CN108605963A - A kind of Pesticidal combination containing four chlorantraniliproles and thiodicarb - Google Patents
A kind of Pesticidal combination containing four chlorantraniliproles and thiodicarb Download PDFInfo
- Publication number
- CN108605963A CN108605963A CN201810798268.2A CN201810798268A CN108605963A CN 108605963 A CN108605963 A CN 108605963A CN 201810798268 A CN201810798268 A CN 201810798268A CN 108605963 A CN108605963 A CN 108605963A
- Authority
- CN
- China
- Prior art keywords
- thiodicarb
- chlorantraniliproles
- composition
- pesticidal combination
- chlorantraniliprole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
Abstract
The invention discloses a kind of Pesticidal combination containing four chlorantraniliproles and thiodicarb, the active ingredient of composition are made of four chlorantraniliproles and thiodicarb, and the weight ratio of four chlorantraniliproles and thiodicarb in the composition is 10：1~1：80, the weight percent of four chlorantraniliproles and thiodicarb weight summation in the composition is 0.01~80%；The Pesticidal combination of the present invention has notable synergistic function, improves active ingredient using effect, reduces compound usage amount, alleviates the pollution to environment, reduce use cost, to the comprehensive treatment important in inhibiting of pest resistance.
Description
Technical field
The present invention relates to a kind of Pesticidal combination containing four chlorantraniliproles and thiodicarb, active ingredient is by four chlorantraniliproles
It is formed with thiodicarb, is applied to crop pests and prevents.
Background technology
Four chlorantraniliproles, anthranilamides, belong to ryanodine receptor activator insecticides, by with fish
Buddhist nun's fourth receptor combines, and opens calcium channel, so that the calcium ion of storage in the cell is sustained release into sarcoplasm, calcium ion and flesh
Mesostroma protein binding is starched, it is twitch, food refusal, final death to cause muscle contracts last, insect bodies Symptoms.
Thiodicarb, carbamate compound inhibit the cholinesterase in insect bodies, keep insect lethal.But this is one
Kind reversible inhibition, such as the not poisoned death of fruit insect, enzyme can be restored with deamination formylated.
Information system of crop pest distribution in China improvement is one of agricultural production important link, is always the weight of agricultural science and technology worker concern
Point project.Increase with the continuity year in year out, Pesticide use amount prevented harmful organism chemicals and non-science
Using the influence of the factors such as pesticide, lead to pest and disease damage resistance getting worse, generates the pest of resistance, germ type is on the increase.
Simultaneously as high intensity uses pesticide, cause a series of social concerns such as exceeded, the pollution environment of Practice for Pesticide Residue in Agricultural Products, no
Conducive to the sustainable development of agricultural.
The mixture of different pesticide species is the common methods of the agriculture resistance pest and disease damage of prevention.It is screened, is sieved by formulation of pesticide
Rational formula is selected, practical control effect can be effectively improved, dosage is reduced, reduces cost, delay pest and disease damage drug resistance
It generates, is the important means of integrated pest management.Four chlorantraniliproles and thiodicarb mixture have apparent synergistic effect.
Invention content
Present invention aims at four chlorantraniliproles and thiodicarb using effect is promoted, dosage is reduced, reduces pesticide in agriculture
Residual quantity on crop delays the generation of target resistance.
Another object of the present invention is to provide a kind of Pesticidal combination and its system containing four chlorantraniliproles and thiodicarb
Preparation Method.
In order to overcome the deficiencies of the prior art, inventor is tested and field control effectiveness test by a large amount of indoor bioassay,
It has been surprisingly found that, four chlorantraniliproles and thiodicarb combine within the scope of certain proportion, to various pests synergistic function.
Technical solution of the present invention：A kind of Pesticidal combination containing four chlorantraniliproles and thiodicarb, composition it is effective at
Divide and be made of four chlorantraniliproles and thiodicarb, the weight ratio of four chlorantraniliproles and thiodicarb in the composition is 10：1~1：80,
Preferred weight ratio is 1：1~1：10, more preferable weight ratio is 1:4.
The weight percent of four chlorantraniliproles and thiodicarb weight summation in the composition is 0.01~80%, remaining is to help
Agent.
