CN104430362B - A kind of pesticidal preparations for storing Rhizoma Zingiberis Recens and application process thereof - Google Patents

A kind of pesticidal preparations for storing Rhizoma Zingiberis Recens and application process thereof Download PDF

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CN104430362B
CN104430362B CN201410649842.XA CN201410649842A CN104430362B CN 104430362 B CN104430362 B CN 104430362B CN 201410649842 A CN201410649842 A CN 201410649842A CN 104430362 B CN104430362 B CN 104430362B
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rhizoma zingiberis
zingiberis recens
pesticidal preparations
storing
application process
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CN104430362A (en
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左兆河
徐加利
史建伟
刘兴岭
张秀波
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TAIAN TAISHAN MODERN AGRICULTURAL TECHNOLOGY CO LTD
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TAI'AN TAISHAN MODERN AGRICULTURAL SCIENCE AND TECHNOLOGY Co Ltd
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Abstract

The invention discloses a kind of pesticidal preparations for storing Rhizoma Zingiberis Recens and application process thereof, its effective ingredient is Nylar, and the mass fraction of described Nylar is 0.1~25%.Application process, including: using described pesticidal preparations when Rhizoma Zingiberis Recens enters cellar for storing things storage, the described pesticidal preparations of pyriproxyfen-containing 15~60 grams used by Rhizoma Zingiberis Recens per ton.Pesticidal preparations for storing Rhizoma Zingiberis Recens provided by the invention can effectively prevent and treat the harm of great Jiang insect storage period (mainly Rhizoma Zingiberis Recens maggot), improves the quality of great Jiang storage period, reduces the drug residue of storage Rhizoma Zingiberis Recens simultaneously, reduces the storage period of the injury to human body.Therefore, pesticidal preparations provided by the invention may be used for storage Rhizoma Zingiberis Recens in Rhizoma Zingiberis Recens is stored, the harm of the insects such as preventing and treating Rhizoma Zingiberis Recens maggot (larva), Rhizoma Zingiberis Recens abnormity eye Tan mosquito (adult).

Description

A kind of pesticidal preparations for storing Rhizoma Zingiberis Recens and application process thereof
Technical field
The present invention relates to Rhizoma Zingiberis Recens storing technology field, be a kind of pesticidal preparations for storing Rhizoma Zingiberis Recens and application process thereof.
Background technology
Rhizoma Zingiberis Recens is the fresh rhizome of Zingiberaceae herbaceos perennial Rhizoma Zingiberis Recens (ZingiberofficinaleRoscoe), another name have race, hundred peppery clouds, hook dress refer to, because of ground boy pungent, hot and cold, fresh ginger, processed with honey Rhizoma Zingiberis Recens.Widely cultivate in Central China, each provinces and regions, the southeast to the west and south.The ground such as Laiwu in Shandong province, Anqiu, Changyi, Qingzhou, Yishui also produce, and Tropical Asian area is common cultivation also.
In the main ginger cultivation region of China, in the past storage Rhizoma Zingiberis Recens was with some high poison persistent pesticide preparations, Long Term Contact, eats and easily causes chronic poisoning;And remain height, accumulate in human body, it is impossible to discharge, internal organs impaired mechanical can be caused, can carcinogenic, teratogenesis when measuring big;Abnormal smells from the patient is poor;Contaminated environment, decomposes the unfavorable factors such as slow.Country has expressly provided cut-off, disabling, and during Rhizoma Zingiberis Recens detection, one it is found that embargo.Utilizing chlopyrifos, phoxim, dichlorvos, chrysanthemum esters etc. to remain less but that the product of poor stability is to store Rhizoma Zingiberis Recens method in addition with some, the Pesticidal products used in these storage proceduress can cause people's acute poisoning.Though remaining less but the smell is awful, it is easily caused vomiting, dizziness.
