CN111411537A - 涤锦粘面料短流程染整工艺 - Google Patents
涤锦粘面料短流程染整工艺 Download PDFInfo
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- CN111411537A CN111411537A CN201910015193.0A CN201910015193A CN111411537A CN 111411537 A CN111411537 A CN 111411537A CN 201910015193 A CN201910015193 A CN 201910015193A CN 111411537 A CN111411537 A CN 111411537A
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- Prior art keywords
- dyeing
- finishing
- polyester
- parts
- water
- Prior art date
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- 238000004043 dyeing Methods 0.000 title claims abstract description 66
- 239000004744 fabric Substances 0.000 title claims abstract description 62
- 239000004677 Nylon Substances 0.000 title claims abstract description 49
- 229920001778 nylon Polymers 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims abstract description 44
- 229920000297 Rayon Polymers 0.000 title claims abstract description 34
- 238000007730 finishing process Methods 0.000 title claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 53
- 238000010438 heat treatment Methods 0.000 claims abstract description 39
- 239000007788 liquid Substances 0.000 claims abstract description 36
- 238000004321 preservation Methods 0.000 claims abstract description 30
- 238000009991 scouring Methods 0.000 claims abstract description 24
- 238000004061 bleaching Methods 0.000 claims abstract description 16
- 238000001816 cooling Methods 0.000 claims abstract description 11
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- 239000004952 Polyamide Substances 0.000 claims abstract description 7
- 239000000853 adhesive Substances 0.000 claims abstract description 7
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- 229920002647 polyamide Polymers 0.000 claims abstract description 7
- 229920006149 polyester-amide block copolymer Polymers 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 66
- 239000003795 chemical substances by application Substances 0.000 claims description 47
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 36
- 239000000975 dye Substances 0.000 claims description 32
- 239000000839 emulsion Substances 0.000 claims description 31
- 229920002545 silicone oil Polymers 0.000 claims description 31
- 238000006243 chemical reaction Methods 0.000 claims description 29
- 239000002270 dispersing agent Substances 0.000 claims description 24
