CN111567540A - Bactericide agent composition containing flumorph and pyraclostrobin - Google Patents
Bactericide agent composition containing flumorph and pyraclostrobin Download PDFInfo
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- CN111567540A CN111567540A CN202010486076.5A CN202010486076A CN111567540A CN 111567540 A CN111567540 A CN 111567540A CN 202010486076 A CN202010486076 A CN 202010486076A CN 111567540 A CN111567540 A CN 111567540A
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- Prior art keywords
- flumorph
- pyraclostrobin
- composition
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- polyoxyethylene ether
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
Abstract
The invention discloses a flumorph and pyraclostrobin bactericide composition, which is a binary composition comprising flumorph and pyraclostrobin as effective components, wherein the weight part ratio of the active components is 1: 1; the weight percentage of the active components in the composition is 5-85%. Can be prepared into pesticide preparations such as suspending agents, dispersible oil suspending agents, water dispersible granules and the like by adopting a general method. The compositions of the present invention have synergistic effects which complement each other and improve plant growth using a smaller amount. The bactericide composition of the invention is safe for cucumbers. The bactericide composition has simple preparation method and convenient application, and can effectively prevent and treat cucumber downy mildew.
Description
Technical Field
The invention relates to an agricultural bactericide, in particular to a bactericide composition binary compounded by flumorph and prothioconazole.
Background
Pyraclostrobin is a novel broad-spectrum bactericide. The mitochondrial respiration inhibitor has the functions of protection, treatment and leaf infiltration conduction. Has permeability and local systemic activity, long effective period and rain wash resistance. Has better control effect on powdery mildew, downy mildew, banana scab and leaf spot.
Flumorph is particularly effective against peronospora, phytophthora. It has bactericidal effect on oomycetes, especially peronosporaceae and phytophthora on grapes, potatoes and tomatoes, and can be mixed with contact fungicide (dithianon, mancozeb or copper compound).
The pyraclostrobin single agent is easy to cause diseases to generate drug resistance after being used for a long time, so that the problems of increased dosage, reduced prevention effect and shortened lasting period are caused, and the pyraclostrobin single agent is not beneficial to sustainable development of the environment. The compounding of the active ingredients with different action mechanisms is a common method for delaying the drug resistance of diseases, and whether the compounding is synergistic action or antagonistic action is judged according to the effect in practical production application. The formula with obvious compounding effect can obviously improve the control effect, greatly reduce the dosage of pesticide, expand the bactericidal spectrum and improve the bactericidal efficiency.
Disclosure of Invention
In order to solve the technical problems, the invention provides a bactericide composition of flumorph and pyraclostrobin. Has obvious synergistic effect through compounding.
The invention provides the following technical scheme:
the bactericide composition takes flumorph and prothioconazole as effective components, and the balance is auxiliary components, the weight ratio of the active components is 1:1, and the active components in the composition account for 5-85% of the mass of the whole preparation.
The auxiliary components comprise surfactant, antiseptic, antifreeze and suspending aid.
A surfactant, which may be an emulsifier, dispersant or wetting agent; may be non-ionic or ionic.
The anionic surfactant comprises one or more of sulfonate, sulfate, carboxylate, phosphate, succinate, lignosulfonate and acrylamide acrylic acid copolymer.