Summary of the invention
In view of this, it is an object of the invention to propose a kind of pesticidal preparations for storing Rhizoma Zingiberis Recens and application process thereof, to improve the storage effect of Rhizoma Zingiberis Recens, reduce the drug residue of storage Rhizoma Zingiberis Recens simultaneously.
Based on above-mentioned purpose, the effective ingredient of the pesticidal preparations for storing Rhizoma Zingiberis Recens provided by the invention is Nylar, and the mass fraction of described Nylar is 0.1~25%.
It is preferred that the mass fraction of described Nylar is 1~15%.
It is preferred that the processing dosage form of described pesticidal preparations is the one in powder, wettable powder, granule, water dispersible granules, cream, suspending agent, microemulsion and aqueous emulsion.
Alternatively, the described pesticidal preparations for storing Rhizoma Zingiberis Recens also includes auxiliary agent and the fillers such as the wetting agent needed for relative dosage form, dispersion regulators, emulsifying agent, synergist, antioxidant.
The present invention also provides for the application process of above-mentioned pesticidal preparations storage Rhizoma Zingiberis Recens, including: using described pesticidal preparations when Rhizoma Zingiberis Recens enters cellar for storing things storage, the described pesticidal preparations of pyriproxyfen-containing 15~60 grams used by Rhizoma Zingiberis Recens per ton.
Preferably, described application process also includes: described pesticidal preparations and silt are mixed according to the weight ratio of 1:5~15, spread fertilizer over the fields, in bottom, Rhizoma Zingiberis Recens cellar for storing things, the silt being mixed with described pesticidal preparations, on silt, then put Rhizoma Zingiberis Recens, then on Rhizoma Zingiberis Recens, spread fertilizer over the fields the silt being mixed with described pesticidal preparations.
Preferably, described pesticidal preparations and silt are mixed according to the mass ratio of 1:8~12, spread fertilizer over the fields, in bottom, Rhizoma Zingiberis Recens cellar for storing things, the silt being mixed with described pesticidal preparations, on silt, then put Rhizoma Zingiberis Recens, then on Rhizoma Zingiberis Recens, spread fertilizer over the fields the silt being mixed with described pesticidal preparations.
Alternatively, the humidity of described silt is 50~60%, and fineness is 30~50 orders.
Described silt at least one in river sand, sea sand.
As can be seen from above, pesticidal preparations for storing Rhizoma Zingiberis Recens provided by the invention can effectively prevent and treat the harm of great Jiang insect storage period (mainly Rhizoma Zingiberis Recens maggot), improve the quality of great Jiang storage period, reduce the drug residue of storage Rhizoma Zingiberis Recens simultaneously, reduce the storage period of the injury to human body.Therefore, pesticidal preparations provided by the invention may be used for storage Rhizoma Zingiberis Recens in Rhizoma Zingiberis Recens is stored, the harm of the insects such as preventing and treating Rhizoma Zingiberis Recens maggot (larva), Rhizoma Zingiberis Recens abnormity eye Tan mosquito (adult).
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention clearly understand, below in conjunction with specific embodiment, the present invention is described in more detail.
Nylar, chemical name: 4-phenoxy phenyl (RS)-2-(2-pyridine radicals oxygen) propyl ether, it is the chitin synthesis inhibitor of a kind of juvenile hormone type, there is strong ovicidal action, also there is interior absorption transfer activity.The inhibitory action of insecticide is shown that affecting insecticide changes in quality and breeding.Nylar can retain at hemolymph middle and high concentration, accelerates the secretion to gonadal hormone of the insecticide thymus;On the other hand, Nylar can make insecticide lack required stimulating factor of laying eggs, it is suppressed that the hatching of fetal development and ovum, or generates the ovum not having viability, thus effectively controlling and reach the purpose of Pest control.Nylar low toxicity, the lasting period is long, to crop safety, efficiently, dosage is few, lasting period length, to crop safety, to Fish low toxicity, the feature that eco-environmental impact is little.Can be used for preventing and treating Homoptera, Thysanoptera, Diptera, lepidoptera pest.The inhibitory action surface of insecticide is being affected casting off a skin and breeding of insecticide by it.To mosquitos and flies class sanitary insect pest, namely the 4 instar larvae low dosage this product in later stage cause stage death of pupating, it is suppressed that adult is formed.Rhizoma Zingiberis Recens maggot (larva), Rhizoma Zingiberis Recens abnormity eye Tan mosquito (adult) can be effectively prevented and treated when being used for storing Rhizoma Zingiberis Recens in Rhizoma Zingiberis Recens is stored.
