CN104757006A - Pesticide composition containing trifluzamide - Google Patents
Pesticide composition containing trifluzamide Download PDFInfo
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- CN104757006A CN104757006A CN201510163180.XA CN201510163180A CN104757006A CN 104757006 A CN104757006 A CN 104757006A CN 201510163180 A CN201510163180 A CN 201510163180A CN 104757006 A CN104757006 A CN 104757006A
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- thifluzamide
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Abstract
The invention relates to a pesticide composition containing trifluzamide and a second active ingredient, wherein the second active ingredient is one or two selected from pymetrozine and dinotefuran, and the weight ratio of pymetrozine to dinotefuran is (1: 3)-(3: 1). The pesticide composition after compounding can treat both plant diseases and insect pests, and trifluzamide has a good bactericidal effect against a variety of fungal diseases and can enable stems and leaves after processing to be healthy and dark green, improve the stress resistance and the absorbing power against a pesticide solution of plants and realize synergy by compounding with a pesticide.
Description
Technical field
The present invention relates to composition pesticide, particularly comprise the composition pesticide of thifluzamide, particularly comprise the composition pesticide of thifluzamide and pymetrozine and/or MTI-446, described composition is for preventing and treating multiple rice disease and insect.
Technical background
Thifluzamide (Thifluzamide) belongs to thiazole amide bactericide, has strong Uptake and translocation and long lasting effect.All there is activity to pathomycetes such as Rhizoctonia, Puccinia, Ustilago, Tilletia, corticium, nuclear cavity Pseudomonas, especially have special efficacy to the fungus-caused disease of Basidiomycetes such as banded sclerotial blight, damping off etc.
At present when carrying out the control of rice stem base portion damage by disease and insect, the traditional spray pattern of usual employing carries out, liquid the unconspicuous medicament of systemic action is difficult to directly spray application to paddy rice base portion, causes liquid waste to have cannot to play its preventive and therapeutic effect to damage by disease and insect; Even if there is the medicament of interior absorption, after the routine spraying of blade face, reject the part of drift, loss photodissociation, the dosage that the medicament of the active component of interior suction is delivered to paddy rice base portion also reduces greatly, the medicament being delivered to rice stem base portion is had a greatly reduced quality, so control efficiency is undesirable.In addition, traditional spray-on process, labour intensity is high, and work efficiency is low, and water consumption is large, is difficult to the needs meeting large-scale planting; Along with the enforcement of China's land transformation policy, soil presents the trend of intensive management, and crop contiguous plant area increases; And China's population aging degree continues to increase now, between twenty and fifty Out-migrant for work mostly in rural area, agricultural labour becomes rare resource gradually, and human cost improves constantly, and the cost directly causing agricultural to become to produce continues to increase.
The single control of the normally sick worm of control of rice pest, time-consumingly takes a lot of work, and dosage is large, contaminated environment; Thifluzamide and pymetrozine effectively composite, can reduce effective ingredient consumption, applied once, double insect pest of curing the disease, time and labour saving; Further, the crop cauline leaf after thifluzamide process can be more healthy dark green, effectively can improve the resistance of crop and the absorbing capacity to liquid, with pesticide compositional, play synergistic function.
Summary of the invention
The object of the present invention is to provide reasonable, the remarkable synergy of a kind of component, the composition pesticide of the high-efficiency low-toxicity that pesticide-germicide is effective.
Above-mentioned purpose is achieved by the following technical solution:
A kind of composition pesticide, it is characterized in that, described composition pesticide active component is thifluzamide and the second active component, described second active component be selected from pymetrozine and MTI-446 one or both, the weight ratio of thifluzamide and the second active component is 1:3-3:1.
Preferably, the weight ratio of the two is 1:1-1:3; Be more preferably 1:1.
The total amount of thifluzamide and the second active component is the 0.1-20% of described composition total weight, is preferably 2-15%, is more preferably 5-12%.
Composition pesticide of the present invention is missible oil, suspended emulsion or granule according to the preparation formulation that method known in those skilled in the art can be prepared.Particularly preferably granule.