The auxiliary agent be solvent, emulsifier, wetting agent, stabilizer, dispersant, thickener, pH adjusting agent, antifoaming agent,
The mixing of one or more of antifreezing agent, colorant, film forming agent and filler is known substance, is commonly used in pesticidal preparations
Various auxiliary agents, can be varied from, be not particularly limited according to different situations.
Solvent is solvent naphtha S-200, trimethylbenzene, durene, methyl naphthalene, methyl oleate, fatty acid methyl ester, loose base oil, big
One kind in soya-bean oil, biodiesel, sec-Butyl Acetate, dimethyl carbonate, diesel oil, white oil, machine oil, N-Methyl pyrrolidone etc. or
Several mixing.
Emulsifier is calcium dodecyl benzene sulfonate, fatty alcohol polyoxyethylene ether, triphenoethyl benzene phenol polyoxypropylene polyoxy second
Alkene block polymer, dibenzyl xenyl polyoxyethylene ether, phenethyl phenol polyethenoxy ether, castor oil polyoxyethylene ether, benzene second
Base fluosite polyoxyethylene ether, phenethyl phenol polyoxyethylene polyoxypropylene ether, alkylaryl polyoxyethylene polyoxypropylene
Ether, phenethyl phenol formaldehyde resin polyoxyethylene ether, Sorbitan aliphatic ester, sorbitan fatty acid ester polyoxyethylene
Ether, natural fatty alcohol and ethylene oxide adduct, aliphatic acid and ethylene oxide condensate, polyoxyethylene fatty acid ester, phenethyl
The mixing of one or more of phenol polyethenoxy ether polyethenoxy ether.
Wetting agent is sodium butylnaphthalenesulfonate, lauryl sodium sulfate, aliphatic alcohol polyethenoxy (6-7) ether, sulfosuccinate
One or more of dioctyl ester sodium salt, Morwet EFW, alkylnaphthalene sulfonate, spaonin powder, bay alcohol radical sodium sulphate etc..It collapses
Solution agent can be one kind in compound sodium nitrophenolate, sodium bicarbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, bentonite or
Several mixing.
Dispersant be polycarboxylate, formaldehyde condensate of sodium methylnaphthalene sulfonate, sodium lignin sulfonate, calcium lignosulfonate,
To methoxyl group fatty acyl anilinesulfonic acid, desugar and the sodium lignin sulfonate of classification, naphthalene sulfonic acid condensate sodium salt, alkyl naphthalene sulfonic acid
The mixing of one or more of condensation polymer sodium salt, APES formaldehyde condensation product sulfuric acid.
Thickener is one or more of xanthans, aluminium-magnesium silicate, bentonite, white carbon etc..PH adjusting agent can be
One or more of ammonium hydroxide, potassium hydroxide, sodium hydroxide, hydrochloric acid, acetic acid, citric acid, phosphoric acid etc..Stabilizer can be
Dibutyl phthalate, hexamethylene diisocyanate, epoxidized soybean oil, epoxychloropropane, butylated hydroxy anisole, two fourths
The mixing of one or more of base hydroxy-methylbenzene, propylgallate, tert-butylhydroquinone.
Antifoaming agent can be one or more of silicone compound, methanol, silicone oil, azone, dimethyl silicone polymer
Mixing.
Antifreezing agent can be mixing one or more of in glycerine, ethylene glycol, propylene glycol, sorbierite, polyethylene glycol.
Carrier can be kaolin, diatomite, bentonite, white carbon, precipitated calcium carbonate, attapulgite, clay, talcum
The mixing of one or more of powder, quartz sand, starch, alkyl polyglycoside, urea, potassium chloride, ammonium chloride.
Sustained release agent is one or both of polyvinyl alcohol, Arabic gum.Preservative can be sodium benzoate.Binder can
To be the mixing of one or more of polyethylene glycol, industrial gelatine.
Colorant is the mixing of one or both of basic rhodamine, aqueous rhodo, acid scarlet.