Embodiment 1 prepares the powder that Nylar mass fraction is 1%
Concrete proportioning is:
Preparation method includes: weigh Nylar, hydrated SiO 2, clay, Gypsum Fibrosum mix homogeneously, remixes to certain fineness (fineness is more than 200 orders) and prepare into the powder that Nylar mass fraction is 1% after eddy current pulverizing.
Embodiment 2 prepares the granule (disintegrative) that Nylar mass fraction is 0.5%
Concrete proportioning is:
Preparation method includes: weighing Nylar, carboxymethyl starch sodium, Kaolin, mix homogeneously by above weight ratio, then add binding agent water to mixture, blended, pelletize prepares into, with dry, the granule that described active constituent content is 0.5%.Wherein, the addition of described water is the 7% of mixture total weight amount, and dried water is removed, and therefore the weight of water is not counted in the weight of granule.
Embodiment 3 prepares the wettable powder that Nylar mass fraction is 25%
Concrete proportioning is:
Preparation method includes: weigh the filler mix homogeneously such as Nylar, sodium lauryl sulphate, dodecylbenzene sodium sulfonate, white carbon, fine particle calcium carbonate by above weight ratio, preparing into described active constituent content through comminution by gas stream is the wettable powder of 25%.
Embodiment 4 prepares the water dispersible granules that Nylar mass fraction is 10%
Concrete proportioning is:
Preparation method includes: weigh the filler mix homogeneously such as Nylar, sodium lauryl sulphate, dodecylbenzene sodium sulfonate, white carbon, fine particle calcium carbonate by above weight ratio, preparing into described active constituent content through comminution by gas stream is the wettable powder of 10%;The water dispersible granules of 10% is can be made into then through pelletize.
Embodiment 5 prepares the suspending agent that Nylar mass fraction is 25%
Concrete proportioning is as follows:
Preparation method: weigh Nylar by above weight ratio, auxiliary agent, emulsifying agent, deionized water are stirred mixing, remix after sand milling after required particle diameter, and preparing into described active constituent content is the suspending agent of 25%.
Embodiment 6 prepares the microemulsion that Nylar mass fraction is 15%
Its formula is as follows:
Preparation method: weigh the mixing such as Nylar, NP-10, Butacide PBO synergist, hexane, ethylene glycol antifreeze by above weight ratio after, adds deionized water and carries out high shear agitation, prepare into the microemulsion that described active constituent content is 15%.
Embodiment 7 prepares the aqueous emulsion that Nylar mass fraction is 20%
Concrete formula is as follows:
Preparation method: weigh the mixing such as Nylar, Nylar parasite killing auxiliary agent, HD-3004 emulsifying dispersant, organic silicon defoamer, dimethylbenzene, hexane equal solvent, ethylene glycol antifreeze by above weight ratio after, add deionized water and carry out high shear agitation, prepare into the aqueous emulsion that described active constituent content is 20%.
