CN1106612A - 橡胶改性苯乙烯聚合物的膨胀发泡珠粒 - Google Patents
橡胶改性苯乙烯聚合物的膨胀发泡珠粒 Download PDFInfo
- Publication number
- CN1106612A CN1106612A CN94190151A CN94190151A CN1106612A CN 1106612 A CN1106612 A CN 1106612A CN 94190151 A CN94190151 A CN 94190151A CN 94190151 A CN94190151 A CN 94190151A CN 1106612 A CN1106612 A CN 1106612A
- Authority
- CN
- China
- Prior art keywords
- rubber
- styrene polymer
- bead
- expanded
- particle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011324 bead Substances 0.000 title claims abstract description 239
- 229920000642 polymer Polymers 0.000 title claims abstract description 209
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 234
- 229920001971 elastomer Polymers 0.000 claims abstract description 201
- 239000005060 rubber Substances 0.000 claims abstract description 201
- 239000002245 particle Substances 0.000 claims abstract description 178
- 150000003440 styrenes Chemical class 0.000 claims abstract description 103
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims description 59
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 47
- 239000000203 mixture Substances 0.000 claims description 37
- 239000011148 porous material Substances 0.000 claims description 29
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 19
- 238000010438 heat treatment Methods 0.000 claims description 16
- 230000008961 swelling Effects 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000000126 substance Substances 0.000 claims description 13
- 238000005520 cutting process Methods 0.000 claims description 12
- 241001237745 Salamis Species 0.000 claims description 10
- 230000004927 fusion Effects 0.000 claims description 10
- 235000015175 salami Nutrition 0.000 claims description 10
- 238000000605 extraction Methods 0.000 claims description 9
- 239000004793 Polystyrene Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 229920002223 polystyrene Polymers 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000012423 maintenance Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 17
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- 239000000243 solution Substances 0.000 description 29
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 26
- 238000002360 preparation method Methods 0.000 description 23
- 239000004088 foaming agent Substances 0.000 description 18
- 230000014509 gene expression Effects 0.000 description 18
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- 230000000052 comparative effect Effects 0.000 description 13
- 239000006185 dispersion Substances 0.000 description 12
- 238000000465 moulding Methods 0.000 description 12
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 12
- 230000008569 process Effects 0.000 description 11
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 10
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- 238000001125 extrusion Methods 0.000 description 9
- 239000000178 monomer Substances 0.000 description 9
- 238000010586 diagram Methods 0.000 description 8
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical class CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 239000011521 glass Substances 0.000 description 7
- 229920002857 polybutadiene Polymers 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
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- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
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- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
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- 238000005554 pickling Methods 0.000 description 3
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- 238000011925 1,2-addition Methods 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 238000006424 Flood reaction Methods 0.000 description 2
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- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
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- 239000013543 active substance Substances 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- ONJMNXFNTYIEEA-UHFFFAOYSA-N benzene ethene Chemical compound C1=CC=CC=C1.C=C.C=C.C=C ONJMNXFNTYIEEA-UHFFFAOYSA-N 0.000 description 2
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 description 2
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- 230000014759 maintenance of location Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
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- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 1
- OEVVKKAVYQFQNV-UHFFFAOYSA-N 1-ethenyl-2,4-dimethylbenzene Chemical compound CC1=CC=C(C=C)C(C)=C1 OEVVKKAVYQFQNV-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- FJZQJINKPHXUHM-UHFFFAOYSA-N 1-ethenyl-3-ethyl-2-methylbenzene Chemical compound CCC1=CC=CC(C=C)=C1C FJZQJINKPHXUHM-UHFFFAOYSA-N 0.000 description 1
- CYXIKYKBLDZZNW-UHFFFAOYSA-N 2-Chloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)CCl CYXIKYKBLDZZNW-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
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- 239000004215 Carbon black (E152) Substances 0.000 description 1