Film forming agent is Arabic gum, animal glue, pectin, xanthans, methylcellulose, ethyl cellulose, carboxymethyl cellulose
Plain sodium, hydroxypropyl cellulose, sodium alginate, polyvinyl alcohol, polyethylene glycol, polyvinylpyrrolidone, polyacrylamide, polypropylene
The mixing of one or both of sour sodium.
The composition of the present invention can be processed into the dosage form agriculturally allowed, and preferable dosage form has aqueous suspension agent, dispersible
Oil-suspending agent, wettable powder, water dispersible granules, granule or seed treatment suspending agent.
The Pesticidal combination of the present invention can be used for preventing crop pests prevention, and generally use sprays, dresses seed, spreads fertilizer over the fields method
Use, can also as needed other techniques used in agriculture may also be adopted.
Compared with prior art, the invention has the advantages that：
1, composition has notable synergistic function, improves active ingredient using effect.
2, four chlorantraniliproles and thiodicarb mechanism of action are inconsistent, the long-term single use of pesticide can be overcome to easy to produce anti-
The shortcomings that property, to the comprehensive treatment important in inhibiting of pest resistance.
3, compound usage amount is reduced, the pollution to environment is alleviated, reduces use cost.
Specific implementation mode
In order to keep the objectives, technical solutions, and advantages of the present invention more concise, present invention following specific examples
It illustrates, however, the present invention is by no means limited to these examples.It is as described below to be only the preferred embodiment of the present invention, it is used only for
The description present invention, should not be understood as limiting the scope of the present invention.It should be pointed out that all in the spirit and principles in the present invention
Within all any modification, equivalent and improvement etc. done, should all include within protection scope of the present invention.Therefore, originally
The protection domain of patent of invention should be determined by the appended claims.
Pesticidal combination of the present invention can be prepared into the aqueous suspension agent, dispersible for being suitble to agriculturally use by known method
Oil-suspending agent, aqueous emulsion, microemulsion, missible oil, wettable powder, water dispersible granules, granule, dry suspending agent or seed treatment are outstanding
Floating agent.It is as described below to be only the preferred embodiment of the present invention, it is used only for explaining the present invention, it cannot be therefore understands that for the present invention
The limitation of the scope of the claims.
Example of formulations 1：25% 4 chlorantraniliprole thiodicarb aqueous suspension agent
Weigh 5 grams of four chlorantraniliprole, 20 grams of thiodicarb, 10 grams of alkylnaphthalene sulfonate, 8 grams of sodium lignin sulfonate, propylene glycol 2
Gram, 3 grams of xanthans, 2 grams of methanol, 1 gram of potassium hydroxide, deionized water is supplemented to 100 grams.Above-mentioned material is mixed, in ball crusher
2~3h of middle grinding, makes a diameter be below 5mm, and obtains 25% 4 chlorantraniliprole thiodicarb aqueous suspension agent.
Example of formulations 2：The 33% 4 dispersible oil-suspending agent of chlorantraniliprole thiodicarb
Weigh 3 grams of four chlorantraniliprole, 30 grams of thiodicarb, 8 grams of lauryl sodium sulfate, 5 grams of Sorbitan aliphatic ester, sulphur
Change 5 grams of dioctyl succinate sodium salt, 1 gram of xanthans, methyl oleate complements to 100 grams.Mentioned component is dissolved into homogeneous oil phase,
Under high velocity agitation, it is mixed to prepare the 33% 4 dispersible oil-suspending agent of chlorantraniliprole thiodicarb.
Example of formulations 3：35% 4 chlorantraniliprole thiodicarb wettable powder
Weigh 5 grams of four chlorantraniliprole, 30 grams of thiodicarb, 6 grams of calcium lignosulfonate, 4 grams of lauryl sodium sulfate, kaolin
It is supplemented to 100 grams.Mentioned component is mixed, is sufficiently stirred in a stirring kettle, is uniformly mixed after being smashed by air jet mill, you can
35% 4 chlorantraniliprole thiodicarb wettable powder is made.