The present invention also provides for the application process of above-mentioned pesticidal preparations, specifically include: by described pesticidal preparations and humidity be 52%~58%, fineness be that the river sand of 30 orders fully mixes according to the mass ratio of 1:10~13, one layer of river sand being mixed with described pesticidal preparations is spread fertilizer over the fields in bottom, Rhizoma Zingiberis Recens cellar for storing things after Jiang Jiao cleans up, then on river sand, continue to put one layer of Rhizoma Zingiberis Recens, then on Rhizoma Zingiberis Recens, spread fertilizer over the fields one layer of river sand being mixed with described pesticidal preparations.Namely often put one layer of Rhizoma Zingiberis Recens, on Rhizoma Zingiberis Recens, just spread fertilizer over the fields the river sand being once mixed with described pesticidal preparations, the river sand being mixed with described pesticidal preparations is spread fertilizer over the fields layer by layer on the Rhizoma Zingiberis Recens in Rhizoma Zingiberis Recens is stored.
Preferably, using described pesticidal preparations when Rhizoma Zingiberis Recens enters cellar for storing things storage, generally use 1 time, the described pesticidal preparations of pyriproxyfen-containing 30~40 grams used by Rhizoma Zingiberis Recens per ton.
Another embodiment as the present invention, described application process specifically may include that by described pesticidal preparations and humidity be 52%~55%, fineness be that the river sand of 40 orders fully mixes according to the mass ratio of 1:8~12, one layer of sea sand being mixed with described pesticidal preparations is spread fertilizer over the fields in bottom, Rhizoma Zingiberis Recens cellar for storing things after Jiang Jiao cleans up, then on river sand, continue to put one layer of Rhizoma Zingiberis Recens, then on Rhizoma Zingiberis Recens, spread fertilizer over the fields one layer of river sand being mixed with described pesticidal preparations.Preferably, using described pesticidal preparations when Rhizoma Zingiberis Recens enters cellar for storing things storage, generally use 1 time, the described pesticidal preparations of pyriproxyfen-containing 15~30 grams used by Rhizoma Zingiberis Recens per ton.
Another embodiment as the present invention, described application process specifically may include that by described pesticidal preparations and humidity be 56%~60%, fineness be that the river sand of 50 orders fully mixes according to the mass ratio of 1:5~10, one layer of river sand being mixed with described pesticidal preparations is spread fertilizer over the fields in bottom, Rhizoma Zingiberis Recens cellar for storing things after Jiang Jiao cleans up, then on river sand, continue to put one layer of Rhizoma Zingiberis Recens, then on Rhizoma Zingiberis Recens, spread fertilizer over the fields one layer of river sand being mixed with described pesticidal preparations.Preferably, using described pesticidal preparations when Rhizoma Zingiberis Recens enters cellar for storing things storage, generally use 1 time, the described pesticidal preparations of pyriproxyfen-containing 45~60 grams used by Rhizoma Zingiberis Recens per ton.
Another embodiment as the present invention, described application process specifically may include that by described pesticidal preparations and humidity be 55%~58%, fineness be that the river sand of 50 orders fully mixes according to the mass ratio of 1:10~15, one layer of sea sand being mixed with described pesticidal preparations is spread fertilizer over the fields in bottom, Rhizoma Zingiberis Recens cellar for storing things after Jiang Jiao cleans up, then on river sand, continue to put one layer of Rhizoma Zingiberis Recens, then on Rhizoma Zingiberis Recens, spread fertilizer over the fields one layer of river sand being mixed with described pesticidal preparations.Preferably, using described pesticidal preparations when Rhizoma Zingiberis Recens enters cellar for storing things storage, generally use 1 time, the described pesticidal preparations of pyriproxyfen-containing 40~50 grams used by Rhizoma Zingiberis Recens per ton.
Application process provided by the invention has to be used conveniently, uses safe advantage, meets the medication custom of Jiang Nong, and through continuous 3 years in Laiwu in Shandong province, the test of pesticide effectiveness carried out with local agricultural sector of Anqiu, Changyi, Qingzhou, Yishui verifies.Adopt the present invention offer pesticidal preparations storage after Rhizoma Zingiberis Recens epidermis is smooth, bright, do not find to be subject to Rhizoma Zingiberis Recens Pnyxia scabiei larva (Rhizoma Zingiberis Recens maggot) to endanger Rhizoma Zingiberis Recens block.Rhizoma Zingiberis Recens after storage detects noresidue through world-class independent third party testing laboratory, complies fully with current export requirement, and economic and social benefit is notable.
