CN111657290A - Pesticide composition containing tetrachlorantraniliprole and tebufenozide - Google Patents
Pesticide composition containing tetrachlorantraniliprole and tebufenozide Download PDFInfo
- Publication number
- CN111657290A CN111657290A CN202010567871.7A CN202010567871A CN111657290A CN 111657290 A CN111657290 A CN 111657290A CN 202010567871 A CN202010567871 A CN 202010567871A CN 111657290 A CN111657290 A CN 111657290A
- Authority
- CN
- China
- Prior art keywords
- tebufenozide
- tetrachloro
- polyoxyethylene ether
- parts
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
Abstract
The invention discloses a pesticide composition containing tetrachloro-zooxanide and tebufenozide, which is a binary composition comprising tetrachloro-zooxanide and tebufenozide as effective components, wherein the weight part ratio of the active components is 1: 1; the weight percentage of active components in the composition is 5-85%. Can be prepared into pesticide preparations such as suspending agents, dispersible oil suspending agents, water dispersible granules and the like by adopting a general method. The pesticide composition of the invention is safe to cabbage. The pesticide composition has simple preparation method and convenient application, and can effectively prevent cabbage caterpillars.
Description
Technical Field
The invention relates to an agricultural insecticide, and in particular relates to an insecticide composition formed by binary compounding of tetrachlorantraniliprole and tebufenozide.
Background
Tetrachloro insect amide: the insecticidal spectrum of the compound is close to that of chlorantraniliprole, and the compound can be used for controlling various pests, and particularly has an outstanding control effect on lepidoptera pests. But the dosage of 15 ml/bag is higher than that of chlorantraniliprole (equal to the dosage of 1.5 bags of chlorantraniliprole), so that the death rate is higher and the lasting period is longer in actual use.
Tebufenozide is a novel non-steroidal insect growth regulator, and is a newly developed insect hormone pesticide. The tebufenozide has high insecticidal activity and strong selectivity, is effective to all lepidoptera larvae, and has special effects on resistant pests, such as cotton bollworms, cabbage caterpillars, diamond back moths, beet armyworms and the like.
The problems of medicament residue, environmental pollution, development of drug-resistant fungi and the like are easily caused by continuously applying a single chemical bactericide at a high dose for a long time, and bactericide compounding is one of the most effective methods for solving the problems.
Disclosure of Invention
In order to solve the technical problems, the invention provides a pesticide composition containing tetrachlorantraniliprole and tebufenozide. Has obvious synergistic effect through compounding.
The invention provides the following technical scheme:
the pesticide composition comprises tetrachloro-zooxanide and tebufenozide as active ingredients and the balance of auxiliary ingredients, wherein the weight ratio of the active ingredients is 1:1, and the active ingredients in the composition account for 5-85% of the mass of the whole preparation.
The auxiliary components comprise surfactant, antiseptic, antifreeze and thickener.
A surfactant, which may be an emulsifier, dispersant or wetting agent; may be non-ionic or ionic.
The anionic surfactant comprises one or more of sulfonate, sulfate, carboxylate, phosphate, succinate, lignosulfonate and acrylamide acrylic acid copolymer.
The nonionic surfactant comprises one or more of fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene ether, fatty amine polyoxyethylene ether, fatty acid polyoxyethylene ether, acid alcohol ester and polyoxyethylene ether thereof, fatty amide and polyoxyethylene ether thereof, alkanolamide and polyoxyethylene ether thereof, polyoxyethylene polyoxypropylene ether block copolymer, alkyl sodium naphthalene sulfonate fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester polyoxyethylene ether. Such as: SK-20TX, SK-21K, SK-24, SK-24R, SK-25CH, SK-33L, SK-33H, SK-35PQ, SK-551, SK-560EP, SK-92FS1, SK-355, SK-5110, SK-5935, YUS-FS1, YUS-FS3000, YUFS 3300, YUS-FS7 FS PG, YUS-TXC, YUS-WG4, YUS-A51G, YUS-D1109S, YUS-EP60P, YUS-207K, YUS-5050PB, YUS-RXB, SP-2728, SP-27001, SP-2750, SP-SC3, SP-SC29, SP-SC3060, SP-6366 SD E, SP-28F, SD 11, 813, Grnsperse 6, Grnsperse 23, MUDA 2827, MUDA 282827, NEXLOL 30680, NEXLOL 30613, NEXLOBE 3680, NEXLOBE 3, NEE-27, NEXLOBE 3, NEXLOL 3645, NEXLOL 3068, NEE-ASE-DE 3645, NEXLOL-ASE-S-80, NEXLOAD-ASE 3, NEX, D305, D518, DF200, DF400, DF500, DF600, D510, sodium methylnaphthalenesulfonate formaldehyde condensates, FS981, YUS-CH1100, YUS-110, YUS-EC2200, YUS-OD1200, YUS135B, YUS-D935, SP-OF3462, SP-OF3472, Greenmul EF68, Atlox 4912, Atlox 4914, D800, GR7M, SK01J, SK10LX, SK-20GR, SK-21, SK-31SX 661, SK-34SC, SK-541B, PICO-WG7, PICO-NW1, PICO-NW2, YUS-CH7000, PICO-CS300M, YUS-LXC, YUS-SP 1203, YUS-JS 1420, PICO-539JS 7, PICO-30, PICO-JK wetting agent, PICO-JSD 819, PICO-CS300M, YUS-LXC, YUS-SP 819, PICO-SP 610, PICO-JS, PICO-JS 28819, PICO-WO 2-NV 816, sodium alkyl sulfonate, sodium salt dispersant, FINSW 685-610, FIW-WO 685-WO 46, sodium salt OF starch, SP2836, dispersant SupergilMNS/90, wetting agent YUS-SXC, dispersant Soprophor FD, calcium lignosulfonate, alkyl naphthalene sulfonate formaldehyde condensate (NNO), and the like.