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- 239000004593 Epoxy Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
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- VLLYOYVKQDKAHN-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene Chemical compound C=CC=C.CC(=C)C=C VLLYOYVKQDKAHN-UHFFFAOYSA-N 0.000 description 1
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- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/901—Radial block
Abstract
Description
Claims (9)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12214393 | 1993-04-27 | ||
JP122143/93 | 1993-04-27 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN97125379A Division CN1067625C (zh) | 1993-04-27 | 1997-12-10 | 生产发泡模塑聚苯乙烯制品的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1106612A true CN1106612A (zh) | 1995-08-09 |
CN1038843C CN1038843C (zh) | 1998-06-24 |
Family
ID=14828680
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN94190151A Expired - Lifetime CN1038843C (zh) | 1993-04-27 | 1994-04-26 | 橡胶改性苯乙烯聚合物的膨胀发泡珠粒,其生产方法及用途 |
CN97125379A Expired - Lifetime CN1067625C (zh) | 1993-04-27 | 1997-12-10 | 生产发泡模塑聚苯乙烯制品的方法 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN97125379A Expired - Lifetime CN1067625C (zh) | 1993-04-27 | 1997-12-10 | 生产发泡模塑聚苯乙烯制品的方法 |
Country Status (10)
Country | Link |
---|---|
US (2) | US5525639A (zh) |
EP (1) | EP0648244B2 (zh) |
KR (2) | KR0150240B1 (zh) |
CN (2) | CN1038843C (zh) |
CA (1) | CA2135078C (zh) |
DE (1) | DE69413777T3 (zh) |
HK (1) | HK1012649A1 (zh) |
MY (1) | MY111891A (zh) |
SG (1) | SG48758A1 (zh) |
WO (1) | WO1994025516A1 (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101311216B (zh) * | 2002-07-31 | 2014-01-08 | 四国化工机株式会社 | 冷压成形用树脂片材及冷压成形加工品 |
CN109139550A (zh) * | 2018-08-14 | 2019-01-04 | 广东美的厨房电器制造有限公司 | 扇叶组件及其制备方法、风扇及家用电器 |
CN110041637A (zh) * | 2019-05-07 | 2019-07-23 | 安徽麦特电子股份有限公司 | 一种高效减震电容器防爆缓冲材料及其制备方法 |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2983435B2 (ja) * | 1993-07-30 | 1999-11-29 | 積水化成品工業株式会社 | 発泡性スチレン系樹脂粒子及び該粒子から得られるスチレン系樹脂発泡成形体 |
DE4416861A1 (de) * | 1994-05-13 | 1995-11-16 | Basf Ag | Expandierbare Styrolpolymerisate |
US5661191A (en) * | 1995-01-13 | 1997-08-26 | Mitsubishi Chemical Basf Company Limited | Expandable rubber-modified styrene resin beads, expanded beads thereof, and expanded molded articles obtained therefrom |
DE19527577A1 (de) * | 1995-07-28 | 1997-01-30 | Basf Ag | Schlagzähe thermoplastische Formmasse |
DE19544487A1 (de) * | 1995-11-29 | 1997-06-05 | Basf Ag | Schaumstoffe auf Basis von Copolymeren von Styrol und 1,1-Diphenylethen |
US6020388A (en) * | 1997-03-04 | 2000-02-01 | Tri-Technologies, Inc. | Methods for impregnating polymer beads |
DE19716572A1 (de) * | 1997-04-19 | 1998-10-22 | Basf Ag | Expandierbare Styrolpolymerisate |
JP3653393B2 (ja) * | 1997-09-12 | 2005-05-25 | 株式会社ジェイエスピー | 発泡性ゴム変性スチレン系樹脂組成物 |
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- 1994-04-26 MY MYPI94001057A patent/MY111891A/en unknown
- 1994-04-26 KR KR1019940704143A patent/KR0150240B1/ko not_active IP Right Cessation
- 1994-04-26 US US08/325,406 patent/US5525639A/en not_active Expired - Lifetime
- 1994-04-26 EP EP94913825A patent/EP0648244B2/en not_active Expired - Lifetime
- 1994-04-26 CA CA002135078A patent/CA2135078C/en not_active Expired - Fee Related
- 1994-04-26 DE DE69413777T patent/DE69413777T3/de not_active Expired - Fee Related
- 1994-04-26 WO PCT/JP1994/000700 patent/WO1994025516A1/en active IP Right Grant
- 1994-04-26 CN CN94190151A patent/CN1038843C/zh not_active Expired - Lifetime
- 1994-04-26 SG SG1996001346A patent/SG48758A1/en unknown
- 1994-04-26 KR KR1019980701069A patent/KR100236851B1/ko not_active IP Right Cessation
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1996
- 1996-06-11 US US08/655,668 patent/US5635543A/en not_active Expired - Lifetime
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1997
- 1997-12-10 CN CN97125379A patent/CN1067625C/zh not_active Expired - Lifetime
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1998
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Cited By (3)
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CN101311216B (zh) * | 2002-07-31 | 2014-01-08 | 四国化工机株式会社 | 冷压成形用树脂片材及冷压成形加工品 |
CN109139550A (zh) * | 2018-08-14 | 2019-01-04 | 广东美的厨房电器制造有限公司 | 扇叶组件及其制备方法、风扇及家用电器 |
CN110041637A (zh) * | 2019-05-07 | 2019-07-23 | 安徽麦特电子股份有限公司 | 一种高效减震电容器防爆缓冲材料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
EP0648244B2 (en) | 2001-07-25 |
KR0150240B1 (ko) | 1998-10-15 |
SG48758A1 (en) | 1998-05-18 |
DE69413777D1 (de) | 1998-11-12 |
WO1994025516A1 (en) | 1994-11-10 |
US5525639A (en) | 1996-06-11 |
MY111891A (en) | 2001-02-28 |
CA2135078C (en) | 1998-09-29 |
KR950701659A (ko) | 1995-04-28 |
EP0648244B1 (en) | 1998-10-07 |
DE69413777T3 (de) | 2002-04-18 |
KR100236851B1 (ko) | 2000-01-15 |
KR19990036400A (ko) | 1999-05-25 |
DE69413777T2 (de) | 1999-06-24 |
CN1193567A (zh) | 1998-09-23 |
CN1067625C (zh) | 2001-06-27 |
CN1038843C (zh) | 1998-06-24 |
EP0648244A1 (en) | 1995-04-19 |
CA2135078A1 (en) | 1994-11-10 |
US5635543A (en) | 1997-06-03 |
HK1012649A1 (en) | 1999-08-06 |
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