CN1118818A - 导电性丙烯酸纤维的制备方法 - Google Patents
导电性丙烯酸纤维的制备方法 Download PDFInfo
- Publication number
- CN1118818A CN1118818A CN94117663A CN94117663A CN1118818A CN 1118818 A CN1118818 A CN 1118818A CN 94117663 A CN94117663 A CN 94117663A CN 94117663 A CN94117663 A CN 94117663A CN 1118818 A CN1118818 A CN 1118818A
- Authority
- CN
- China
- Prior art keywords
- acrylic fiber
- compound
- preparation
- cupric ion
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002972 Acrylic fiber Polymers 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 238000000034 method Methods 0.000 title abstract description 18
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000000835 fiber Substances 0.000 claims abstract description 31
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 10
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims abstract description 6
- 235000019345 sodium thiosulphate Nutrition 0.000 claims abstract description 6
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims abstract description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical group OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 7
- 229960001484 edetic acid Drugs 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 4
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 3
- YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 2
- 239000005749 Copper compound Substances 0.000 claims 1
- 150000001880 copper compounds Chemical class 0.000 claims 1
- 229920000768 polyamine Polymers 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 13
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 abstract description 6
- 230000000704 physical effect Effects 0.000 abstract description 5
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 abstract 1
- 229910000365 copper sulfate Inorganic materials 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000010949 copper Substances 0.000 description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 13
- 229910052802 copper Inorganic materials 0.000 description 13
- 229910001431 copper ion Inorganic materials 0.000 description 13
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000013522 chelant Substances 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000009987 spinning Methods 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 2
- 240000007817 Olea europaea Species 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- ZTOGYGRJDIWKAQ-UHFFFAOYSA-N cyclohexene-1,2-diamine Chemical compound NC1=C(N)CCCC1 ZTOGYGRJDIWKAQ-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- -1 two amines Chemical class 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
- D06M11/42—Oxides or hydroxides of copper, silver or gold
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/18—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/49—Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/16—Physical properties antistatic; conductive
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
Claims (3)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019940012987A KR960011594B1 (ko) | 1994-06-09 | 1994-06-09 | 도전성 아크릴섬유의 제조방법 |
KR94-12987 | 1994-06-09 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1118818A true CN1118818A (zh) | 1996-03-20 |
CN1058999C CN1058999C (zh) | 2000-11-29 |
Family
ID=19384994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN94117663A Expired - Fee Related CN1058999C (zh) | 1994-06-09 | 1994-10-27 | 导电性丙烯酸纤维的制备方法 |
Country Status (2)
Country | Link |
---|---|