For missible oil, those skilled in the art are familiar with the corresponding auxiliary agent of use and complete the present invention very much.Emulsifier is as calcium dodecyl benzene sulfonate (agriculture breast 500#), Nongru-700 # (common name: alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201#, this dish-60# (common name: Span60), Tween-60 # (common name: polyoxyethylene sorbitan stearate), TX-10 (common name: octyl phenol polyoxyethylene (10) ether), agriculture breast 1601# (common name: triphenoethyl benzene phenol polyoxyethylene polyoxypropylene block polymer), agriculture breast 600#, agriculture breast 400# in one or more, stabilizing agent as in triphenyl phosphite, triphenyl phosphate, epoxychloropropane, aceticanhydride one or more, solvent as in dimethylbenzene, toluene, solvent naphtha (S-150, S-180, S-200), toluene, methyl alcohol, dimethyl formamide, 1-METHYLPYRROLIDONE, cyclohexanone, acetone, dimethyl sulfoxide (DMSO) one or more.
To suspended emulsion, spendable auxiliary agent has: dispersant as in polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate (dispersing agent NNO), TERSPERSE2425 (Huntsman Corporation of the U.S. produce, alkyl naphthalene sulfonic acid salt) one or more; Emulsifier is as one or more in Nongru-700 # (common name: alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201, this dish-60# (common name: sorbitan monostearate), Tween-60 # (common name: sorbitan monostearate APEO), agriculture breast 1601# (common name: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), triphen ethyl phenol polyoxyethylene groups ether phosphate, TERSPERSE 4894 (Huntsman Corporation of U.S. product); Wetting agent as in alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE2500 one or more; Solvent: one or more in dimethylbenzene, toluene, cyclohexanone, acetone, ethyl acetate, solvent naphtha (S-150, S-180, S-200); Thickener as in xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate one or more; Preservative as in formaldehyde, benzoic acid, Sodium Benzoate one or more; Defoamer is as organic silicon defoamer; Antifreezing agent as ethylene glycol, propane diols, glycerine, urea, inorganic salts as in sodium chloride one or more; Stabilizing agent as in triphenyl phosphite, triphenyl phosphate, epoxychloropropane, aceticanhydride one or more; Water is deionized water.
To granule, spendable auxiliary agent has: carrier is as clay, kaolin, talcum, calcium carbonate, diatomite, corn starch, alumina silicate, attapulgite etc.; Dispersant as in polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate one or more; Wetting agent as in alkyl sulfate, alkylsulfonate, naphthalene sulfonate one or more; Sustained release agent is the one in polyvinyl alcohol, gum Arabic; Stabilizing agent as in such as triphenyl phosphite, triphenyl phosphate, epoxychloropropane, aceticanhydride one or more; Adhesive as in polyvinyl alcohol, dextrin, polyvinylpyrrolidone one or more.
Preferably, the invention provides a kind of composition pesticide granule, it is characterized in that, the thifluzamide and the second active component, the polyvinylpyrrolidone that comprise 10 % by weight in described composition pesticide are 4-8 % by weight, sodium lignin sulfonate 5-8 % by weight, and surplus is filler; The weight ratio of described thifluzamide and the second active component is 1:3; Described filler is the filler being selected from one or more kaolin, calcium carbonate, alumina silicate, attapulgite.More preferably, described filler is be selected from kaolin and weight of calcium carbonate than the compounded mix for 1:1.
Further, the invention further relates to above-mentioned composition pesticide is used for preventing and treating rice disease, particularly rice sheath blight disease and Brown Planthopper.
The technological merit of the above-mentioned composition pesticide of the present invention is:
1) composite rear damage by disease and insect is double controls, thifluzamide is except having good bactericidal effect to many kinds of fungal diseases, and treated cauline leaf can be healthy dark green, improves the resistance of plant and the absorbing capacity to liquid, with pesticide compositional, play the effect of Synergistic.
2) time and labour saving.Compared with traditional insecticide-applying way, simple to operate when the present invention uses, without the need to adding water or mixing soil, adopt seedling dish process or spread fertilizer over the fields, using conveniently, without the need to using machinery, time saving and energy saving.Use the conventional dispenser of product every mu ratio of the present invention to improve work efficiency 6-8 doubly, greatly alleviate dispenser labour intensity, the workload effectively solving traditional application method is heavy consuming time, the problems such as work efficiency is low.