The nonionic surfactant comprises one or more of fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene ether, fatty amine polyoxyethylene ether, fatty acid polyoxyethylene ether, acid alcohol ester and polyoxyethylene ether thereof, fatty amide and polyoxyethylene ether thereof, alkanolamide and polyoxyethylene ether thereof, polyoxyethylene polyoxypropylene ether block copolymer, alkyl sodium naphthalene sulfonate fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester polyoxyethylene ether. Such as: SK-20TX, SK-21K, SK-24, SK-24R, SK-25CH, SK-33L, SK-33H, SK-35PQ, SK-551, SK-560EP, SK-92FS1, SK-355, SK-5110, SK-5935, YUS-FS1, YUS-FS3000, YUFS 3300, YUS-FS7 FS PG, YUS-TXC, YUS-WG4, YUS-A51G, YUS-D1109S, YUS-EP60P, YUS-207K, YUS-5050PB, YUS-RXB, SP-2728, SP-27001, SP-2750, SP-SC3, SP-SC29, SP-SC3060, SP-6366 SD E, SP-28F, SD 11, 813, Grnsperse 6, Grnsperse 23, MUDA 2827, MUDA 282827, NEXLOL 30680, NEXLOL 30613, NEXLOBE 3680, NEXLOBE 3, NEE-27, NEXLOBE 3, NEXLOL 3645, NEXLOL 3068, NEE-ASE-DE 3645, NEXLOL-ASE-S-80, NEXLOAD-ASE 3, NEX, D305, D518, DF200, DF400, DF500, DF600, D510, sodium methylnaphthalenesulfonate formaldehyde condensates, FS981, YUS-CH1100, YUS-110, YUS-EC2200, YUS-OD1200, YUS135B, YUS-D935, SP-OF3462, SP-OF3472, Greenmul EF68, Atlox 4912, Atlox 4914, D800, GR7M, SK01J, SK10LX, SK-20GR, SK-21, SK-31SX 661, SK-34SC, SK-541B, PICO-WG7, PICO-NW1, PICO-NW2, YUS-CH7000, PICO-CS300M, YUS-LXC, YUS-SP 1203, YUS-JS 1420, PICO-539JS 7, PICO-30, PICO-JK wetting agent, PICO-JSD 819, PICO-CS300M, YUS-LXC, YUS-SP 819, PICO-SP 610, PICO-JS, PICO-JS 28819, PICO-WO 2-NV 816, sodium alkyl sulfonate, sodium salt dispersant, FINSW 685-610, FIW-WO 685-WO 46, sodium salt OF starch, SP2836, dispersant SupergilMNS/90, wetting agent YUS-SXC, dispersant Soprophor FD, calcium lignosulfonate, alkyl naphthalene sulfonate formaldehyde condensate (NNO), and the like.
The antiseptic is selected from Kathon, EQ or sodium benzoate.
The antifreeze is one or two of ethylene glycol, 1, 2-propylene glycol, glycerol and urea.
Suspending agent (thickening agent such as xanthan gum, gelatin, gum arabic, polyvinylpyrrolidone, magnesium aluminum silicate, polyvinyl alcohol, polyethylene glycol, methylcellulose, white carbon black, soluble starch, carboxymethyl cellulose or sodium alginate) is added into the preparation in form of powder, granule or latex.
The carrier included in the fungicidal preparation composition of the present invention, and any carrier generally used for formulating fungicidal compositions can be used. Such as: water, methyl cellosolve, methyl oleate, ethyl oleate, vegetable oil, methylated vegetable oil and the like. Mixtures of different liquids are often suitable.
Compared with the prior art, the invention has the beneficial effects that: the invention provides the pesticide composition suspending agent containing the fluorine morpholine and the pyraclostrobin, which has excellent physical properties and prevention effects, and the preferable pesticide composition suspending agent formula containing the fluorine morpholine and the pyraclostrobin is obtained by screening the surfactant, screening the synergistic assistant, and optimizing the compounding of the surfactant and the synergistic assistant, so that the influence of the addition of the synergistic assistant on the performance exertion of the surfactant is avoided, the aggregation and agglomeration of the pyraclostrobin easily occurring in the storage process is avoided, the uniformity of the whole system is maintained while the aggregation and agglomeration are avoided, and the stability and prevention effects of the suspending agent are improved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
10% flumorph-pyraclostrobin suspending agent
According to the formula requirement, 5 parts of flumorph, 5 parts of pyraclostrobin, 3 parts of SP-2728, 5 parts of SP-28F, 5 parts of SP-3266E, 2 parts of magnesium aluminum silicate, 1 part of white carbon black, 0.25 part of xanthan gum, 0.4 part of kasong, 4 parts of ethylene glycol and the balance of water are sequentially added into a mixing tank, coarse crushing and homogenization are performed through high shear, then the mixture is pumped into a sand mill for fine grinding, a particle size distribution instrument is used for detecting the particle size of materials through sand grinding, and after the particle size reaches the standard requirement, filtration is performed, so that the 10% flumorph-pyraclostrobin suspending agent can be obtained.