The antiseptic is selected from Kathon, EQ or sodium benzoate.
The antifreeze is one or two of ethylene glycol, 1, 2-propylene glycol, glycerol and urea.
Suspending agent (thickener) such as xanthan gum, gelatin, gum arabic, polyvinylpyrrolidone, magnesium aluminum silicate, polyvinyl alcohol, polyethylene glycol, methylcellulose, white carbon black, soluble starch, carboxymethyl cellulose or sodium alginate is added into the preparation in form of powder, granule or latex.
The carrier included in the fungicidal preparation composition of the present invention, and any carrier generally used for formulating fungicidal compositions can be used. Such as: water, methyl cellosolve, methyl oleate, ethyl oleate, vegetable oil, methylated vegetable oil and the like. Mixtures of different liquids are often suitable.
Compared with the prior art, the invention has the beneficial effects that: according to the invention, the tetrachlorantraniliprole and the tebufenozide are compounded, the co-toxicity coefficient of the toxicity test on cabbage caterpillars is more than 200, the compounding shows a synergistic effect, and the plant growth can be improved by using less amount. The pesticide composition of the invention is safe to cabbage. The pesticide composition has simple preparation method and convenient application, and can effectively prevent cabbage caterpillars.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
10% tetrachloro-worm-amide-tebufenozide suspension
According to the formula requirement, 5 parts of tetrachloro-tetramisole, 5 parts of tebufenozide, 3 parts of YUS-FS1, 5 parts of SP-28F, 5 parts of SP-3266E, 2 parts of magnesium aluminum silicate, 1 part of white carbon black, 0.25 part of xanthan gum, 0.4 part of EQ, 4 parts of ethylene glycol and the balance of water are sequentially added into a mixing tank, coarse crushing and homogenization are performed through high shear, then the mixture is pumped into a sand mill for fine grinding, a particle size distribution instrument detects the particle size of a ground material, and after the particle size reaches the standard requirement, filtration is performed to obtain the 10% tetrachloro-tetramisole tebufenozide suspending agent.
Example 2
20% tetrachloro-worm-amide-tebufenozide suspending agent
According to the formula requirement, 10 parts of tetrachloro-zoomid, 10 parts of tebufenozide, 2 parts of SK-20TX, 5 parts of SD811, 4 parts of YUS-FS3000, 3 parts of SP-27001, 2 parts of SP-3266E, 0.8 part of magnesium aluminum silicate, 0.8 part of white carbon black, 0.16 part of xanthan gum, 0.2 part of EQ, 4 parts of 1, 2-propylene glycol and the balance of water are sequentially added into a mixing tank, coarse crushing and homogenization are carried out through high shear, then the mixture is pumped into a sand mill for fine grinding, a particle size distribution instrument detects the particle size of a sand grinding material, and after the particle size reaches the standard requirement, filtration is carried out, so that the 20% tetrachloro-zoomid-tebufenozide suspending agent can be obtained.