Example of formulations 4：35% 4 chlorantraniliprole thiodicarb water dispersible granules
Weigh 30 grams of four chlorantraniliprole, 5 grams of thiodicarb, 5 grams of alkyl naphthalene sulfonic acid condensation polymer sodium salt, 5 grams of alkylnaphthalene sulfonate,
7 grams of magnesium chloride, 3 grams of ammonium hydroxide, 2 grams of methanol, 3 grams of epoxychloropropane, white carbon is supplemented to 100 grams.Mentioned component is mixed
Uniformly, it is crushed, is added in fluidized-bed granulation dryer after kneading after being granulated, drying, sieve with micro jet,
It can be prepared by 35% 4 chlorantraniliprole thiodicarb water dispersible granules.
Example of formulations 5：8.4% 4 chlorantraniliprole thiodicarb granule
Weigh 0.4 gram of four chlorantraniliprole, 8 grams of thiodicarb, 6 grams of aliphatic ester sulfate, 4 grams of polycarboxylic acid salt, corn flour 8
Gram, 7 grams of sodium lignin sulfonate, diatomite is supplemented to 100 grams；Above-mentioned material is added together in cone-type mixer and is uniformly mixed,
It is crushed by airslide disintegrating mill, the material after crushing is mixed through cone-type mixer again, and mixed fineness of materials 98% passes through 600
Mesh standard sieve is added in kneader and is kneaded into plasticity material, this material is finally put into extruder grain in Squeezinggranulator, is made
8.4% 4 chlorantraniliprole thiodicarb granule is obtained after drying, screening after grain.
Example of formulations 6：40% 4 chlorantraniliprole thiodicarb seed treatment suspending agent
Weigh 20 grams of four chlorantraniliprole, 20 grams of thiodicarb, polycarboxylate 3%, sodium butylnaphthalenesulfonate 5%, methanol 0.5%,
Aluminium-magnesium silicate 0.5%, glycerine 0.5%, Arabic gum 2%, basic rhodamine 2%, deionized water carrier complement to 100%.It will
Above-mentioned material mixes, and disperses through high speed shear after being sanded in sand mill, and the suspended substance of high dispersive, stabilization is formed in water-medium
40% 4 chlorantraniliprole thiodicarb seed treatment suspending agent is made in system.
Different types of pesticide active ingredient is compounded, is the current cost and anti-of solving during pesticide single dose use
The effective measures of the problems such as property.After different types of pesticide active ingredient mixing, three kinds of type of action are typically exhibited, i.e.,
Summation action, synergistic effect and antagonism.But it is specially which kind of effect, only can be just known by a large amount of bioassay test
Road.
Assays Example 1：Indoor toxicity determination test
With reference to the method in NY/T 1154.14-2008 standards, using leaf dipping method.Feed is immersed in liquid to be measured, 10s
After take out, naturally dry is put into the culture dish containing moisturizing filter paper, accesses test worm, often repeatedly 10 cephalont, often processing setting 4
A repetition, and to contain solvent as blank control.Test worm death condition is checked after 72h, and is recorded, and test worm death judges
Gently to be contacted with writing brush, test worm is reactionless to be calculated as death to standard.It is for statistical analysis with DPS statistical analysis softwares, pass through calculating
The LC of each medicament50It evaluates the insecticidal activity of each medicament, and calculates the co-toxicity coefficient (CTC values) of mixture according to Sun Yunpei's Method.
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100。
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent.
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixtures theoretical toxicity index (TTI)] × 100.