Example 2
20% flumorph-pyraclostrobin suspending agent
According to the formula requirement, 10 parts of flumorph, 10 parts of pyraclostrobin, 2 parts of SK-20TX, 5 parts of SD811, 4 parts of SK-92FS1, 3 parts of SP-27001, 2 parts of SP-3266E, 0.8 part of magnesium aluminum silicate, 0.8 part of white carbon black, 0.16 part of xanthan gum, 0.2 part of EQ, 4 parts of 1, 2-propylene glycol and the balance of water are sequentially added into a mixing tank, coarse crushing and homogenization are performed through high shear, then the mixture is pumped into a sand mill for fine grinding, a particle size distribution instrument detects the particle size of a sand-ground material, and after the particle size reaches the standard requirement, filtration is performed to obtain the 20% flumorph-pyraclostrobin suspending agent.
Example 3
30% flumorph-pyraclostrobin suspending agent
According to the formula requirement, 15 parts of flumorph, 15 parts of pyraclostrobin, 2 parts of YUS-TXC, 5 parts of GreenspermeBE 02, 3 parts of TANEMUL DA2880, 4 parts of SK-21K, 2 parts of agricultural emulsifier 1601, 0.5 part of magnesium aluminum silicate, 0.5 part of white carbon black, 0.15 part of xanthan gum, 0.2 part of EQ, 4 parts of glycerol and the balance of water are sequentially added into a mixing tank, coarse crushing and homogenization are carried out through high shear, then the mixture is pumped into a sand mill for fine grinding, a particle size distribution instrument detects the particle size of a sand-milled material, and after the particle size reaches the standard requirement, filtration is carried out, so that the 30% flumorph-pyraclostrobin suspending agent is obtained.
Example 4
40% flumorph-pyraclostrobin suspending agent
According to the formula requirement, 20 parts of flumorph, 20 parts of pyraclostrobin, 5 parts of SP-SC29, 4 parts of Nongru 0201B, 5 parts of SP-2728, 2 parts of Nongru 1601, 0.4 part of magnesium aluminum silicate, 0.4 part of white carbon black, 0.1 part of xanthan gum, 0.2 part of EQ, 4 parts of ethylene glycol and the balance of water are sequentially added into a mixing tank, and are subjected to high-shear coarse crushing and homogenization, and then pumped into a sand mill for fine grinding, a particle size distribution instrument detects the particle size of a sand-ground material, and after the particle size reaches the standard requirement, the 40% flumorph-pyraclostrobin suspending agent is obtained by filtering.
Example 5
10% flumorph-pyraclostrobin dispersible oil suspending agent
According to the formula requirement, 5 parts OF flumorph, 5 parts OF pyraclostrobin, 4 parts OF dispersant YUS-CH1100, 4 parts OF dispersant SP-OF3472B, 4 parts OF dispersant SP-OF3468, 5 parts OF agricultural emulsifier 0201B, 2 parts OF agricultural emulsifier 500, 15 parts OF methyl oleate and the balance OF methyl cellosolve are sequentially added into a mixing tank for mixing, firstly, high-shear coarse crushing and homogenization are carried out, then, the mixture is pumped into a sand mill for fine grinding, the particle size OF the sanded material is detected by a particle size distribution instrument, and after the particle size reaches the standard requirement, the mixture is filtered, so that the 10% flumorph-pyraclostrobin dispersible oil suspending agent can be obtained.
Example 6
20% flumorph-pyraclostrobin dispersible oil suspending agent
According to the formula requirement, 10 parts of flumorph, 10 parts of pyraclostrobin, 4 parts of dispersant Greenmul EF68, 5 parts of dispersant Atlox 4912, 5 parts of Nongru 0201B, 2 parts of Nongru 1601, 1 part of bentonite, 1 part of white carbon black and the balance of methyl oleate are sequentially added into a mixing tank for mixing, coarse crushing and homogenization are performed through high shear, then the mixture is pumped into a sand mill for fine grinding, the particle size of the ground material is detected through a particle size distribution instrument, and after the particle size reaches the standard requirement, the filtration is performed, so that the 20% flumorph-pyraclostrobin dispersible oil suspending agent can be obtained.
Example 7
30% flumorph-pyraclostrobin dispersible oil suspending agent
According to the formula requirement, 15 parts OF flumorph, 15 parts OF pyraclostrobin, 4 parts OF dispersant YUS-EP60P, 3 parts OF dispersant D305, 3 parts OF dispersant SP-OF3472B, 5 parts OF Nongru 0201B, 1 part OF organobentonite and the balance OF methylated soybean oil are sequentially added into a mixing tank for mixing, coarse crushing and homogenization are firstly carried out through high shear, then the mixture is pumped into a sand mill for fine grinding, the granularity OF the sand-ground material is detected by a granularity distribution instrument, and after the granularity reaches the standard requirement, the mixture is filtered, so that the 30% flumorph-pyraclostrobin dispersible oil suspending agent can be obtained.