3) improve the availability of pesticide active ingredient, improve control efficiency, reduce dosage.Especially, the composition pesticide of the application is prepared into granule, root application, and active ingredient from root absorption, then enters into crop plant tissue inside and plays a role, and improves the availability of farm chemical ingredients; In water under the effect of dispersant sodium lignin sulfonate, assemble at rice stem base portion, directly can contact scab and the Brown Planthopper of rice sheath blight disease, especially improve the control efficiency to rice stem base portion damage by disease and insect, reduce dosage.In addition, the active ingredient release in the controlled granulation agent of sustained release agent, extends the lasting period.
4) dispenser weatherproof, prevents float of mist droplet during conventional spray pesticide simultaneously, decreases the harm to people, animal.
Embodiment
In order to prevent and treat brown planthopper on paddy rice and rice sheath blight disease, thifluzamide and pymetrozine or MTI-446 have been carried out mutual composite synergy research by applicant.
Toxicity Determination:
The indoor virulence of table 1 pair Brown Planthopper and Rhizoctonia solani Kuhn
From the data in table 1, thifluzamide and pymetrozine or MTI-446 composite after, compare single dose, have obvious synergistic effect to the preventive effect of Brown Planthopper and banded sclerotial blight, when the ratio of the two is 1:3, it is the most obvious to the synergistic effect of brown planthopper, when the ratio of the two is 3:1, it is the most obvious to the synergistic effect of Rhizoctonia solani Kuhn, when the two is 1:1, all has good synergistic effect to brown planthopper and banded sclerotial blight germ simultaneously.
Above-mentioned test method is with reference to " People's Republic of China (PRC) agricultural industry criteria NY/T1154.6-2006 ".
Example of formulations 1
Take 15% thifluzamide, 5% pymetrozine, 4% agriculture breast 500#, 2% agriculture breast 600#, 3% agriculture breast 2201#, 1% triphenyl phosphite, 2% dimethyl sulfoxide (DMSO), dimethylbenzene add to 100% weight portion.Above-mentioned raw materials is through mixing, and stirring and dissolving is obtained 20% thifluzamide pymetrozine missible oil completely afterwards.
Example of formulations 2
Take 6% thifluzamide, 6% pymetrozine, 2.5% triphen ethyl phenol polyoxyethylene groups ether phosphate, 1.5% dispersing agent NNO, 4%TERSPERSE4894 (Huntsman Corporation of U.S. product), 10% toluene, 3.5% this dish-60#, 3.5% Tween-60 #, 1%TERSPERSE2500 (Huntsman Corporation of U.S. product), 2% aluminium-magnesium silicate, 0.2% xanthans, 5% ethylene glycol, 1% epoxychloropropane, 0.3% benzoic acid, 0.5% silicone defoaming agent (trade name: s-29 Nanjing "four news" (new ideas applied chemistry product Company), deionized water adds to 100% weight portion.Operating procedure: 1, in above-mentioned raw materials thifluzamide and dissolution with solvents completely after add emulsifier and stabilizing agent mixes, 2, unclassified stores is through mixing, 3, drop in 2 materials by mixing material in 1, high speed shear dispersion 30min, with 12% thifluzamide pymetrozine suspension emulsion obtained after sand mill sand milling.
Example of formulations 3
Take 15% thifluzamide, 5% pymetrozine, 3% sodium lignin sulfonate, 2% neopelex, 3% polyvinyl alcohol, 3% triphenyl phosphite, kaolin adds to 100% weight portion.Add water mentioned component kneading, uses pinch-out granulator pinch out and be shaped, afterwards by particle fluid-bed drying, and adjustment particle size, obtained 20% thifluzamide pymetrozine granule.
Example of formulations 4
Take 6% thifluzamide, 6% pymetrozine, 3% sodium lignin sulfonate, 2% neopelex, 3% polyvinyl alcohol, 3% triphenyl phosphite, kaolin adds to 100% weight portion.Add water mentioned component kneading, uses pinch-out granulator pinch out and be shaped, afterwards by particle fluid-bed drying, and adjustment particle size, obtained 12% thifluzamide pymetrozine granule.
Example of formulations 5
Take 5% thifluzamide, 5% pymetrozine, the polyvinylpyrrolidone of 6%, the sodium lignin sulfonate of 8%, kaolin adds to 100% weight portion.Add water mentioned component kneading, uses pinch-out granulator pinch out and be shaped, afterwards by particle fluid-bed drying, and adjustment particle size, obtained 10% thifluzamide pymetrozine granule.