The criteria for classifying is acted on according to NY/T11547.7-2006 insecticide combinations:Co-toxicity coefficient (CTC) >=120 shows as increasing
Effect acts on；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
1 four chlorantraniliprole of table combines the indoor toxicity determination test result to bright and beautiful earworm with thiodicarb
| Active ingredient matches (weight ratio) | LC50(mg/L) | ATI | TTI | CTC |
| Four chlorantraniliproles | 1.95 | 100.00 | / | / |
| Thiodicarb | 13.07 | 14.92 | / | / |
| Four chlorantraniliproles:Thiodicarb (20:1) | 2.04 | 95.59 | 95.95 | 99.62 |
| Four chlorantraniliproles:Thiodicarb (10:1) | 1.58 | 123.42 | 92.27 | 133.76 |
| Four chlorantraniliproles:Thiodicarb (1:1) | 2.33 | 83.69 | 57.46 | 145.65 |
| Four chlorantraniliproles:Thiodicarb (1:2) | 3.07 | 63.52 | 43.28 | 146.76 |
| Four chlorantraniliproles:Thiodicarb (1:4) | 4.12 | 47.33 | 31.94 | 148.20 |
| Four chlorantraniliproles:Thiodicarb (1:6) | 4.81 | 40.54 | 27.07 | 149.74 |
| Four chlorantraniliproles:Thiodicarb (1:8) | 5.17 | 37.72 | 24.37 | 154.75 |
| Four chlorantraniliproles:Thiodicarb (1:10) | 5.43 | 35.91 | 22.65 | 158.52 |
| Four chlorantraniliproles:Thiodicarb (1:20) | 6.48 | 30.09 | 18.97 | 158.62 |
| Four chlorantraniliproles:Thiodicarb (1:40) | 7.19 | 27.12 | 16.99 | 159.58 |
| Four chlorantraniliproles:Thiodicarb (1:80) | 7.85 | 24.84 | 15.97 | 155.55 |
As can be seen from Table 1, four chlorantraniliproles and thiodicarb are 10:1~1：Combination in 80 proportional region, to bright and beautiful earworm
Synergistic effect is shown as, still, four chlorantraniliproles are with thiodicarb 20:1 ratio combination shows as summation action.
2 four chlorantraniliprole of table combines the indoor toxicity determination test result to peanut grub with thiodicarb
As can be seen from Table 2, four chlorantraniliproles and thiodicarb are 10：1~1：Combination in 80 proportional region, to bright and beautiful earworm
Synergistic effect is shown as, still, four chlorantraniliproles are with thiodicarb 1:120 ratio combination shows as summation action.
Assays Example 2：Field control effectiveness test
(1) field control effectiveness test of present composition prevention cotton boll worm.
It is used in cotton worm larva early period of origination, medicament is watered spraying.
Test site is located at Xinjiang Jinghe County Bo Zhou, is suspended with 10% 4 chlorantraniliprole suspending agent, 375 grams per liter thiodicarbs
Agent compares medicine, and experiment sets 4 chemicals treatments altogether, each handles 4 repetitions, 2 days after dispenser, respectively investigates and record anti-within 20 days
Control effect.
3 four chlorantraniliprole of table and thiodicarb combination prevention cotton boll worm field test results
As can be seen from Table 3, present composition prevention cotton boll worm is with obvious effects is better than four chlorantraniliproles and sulphur pair
Each single use of prestige reduces pharmaceutical use, extends the lasting period.
(2) field control effectiveness test of present composition prevention peanut grub.
Test site is located at faithful and honest county of Heyuan City of Guangdong Province, with 50% 4 chlorantraniliprole seed treatment suspending agent, 375 grams/
It rising thiodicarb suspension seed-coating agent and compares medicine, peanut seed seed dressing, experiment sets 4 chemicals treatments, each handles 4 repetitions altogether,
It is respectively investigated in after planting 30 days, 50 days and records control effect.
4 four chlorantraniliprole of table and thiodicarb combination prevention peanut grub field test results
As can be seen from Table 4, Pesticidal combination of the present invention carries out seed treatment prevention peanut grub is with obvious effects to be better than four
The single use of chlorantraniliprole and thiodicarb reduces pharmaceutical use, extends the lasting period.
Claims (5)
1. a kind of Pesticidal combination containing four chlorantraniliproles and thiodicarb, it is characterised in that：The active ingredient of composition is by four
Chlorantraniliprole and thiodicarb composition, the weight ratio of four chlorantraniliproles and thiodicarb in the composition are 10：1~1：80, tetrachloro worm
The weight percent of amide and thiodicarb weight summation in the composition is 0.01~80%.
2. a kind of Pesticidal combination containing four chlorantraniliproles and thiodicarb according to claim 1, it is characterised in that：Four
The weight ratio of chlorantraniliprole and thiodicarb in the composition is 1：1~1：10.