In order to further illustrate the feasibility of method provided by the invention, illustrate below in conjunction with concrete test.
Store sth. in a cellar Rhizoma Zingiberis Recens Rhizoma Zingiberis Recens maggot because of preventing and treating and be not enrolled for pesticide, select the medicament phoxim of local currently used preventing and treating Rhizoma Zingiberis Recens maggot.
Table 1 Nylar virulence to Rhizoma Zingiberis Recens Pnyxia scabiei 3 instar larvae
Medicament Regression equation (y=) LC50(mg/L) 95% confidence limit
Phoxim 1.6883+1.8926x 56.208 46.463~67.997
Nylar 3.9133+1.8691x 3.8140 3.3374~4.3586
Found out by table 1 result, the Nylar LC to Rhizoma Zingiberis Recens Pnyxia scabiei 3 instar larvae 240h50For 3.8140mg/L, relatively comparison medicament phoxim (72hLC50Be 56.208) virulence high 14.7 times.But because Nylar belongs to juvenoid, Virulence Expression is slower, but the Rhizoma Zingiberis Recens actual control action of maggot population is very strong, so Nylar is the efficient medicament preventing and treating Rhizoma Zingiberis Recens maggot at present.
Medication in conjunction with Rhizoma Zingiberis Recens main producing region Jiang Nong such as Shandong is accustomed to, select above-described embodiment product, all utilize containing effective ingredient Nylar 15 grams, 30 grams, the dosage of 60 g ton Rhizoma Zingiberis Recenss to store Rhizoma Zingiberis Recens, wherein 1% Nylar powder is directly mixed homogeneously according to 1:10 ratio with fluvial sand, standby;0.5% Nylar granule, 25% wettable powder, 10% water dispersible granules are mixed homogeneously with fluvial sand after dissolving with a small amount of water again, standby;25% Nylar suspending agent, 15% Nylar microemulsion, 20% Nylar aqueous emulsion are mixed homogeneously with fluvial sand after being diluted with a small amount of water again, standby.The number of emerging of each process is observed after 10 days, with or without symptom of chemical damage performance etc. in dispenser.
The impact that Shandong Rhizoma Zingiberis Recens No. is germinateed by table 2 pesticidal preparations provided by the invention
From table 2 it can be seen that select above-described embodiment product, with effective ingredient 15 grams, 30 grams and 60 g ton Rhizoma Zingiberis Recenss dosage storage after the number of emerging of Shandong Rhizoma Zingiberis Recens No. there was no significant difference compared with the control, and show without symptom of chemical damage.
Table 3 compositions provided by the invention is on the middle areas in Shandong Province great Jiang impact germinateed
From table 3 it can be seen that select above-described embodiment product, with effective ingredient 15 grams, 30 grams and 60 g ton Rhizoma Zingiberis Recenss dosage storage after the number of emerging of middle areas in Shandong Province great Jiang there was no significant difference compared with the control, and show without symptom of chemical damage.
The impact that mountain agriculture one is germinateed by table 4 compositions provided by the invention
From table 4, it can be seen that select above-described embodiment product, with effective ingredient 15 grams, 30 grams and 60 g ton Rhizoma Zingiberis Recenss dosage storage after the number of emerging of mountain agriculture one there was no significant difference compared with the control, and show without symptom of chemical damage.
The impact of a table 5 compositions Shandong provided by the invention number plant height of Rhizoma Zingiberis Recens
As can be seen from Table 5, select above-described embodiment product, with effective ingredient 15 grams, 30 grams and 60 g ton Rhizoma Zingiberis Recenss dosage storage after Shandong Rhizoma Zingiberis Recens No., after dispenser 30 days, each dosage processes plant height and growth rate to Rhizoma Zingiberis Recens seedling and has no significant effect compared with the control, and show without obvious symptom of chemical damage, its safety coefficient reaches 4.