- 230000007935 neutral effect Effects 0.000 claims description 21
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 13
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- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 12
- 150000005690 diesters Chemical class 0.000 claims description 12
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 12
- 239000011976 maleic acid Substances 0.000 claims description 12
- 239000000178 monomer Substances 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- 239000003381 stabilizer Substances 0.000 claims description 12
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 12
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 10
- 239000000986 disperse dye Substances 0.000 claims description 10
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 10
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- 239000000985 reactive dye Substances 0.000 claims description 8
- 229920004933 Terylene® Polymers 0.000 claims description 7
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
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- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 229920006052 Chinlon® Polymers 0.000 claims description 4
- NRTJGTSOTDBPDE-UHFFFAOYSA-N [dimethyl(methylsilyloxy)silyl]oxy-dimethyl-trimethylsilyloxysilane Chemical compound C[SiH2]O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C NRTJGTSOTDBPDE-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
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- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 4
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 4
- 239000003223 protective agent Substances 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 abstract description 4
- 239000003921 oil Substances 0.000 abstract description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 2
- 238000012545 processing Methods 0.000 abstract description 2
- 229910052710 silicon Inorganic materials 0.000 abstract description 2
- 239000010703 silicon Substances 0.000 abstract description 2
- 238000004513 sizing Methods 0.000 abstract description 2
- 230000005611 electricity Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 26
- 239000012086 standard solution Substances 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 239000000523 sample Substances 0.000 description 11