3. a kind of Pesticidal combination containing four chlorantraniliproles and thiodicarb according to claim 1, it is characterised in that：Four
The weight ratio of chlorantraniliprole and thiodicarb in the composition is 1:1、1:2、1:4、1:6、1:8 or 1:10.
4. a kind of Pesticidal combination containing four chlorantraniliproles and thiodicarb according to claim 1, it is characterised in that：Institute
The dosage form for stating Pesticidal combination is aqueous suspension agent, dispersible oil-suspending agent, wettable powder, granule, water dispersible granules or kind
Subprocessing suspending agent.
5. a kind of Pesticidal combination containing four chlorantraniliproles and thiodicarb described in claim 1 in prevention cotton boll worm and
The application of peanut grub.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810798268.2A CN108605963A (en) | 2018-07-19 | 2018-07-19 | A kind of Pesticidal combination containing four chlorantraniliproles and thiodicarb |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810798268.2A CN108605963A (en) | 2018-07-19 | 2018-07-19 | A kind of Pesticidal combination containing four chlorantraniliproles and thiodicarb |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108605963A true CN108605963A (en) | 2018-10-02 |
Family
ID=63666619
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810798268.2A Pending CN108605963A (en) | 2018-07-19 | 2018-07-19 | A kind of Pesticidal combination containing four chlorantraniliproles and thiodicarb |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108605963A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113396900A (en) * | 2021-05-20 | 2021-09-17 | 潍坊海邦化工有限公司 | Thiodicarb aqueous suspension and preparation method thereof |
-
2018
- 2018-07-19 CN CN201810798268.2A patent/CN108605963A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113396900A (en) * | 2021-05-20 | 2021-09-17 | 潍坊海邦化工有限公司 | Thiodicarb aqueous suspension and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104663670B (en) | One kind collaboration miticide composition | |
| CN104663679B (en) | A kind of insecticide acaricide composition containing macrolide insecticide | |
| CN104663668A (en) | Insecticidal and acaricidal composition containing acetyl coenzyme A inhibitor insecticide | |
| CN103155929B (en) | Binary pesticide composition and application thereof | |
| CN104222145A (en) | Insecticide composition containing clothianidin and diazinon | |
| CN105052984A (en) | Insecticidal composition for rice | |
| CN102805102B (en) | Disinsection combination containing fosthiazate and ryanodine receptor inhibitor insecticide | |
| CN104757006A (en) | Pesticide composition containing trifluzamide | |
| CN108605963A (en) | A kind of Pesticidal combination containing four chlorantraniliproles and thiodicarb | |
| CN104663688B (en) | A kind of insecticide acaricide composition containing Bifenazate | |
| CN105494407A (en) | Herbicide composition containing metamifop and cafenstrole | |
| CN102440252B (en) | Insecticidal composition containing cycloxaprid and pyrazole insecticide | |
| CN103155935B (en) | Binary pesticide composition | |
| CN108477189A (en) | A kind of composition pesticide containing tetramycin and isotianil | |
| CN109042715A (en) | One kind is containing double third ring worm esters and four chlorantraniliprole compositions | |
| CN105638715B (en) | A kind of agricultural pesticide composition and application thereof | |
| CN103688972B (en) | A kind of containing cyhalofop-butyl with the Herbicidal combinations of cafenstrole | |
| CN104186471B (en) | A kind of composition pesticide containing chlorine fluorine cyanogen insect amide and methoxyfenozide | |
| CN106665614A (en) | Weeding composition containing penoxsulam, bispyribac-sodium and mefenacet | |
| CN103749510A (en) | Weeding composition containing flucarbazone and monosulfuron-ester | |
| CN104430436B (en) | Diafenthiuron and pyridalyl Pesticidal combination | |
| CN108308192A (en) | A kind of composition pesticide containing furan tebufenozide and Tefluthrin | |
| CN108651514A (en) | A kind of composition pesticide containing fosthiazate and fluxapyroxad | |
| CN109392928A (en) | A kind of Pesticidal combination containing emamectin benzoate Yu second azoles mite nitrile | |
| CN102771495A (en) | Pesticide synergic insect-killing composition containing guadipyr |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20181002 |
|
| WD01 | Invention patent application deemed withdrawn after publication |