CN111670242A - 模块香料混合物 - Google Patents
模块香料混合物 Download PDFInfo
- Publication number
- CN111670242A CN111670242A CN201980012436.3A CN201980012436A CN111670242A CN 111670242 A CN111670242 A CN 111670242A CN 201980012436 A CN201980012436 A CN 201980012436A CN 111670242 A CN111670242 A CN 111670242A
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- CN
- China
- Prior art keywords
- ethyl
- modular
- acetate
- perfume
- fragrance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- AOGQPLXWSUTHQB-UHFFFAOYSA-N hexyl acetate Chemical compound CCCCCCOC(C)=O AOGQPLXWSUTHQB-UHFFFAOYSA-N 0.000 claims abstract description 20
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Abstract
本发明提供在添加到化妆品或饮食品中的情况下可维持主要香料成分的香调不变、并感觉到幸福感的模块香料混合物。本发明所涉及的与主要香料成分组合的模块香料混合物包含乙酸己酯和柠檬烯、并包含选自下述的一种或两种以上：乙酸异戊酯、2‑甲基戊酸乙酯、反式‑2‑己烯‑1‑醇、α‑突厥酮、顺式‑3‑己烯‑1‑醇、芳樟醇、乙酸乙酯、2‑甲基乙酸乙酯、壬醛、橙花醛、乙酸橙花酯、香叶醛、乙酸香叶酯、香茅醇、橙花醇、香叶醇、丙酸乙酯、己醛、己酸乙酯、玫瑰醚、己醇、乙酸3‑己烯酯、氨茴酸甲酯、丙二酸二乙酯、癸酸乙酯、辛醛、癸醛、2‑甲基戊酸乙酯、乙酸2‑(叔丁基)环己酯和乙酸二甲基苯乙基原酯，其特征在于：相对于模块香料混合物和主要香料成分的总计量，掺混0.05～5质量%的该模块香料混合物。
Description
相关申请
本申请要求于2018年2月8日申请的日本专利申请2018-20746号的优先权，并将其纳入本说明书中。
技术领域
本发明涉及模块香料混合物，特别是涉及在添加到化妆品或饮食品(food orbeverage)中的情况下可维持主要香料成分的香调不变、并感觉到幸福感的模块香料混合物。
背景技术
在饮食品或化妆品等中通常添加有各种各样的香料。由于制品(产品)的印象会根据制品所具有的香味而发生变化，因此所添加的香料的选择较为重要。
近年来，开发了含有使制品所具有的香味发生变化的各种各样的香料的赋香剂(香り付与剤)。例如，专利文献1中公开了对无酒精饮料赋予酒精感的酒精感赋予剂等。
然而，可对不具有幸福感的香味或幸福感的香味少的制品赋予幸福感的香料尚未开发。
现有技术文献
专利文献
专利文献1：日本特开2014-45712号公报。
发明内容
发明所要解决的课题
本发明是鉴于上述现有技术而进行的发明，其所要解决的课题在于：提供在添加到化妆品或饮食品中的情况下可维持主要香料成分的香调不变、并感觉到幸福感的模块香料混合物。
用于解决课题的手段
为了解决上述课题，本发明人进行了深入研究，结果发现：通过相对于主要香料成分总量掺混0.05～5质量%的包含特定的香料成分的模块香料混合物，可得到在添加到化妆品或饮食品中的情况下可维持主要香料成分的香调不变、并感觉到幸福感的模块香料混合物，从而完成了本发明。
即，本发明所涉及的与主要香料成分组合的模块香料混合物包含乙酸己酯和柠檬烯、并包含选自下述的一种或两种以上：乙酸异戊酯、2-甲基戊酸乙酯、反式-2-己烯-1-醇、α-突厥酮、顺式-3-己烯-1-醇、芳樟醇、乙酸乙酯、2-甲基乙酸乙酯、壬醛、橙花醛、乙酸橙花酯、香叶醛、乙酸香叶酯、香茅醇、橙花醇、香叶醇、丙酸乙酯、己醛、己酸乙酯、玫瑰醚、己醇、乙酸3-己烯酯、氨茴酸甲酯、丙二酸二乙酯、癸酸乙酯、辛醛、癸醛、2-甲基戊酸乙酯、乙酸2-(叔丁基)环己酯和乙酸二甲基苯乙基原酯，其特征在于：相对于模块香料混合物和主要香料成分的总计量，掺混0.05～5质量%的该模块香料混合物。