KR (1) | KR960011594B1 (zh) |
CN (1) | CN1058999C (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103052339A (zh) * | 2011-07-11 | 2013-04-17 | 日本蚕毛染色株式会社 | 刷子用纤维、使用该刷子用纤维的刷子、及刷子用纤维的制造方法 |
CN103635118A (zh) * | 2012-06-27 | 2014-03-12 | 日本蚕毛染色株式会社 | 刷子用刷头的制造方法 |
WO2017049814A1 (zh) * | 2015-09-25 | 2017-03-30 | 中国石油化工股份有限公司 | 一种导电聚合物纤维及其制备方法和应用 |
JP2018514662A (ja) * | 2015-03-27 | 2018-06-07 | 株式会社リテンド | 機能性硫化銅組成物及びこれから製造された機能性繊維 |
CN108286120A (zh) * | 2018-03-30 | 2018-07-17 | 青岛迦南美地家居用品有限公司 | 抗静电面料 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20030006409A (ko) * | 2001-07-12 | 2003-01-23 | 최창식 | 블라인드용 기능성 원단 |
CN101240462B (zh) * | 2008-03-14 | 2010-06-23 | 东华大学 | 一种腈纶-蛋白质-铜盐复合抗静电纤维的制造方法 |
KR101156368B1 (ko) * | 2010-11-25 | 2012-06-13 | 숭실대학교산학협력단 | 고내열성 아크릴 도전성 섬유 제조 방법 |
KR101623405B1 (ko) * | 2014-01-06 | 2016-05-23 | 한국과학기술연구원 | 금속이 배위 결합된 킬레이트 흡착제의 제조방법 및 그 흡착제 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5551873A (en) * | 1978-10-09 | 1980-04-15 | Nippon Sanmou Senshiyoku Kk | Production of electrically conductive fiber |
DE3165320D1 (en) * | 1980-03-05 | 1984-09-13 | Nihon Sanmo Dyeing Co | Electrically conducting fibres and method of making same |
JPS60134099A (ja) * | 1983-12-22 | 1985-07-17 | 旭化成株式会社 | 制電性合成紙 |
JPS6215631A (ja) * | 1985-07-15 | 1987-01-24 | Hadoson:Kk | 情報プレ−ヤ |
US4746541A (en) * | 1985-12-16 | 1988-05-24 | Hoechst Celanese Corporation | Electrically conductive thermally stabilized acrylic fibrous material and process for preparing same |
CN87200258U (zh) * | 1987-01-05 | 1988-02-03 | 海盐县特种纤维织造厂 | 防静电除尘滤袋 |
CN1021924C (zh) * | 1988-02-01 | 1993-08-25 | 徐文治 | 含聚丙烯腈纤维的导电织物及其制备方法 |
-
1994
- 1994-06-09 KR KR1019940012987A patent/KR960011594B1/ko not_active IP Right Cessation
- 1994-10-27 CN CN94117663A patent/CN1058999C/zh not_active Expired - Fee Related
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103052339A (zh) * | 2011-07-11 | 2013-04-17 | 日本蚕毛染色株式会社 | 刷子用纤维、使用该刷子用纤维的刷子、及刷子用纤维的制造方法 |
CN103635118A (zh) * | 2012-06-27 | 2014-03-12 | 日本蚕毛染色株式会社 | 刷子用刷头的制造方法 |
CN103635118B (zh) * | 2012-06-27 | 2015-10-14 | 日本蚕毛染色株式会社 | 刷子用刷头的制造方法 |
US9192226B2 (en) | 2012-06-27 | 2015-11-24 | Nihon Sanmo Dyeing Co., Ltd. | Method for manufacturing bristle head for brush |
JP2018514662A (ja) * | 2015-03-27 | 2018-06-07 | 株式会社リテンド | 機能性硫化銅組成物及びこれから製造された機能性繊維 |
WO2017049814A1 (zh) * | 2015-09-25 | 2017-03-30 | 中国石油化工股份有限公司 | 一种导电聚合物纤维及其制备方法和应用 |
CN108286120A (zh) * | 2018-03-30 | 2018-07-17 | 青岛迦南美地家居用品有限公司 | 抗静电面料 |
CN108286120B (zh) * | 2018-03-30 | 2020-06-26 | 青岛迦南美地家居用品有限公司 | 抗静电面料 |
Also Published As
Publication number | Publication date |
---|---|
KR960011594B1 (ko) | 1996-08-24 |
KR960001211A (ko) | 1996-01-25 |
CN1058999C (zh) | 2000-11-29 |
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GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: DONGYANG MEIJIA CO., LTD. ADDRESS Free format text: FORMER OWNER: CO., LTD. HANYI SHINGOSEN ADDRESS Effective date: 20081121 |
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Effective date of registration: 20081121 Address after: Seoul, South Kerean Patentee after: East Mega Corporation Address before: Gyeongnam, South Korea Patentee before: Hanil Hapsum Company, Limited |
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Owner name: DONGYANG MEIJIA CO., LTD. Free format text: FORMER OWNER: CO., LTD. HANYI SHINGOSEN Effective date: 20081121 |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20001129 Termination date: 20131027 |