Example of formulations 6
Take 5% thifluzamide, 5% pymetrozine, the polyvinylpyrrolidone of 6%, the sodium lignin sulfonate of 8%, weight ratio is that the kaolin of 1:1 and calcium carbonate add to 100% weight portion as compounded mix.Add water mentioned component kneading, uses pinch-out granulator pinch out and be shaped, afterwards by particle fluid-bed drying, and adjustment particle size, obtained 10% thifluzamide pymetrozine granule.
Example of formulations 7-12: except pymetrozine is wherein replaced with except MTI-446, all the other correspond respectively to example of formulations 1-6, namely obtain 20% thifluzamide MTI-446 missible oil, 12% thifluzamide MTI-446 suspended emulsion, 20% thifluzamide MTI-446 granule, 12% thifluzamide MTI-446 granule, 10% thifluzamide MTI-446 granule and 10% thifluzamide MTI-446 granule respectively.
Comparative examples 1
Take 10% thifluzamide, the polyvinylpyrrolidone of 6%, the sodium lignin sulfonate of 8%, weight ratio is that the kaolin of 1:1 and calcium carbonate add to 100% weight portion as compounded mix.Add water mentioned component kneading, uses pinch-out granulator pinch out and be shaped, afterwards by particle fluid-bed drying, and adjustment particle size, obtained 10% thifluzamide granule.
Comparative examples 2
Take 10% pymetrozine, the polyvinylpyrrolidone of 6%, the sodium lignin sulfonate of 8%, weight ratio is that the kaolin of 1:1 and calcium carbonate add to 100% weight portion as compounded mix.Add water mentioned component kneading, uses pinch-out granulator pinch out and be shaped, afterwards by particle fluid-bed drying, and adjustment particle size, obtained 10% pymetrozine granule.
Comparative examples 3
Take 10% MTI-446, the polyvinylpyrrolidone of 6%, the sodium lignin sulfonate of 8%, weight ratio is that the kaolin of 1:1 and calcium carbonate add to 100% weight portion as compounded mix.Add water mentioned component kneading, uses pinch-out granulator pinch out and be shaped, afterwards by particle fluid-bed drying, and adjustment particle size, obtained 10% MTI-446 granule.
Field trial:
The preventive effect of table 2 pair rice hoppers and rice sheath blight disease
From the data in table 2, thifluzamide and pymetrozine or MTI-446 composite after, compare single dose, have obvious synergistic effect in field to the preventive effect of rice hoppers and banded sclerotial blight; Under identical active ingredient, same amount, the field efficacy of granule is higher than the drug effect of missible oil, suspending agent, in addition when the specific granule auxiliary agent of selection, particularly during specific filler, its effect is optimum, the effect of the i.e. granule of embodiment 4, embodiment 5, embodiment 6, and embodiment 10,11 and 12 is more excellent successively.
A kind of composition pesticide comprising thifluzamide of the present invention is described by concrete example, those skilled in the art can use for reference content of the present invention, the links such as suitable feed change, process conditions realize other object corresponding, its relevant change does not all depart from content of the present invention, all similar replacements and change will become apparent to those skilled in the art that and be all deemed to be included within scope of the present invention.
Claims (10)
1. a composition pesticide, it is characterized in that, described composition pesticide active component is thifluzamide and the second active component, described second active component be selected from pymetrozine and MTI-446 one or both, the weight ratio of thifluzamide and the second active component is 1:3-3:1.
2. composition pesticide according to claim 1, is characterized in that, the weight ratio of the two is 1:1-1:3.
3. composition pesticide according to claim 1, is characterized in that, the weight ratio of the two is 1:1.
4. composition pesticide according to claim 1, is characterized in that, the total amount of thifluzamide and the second active component is the 0.1-20% of described composition total weight.
5. composition pesticide according to claim 1, is characterized in that, the total amount of thifluzamide and the second active component is the 2-15% of described composition total weight.
6. composition pesticide according to claim 1, is characterized in that, the total amount of thifluzamide and the second active component is the 5-12% of described composition total weight.
7., according to the arbitrary described composition pesticide of claim 1 to 6, it is characterized in that, described composition pesticide is mixed with missible oil, suspended emulsion or granule.
8. according to the arbitrary described composition pesticide of claim 1 to 6, it is characterized in that, the thifluzamide and the second active component, the polyvinylpyrrolidone that comprise 10 % by weight in described composition pesticide are 4-8 % by weight, sodium lignin sulfonate 5-8 % by weight, and surplus is filler; The weight ratio of described thifluzamide and the second active component is 1:3; Described filler is the filler being selected from one or more kaolin, calcium carbonate, alumina silicate, attapulgite.