The impact of table 6 compositions provided by the invention middle areas in Shandong Province great Jiang plant height
As can be seen from Table 6, select above-described embodiment product, with effective ingredient 15 grams, 30 grams and 60 g ton Rhizoma Zingiberis Recenss dosage storage after middle areas in Shandong Province great Jiang, after dispenser 30 days, each dosage processes plant height and growth rate to Rhizoma Zingiberis Recens seedling and has no significant effect compared with the control, and show without obvious symptom of chemical damage, its safety coefficient reaches 4.
The impact of a table 7 agriculture number plant height in compositions mountain provided by the invention
As can be seen from Table 7, select above-described embodiment product, with effective ingredient 15 grams, 30 grams and 60 g ton Rhizoma Zingiberis Recenss dosage storage after mountain agriculture one, after dispenser 30 days, each dosage processes plant height and growth rate to Rhizoma Zingiberis Recens seedling and has no significant effect compared with the control, and show without obvious symptom of chemical damage, its safety coefficient reaches 4.
As can be seen here, pesticidal preparations for storing Rhizoma Zingiberis Recens provided by the invention can effectively prevent and treat the harm of great Jiang insect storage period (mainly Rhizoma Zingiberis Recens maggot), improve the quality of great Jiang storage period, reduce the drug residue of storage Rhizoma Zingiberis Recens simultaneously, reduce the storage period of the injury to human body.Therefore, pesticidal preparations provided by the invention may be used for storage Rhizoma Zingiberis Recens in Rhizoma Zingiberis Recens is stored, the harm of the insects such as preventing and treating Rhizoma Zingiberis Recens maggot (larva), Rhizoma Zingiberis Recens abnormity eye Tan mosquito (adult).
Those of ordinary skill in the field are it is understood that the foregoing is only specific embodiments of the invention; it is not limited to the present invention; all within the spirit and principles in the present invention, any amendment of making, equivalent replacement, improvement etc., should be included within protection scope of the present invention.

Claims (6)

1. the application process being used for storing the pesticidal preparations of Rhizoma Zingiberis Recens, it is characterised in that including:
Described pesticidal preparations and silt are mixed according to the weight ratio of 1:5~15, spreads fertilizer over the fields, in bottom, Rhizoma Zingiberis Recens cellar for storing things, the silt being mixed with described pesticidal preparations, on silt, then put Rhizoma Zingiberis Recens, then on Rhizoma Zingiberis Recens, spread fertilizer over the fields the silt being mixed with described pesticidal preparations;
The effective ingredient of the described pesticidal preparations for storing Rhizoma Zingiberis Recens is Nylar, and the mass fraction of described Nylar is 0.1~25%, and the described pesticidal preparations of pyriproxyfen-containing 15~60 grams used by Rhizoma Zingiberis Recens per ton.
2. the application process of the pesticidal preparations for storing Rhizoma Zingiberis Recens according to claim 1, it is characterised in that described pesticidal preparations and silt are mixed according to the mass ratio of 1:8~12.
3. the application process of the pesticidal preparations for storing Rhizoma Zingiberis Recens according to claim 1, it is characterised in that the humidity of described silt is 50~60%, fineness is 30~50 orders.
4. the application process of the pesticidal preparations for storing Rhizoma Zingiberis Recens according to claim 1, it is characterised in that described silt at least one in river sand, sea sand.
5. the application process of the pesticidal preparations for storing Rhizoma Zingiberis Recens according to claim 1, it is characterised in that described Nylar is active constituent content is 1~20%.
6. the application process of the pesticidal preparations for storing Rhizoma Zingiberis Recens according to claim 1, it is characterized in that, the processing dosage form of described pesticidal preparations is the one in powder, wettable powder, granule, water dispersible granules, cream, suspending agent, microemulsion and aqueous emulsion.
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