Example 8
40% flumorph-pyraclostrobin dispersible oil suspending agent
According to the formula requirement, 20 parts OF flumorph, 20 parts OF pyraclostrobin, 4 parts OF dispersant Greenmul EF68, 5 parts OF SK-560EP, 5 parts OF dispersant SP-OF3468, 4 parts OF Nongru 0201B, 1 part OF organic bentonite and the balance OF methyl oleate are sequentially added into a mixing tank for mixing, coarse crushing and homogenization are carried out through high shear, then the mixture is pumped into a sand mill for fine grinding, the granularity OF a sanded material is detected through a granularity distribution instrument, and after the granularity reaches the standard requirement, the mixture is filtered, so that the 40% flumorph-pyraclostrobin dispersible oil suspension agent can be obtained.
Example 9
Preparation of 50% flumorph-pyraclostrobin water dispersible granule
According to the formula requirement, 25 parts of flumorph, 25 parts of pyraclostrobin, 1 part of Morwet EFW, 4 parts of dispersant YUS-WG5, 4 parts of sodium salt of alkyl naphthalene sulfonic acid polycondensate, 4 parts of alkyl naphthalene sulfonate formaldehyde condensate, 12 parts of soluble starch, 10 parts of sodium sulfate and bentonite are added together until the total content is 100%, mixed and crushed, and then added with water for kneading, and then added into a granulator with a screen mesh with a certain specification for granulation. Then drying and screening (according to the range of a screen) are carried out, thus obtaining the 50% flumorph-pyraclostrobin water dispersible granule.
Example 10
Preparation of 70% flumorph-pyraclostrobin water dispersible granule
According to the formula requirement, 35 parts of flumorph, 35 parts of pyraclostrobin, 1 part of Morwet EFW, 4 parts of dispersant PICO-CS300M, 5 parts of SK-20GR, 4 parts of alkyl naphthalene sulfonate formaldehyde condensate, 3 parts of soluble starch, 3 parts of sodium sulfate and the balance of bentonite are added together, mixed and crushed, and then added into a granulator with a screen of a certain specification for granulation after being kneaded by adding water. Then drying and screening (according to the range of a screen) are carried out, thus obtaining the 70% flumorph-pyraclostrobin water dispersible granule.
The following is a drug effect test of the bactericidal composition for preventing and treating cucumber downy mildew
The control medicament is 25 percent metalaxyl wettable powder (purchased from market), 20 percent benalaxyl wettable powder (purchased from market), 20 percent flumorph wettable powder (purchased from market) and 25 percent pyraclostrobin missible oil (purchased from market).
The disease condition of cucumber downy mildew is investigated before medicine application, and the medicine is applied for the first time at the early stage of the disease condition, once every 7 days and 2 times in total. The disease index of cucumber downy mildew is investigated and the control effect is calculated 7 days, 14 days and 30 days after the last application. The experimental results are shown below:
table 1 shows the efficacy test of the bactericidal composition of flumorph and pyraclostrobin on controlling cucumber downy mildew
As can be seen from the table 1, after the pyraclostrobin and the flumorph are compounded, the cucumber downy mildew can be effectively prevented and controlled, the prevention and control effect is superior to that of a control medicament, and the persistent period is long. Has no adverse effect on target crops in the application range of the test, has good control effect on cucumber downy mildew, and the control effect reaches over 90 percent.
The compositions of the present invention have synergistic effects which complement each other and improve plant growth using a smaller amount. The bactericide composition of the invention is safe for cucumbers. The bactericide composition has simple preparation method and convenient application, and can effectively prevent and treat cucumber downy mildew.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (9)
1. A bactericide composition of flumorph and pyraclostrobin is characterized in that: the bactericide composition takes flumorph and pyraclostrobin as effective components, and the balance auxiliary components, the weight ratio of active components is 1:1, and the active components in the composition account for 5-85% of the total preparation mass.