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- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 8
- 239000001639 calcium acetate Substances 0.000 description 8
- 235000011092 calcium acetate Nutrition 0.000 description 8
- 229960005147 calcium acetate Drugs 0.000 description 8
- 239000012488 sample solution Substances 0.000 description 8
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 7
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 7
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- 239000012153 distilled water Substances 0.000 description 6
- 229910001447 ferric ion Inorganic materials 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000004902 Softening Agent Substances 0.000 description 5
- 235000019270 ammonium chloride Nutrition 0.000 description 5
- 238000007599 discharging Methods 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 238000004448 titration Methods 0.000 description 5
- HKGKYUVCADNOOC-UHFFFAOYSA-N 1-aminotetradecan-2-ol Chemical compound CCCCCCCCCCCCC(O)CN HKGKYUVCADNOOC-UHFFFAOYSA-N 0.000 description 4
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 4
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 4
- 229940126062 Compound A Drugs 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 4
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- 239000002738 chelating agent Substances 0.000 description 3
- 230000009920 chelation Effects 0.000 description 3
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000012875 nonionic emulsifier Substances 0.000 description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- MHXFWEJMQVIWDH-UHFFFAOYSA-N 1-amino-4-hydroxy-2-phenoxyanthracene-9,10-dione Chemical compound C1=C(O)C=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C1OC1=CC=CC=C1 MHXFWEJMQVIWDH-UHFFFAOYSA-N 0.000 description 2
- QCMHUGYTOGXZIW-UHFFFAOYSA-N 3-(dimethylamino)propane-1,2-diol Chemical compound CN(C)CC(O)CO QCMHUGYTOGXZIW-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical group [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 2
- 239000012847 fine chemical Substances 0.000 description 2
- 239000010977 jade Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- WGESLFUSXZBFQF-UHFFFAOYSA-N n-methyl-n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCN(C)CC=C WGESLFUSXZBFQF-UHFFFAOYSA-N 0.000 description 2
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