9. composition pesticide according to claim 8, is characterized in that, described filler is be selected from kaolin and weight of calcium carbonate than the compounded mix for 1:1.
10. according to the purposes of the arbitrary described composition pesticide water prevention rice sheath blight of claim 1 to 6 and Brown Planthopper.
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| CN201510163180.XA CN104757006B (en) | 2015-04-08 | 2015-04-08 | Pesticide composition containing trifluzamide |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105557719A (en) * | 2016-02-01 | 2016-05-11 | 中国水稻研究所 | Pymetrozine and difenoconazole compound pesticide and pymetrozine and thifluzamide compound pesticide |
| CN106508949A (en) * | 2016-11-04 | 2017-03-22 | 淄博市农业科学研究院 | Compounded seed coating agent containing pyraclostrobin, thifluzamide and dinotefuran and application |
| CN106538585A (en) * | 2016-09-30 | 2017-03-29 | 江苏新农化工有限公司 | Composition containing MTI-446, thifluzamide and probenazole and its preparation and application |
| CN113712034A (en) * | 2021-09-07 | 2021-11-30 | 四川眉山凯尔化工有限公司 | Pesticide containing chlorantraniliprole and dinotefuran and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08291009A (en) * | 1995-04-20 | 1996-11-05 | Mitsui Toatsu Chem Inc | Insecticidal and bactericidal composition |
| CN102308812A (en) * | 2011-10-19 | 2012-01-11 | 北京燕化永乐农药有限公司 | Insecticidal composition |
| CN102450271A (en) * | 2010-11-01 | 2012-05-16 | 海利尔药业集团股份有限公司 | Insecticidal composition comprising thiazide insect amide and pymetrozine |
| CN103766381A (en) * | 2013-12-09 | 2014-05-07 | 广东中迅农科股份有限公司 | Ultralow-volume liquid containing dinotefuran and thifluzamide |
| CN103766380A (en) * | 2013-12-09 | 2014-05-07 | 广东中迅农科股份有限公司 | Pesticide composition containing dinotefuran and thifluzamide |
-
2015
- 2015-04-08 CN CN201510163180.XA patent/CN104757006B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08291009A (en) * | 1995-04-20 | 1996-11-05 | Mitsui Toatsu Chem Inc | Insecticidal and bactericidal composition |
| CN102450271A (en) * | 2010-11-01 | 2012-05-16 | 海利尔药业集团股份有限公司 | Insecticidal composition comprising thiazide insect amide and pymetrozine |
| CN102308812A (en) * | 2011-10-19 | 2012-01-11 | 北京燕化永乐农药有限公司 | Insecticidal composition |
| CN102308812B (en) * | 2011-10-19 | 2013-10-23 | 北京燕化永乐农药有限公司 | Insecticidal composition |
| CN103766381A (en) * | 2013-12-09 | 2014-05-07 | 广东中迅农科股份有限公司 | Ultralow-volume liquid containing dinotefuran and thifluzamide |
| CN103766380A (en) * | 2013-12-09 | 2014-05-07 | 广东中迅农科股份有限公司 | Pesticide composition containing dinotefuran and thifluzamide |
Non-Patent Citations (1)
| Title |
|---|
| 甄洁 等: "噻呋酰胺24%悬浮剂防治水稻纹枯病试验", 《农药科学与管理》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105557719A (en) * | 2016-02-01 | 2016-05-11 | 中国水稻研究所 | Pymetrozine and difenoconazole compound pesticide and pymetrozine and thifluzamide compound pesticide |
| CN106538585A (en) * | 2016-09-30 | 2017-03-29 | 江苏新农化工有限公司 | Composition containing MTI-446, thifluzamide and probenazole and its preparation and application |
| CN106508949A (en) * | 2016-11-04 | 2017-03-22 | 淄博市农业科学研究院 | Compounded seed coating agent containing pyraclostrobin, thifluzamide and dinotefuran and application |
| CN113712034A (en) * | 2021-09-07 | 2021-11-30 | 四川眉山凯尔化工有限公司 | Pesticide containing chlorantraniliprole and dinotefuran and preparation method thereof |
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| Publication number | Publication date |
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| CN104757006B (en) | 2017-04-19 |
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