CN111433175A - 脱氢方法 - Google Patents

脱氢方法 Download PDF

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Publication number
CN111433175A
CN111433175A CN201880078087.0A CN201880078087A CN111433175A CN 111433175 A CN111433175 A CN 111433175A CN 201880078087 A CN201880078087 A CN 201880078087A CN 111433175 A CN111433175 A CN 111433175A
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China
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catalyst
pellet diameter
screen
slot width
range
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CN201880078087.0A
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English (en)
Chinese (zh)
Inventor
曼纽拉·谢尔班
迈克尔·J·维特尔
格雷戈里·J·内多欣
克莱顿·C·萨德勒
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Honeywell UOP LLC
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UOP LLC
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0207—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
    • B01J8/0214—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal in a cylindrical annular shaped bed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/04—Purification; Separation; Use of additives by distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00539—Pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00805—Details of the particulate material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00884—Means for supporting the bed of particles, e.g. grids, bars, perforated plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023—Details
    • B01J2208/024—Particulate material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00191—Control algorithm
    • B01J2219/00193—Sensing a parameter
    • B01J2219/00195—Sensing a parameter of the reaction system
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Fluid Mechanics (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Nanotechnology (AREA)
CN201880078087.0A 2017-11-02 2018-11-01 脱氢方法 Pending CN111433175A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201762580768P 2017-11-02 2017-11-02
US201762580794P 2017-11-02 2017-11-02
US62/580,768 2017-11-02
US62/580,794 2017-11-02
PCT/US2018/058612 WO2019089869A1 (fr) 2017-11-02 2018-11-01 Procédé de déshydrogénation

Publications (1)

Publication Number Publication Date
CN111433175A true CN111433175A (zh) 2020-07-17

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CN201880078079.6A Active CN111433174B (zh) 2017-11-02 2018-11-01 降低的氢气与烃的比率下的脱氢方法
CN201880078087.0A Pending CN111433175A (zh) 2017-11-02 2018-11-01 脱氢方法

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CN201880078079.6A Active CN111433174B (zh) 2017-11-02 2018-11-01 降低的氢气与烃的比率下的脱氢方法

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Country Link
US (3) US10647637B2 (fr)
EP (1) EP3704083A4 (fr)
KR (2) KR102413286B1 (fr)
CN (2) CN111433174B (fr)
WO (3) WO2019089958A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3646945A1 (fr) * 2018-10-29 2020-05-06 Casale Sa Réacteur chimique radial ou axial-radial avec un catalyseur de particules fines

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4102776A (en) * 1975-10-24 1978-07-25 Uop Inc. Moving bed contacting process
US5243122A (en) * 1991-12-30 1993-09-07 Phillips Petroleum Company Dehydrogenation process control
CN1371304A (zh) * 1999-08-27 2002-09-25 胡茨曼石油化学公司 脱氢催化剂的改进
US20080219898A1 (en) * 2007-03-08 2008-09-11 Gregor Joseph H Secondary Containment for a Perforated Plate
US20130340229A1 (en) * 2012-06-20 2013-12-26 Uop Llc Apparatus for Retaining Solid Material in a Radial Flow Reactor and Method of Making