Example 3
30% tetrachloro-tebufenozide suspension
According to the formula requirement, 15 parts of tetrachloro-zoon amide, 15 parts of tebufenozide, 2 parts of YUS-TXC, 5 parts of GreenspermeBE 02, 3 parts of SD811, 3 parts of SK-20TX, 2 parts of agricultural milk 1601, 0.5 part of magnesium aluminum silicate, 0.5 part of white carbon black, 0.15 part of xanthan gum, 0.3 part of kasong, 4 parts of glycerol and the balance of water are sequentially added into a mixing tank, coarse crushing and homogenization are carried out through high shear, then the mixture is pumped into a sand mill for fine milling, a particle size distribution instrument is used for detecting the particle size of a sanded material, and after the particle size reaches the standard requirement, filtration is carried out, so that the 30% of tetrachloro-zoon amide-tebufenozide suspending agent can be obtained.
Example 4
40% tetrachloro-tetramat-tebufenozide suspension
According to the formula requirement, 20 parts of tetrachloro-zoomid, 20 parts of tebufenozide, 5 parts of SP-2728, 5 parts of SP-SC29, 4 parts of Nongru 0201B, 2 parts of SK-560EP, 0.4 part of magnesium aluminum silicate, 0.4 part of white carbon black, 0.1 part of xanthan gum, 0.2 part of EQ, 4 parts of ethylene glycol and the balance of water are sequentially added into a mixing tank, coarse crushing and homogenization are performed through high shear, then the mixture is pumped into a sand mill for fine grinding, a particle size distribution instrument detects the particle size of a sand-ground material, and after the particle size reaches the standard requirement, the mixture is filtered, so that the 40% tetrachloro-zoomid-tebufenozide suspending agent is obtained.
Example 5
10% tetrachloro-tetramat-tebufenozide dispersible oil suspending agent
According to the formula requirement, 5 parts OF tetrachloro-tetramisole, 5 parts OF tebufenozide, 5 parts OF a dispersant SP-OF34 3472B, 5 parts OF a dispersant SP-OF3468, 4 parts OF Nongru 0201B, 2 parts OF Nongru 500, 2 parts OF bentonite, 1 part OF white carbon black and the balance OF methyl oleate are sequentially added into a mixing tank for mixing, coarse crushing and homogenization are firstly carried out through high shear, then the mixture is pumped into a sand mill for fine grinding, the granularity OF the ground material is detected by a granularity distribution instrument, and after the granularity reaches the standard requirement, the filtration is carried out, so that the 10% tetrachloro-tetramisole-tebufenozide dispersible oil suspending agent can be obtained.
Example 6
20% tetrachloro-tetramat-tebufenozide dispersible oil suspending agent
According to the formula requirement, 10 parts of tetrachloro-zoomid, 10 parts of tebufenozide, 4 parts of dispersant Greenmul EF68, 5 parts of dispersant Atlox 4912, 5 parts of YUS-EC2200, 2 parts of agricultural emulsion 1601, 1 part of bentonite, 1 part of white carbon black and the balance of methyl oleate are sequentially added into a mixing tank for mixing, firstly, high shear is carried out for coarse crushing and homogenization, then, the mixture is pumped into a sand mill for fine grinding, a particle size distribution instrument is used for detecting the particle size of the ground material, and after the particle size reaches the standard requirement, the filtration is carried out, thus obtaining the 20% tetrachloro-zoomid-tebufenozide dispersible oil suspending agent.
Example 7
Dispersible oil suspending agent containing 30% of tetrachloro-tetramat and tebufenozide
According to the formula requirement, 15 parts OF tetrachloro-zoomid, 15 parts OF tebufenozide, 4 parts OF dispersant YUS-OD1200, 3 parts OF dispersant D305, 3 parts OF dispersant SP-OF3472B, 5 parts OF agricultural emulsifier 0201B, 1 part OF organic bentonite and the balance OF methyl oleate are sequentially added into a mixing tank for mixing, coarse crushing and homogenization are firstly carried out through high shear, then the mixture is pumped into a sand mill for fine grinding, the granularity OF the ground material is detected by a granularity distributor, and after the granularity reaches the standard requirement, the mixture is filtered, so that the 30% tetrachloro-zoomid-tebufenozide dispersible oil suspending agent can be obtained.
Example 8
40% tetrachloro-tetramat-tebufenozide dispersible oil suspending agent
According to the formula requirement, 20 parts of tetrachloro-zoomid, 20 parts of tebufenozide, 4 parts of dispersant Greenmul EF68, 5 parts of YUS-D935, 4 parts of Nongru 0201B, 2 parts of Nongru 500, 1 part of organic bentonite and the balance of methyl oleate are sequentially added into a mixing tank for mixing, coarse crushing and homogenization are performed through high shear, then the mixture is pumped into a sand mill for fine grinding, the granularity of the sand-ground material is detected through a granularity distribution instrument, and after the granularity reaches the standard requirement, the mixture is filtered, so that the 40% tetrachloro-zoomid-tebufenozide dispersible oil suspending agent can be obtained.