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- 239000001632 sodium acetate Substances 0.000 description 2
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- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- MPCYPRXRVWZKGF-UHFFFAOYSA-J tetrasodium 5-amino-3-[[4-[4-[(8-amino-1-hydroxy-3,6-disulfonatonaphthalen-2-yl)diazenyl]phenyl]phenyl]diazenyl]-4-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(N=NC3=CC=C(C=C3)C3=CC=C(C=C3)N=NC3=C(C=C4C=C(C=C(C4=C3O)N)S([O-])(=O)=O)S([O-])(=O)=O)=C(O)C2=C1N MPCYPRXRVWZKGF-UHFFFAOYSA-J 0.000 description 2
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- SIOXPEMLGUPBBT-UHFFFAOYSA-N Picolinic acid Natural products OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 description 1
- 241000083869 Polyommatus dorylas Species 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
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- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 125000000373 fatty alcohol group Chemical group 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229940081066 picolinic acid Drugs 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 102220171501 rs541476418 Human genes 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- YXZRCLVVNRLPTP-UHFFFAOYSA-J turquoise blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Cu+2].NC1=NC(Cl)=NC(NC=2C=C(NS(=O)(=O)C3=CC=4C(=C5NC=4NC=4[N-]C(=C6C=CC(=CC6=4)S([O-])(=O)=O)NC=4NC(=C6C=C(C=CC6=4)S([O-])(=O)=O)NC=4[N-]C(=C6C=CC(=CC6=4)S([O-])(=O)=O)N5)C=C3)C(=CC=2)S([O-])(=O)=O)=N1 YXZRCLVVNRLPTP-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/65—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing epoxy groups
- D06M15/652—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing epoxy groups comprising amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/39—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
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Abstract
本发明公开一种涤锦粘面料短流程染整工艺，包括精练漂白前处理、一浴法染色、后整理工序，精练漂白前处理：配置前处理液、浸入涤锦粘面料，升温至100℃，保温处理30min；一浴法染色：按浴比配置染液，升温至70℃、保温染色15min，再升温至110℃、保温染色30min，降温、排液、水洗；后整理：涤锦粘面料浸轧后整理液，170‑180℃条件下，30‑40m/min车速定型。将精练、漂白合为一浴进行面料的前处理、一浴一步法染色，并于后整理时以高阳离子密度的硅油进行染色面料的柔软、固色整理，这些都极大地缩短了涤锦粘面料的染整工艺流程，染整加工时间大大缩短，节约了水电汽。
Description
技术领域
本发明涉及面料的染整工艺，具体涉及涤锦粘面料的短流程染整工艺。
背景技术
涤锦粘面料，又称TNR面料，是涤纶、锦纶、粘胶三种成份的纱线纺织成的面料。面料手感滑爽，舒适透气，风格新颖别致，强度、耐磨性好，弹性恢复率好，适合制作棉服、休闲夹克、裤料、风衣、户外服等。