与主要香料成分组合的模块香料混合物，其特征在于：在上述模块香料混合物中，乙酸己酯和柠檬烯的掺混量在模块香料组合物总量中为5～40质量%。
在上述模块香料混合物中，优选可感觉到幸福感。
发明效果
本发明可提供在添加到化妆品或饮食品中的情况下可维持主要香料成分的香调不变、并感觉到幸福感的模块香料混合物。
附图说明
[图1]是显示“每个样品的产生愉快的感情的效果的程度”的图(表情分析)。
[图2]是显示“每个样品的香味的印象评价结果(幸福)”的图(感官评价)。
具体实施方式
本发明所涉及的模块香料混合物通过与主要香料成分组合，在以特定量添加到化妆品或饮食品中的情况下可维持主要香料成分的香调不变、并感觉到幸福感。
模块香料混合物需要包含乙酸己酯和柠檬烯作为必须成分。
另外，除上述必须成分以外，还需要包含选自下述的一种或两种以上：乙酸异戊酯、2-甲基戊酸乙酯、反式-2-己烯-1-醇、α-突厥酮、顺式-3-己烯-1-醇、芳樟醇、乙酸乙酯、2-甲基乙酸乙酯、壬醛、橙花醛、乙酸橙花酯、香叶醛、乙酸香叶酯、香茅醇、橙花醇、香叶醇、丙酸乙酯、己醛、己酸乙酯、玫瑰醚、己醇、乙酸3-己烯酯、氨茴酸甲酯、丙二酸二乙酯、癸酸乙酯、辛醛、癸醛、2-甲基戊酸乙酯、乙酸2-(叔丁基)环己酯、乙酸二甲基苯乙基原酯。
优选在模块香料组合物总量中乙酸己酯和柠檬烯的掺混量为5～40质量%。在乙酸己酯和柠檬烯的掺混量低于5质量%的情况下，有时难以赋予幸福感。若乙酸己酯和柠檬烯的掺混量超过40质量%，则有时难以赋予幸福感。
相对于模块香料混合物和主要香料成分的总计量，模块香料混合物的掺混量需要是0.05～5质量%。若掺混量低于0.05质量%，则有时无法赋予幸福感。若模块香料混合物的掺混量超过5质量%，则有时会对香调产生影响。
对主要香料成分没有特别限定，例如可列举：柑橘香调、花香调、果香调、绿色香调等。特别是，优选包含花香调、果香调。通过使用柑橘香调、花香调、果香调、绿色香调的主要香料成分，有时可更显著地体现本申请的模块香料混合物的效果。
另外，优选在主要香料成分总量中包含99重量%以上、更优选包含99～99.5重量%的柑橘香调、花香调、果香调、绿色香调的香料。
对掺混模块香料混合物的制品没有特别限定，可列举：化妆品、饮食品等。
作为化妆品，例如可列举：洗发精、护发素、头发护理剂、发油、发膏、发蜡(润发油)、护发香水等毛发化妆品；口红、香粉等美容化妆品；化妆水、乳液、美容液、润肤霜(身体乳霜)、润肤凝胶(身体凝胶)等护肤化妆品等。
作为饮食品，例如可列举：碳酸饮料、果汁饮料、蔬菜饮料、运动饮料、豆浆(soya-bean milk)、维生素补充饮料、矿物质补充饮料、营养饮料、乳酸菌饮料、乳饮料等软饮料类；绿茶、乌龙茶、红茶、香草茶(herbal tea)、奶茶、咖啡饮料等嗜好饮料类；勾兑酒(チューハイ)、鸡尾酒、发泡酒、果酒等酒精饮料类；牛奶、黄油、奶酪、酸奶等乳制品；冰激凌、酸奶、布丁、果冻等甜点类；饴糖(糖稀)、焦糖、薄脆饼干、饼干、曲奇、派(pie)、巧克力、零食(スナック菓子)等点心类；面包、汤、方便食品等普通食品类等。
作为其他制品，例如可列举：肥皂、洗涤用洗涤剂、消毒用洗涤剂、防臭洗涤剂等洗涤剂类；香水、室内芳香剂、车用芳香剂等芳香制品；牙膏、纸巾、卫生纸等。
对掺混模块香料混合物的制品的制造方法没有特别限定，可在制品的制造方法的任意阶段掺混本发明的模块香料混合物。例如，可通过在制造包含主要香料成分的制品之后添加模块香料混合物而得到。
掺混了模块香料混合物的制品与未掺混的制品相比可具有幸福感高的香味。
实施例
以下，列举实施例以进一步对本发明进行详述，但本发明并不受该实施例的任何限定。只要没有特别记载，则掺混量以质量%显示。
在说明实施例之前，对本发明中采用的评价试验方法进行说明。
评价(1)：表情分析
进行以64名普通评审员为对象的评价试验。通过分别闻4种香味，确认是否有幸福的心情。由各评审员闻香味，拍摄就其香味进行说明时的表情。确认由此时的表情客观、定量地推断的愉快程度是否根据香味而不同。对表情进行了动画摄影，但关于是以哪个时间点的表情作为分析对象，则在测定后让评审员本人观看动画，针对每种香味选定最能体现印象的表情。对于各评审员对4种香味分别选择的表情的图像，由面部的图像客观、定量地分析表情，使用可评价感情状态的FaceReader (Noldus公司制造)进行表情分析。本方法是根据日本特愿2018-10593进行试验的方法。