Example 9
Preparation of 50% tetrachloro-tetramide-tebufenozide water dispersible granule
According to the formula requirement, 25 parts of tetrachloro-zoon amide, 25 parts of tebufenozide, 1 part of Morwet EFW, 6 parts of dispersant YUS-WG5, 4 parts of sodium salt of alkyl naphthalene sulfonic acid polycondensate, 4 parts of SD819, 8 parts of soluble starch, 10 parts of sodium sulfate and the balance of bentonite are added together, mixed and crushed, and then added into a granulator with a screen of a certain specification for granulation after being kneaded by adding water. Then drying and screening (according to the range of a screen) are carried out, thus obtaining the 50% tetrachloro-tetramethrin-tebufenozide water dispersible granule.
Example 10
Preparation of 70% tetrachloro-tebufenozide water dispersible granule
According to the formula requirement, 35 parts of tetrachloro-zoonoside, 35 parts of tensofix, 1 part of wetting agent TENSILOXX BCZ, 4 parts of dispersant PICO-CS300M, 5 parts of YUS-WG4, 4 parts of alkyl naphthalene sulfonate formaldehyde condensate, 5 parts of soluble starch and the balance of bentonite are added together, mixed and crushed, and then added into a granulator with a sieve with certain specification for granulation after being kneaded by adding water. Then drying and screening (according to the range of a screen) are carried out, thus obtaining the 70% tetrachloro-tetramethrin-tebufenozide water dispersible granule.
Results of virulence determination
Table 1 Analyzer table of toxicity test results of tetrachlorantraniliprole and tebufenozide compound on cabbage caterpillar
| Reagent for testing | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Tetrachlorantraniliprole | - | 0.55 | - |
| Tebufenozide | - | 4.35 | - |
| Tetrachloro insect amide: tebufenozide | 1∶1 | 0.46 | 238.83 |
When the ratio of the tetrachloro-zooxanide to the tebufenozide to the cabbage caterpillar is 1:1, the co-toxicity coefficient is 238.83, which shows that the synergistic effect is shown when the tetrachloro-zooxanide and the tebufenozide are mixed at 1: 1.
Table 2 efficacy test of compounding tetrachlorantraniliprole and tebufenozide for preventing cabbage caterpillars
As can be seen from the table 2, after the tetrachlorantraniliprole and the tebufenozide are compounded, the cabbage caterpillar can be effectively controlled, the control effect is superior to that of a single dose, and the cabbage diamondback moth can be controlled, and the control effect is more than 95%. Has no adverse effect on target crops in the application range of the test.
The compositions of the present invention have synergistic effects which complement each other and improve plant growth using a smaller amount. The pesticide composition of the invention is safe to cabbage. The pesticide composition has simple preparation method and convenient application, and can effectively prevent cabbage caterpillars.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (9)
1. A pesticide composition of tetrachloro-zooxanide and tebufenozide is characterized in that: the bactericide composition takes tetrachloro-zooxanthamide and tebufenozide as active ingredients and the balance auxiliary ingredients, the weight ratio of the active ingredients is 1:1, and the active ingredients in the composition account for 5-85% of the mass of the whole preparation.
2. The insecticidal composition of tetrachloro insect amide and tebufenozide of claim 1, wherein: the auxiliary components comprise surfactant, antiseptic, antifreeze and thickener.
3. The insecticidal composition of tetrachloro insect amide and tebufenozide of claim 2, wherein: the surfactant is emulsifier, dispersant, wetting agent, nonionic or ionic.
4. The insecticidal composition of tetrachloro insect amide and tebufenozide of claim 3, wherein: the ionic type adopts anionic surfactant, and the anionic surfactant comprises one or more of sulfonate, sulfate, carboxylate, phosphate, succinate, lignosulfonate and acrylamide acrylic copolymer.
5. The insecticidal composition of tetrachloro insect amide and tebufenozide of claim 3, wherein: the nonionic surfactant comprises one or more of fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene ether, fatty amine polyoxyethylene ether, fatty acid polyoxyethylene ether, acid alcohol ester and polyoxyethylene ether thereof, fatty amide and polyoxyethylene ether thereof, alkanolamide and polyoxyethylene ether thereof, polyoxyethylene polyoxypropylene ether block copolymer, alkyl sodium naphthalene sulfonate fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester polyoxyethylene ether.
6. The insecticidal composition of tetrachloro insect amide and tebufenozide of claim 2, wherein: the preservative is cason, EQ or sodium benzoate.
7. The insecticidal composition of tetrachloro insect amide and tebufenozide of claim 2, wherein: the antifreezing agent is one or two of ethylene glycol, 1, 2-propylene glycol, glycerol and urea.