涤锦粘面料通常采用三浴法染色，即分别染粘、锦、涤组份，因而染色工序多，染色时间长，所以颜色稳定性较差，染色工艺控制难度大。
发明内容
本发明目的是提供一种涤锦粘面料短流程染整工艺，采用一浴染色法，即涤、锦、粘纤维组份一浴染色，从而缩短染整工艺流程。
为实现上述目的，本发明采用如下的技术方案。
涤锦粘面料短流程染整工艺，包括精练漂白前处理、一浴法染色、后整理工序，
精练漂白前处理：配置前处理液、浸入涤锦粘面料，升温至100℃，保温处理30min；
一浴法染色：按浴比配置染液，投入面料，升温至70℃、保温染色15min，再升温至110℃、保温染色30min，降温、排液、水洗；
后整理：涤锦粘面料浸轧后整理液，170-180℃条件下，30-40m/min车速定型；
前处理液由10g/L NaOH、6g/L双氧水、3g/L双氧水稳定剂、3g/L精练剂、4g/L螯合分散剂及水组成；
染液由分散染料、中性固色活性染料、中性染料及2g/L螯合分散剂、2g/L高温匀染剂、1g/L锦纶匀染剂、8g/L元明粉及水组成；
后整理液由20g/L硅油乳液及水组成；
所述的螯合分散剂，其制备方法为：360份水中加入12份马来酸酐及25份如式1所示的马来酸混合双酯，搅拌溶解，升温至82℃，滴加20份丙烯酸及0.6份过硫酸钾与20份水的溶液，2h滴加完毕，再保温反应4h；反应体系降至室温，按摩尔比n(马来酸混合双酯)：n(NaOH)：n(CS2)＝1:2.2:2.2的比例，先加入NaOH，溶解搅拌均匀，再于室温缓慢滴加CS2，滴加时间1h，然后继续保温反应2h，得所述的螯合分散剂；
所述的硅油乳液，其制备方法为：反应器中加入320份水、12份乳化剂、40份D4(八甲基四硅氧烷)单体、6份如式2所示的季铵盐硅烷偶联剂、4份氢氧化钠，搅拌、溶解、乳化30min；升温至80℃，保温聚合反应4h；降温至50℃以下，以酸调节pH值至中性；升温至70℃，滴加10份如式3所示的可聚合季铵盐单体及0.4份过硫酸钠与20份水的溶液，1h滴完，再于75℃恒温反应2h，即得所述硅油乳液。
所述的双氧水稳定剂为氧浴保护剂OWS、双氧水稳定剂M-1021CC中的一种。
所述的精练剂为精练剂SK、精练剂LS66中的一种。
所述的高温匀染剂为高温耐盐匀染剂RS-11、涤纶染色宝DM-2831中的一种。
所述的锦纶匀染剂为匀染剂O、尼龙匀染剂B-31中的一种。
本发明涤锦粘面料短流程染整工艺，将精练、漂白合为一浴进行面料的前处理，涤、锦、粘的分散染料、酸性染料、活性染料三浴分别套染合为一浴一步法染色，其中，涤纶组份为分散染料低温染色工艺，并于后整理时以高阳离子密度的硅油进行染色面料的柔软、固色一浴整理，这些都极大地缩短了涤锦粘面料的染整工艺流程，染整加工时间由传统工艺的7-8小时缩短为3-4小时，节时降耗。
硅油乳液合成中引入季铵盐硅烷偶联剂，在D4开环缩聚形成的分子链中接入含双键的季铵盐单元，再与季铵盐单体共聚，形成的硅油乳液阳离子密度高，提高了面料的柔软手感，并对染色面料进行固色处理。
具体实施方式
本发明公开了一种涤锦粘面料短流程染整工艺，包括精练漂白前处理、一浴法染色、后整理工序。
精练漂白前处理：配置前处理液、浸入涤锦粘面料，升温至100℃，保温处理30min；前处理液由10g/L NaOH、6g/L双氧水、3g/L双氧水稳定剂、3g/L精练剂、4g/L螯合分散剂及水组成。
一浴法染色：按浴比配置染液，升温至70℃、保温染色15min，再升温至110℃、保温染色30min，降温、排液、水洗；染液由分散染料、中性固色活性染料、中性染料及2g/L螯合分散剂、2g/L高温匀染剂、1g/L锦纶匀染剂、8g/L元明粉及水组成。
双氧水稳定剂、精练剂、高温匀染剂、锦纶匀染剂等均可市购得到，为本领域常规产品，可选用如下产品：
所述的双氧水稳定剂为氧浴保护剂OWS(苏州联胜化学有限公司)、双氧水稳定剂M-1021CC(杭州美高华颐化工有限公司)；
所述的精练剂为精练剂SK(上海天坛助剂有限公司)、精练剂LS66(苏州联胜化学有限公司)；
所述的高温匀染剂为高温耐盐匀染剂RS-11(苏州联胜化学有限公司)、涤纶染色宝DM-2831(广东德美精细化工集团股份有限公司)；
所述的锦纶匀染剂为匀染剂O(上海天坛助剂有限公司)、尼龙匀染剂B-31(苏州联胜化学有限公司)中的一种。
所述的分散染料、中性固色活性染料、中性染料均为常规染料，市售产品如分散黄E-3G、分散红FB、分散蓝2BLN、分散黄C-4G、分散红玉SE-GFL、分散蓝SE-2R、
黄NF-4G、
黄NF-GR、
黄NF-GL、
大红NF-GL、
红NF-3B、
翠蓝NF-2G、
蓝NF-BN、
藏青NF-MG、
藏青NF-BG、
嫩黄M-4G、
黄M-2R、
黄M-NS、
橙M-RN、
红M-G、
红M-3B、
红M-NS、
蓝M-2RN、
蓝M-NS、
藏青M-R、
棕M-B、
灰M-G、
灰M-2G、
黑M-AR、
黑ACE 120％等。
中性固色活性染料又称热固型活性染料，这类活性染料通常含有不同于其他类型活性染料的新型基团——季铵型吡啶甲酸，它以季铵基为离去基，反应性强，在中性高温(>100℃)条件下便可与纤维素纤维发生固着反应，与中性染料染锦纶、分散染料染涤纶所要求的染色条件相近，可以实现染色一浴化。
后整理：涤锦粘面料浸轧后整理液，170-180℃条件下，30-40m/min车速定型；后整理液由20g/L硅油乳液及水组成。