评价(2)：感官评价(嗜好、幸福的印象、相同香调的印象)
让总计64名女性评审员闻各样品，按照以下的标准对嗜好、幸福的印象、相同香调的印象进行了评价。
(嗜好)
4：喜欢；
3：稍微喜欢；
2：说不出是哪一种；
1：稍微讨厌；
0：讨厌。
(幸福的印象、相同香调的印象)
5：可感觉到；
4：稍微感觉到；
3：说不出是哪一种
2：稍微感觉不到；
1：感觉不到。
本发明人按照64名专业评审员的上述评价标准(1)，对以下所示的未掺混香料的洗发精基质(样品D)、相对于二丙二醇添加了1质量%的各香料组合物(A、B)而得的样品A、样品B、以及不香的样品C (100%的二丙二醇)的香味进行了评价。结果见图1。作为统计检验的方法，对于由FaceReader (Noldus公司制造)从所选择的图像相对地算出的值进行方差分析，在确认了香味的值的差别之后，进行了基于Bonferroni检验的多重比较。
・基质
・香料组合物A
・香料组合物B
根据图1确认到：样品A和样品B具有显著的幸福感。
本发明人将以上述的香料组合物A作为主要香料成分(果香花香基质的香料组合物)、并掺混了0%、0.5%、1%的作为上述香料组合物B的模块香料混合物的所得物稀释在1%的二丙二醇中，调制了样品(分别为样品P、样品Q、样品R)。然后，使用各样品，按照上述评价标准(2)进行了评价。结果见表1。
[表1]
与主要香料样品P相比，在样品P中加入了0.5～1%的模块香料混合物的样品Q和R看到了可感觉到幸福的印象的趋势。可知：在主要香料样品P中混合了模块香料混合物的组合物和只有主要香料成分的组合物得到了具有几乎同等的印象的结果，可维持香调。
因此，可以说：通过在主要香料成分中掺混模块香料混合物，可在维持香调的同时赋予幸福感。
另外，明确了：嗜好与幸福感无关。
由本发明人的这些研究的结果明确了：通过相对于模块香料混合物和主要香料成分的总计量掺混0.05～5质量%的该模块香料混合物，可维持主要香料成分的香调不变、并感觉到幸福感，所述模块香料混合物包含乙酸己酯和柠檬烯、并包含选自下述的一种或两种以上：乙酸异戊酯、2-甲基戊酸乙酯、反式-2-己烯-1-醇、α-突厥酮、顺式-3-己烯-1-醇、芳樟醇、乙酸乙酯、2-甲基乙酸乙酯、壬醛、橙花醛、乙酸橙花酯、香叶醛、乙酸香叶酯、香茅醇、橙花醇、香叶醇、丙酸乙酯、己醛、己酸乙酯、玫瑰醚、己醇、乙酸3-己烯酯、氨茴酸甲酯、丙二酸二乙酯、癸酸乙酯、辛醛、癸醛、2-甲基戊酸乙酯、乙酸2-(叔丁基)环己酯、乙酸二甲基苯乙基原酯。
Claims (3)
1.模块香料混合物，其与主要香料成分组合，该模块香料混合物包含乙酸己酯和柠檬烯、并包含选自下述的一种或两种以上：乙酸异戊酯、2-甲基戊酸乙酯、反式-2-己烯-1-醇、α-突厥酮、顺式-3-己烯-1-醇、芳樟醇、乙酸乙酯、2-甲基乙酸乙酯、壬醛、橙花醛、乙酸橙花酯、香叶醛、乙酸香叶酯、香茅醇、橙花醇、香叶醇、丙酸乙酯、己醛、己酸乙酯、玫瑰醚、己醇、乙酸3-己烯酯、氨茴酸甲酯、丙二酸二乙酯、癸酸乙酯、辛醛、癸醛、2-甲基戊酸乙酯、乙酸2-(叔丁基)环己酯和乙酸二甲基苯乙基原酯，其特征在于：相对于模块香料混合物和主要香料成分的总计量，掺混0.05～5质量%的该模块香料混合物。
2.权利要求1所述的模块香料混合物，该模块香料混合物与主要香料成分组合，其特征在于：在模块香料组合物总量中，乙酸己酯和柠檬烯的掺混量为5～40质量%。
3.权利要求1或2所述的模块香料混合物，该模块香料混合物与主要香料成分组合，其特征在于：可感觉到幸福感。
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| JP7033460B2 (ja) | 2022-03-10 |
| EP3750977A1 (en) | 2020-12-16 |
| JP2019137745A (ja) | 2019-08-22 |
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