8. The insecticidal composition of tetrachloro insect amide and tebufenozide of claim 2, wherein: the thickening agent is xanthan gum, gelatin, gum arabic, polyvinylpyrrolidone, magnesium aluminum silicate, polyvinyl alcohol, polyethylene glycol, methyl cellulose, white carbon black, soluble starch, carboxymethyl cellulose or sodium alginate, and is added into the preparation in the form of powder, granule or latex.
9. The application of the pesticide composition of tetrachloro insect amide and tebufenozide of claim 1, which is characterized in that: the composition can be used for preventing and treating cabbage caterpillar.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010567871.7A CN111657290A (en) | 2020-06-19 | 2020-06-19 | Pesticide composition containing tetrachlorantraniliprole and tebufenozide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010567871.7A CN111657290A (en) | 2020-06-19 | 2020-06-19 | Pesticide composition containing tetrachlorantraniliprole and tebufenozide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111657290A true CN111657290A (en) | 2020-09-15 |
Family
ID=72389102
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010567871.7A Pending CN111657290A (en) | 2020-06-19 | 2020-06-19 | Pesticide composition containing tetrachlorantraniliprole and tebufenozide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111657290A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103688942A (en) * | 2013-12-19 | 2014-04-02 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition |
| CN103918685A (en) * | 2013-01-11 | 2014-07-16 | 陕西汤普森生物科技有限公司 | Insect disinfestation composition containing tetrachlorantraniliprole |
-
2020
- 2020-06-19 CN CN202010567871.7A patent/CN111657290A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103918685A (en) * | 2013-01-11 | 2014-07-16 | 陕西汤普森生物科技有限公司 | Insect disinfestation composition containing tetrachlorantraniliprole |
| CN103688942A (en) * | 2013-12-19 | 2014-04-02 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104663670B (en) | One kind collaboration miticide composition | |
| CN103380778A (en) | Pesticide composition of thiamethoxam and azoxystrobin | |
| CN1113600C (en) | Herbicide composition | |
| CN111820223A (en) | Tetrachlorantraniliprole and thiacloprid pesticide composition | |
| CN111657290A (en) | Pesticide composition containing tetrachlorantraniliprole and tebufenozide | |
| CN104115861A (en) | Insect and mite killing composition containing xiaochongthion and cyflumetofen | |
| CN104663688B (en) | A kind of insecticide acaricide composition containing Bifenazate | |
| CN104920368A (en) | Pesticide composite comprising fluroxypyr and benzobicyclon and application of pesticide composite in prevention of lemnaceae plants | |
| CN104381294A (en) | Insect and mite killing composition containing xiaochongliulin and spirodiclofen | |
| CN104642373A (en) | Insecticide composition containing chlorine-fluorine cyantraniliprole and high-efficiency chlorine-fluorine clocythrin | |
| CN104286010B (en) | Composition pesticide containing sulfur-phosphor and Bifenazate | |
| CN114246186A (en) | Dispersible oil suspending agent containing kojic acid and cyantraniliprole as well as preparation method and application thereof | |
| CN106993624A (en) | A kind of composition pesticide | |
| CN108651505A (en) | A kind of composition pesticide containing guadipyr and (R)-4-isopropenyl-1-methyl-1-cyclohexene | |
| CN111567540A (en) | Bactericide agent composition containing flumorph and pyraclostrobin | |
| CN107711868B (en) | Bactericidal composition containing prochloraz and biological antibacterial substance HSAF and application thereof | |
| UA58490C2 (en) | FUNGICIDAL COMPOSITION AND METHOD FOR TREATMENT OF CROPS for control or prophylaxis of fungicidal attacks | |
| CN110973167A (en) | Pesticide composition containing fructus psoraleae seed extract | |
| CN110250183A (en) | A kind of composition and application thereof comprising S-Ethyl ethylthio sulfonate and jinggangmeisu | |
| CN111567538A (en) | Bactericide composition containing flumorph and prothioconazole | |
| CN108849933A (en) | A kind of composition pesticide containing (R)-4-isopropenyl-1-methyl-1-cyclohexene and paichongding | |
| CN110477025B (en) | Pesticide composition for muscovidae pests and application thereof | |
| CN111700069A (en) | Fungicide composition containing flumorph and fluopicolide | |
| CN114097813B (en) | Suspending agent containing indoxacarb and methoxyfenozide and preparation method thereof | |
| CN108402072A (en) | A kind of composition pesticide containing sulfime ether and guadipyr |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200915 |
|
| RJ01 | Rejection of invention patent application after publication |