所述的螯合分散剂，其制备方法为：360份水中加入12份马来酸酐及25份如式1所示的马来酸混合双酯，搅拌溶解，升温至82℃，滴加20份丙烯酸及0.6份过硫酸钾与20份水的溶液，2h滴加完毕，再保温反应4h；反应体系降至室温，按摩尔比n(马来酸混合双酯)：n(NaOH)：n(CS2)＝1:2.2:2.2的比例，先加入NaOH，溶解搅拌均匀，再于室温缓慢滴加CS2，滴加时间1h，然后继续保温反应2h，得所述的螯合分散剂；
所述的马来酸混合双酯，制备方法为：在配备搅拌器、温度计及回流冷凝器的反应器中加入摩尔比n(脂肪醇聚氧乙烯醚AEO-15)：n(马来酸酐)＝1:1.2的比例加入AEO-15及马来酸酐，并加入占马来酸酐质量1.2％的乙酸钠催化剂，氮气保护下，升温至105℃后，保温反应3h；再按摩尔比n(马来酸酐)：n(十二烷基单乙醇胺)＝1:1.05的比例，向反应器中加入十二烷基单乙醇胺，并加入占马来酸酐质量1.5％的硼酸，升温至130℃，保温反应4h，得马来酸混合双酯。反应过程如下式(1)、(2)所示。
所述的硅油乳液，其制备方法为：反应器中加入320份水、12份乳化剂、40份D4(八甲基四硅氧烷)单体、6份如式2所示的季铵盐硅烷偶联剂、4份氢氧化钠，搅拌、溶解、乳化30min；升温至80℃，保温聚合反应4h；降温至50℃以下，以酸调节pH值至中性；升温至70℃，滴加10份如式3所示的可聚合季铵盐单体及0.4份过硫酸钠与20份水的溶液，1h滴完，再于75℃恒温反应2h，即得所述硅油乳液。
涤锦棉面料通常在染色后，需另设水浴针对棉、锦进行固色处理，这样做得目的是提升染色后面料的色牢度。采用的固色剂一般为阳离子有机聚合物，若将固色处理工艺与后整理工艺结合，即在染色后面料进行柔软定型时，将固色剂与柔软剂复配对面料进行处理，则可减省染色后单独水浴固色工序。但常规市售的固色剂与柔软剂，按手感及牢度要求以一定比例复配成整理液并置于定型机料槽中，在运行的面料剪切作用下，固色剂与柔软剂往往会发生凝结而容易在面料表面形成硅油斑。这一现象主要是固色剂、柔软剂相容性差引起，这会导致整理液稳定性下降。
本发明所述硅油乳液，合成时引入季铵盐硅烷偶联剂，在D4开环缩聚形成的分子链中接入含双键的季铵盐单元，再与季铵盐单体共聚，形成的硅油乳液阳离子密度高。该硅油乳液的优点是，避免了常规固色剂与柔软剂复配易因表面张力差异而导致分相、凝结现象。因此，本发明所述硅油乳液，提高面料的柔软手感，并对染色面料进行固色处理，将固色与柔软整理一浴进行，无需染色后专门设置水浴进行固色的工序。
所述的季铵盐硅烷偶联剂，其制备方法为：a、在氮气保护下，按摩尔比2.02:1，将3-异氰酸酯基丙基三甲氧基硅烷、3-二甲氨基-1,2-丙二醇加入至反应器中，加入占3-异氰酸酯基丙基三甲氧基硅烷质量0.5％的辛酸亚锡，在70℃下搅拌反应5h，得化合物A；b、在氮气保护下，按摩尔比1:1.1将步骤a所得的化合物A及烯丙基氯加入反应器中，恒温水浴加热，55℃反应5h，反应过程中冷凝回流，反应结束后将粗产品旋转蒸发除去过量的烯丙基氯，得所述的季铵盐硅烷偶联剂。反应过程如反应方程式(3)、(4)所示。
所述的可聚合季铵盐单体为氯化二烯丙基甲基环氧丙基铵，制备方法如下：反应器中加入1mol的二烯丙基甲基胺及1.05mol的环氧氯丙烷，10mol的四氢呋喃，在60℃反应7h，提纯，得到氯化二烯丙基甲基环氧丙基铵。反应过程如反应式(5)所示：
硅油乳液聚合涉及的乳化剂，由非离子、阳离子乳化剂组成，非离子乳化剂为脂肪醇聚氧乙烯醚，如AEO-7、AEO-9、AEO-15等，阳离子乳化剂如十二烷基三甲基氯化铵、十六烷基三甲基溴化铵、十八烷基三甲基氯化铵等。非离子乳化剂与阳离子乳化剂质量比为1:2。
实施例1：
一种螯合分散剂，其制备方法为：360份水中加入12份马来酸酐及25份如式1所示的马来酸混合双酯，搅拌溶解，升温至82℃，滴加20份丙烯酸及0.6份过硫酸钾与20份水的溶液，2h滴加完毕，再保温反应4h；反应体系降至室温，按摩尔比n(马来酸混合双酯)：n(NaOH)：n(CS2)＝1:2.2:2.2的比例，先加入NaOH，溶解搅拌均匀，再于室温缓慢滴加CS2，滴加时间1h，然后继续保温反应2h，得所述的螯合分散剂；
其中的马来酸混合双酯，制备方法为：在配备搅拌器、温度计及回流冷凝器的反应器中加入摩尔比n(脂肪醇聚氧乙烯醚AEO-15)：n(马来酸酐)＝1:1.2的比例加入AEO-15及马来酸酐，并加入占马来酸酐质量1.2％的乙酸钠催化剂，氮气保护下，升温至105℃后，保温反应3h；再按摩尔比n(马来酸酐)：n(十二烷基单乙醇胺)＝1:1.05的比例，向反应器中加入十二烷基单乙醇胺，并加入占马来酸酐质量1.5％的硼酸，升温至130℃，保温反应4h，得马来酸混合双酯。反应过程如上述反应方程式(1)、(2)所示。
钙离子、三价铁离子、二价铜离子及钙分散力分别为：353mg/g、227mg/g、204mg/g、536mg/g。
实施例2：
一种硅油乳液，制备方法包括步骤如下：反应器中加入320份水、12份乳化剂、40份D4(八甲基四硅氧烷)单体、6份如式2所示的季铵盐硅烷偶联剂、4份氢氧化钠，搅拌、溶解、乳化30min；升温至80℃，保温聚合反应4h；降温至50℃以下，以酸调节pH值至中性；升温至70℃，滴加10份如式3所示的可聚合季铵盐单体及0.4份过硫酸钠与20份水的溶液，1h滴完，再于75℃恒温反应2h，即得所述硅油乳液。乳化剂由AEO-9、十二烷基三甲基氯化铵按质量比1:2组成。
