A CN 112794954A CN 201911110689 A CN201911110689 A CN 201911110689A CN 112794954 A CN112794954 A CN 112794954A
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reinforced plastic
plastic material
resistant glass
heat
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任文斌
任文卓
周鹏飞
刘逸鹤
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Shaoyang Qianliang New Environmental Protection Building Material Co ltd
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Abstract

本发明提供一种耐热玻璃钢材料，包括如下重量成分：树脂40‑60份，混合纤维11‑18份，填料50‑80份，十溴二苯醚15‑20份，邻苯二甲酸酐30‑50份、戊二酸15‑25份、反丁烯二酸15‑20份、亚麻油2‑5份、新戊二醇8‑16份、苯乙烯7‑10份、甲基丙烯酸甲酯6‑10份、邻苯二甲酸二烯丙酯5‑10份，固化剂4‑6份，碳纳米管3‑7份、硅烷偶联剂2‑5份，防老剂1‑2份。与相关技术相比，本发明提供的耐热玻璃钢材料机械性能、阻燃性、耐候性和耐高温性能好。

Description

耐热玻璃钢材料
技术领域
本发明涉及塑料技术领域，尤其涉及一种耐热玻璃钢材料。
背景技术
玻璃钢又称纤维强化塑料，它是以玻璃纤维及其制品(玻璃布、带、毡、纱等)作为增强材料，以合成树脂作基体材料的一种复合材料。纤维增强复合材料是由增强纤维和基体组成。玻璃钢具有轻质高强、耐腐蚀、热性能良好、工艺性优良等优点，但是玻璃钢的长期耐温性差，长期处于高温环境中会降低玻璃钢的性能，缩短其使用寿命。
因此，有必要提供一种新型的耐热玻璃钢材料，以克服上述缺陷。
发明内容
本发明的目的在于提供一种新型的耐热玻璃钢材料，其机械性能、阻燃性、耐候性和耐高温性能好。
为了达到上述目的，本发明提供一种耐热玻璃钢材料，包括如下重量成分：混合纤维11-18份，填料50-80份，十溴二苯醚15-20份，邻苯二甲酸酐30-50份、戊二酸15-25份、反丁烯二酸15-20份、亚麻油2-5份、新戊二醇8-16份、苯乙烯7-10份、甲基丙烯酸甲酯6-10份、邻苯二甲酸二烯丙酯5-10份，固化剂4-6份，碳纳米管3-7份、硅烷偶联剂2-5份，防老剂1-2份。
进一步，包括如下重量成分：混合纤维15份，填料60份，十溴二苯醚18份，邻苯二甲酸酐40份、戊二酸20份、反丁烯二酸18份、亚麻油3份、新戊二醇12份、苯乙烯9份、甲基丙烯酸甲酯8份、邻苯二甲酸二烯丙酯7份，固化剂5份，碳纳米管5份、硅烷偶联剂4份，防老剂2份。
进一步，所述填料为硅微粉、轻质碳酸钙、膨润土、硫酸钡、氢氧化铝中的至少两种。
进一步，所述混合纤维为玄武岩纤维、碳纤维、竹纤维的至少两种。
进一步，所述固化剂为过氧化环乙酮。
与相关技术相比较，本发明的耐热玻璃钢材料提升产品的拉伸、抗冲击强度，有效提升其阻燃性能，改善流动性并增加耐压度，提高使用价值。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅是本发明的一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其它实施例，都属于本发明保护的范围。
本发明提供一种耐热玻璃钢材料，包括如下重量成分：混合纤维11-18份，填料50-80份，十溴二苯醚15-20份，邻苯二甲酸酐30-50份、戊二酸15-25份、反丁烯二酸15-20份、亚麻油2-5份、新戊二醇8-16份、苯乙烯7-10份、甲基丙烯酸甲酯6-10份、邻苯二甲酸二烯丙酯5-10份，固化剂4-6份，碳纳米管3-7份、硅烷偶联剂2-5份，防老剂1-2份。
实施例一，包括如下重量成分：混合纤维15份，填料60份，十溴二苯醚18份，邻苯二甲酸酐40份、戊二酸20份、反丁烯二酸18份、亚麻油3份、新戊二醇12份、苯乙烯9份、甲基丙烯酸甲酯8份、邻苯二甲酸二烯丙酯7份，固化剂5份，碳纳米管5份、硅烷偶联剂4份，防老剂2份。
进一步，所述填料为硅微粉、轻质碳酸钙、膨润土、硫酸钡、氢氧化铝中的至少两种。
进一步，所述混合纤维为玄武岩纤维、碳纤维、竹纤维的至少两种。
进一步，所述固化剂为过氧化环乙酮。
耐热玻璃钢材料的制作方法为：1、在氮气保护下，将新戊二醇、反丁烯二酸加入到反应容器中升温，再加入邻苯二甲酸酐、戊二酸、亚麻油，后加入苯乙烯、甲基丙烯酸甲酯、邻苯二甲酸二烯丙酯，得不饱和聚酯树脂；
2、将不饱和聚酯树脂、填料、固化剂，碳纳米管、硅烷偶联剂、防老剂混合，得树脂胶液；
3、将混合纤维加入树脂胶液混合均匀，在树脂胶液中进行浸胶，得到耐热玻璃钢材料。
与相关技术相比较，本发明的耐热玻璃钢材料提升产品的拉伸、抗冲击强度，有效提升其阻燃性能，改善流动性并增加耐压度，提高使用价值。
以上所述仅为本发明的实施例，并非因此限制本发明的专利范围，凡是利用本发明说明书内容所作的等效结构或等效流程变换，或直接或间接运用在其它相关的技术领域，均同理包括在本发明的专利保护范围内。