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US3670044A (en) 1969-07-18 1972-06-13 Phillips Petroleum Co Catalytic dehydrogenation process
US4343724A (en) * 1979-10-01 1982-08-10 Uop Inc. Hydrocarbon dehydrogenation with an attenuated superactive multimetallic catalytic composite for use therein
US4418237A (en) 1981-03-30 1983-11-29 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4613715A (en) 1985-07-12 1986-09-23 Phillips Petroleum Company Oxygen addition to a steam-active dehydrogenation reactor
US4717779A (en) * 1985-09-11 1988-01-05 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4788371A (en) 1987-12-30 1988-11-29 Uop Inc. Catalytic oxidative steam dehydrogenation process
ATE64551T1 (de) * 1988-02-11 1991-07-15 Fina Research Verfahren zur herstellung von platingruppenmetallen enthaltenden katalysatoren und deren verwendungen.
US4914075A (en) 1988-12-05 1990-04-03 Uop Dehydrogenation catalyst composition
DE69116002T2 (de) 1990-06-05 1996-05-15 Huntsman Spec Chem Corp Verfahren zur Dehydrierung von Paraffinen
US5489724A (en) * 1994-12-13 1996-02-06 Mobil Oil Corporation High pressure drop endothermic process
CN1084224C (zh) 1997-06-09 2002-05-08 中国科学院大连化学物理研究所 一种饱和烃脱氢催化剂及其制备方法
US6472577B1 (en) 1998-12-17 2002-10-29 Uop Llc Process for increasing the yield and selectivity of a dehydrogenation process using side-by-side reaction zones
RU2178399C1 (ru) * 2000-12-09 2002-01-20 Институт катализа им. Г.К. Борескова СО РАН Способ каталитического дегидрирования углеводородов
US6756340B2 (en) 2002-04-08 2004-06-29 Uop Llc Dehydrogenation catalyst composition
US7756256B1 (en) 2003-11-26 2010-07-13 Openwave Systems Inc. Unified and best messaging systems for communication devices
FR2910346B1 (fr) 2006-12-22 2010-10-15 Inst Francais Du Petrole Procede de deshydrogenation en presence d'un catalyseur bimetallique ou multi-metallique ayant un indice de bimetallicite et une capacite d'adsorption d'hydrogene optimises
DE102009034464A1 (de) * 2009-07-22 2011-08-18 Uhde GmbH, 44141 Verfahren und Vorrichtung zur Dehydrierung von Alkanen mit einer Vergleichmäßigung der Produktzusammensetzung
US8895797B2 (en) 2010-03-30 2014-11-25 Uop Llc Process for dehydrogenation of hydrocarbons in a multi-stage fluidized bed reactor
US9266091B2 (en) 2012-03-29 2016-02-23 Uop Llc Reforming catalysts with tuned acidity for maximum aromatics yield
US8912110B2 (en) 2012-03-29 2014-12-16 Uop Llc Catalyst for conversion of hydrocarbons
CN103420750A (zh) * 2012-05-16 2013-12-04 中国石油化工股份有限公司 低碳烷烃制烯烃的方法
MX2014015981A (es) 2012-06-21 2015-07-06 Reliance Ind Ltd Regeneracion de un catalizador de deshidrogenacion de parafina agotado.
CN105246863A (zh) * 2013-05-31 2016-01-13 沙特基础工业公司 用于烷烃脱氢的方法
KR101527845B1 (ko) 2013-12-04 2015-06-16 희성촉매 주식회사 스폰지형 담체를 이용한 탄화수소 탈수소화 촉매 제조방법
CN105214657B (zh) 2014-05-30 2018-03-20 中国石油化工股份有限公司 一种低碳烷烃脱氢制烯烃催化剂及其制备方法
WO2016005896A2 (fr) 2014-07-08 2016-01-14 Reliance Industries Limited Composite catalyseur de déshydrogénation et procédé pour le préparer
KR101981886B1 (ko) * 2018-02-01 2019-05-23 효성화학 주식회사 탈수소화 촉매

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4102776A (en) * 1975-10-24 1978-07-25 Uop Inc. Moving bed contacting process
US5243122A (en) * 1991-12-30 1993-09-07 Phillips Petroleum Company Dehydrogenation process control
CN1371304A (zh) * 1999-08-27 2002-09-25 胡茨曼石油化学公司 脱氢催化剂的改进
US20080219898A1 (en) * 2007-03-08 2008-09-11 Gregor Joseph H Secondary Containment for a Perforated Plate
US20130340229A1 (en) * 2012-06-20 2013-12-26 Uop Llc Apparatus for Retaining Solid Material in a Radial Flow Reactor and Method of Making

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EP3704083A4 (fr) 2022-03-23
US20190127297A1 (en) 2019-05-02
WO2019089869A1 (fr) 2019-05-09
KR102413286B1 (ko) 2022-06-28
WO2019089939A1 (fr) 2019-05-09
CN111433174A (zh) 2020-07-17
KR20200071122A (ko) 2020-06-18
CN111433174B (zh) 2023-03-24
US20190127296A1 (en) 2019-05-02
KR102411271B1 (ko) 2022-06-23
KR20200074977A (ko) 2020-06-25
US20190127298A1 (en) 2019-05-02
US10647636B2 (en) 2020-05-12
US10843984B2 (en) 2020-11-24
EP3704083A1 (fr) 2020-09-09
WO2019089958A1 (fr) 2019-05-09
US10647637B2 (en) 2020-05-12

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