所述的季铵盐硅烷偶联剂，其制备方法为：a、在氮气保护下，按摩尔比2.02:1，将3-异氰酸酯基丙基三甲氧基硅烷、3-二甲氨基-1,2-丙二醇加入至反应器中，加入占3-异氰酸酯基丙基三甲氧基硅烷质量0.5％的辛酸亚锡，在70℃下搅拌反应5h，得化合物A；b、在氮气保护下，按摩尔比1:1.1将步骤a所得的化合物A及烯丙基氯加入反应器中，恒温水浴加热，55℃反应5h，反应过程中冷凝回流，反应结束后将粗产品旋转蒸发除去过量的烯丙基氯，得所述的季铵盐硅烷偶联剂。反应过程如上述反应方程式(3)、(4)所示。
所述的可聚合季铵盐单体为氯化二烯丙基甲基环氧丙基铵，制备方法如下：反应器中加入1mol的二烯丙基甲基胺及1.05mol的环氧氯丙烷，10mol的四氢呋喃，在60℃反应7h，提纯，得到氯化二烯丙基甲基环氧丙基铵。反应过程如上述反应式(5)所示。
乳液机械稳定性：取100mL硅油乳液在高速分散机2800r/min高速分散60min。以凝聚物的多少表征机械稳定性，无凝聚物则表示乳液机械稳定性通过。经测试，本实施例的硅油乳液高速分散60min后，仍透明，没有飘油，也没有凝胶。
实施例3：
涤锦粘斜纹160D*R21S/70D 130*82 39％粘胶、37％涤纶、24％锦纶
涤锦粘面料短流程染整工艺，包括精练漂白前处理、一浴法染色、后整理工序，
精练漂白前处理：按浴比配置前处理液，浸入涤锦粘面料，升温至100℃，保温处理30min；
一浴法染色：按浴比配置染液，投入面料，升温至70℃、保温染色15min，再升温至110℃、保温染色30min，降温、排液、水洗；
后整理：涤锦粘面料浸轧后整理液，170-180℃条件下，30-40m/min车速定型；
前处理液由10g/L NaOH、6g/L双氧水、3g/L氧浴保护剂OWS(苏州联胜化学有限公司)、3g/L精练剂SK(上海天坛助剂有限公司)、4g/L螯合分散剂及水组成；浴比为1:8；
染液由分散染料、中性固色活性染料、中性染料及2g/L螯合分散剂、2g/L高温耐盐匀染剂RS-11(苏州联胜化学有限公司)、1g/L匀染剂O(上海天坛助剂有限公司)、8g/L元明粉及水组成；其中，染料处方为分散黄E-3G 0.17％、分散黄C-4G 0.36％、
黄NF-GR 0.23％、
黄NF-GL 0.38％、
黄M-2R 0.31％、
黄M-NS0.27％；浴比为1:10；
后整理液由硅油乳液及水组成，后整理液中硅油乳液的含量为20g/L；
其中的螯合分散剂由实施例1方法制备、硅油乳液由实施例2方法制备。
实施例4：
涤锦粘面料规格100D×32S+70D/234X138 44％粘胶、46％涤纶、10％锦纶
涤锦粘面料短流程染整工艺，包括精练漂白前处理、一浴法染色、后整理工序，
精练漂白前处理：按浴比配置前处理液，浸入涤锦粘面料，升温至100℃，保温处理30min；
一浴法染色：按浴比配置染液，投入面料，升温至70℃、保温染色15min，再升温至110℃、保温染色30min，降温、排液、水洗；
后整理：涤锦粘面料浸轧后整理液，170-180℃条件下，30-40m/min车速定型；
前处理液由10g/L NaOH、6g/L双氧水、3g/L双氧水稳定剂M-1021CC(杭州美高华颐化工有限公司)、3g/L精练剂LS66(苏州联胜化学有限公司)、4g/L螯合分散剂及水组成；浴比为1:8；
染液由分散染料、中性固色活性染料、中性染料及2g/L螯合分散剂、2g/L涤纶染色宝DM-2831(广东德美精细化工集团股份有限公司)、1g/L尼龙匀染剂B-31(苏州联胜化学有限公司)、8g/L元明粉及水组成；其中，染料处方为分散蓝2BLN 1.2％、
蓝NF-BN1.32％、
蓝M-2RN 0.74％、
蓝M-NS 0.53％；浴比为1:10；
后整理液由硅油乳液及水组成，后整理液中硅油乳液的含量为20g/L；
其中的螯合分散剂由实施例1方法制备、硅油乳液由实施例2方法制备。
实施例5：
涤锦粘面料规格70D×32S+40D/133×7247％涤纶、32％锦纶、21％粘胶
涤锦粘面料短流程染整工艺，包括精练漂白前处理、一浴法染色、后整理工序，
精练漂白前处理：按浴比配置前处理液、浸入涤锦粘面料，升温至100℃，保温处理30min；
一浴法染色：按浴比配置染液，投入面料，升温至70℃、保温染色15min，再升温至110℃、保温染色30min，降温、排液、水洗；
后整理：涤锦粘面料浸轧后整理液，170-180℃条件下，30-40m/min车速定型；
前处理液由10g/L NaOH、6g/L双氧水、3g/L双氧水稳定剂M-1021CC(杭州美高华颐化工有限公司)、3g/L精练剂SK(上海天坛助剂有限公司)、4g/L螯合分散剂及水组成；浴比为1:8；
染液由分散染料、中性固色活性染料、中性染料及2g/L螯合分散剂、2g/L高温耐盐匀染剂RS-11(苏州联胜化学有限公司)、1g/L尼龙匀染剂B-31(苏州联胜化学有限公司)、8g/L元明粉及水组成；其中，染料处方为分散红FB 0.47％、分散红玉SE-GFL 0.38％、
大红NF-GL 0.34％、
红NF-3B 0.57％、
红M-G 0.41％、
红M-3B 0.46％；浴比为1:10；
后整理液由硅油乳液及水组成，后整理液中硅油乳液的含量为20g/L；
其中的螯合分散剂由实施例1方法制备、硅油乳液由实施例2方法制备。
实施例3-5的三个染色试样按照相关标准测试了摩擦牢度、皂洗牢度，结果见表1所示。
表1不同染色试样的染色效果
经本发明短流程染整工艺的涤锦棉面料的干摩擦牢度、湿摩擦牢度和皂洗牢度优良，可满足服用要求，表明本发明短流程工艺可行。
摩擦牢度测试按照GB/T 3920-2008纺织品色牢度试验耐摩擦色牢度；
皂洗牢度测试按照GB/T3921-2008纺织品色牢度试验耐洗色牢度。