2. The bactericidal composition of flumorph and pyraclostrobin according to claim 1, wherein: the auxiliary components comprise surfactant, antiseptic, antifreeze and suspending aid.
3. The bactericidal composition of flumorph and pyraclostrobin according to claim 2, wherein: the surfactant is emulsifier, dispersant, wetting agent, nonionic or ionic.
4. The bactericidal agent composition of flumorph and pyraclostrobin according to claim 3, wherein: the ionic type adopts anionic surfactant, and the anionic surfactant comprises one or more of sulfonate, sulfate, carboxylate, phosphate, succinate, lignosulfonate and acrylamide acrylic copolymer.
5. The bactericidal agent composition of flumorph and pyraclostrobin according to claim 3, wherein: the nonionic surfactant comprises one or more of fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene ether, fatty amine polyoxyethylene ether, fatty acid polyoxyethylene ether, acid alcohol ester and polyoxyethylene ether thereof, fatty amide and polyoxyethylene ether thereof, alkanolamide and polyoxyethylene ether thereof, polyoxyethylene polyoxypropylene ether block copolymer, alkyl sodium naphthalene sulfonate fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester polyoxyethylene ether.
6. The bactericidal composition of flumorph and pyraclostrobin according to claim 2, wherein: the preservative is cason, EQ or sodium benzoate.
7. The bactericidal composition of flumorph and pyraclostrobin according to claim 2, wherein: the antifreezing agent is one or two of ethylene glycol, 1, 2-propylene glycol, glycerol and urea.
8. The bactericidal composition of flumorph and pyraclostrobin according to claim 2, wherein: the suspending aid is xanthan gum, gelatin, gum arabic, polyvinylpyrrolidone, magnesium aluminum silicate, polyvinyl alcohol, polyethylene glycol, methyl cellulose, white carbon black, soluble starch, carboxymethyl cellulose or sodium alginate, and is added into the preparation in the form of powder, granule or latex.
9. The application of the flumorph and pyraclostrobin bactericide composition as claimed in claim 1, wherein the composition comprises: the composition is used for preventing and treating cucumber downy mildew.
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| CN202010486076.5A CN111567540A (en) | 2020-06-01 | 2020-06-01 | Bactericide agent composition containing flumorph and pyraclostrobin |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115943952A (en) * | 2022-12-20 | 2023-04-11 | 惠州市银农科技股份有限公司 | Suspending agent containing pyraclostrobin and flumorph and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102177903A (en) * | 2011-03-23 | 2011-09-14 | 陕西汤普森生物科技有限公司 | Antibacterial composition containing pyraclostrobin and amide compounds |
| CN102657210A (en) * | 2012-05-15 | 2012-09-12 | 玉林师范学院 | Hot fogging concentrate containing pyraclostrobin and sterol synthesis inhibitor |
| CN103719123A (en) * | 2013-12-13 | 2014-04-16 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing composite of pyraclostrobin and morpholine bactericide |
| CN109006851A (en) * | 2018-08-22 | 2018-12-18 | 惠州市银农科技股份有限公司 | Composition pesticide suspending agent and preparation method thereof containing flumorph and pyraclostrobin |
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2020
- 2020-06-01 CN CN202010486076.5A patent/CN111567540A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102177903A (en) * | 2011-03-23 | 2011-09-14 | 陕西汤普森生物科技有限公司 | Antibacterial composition containing pyraclostrobin and amide compounds |
| CN102657210A (en) * | 2012-05-15 | 2012-09-12 | 玉林师范学院 | Hot fogging concentrate containing pyraclostrobin and sterol synthesis inhibitor |
| CN103719123A (en) * | 2013-12-13 | 2014-04-16 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing composite of pyraclostrobin and morpholine bactericide |
| CN109006851A (en) * | 2018-08-22 | 2018-12-18 | 惠州市银农科技股份有限公司 | Composition pesticide suspending agent and preparation method thereof containing flumorph and pyraclostrobin |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115943952A (en) * | 2022-12-20 | 2023-04-11 | 惠州市银农科技股份有限公司 | Suspending agent containing pyraclostrobin and flumorph and preparation method thereof |
| CN115943952B (en) * | 2022-12-20 | 2023-08-22 | 惠州市银农科技股份有限公司 | Suspending agent containing pyraclostrobin and flumorph and preparation method thereof |
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Application publication date: 20200825 |
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