CN112154161B - 用于合成具有可控结构的乙烯基芳香族聚合物的聚合方法 - Google Patents

用于合成具有可控结构的乙烯基芳香族聚合物的聚合方法 Download PDF

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CN112154161B
CN112154161B CN201980031287.5A CN201980031287A CN112154161B CN 112154161 B CN112154161 B CN 112154161B CN 201980031287 A CN201980031287 A CN 201980031287A CN 112154161 B CN112154161 B CN 112154161B
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acetate
reaction
group
styrene
vinyl aromatic
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CN112154161A (zh
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佛朗哥·盖尔菲
安吉洛·费兰多
阿尔多·隆戈
米尔科·布法尼
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Versalis SpA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02—Monomers containing only one unsaturated aliphatic radical
    • C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06—Hydrocarbons
    • C08F112/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
CN201980031287.5A 2018-05-09 2019-05-08 用于合成具有可控结构的乙烯基芳香族聚合物的聚合方法 Active CN112154161B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT102018000005186 2018-05-09
IT102018000005186A IT201800005186A1 (it) 2018-05-09 2018-05-09 Procedimento di polimerizzazione per la produzione di polimeri vinil aromatici a struttura controllata
PCT/IB2019/053763 WO2019215626A1 (en) 2018-05-09 2019-05-08 Polymerization process for the synthesis of vinyl aromatic polymers with a controlled structure

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CN112154161A CN112154161A (zh) 2020-12-29
CN112154161B true CN112154161B (zh) 2023-08-01

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US (1) US11725070B2 (https=)
EP (1) EP3790910B1 (https=)
JP (1) JP7570923B2 (https=)
KR (1) KR102819629B1 (https=)
CN (1) CN112154161B (https=)
BR (1) BR112020022613B1 (https=)
ES (1) ES2912891T3 (https=)
HU (1) HUE057878T2 (https=)
IT (1) IT201800005186A1 (https=)
MX (1) MX2020011895A (https=)
PL (1) PL3790910T3 (https=)
WO (1) WO2019215626A1 (https=)

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CN113956468B (zh) * 2021-12-14 2024-04-16 陕西科技大学 一种聚肽/聚烯烃杂化共聚物的合成方法

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CN1186079A (zh) * 1996-12-26 1998-07-01 埃勒夫阿托化学有限公司 受控(甲基)丙烯基、乙烯基、亚乙烯基和二烯单体的自由基聚合或共聚方法,以及获得的(共)聚合物
WO1998040415A1 (en) * 1997-03-11 1998-09-17 Carnegie Mellon University Improvements in atom or group transfer radical polymerization
CN1203927A (zh) * 1998-05-06 1999-01-06 华东理工大学 活性阴离子向活性自由基变换合成嵌段共聚物的方法
CN1456577A (zh) * 2003-05-26 2003-11-19 华南理工大学 有机硅氧烷改性苯乙烯－丙烯酸酯纳米乳液及其制备方法
CN101555306A (zh) * 2009-05-05 2009-10-14 苏州大学 一种合成水凝胶的方法
JP2010095591A (ja) * 2008-10-15 2010-04-30 Seiko Pmc Corp 水性インク用顔料分散剤及び水性インク組成物
CN104961133A (zh) * 2015-06-24 2015-10-07 齐鲁工业大学 一种制备具有核壳间距的二氧化硅核壳材料的方法

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US7893174B2 (en) 2004-03-05 2011-02-22 Carnegie Mellon University Atom transfer radical polymerization process
WO2012020545A1 (ja) 2010-08-10 2012-02-16 株式会社カネカ （メタ）アクリル系重合体の製造方法
US9533297B2 (en) * 2012-02-23 2017-01-03 Carnegie Mellon University Ligands designed to provide highly active catalyst complexes
WO2014175221A1 (ja) 2013-04-25 2014-10-30 株式会社カネカ ビニル系重合体の製造方法
CN108884004B (zh) 2016-02-13 2020-02-25 多尔夫凯塔尔化学制品（I）私人有限公司 用于控制和抑制乙烯基芳族单体聚合的组合物，及其使用方法

Patent Citations (7)

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CN1186079A (zh) * 1996-12-26 1998-07-01 埃勒夫阿托化学有限公司 受控(甲基)丙烯基、乙烯基、亚乙烯基和二烯单体的自由基聚合或共聚方法,以及获得的(共)聚合物
WO1998040415A1 (en) * 1997-03-11 1998-09-17 Carnegie Mellon University Improvements in atom or group transfer radical polymerization
CN1203927A (zh) * 1998-05-06 1999-01-06 华东理工大学 活性阴离子向活性自由基变换合成嵌段共聚物的方法
CN1456577A (zh) * 2003-05-26 2003-11-19 华南理工大学 有机硅氧烷改性苯乙烯－丙烯酸酯纳米乳液及其制备方法
JP2010095591A (ja) * 2008-10-15 2010-04-30 Seiko Pmc Corp 水性インク用顔料分散剤及び水性インク組成物
CN101555306A (zh) * 2009-05-05 2009-10-14 苏州大学 一种合成水凝胶的方法
CN104961133A (zh) * 2015-06-24 2015-10-07 齐鲁工业大学 一种制备具有核壳间距的二氧化硅核壳材料的方法

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High efficiency micellar electrokinetic chromatography of hydrophobic analytes on poly(dimethylsiloxane) microchips;Gregory T. Roman等;《Analyst》;20051111;第131卷(第2期);第194-201 页 *
Understanding Atom Transfer Radical Polymerization: Effect of Ligand and Initiator Structures on the Equilibrium Constants;Wei Tang等;《JACS》;20080719;第130卷(第32期);第10702–10713页 *
Unusual Cross-Linked Polystyrene by Copper-Catalyzed ARGET ATRP Using a Bifunctional Initiator and No Cross-Linking Agent;Niccolò Braidi等;《Macromolecular Research》;20210424;第29卷(第4期);第280-288页 *

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Publication number Publication date
US11725070B2 (en) 2023-08-15
WO2019215626A1 (en) 2019-11-14
JP2021523267A (ja) 2021-09-02
JP7570923B2 (ja) 2024-10-22
EP3790910A1 (en) 2021-03-17
EP3790910B1 (en) 2022-03-02
HUE057878T2 (hu) 2022-06-28
KR102819629B1 (ko) 2025-06-11
IT201800005186A1 (it) 2019-11-09
BR112020022613B1 (pt) 2023-10-03
CN112154161A (zh) 2020-12-29
KR20210008398A (ko) 2021-01-21
US20210371555A1 (en) 2021-12-02
PL3790910T3 (pl) 2022-05-16
MX2020011895A (es) 2021-01-29
ES2912891T3 (es) 2022-05-30
BR112020022613A2 (pt) 2021-02-02

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