螯合分散剂性能测试方法如下：
1、螯合钙离子的测定
准确称取2g样品(精确至0.0001g)，加蒸馏水配成100mL溶液，然后移取25mL样品溶液至锥形瓶中，加入氨氯化铵缓冲溶液(pH＝10)5mL和少量质量分数为2％的草酸钠溶液。用0.1mol/L的乙酸钙标准溶液滴定，直至产生永久性白色沉淀为终点。按照上述步骤同时进行空白试验。每克螯合剂所螯合的CaCO3的毫克数即为钙离子的螯合值,按下式计算：
A＝[(V1-V0)C钙×M]/(G×25/100)
即A＝[(V1-V0)C钙×4M]/G
式中:C钙为乙酸钙标准溶液的浓度，mol/L；
V1为样品溶液消耗乙酸钙标准溶液的体积，mL；
V0为空白试验时消耗乙酸钙标准滴定溶液的体积，mL；
G为样品质量，g；
A为样品螯合钙离子的值；
M为100，表示螯合的碳酸钙的摩尔质量。
2、螯合三价铁离子的测定
准确称取1g样品(精确至0.0001g)，加蒸馏水配成100mL溶液，然后移取10mL样品溶液至锥形瓶中，加入蒸馏水40mL，用30％氢氧化钠溶液调节pH值为12。用1g/LFe3+标准溶液滴定，直至产生永久性混浊为终点(注意滴定过程中，若pH值变化，应加入30％氢氧化钠溶液调节，使pH值保持在12)。按照上述步骤同时进行空白试验。每克螯合剂络合三价铁离子的毫克数即为标准溶液滴定时所消耗的毫升数。三价铁离子的螯合值按下式计算：
A＝(V1-V0)/(G×10/100)
即A＝(V1-V0)×10/G
式中：V1为样品溶液消耗三价铁标准溶液的体积，mL；
V0为空白试验时消耗三价铁标准滴定溶液的体积，mL；
G为样品质量，g；
A为样品螯合三价铁离子的值。
3、螯合二价铜离子的测定
准确称取1g样品(精确至0.0001g)，加蒸馏水配成100mL溶液，然后移取10mL样品溶液至锥形瓶中，加入蒸馏水40mL，然后用30％氢氧化钠溶液调节pH值为12。用1g/L的Cu2+标准溶液滴定，直至产生永久性混浊为终点(注意滴定过程中，若pH值变化，应加入30％氢氧化钠溶液调节，使pH值保持在12)。按照上述步骤同时进行空白试验。每克螯合剂络合二价铜离子的毫克数即为标准溶液滴定时所消耗的毫升数。铜离子的螯合值按下式计算：
A＝(V1-V0)/(G×10/100)
即A＝(V1-V0)×10/G
式中：V1为样品溶液消耗铜离子标准溶液的体积，mL；
V0为空白试验时消耗铜离子标准滴定溶液的体积，mL；
G为样品质量，g；
A为样品螯合铜离子的值。
4、分散力的测定
准确称取4g样品(精确至0.0001g)配成100mL溶液，然后移取25mL样品溶液至锥形瓶中，加入10％的碳酸钠溶液10mL和30mL的蒸馏水。用0.1mol/L的乙酸钙标准溶液滴定，直至产生永久性白色沉淀为终点。同时做空白试验。分散力按下式进行计算：
F＝(V1-V0)C×100/(G×25/100)
即F＝(V1-V0)C×400/G
式中:C为乙酸钙标准溶液的浓度，mol/L；
V0为空白试验时消耗乙酸钙标准溶液的体积，mL；
V1为样液消耗乙酸钙标准溶液的体积，mL；
G为样品质量，g。
Claims (5)
1.涤锦粘面料短流程染整工艺，包括精练漂白前处理、一浴法染色、后整理工序，
精练漂白前处理：配置前处理液、浸入涤锦粘面料，升温至100℃，保温处理30min；
一浴法染色：按浴比配置染液，升温至70℃、保温染色15min，再升温至110℃、保温染色30min，降温、排液、水洗；
后整理：涤锦粘面料浸轧后整理液，170-180℃条件下，30-40m/min车速定型；
前处理液由10g/LNaOH、6g/L双氧水、3g/L双氧水稳定剂、3g/L精练剂、4g/L螯合分散剂及水组成；
染液由分散染料、中性固色活性染料、中性染料及2g/L螯合分散剂、2g/L高温匀染剂、1g/L锦纶匀染剂、8g/L元明粉及水组成；
后整理液由20g/L硅油乳液及水组成；
所述的螯合分散剂，其制备方法为：360份水中加入12份马来酸酐及25份如式1所示的马来酸混合双酯，搅拌溶解，升温至82℃，滴加20份丙烯酸及0.6份过硫酸钾与20份水的溶液，2h滴加完毕，再保温反应4h；反应体系降至室温，按摩尔比n(马来酸混合双酯)：n(NaOH)：n(CS2)＝1:2.2:2.2的比例，先加入NaOH，溶解搅拌均匀，再于室温缓慢滴加CS2，滴加时间1h，然后继续保温反应2h，得所述的螯合分散剂；
所述的硅油乳液，其制备方法为：反应器中加入320份水、12份乳化剂、40份D4(八甲基四硅氧烷)单体、6份如式2所示的季铵盐硅烷偶联剂、4份氢氧化钠，搅拌、溶解、乳化30min；升温至80℃，保温聚合反应4h；降温至50℃以下，以酸调节pH值至中性；升温至70℃，滴加10份如式3所示的可聚合季铵盐单体及0.4份过硫酸钠与20份水的溶液，1h滴完，再于75℃恒温反应2h，即得所述硅油乳液。
2.根据权利要求1所述的涤锦粘面料短流程染整工艺，其特征在于：所述的双氧水稳定剂为氧浴保护剂OWS、双氧水稳定剂M-1021CC中的一种。
3.根据权利要求1所述的涤锦粘面料短流程染整工艺，其特征在于：所述的精练剂为精练剂SK、精练剂LS66中的一种。
4.根据权利要求1所述的涤锦粘面料短流程染整工艺，其特征在于：所述的高温匀染剂为高温耐盐匀染剂RS-11、涤纶染色宝DM-2831中的一种。
5.根据权利要求1所述的涤锦粘面料短流程染整工艺，其特征在于：所述的锦纶匀染剂为匀染剂O、尼龙匀染剂B-31中的一种。
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