Claims (5)

1.一种耐热玻璃钢材料，其特征在于，包括如下重量成分：树脂40-60份，混合纤维11-18份，填料50-80份，十溴二苯醚15-20份，邻苯二甲酸酐30-50份、戊二酸15-25份、反丁烯二酸15-20份、亚麻油2-5份、新戊二醇8-16份、苯乙烯7-10份、甲基丙烯酸甲酯6-10份、邻苯二甲酸二烯丙酯5-10份，固化剂4-6份，碳纳米管3-7份、硅烷偶联剂2-5份，防老剂1-2份。
2.如权利要求1所述的耐热玻璃钢材料，其特征在于，包括如下重量成分：树脂50份，混合纤维15份，填料60份，十溴二苯醚18份，邻苯二甲酸酐40份、戊二酸20份、反丁烯二酸18份、亚麻油3份、新戊二醇12份、苯乙烯9份、甲基丙烯酸甲酯8份、邻苯二甲酸二烯丙酯7份，固化剂5份，碳纳米管5份、硅烷偶联剂4份，防老剂2份。
3.如权利要求1所述的耐热玻璃钢材料，其特征在于：所述填料为硅微粉、轻质碳酸钙、膨润土、硫酸钡、氢氧化铝中的至少两种。
4.如权利要求1所述的耐热玻璃钢材料，其特征在于：所述混合纤维为玄武岩纤维、碳纤维、竹纤维的至少两种。
5.如权利要求1所述的耐热玻璃钢材料，其特征在于：所述固化剂为过氧化环乙酮。
CN201911110689.2A 2019-11-14 2019-11-14 耐热玻璃钢材料 Pending CN112794954A (zh)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109206562A (zh) * 2018-11-22 2019-01-15 安徽汇创新材料有限公司 一种玻璃钢化粪池及其制备方法
CN109294196A (zh) * 2018-10-29 2019-02-01 安徽汇创新材料有限公司 一种化粪池用玻璃钢材料
CN109486143A (zh) * 2018-10-29 2019-03-19 安徽汇创新材料有限公司 一种化粪池用耐热玻璃钢材料
CN109517354A (zh) * 2018-11-22 2019-03-26 安徽汇创新材料有限公司 一种用于玻璃钢化粪池的阻燃抗压复合材料及其制备方法
CN110093002A (zh) * 2019-03-14 2019-08-06 江西强发科技有限公司 一种玻璃钢化粪池及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109294196A (zh) * 2018-10-29 2019-02-01 安徽汇创新材料有限公司 一种化粪池用玻璃钢材料
CN109486143A (zh) * 2018-10-29 2019-03-19 安徽汇创新材料有限公司 一种化粪池用耐热玻璃钢材料
CN109206562A (zh) * 2018-11-22 2019-01-15 安徽汇创新材料有限公司 一种玻璃钢化粪池及其制备方法
CN109517354A (zh) * 2018-11-22 2019-03-26 安徽汇创新材料有限公司 一种用于玻璃钢化粪池的阻燃抗压复合材料及其制备方法
CN110093002A (zh) * 2019-03-14 2019-08-06 江西强发科技有限公司 一种玻璃钢化粪池及其制备方法

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Application publication date: 20210514