CN110291131B - 氧清除塑性材料 - Google Patents
氧清除塑性材料 Download PDFInfo
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- CN110291131B CN110291131B CN201880011550.XA CN201880011550A CN110291131B CN 110291131 B CN110291131 B CN 110291131B CN 201880011550 A CN201880011550 A CN 201880011550A CN 110291131 B CN110291131 B CN 110291131B
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- polyether
- hydrocarbon residue
- segment
- carbon atoms
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 76
- 229910052760 oxygen Inorganic materials 0.000 title claims description 76
- 239000001301 oxygen Substances 0.000 title claims description 76
- 229920003023 plastic Polymers 0.000 title claims description 23
- 239000004033 plastic Substances 0.000 title claims description 23
- 239000000463 material Substances 0.000 title claims description 19
- 230000002000 scavenging effect Effects 0.000 title description 29
- -1 polytetramethylene Polymers 0.000 claims abstract description 68
- 229920000728 polyester Polymers 0.000 claims abstract description 43
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 26
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 18
- 229920000570 polyether Polymers 0.000 claims abstract description 18
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract 9
- 239000000203 mixture Substances 0.000 claims description 38
- 230000004888 barrier function Effects 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 21
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 15
- 229910052723 transition metal Inorganic materials 0.000 claims description 13
- 150000003624 transition metals Chemical class 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 10
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 5
- 125000004989 dicarbonyl group Chemical group 0.000 claims description 4
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 229920001169 thermoplastic Polymers 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 125000003542 3-methylbutan-2-yl group Chemical group [H]C([H])([H])C([H])(*)C([H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims description 2
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 2
- 125000006547 cyclononyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 claims description 2
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 claims description 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 claims description 2
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 125000003548 sec-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 description 30
- 238000002156 mixing Methods 0.000 description 23
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 16
- 125000003118 aryl group Chemical group 0.000 description 16
- 239000010410 layer Substances 0.000 description 16
- 229920000139 polyethylene terephthalate Polymers 0.000 description 16
- 239000005020 polyethylene terephthalate Substances 0.000 description 16
- 239000000047 product Substances 0.000 description 16
- 238000004806 packaging method and process Methods 0.000 description 15
- 238000000071 blow moulding Methods 0.000 description 12
- 238000002347 injection Methods 0.000 description 12
- 239000007924 injection Substances 0.000 description 12
- 239000011112 polyethylene naphthalate Substances 0.000 description 12
- 235000013305 food Nutrition 0.000 description 10
- 238000001125 extrusion Methods 0.000 description 9
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 8
- 235000013361 beverage Nutrition 0.000 description 8
- 150000002430 hydrocarbons Chemical group 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 7
- 150000001338 aliphatic hydrocarbons Chemical group 0.000 description 7
- 150000002009 diols Chemical class 0.000 description 7
- 229920005669 high impact polystyrene Polymers 0.000 description 7
- 239000004797 high-impact polystyrene Substances 0.000 description 7
- 230000036284 oxygen consumption Effects 0.000 description 7
- 229920000098 polyolefin Polymers 0.000 description 7
- 229920001451 polypropylene glycol Polymers 0.000 description 7
- 239000002356 single layer Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 229940123973 Oxygen scavenger Drugs 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 229920001519 homopolymer Polymers 0.000 description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 229920002223 polystyrene Polymers 0.000 description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 6
- 239000007858 starting material Substances 0.000 description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 229920001400 block copolymer Polymers 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 5
- 239000010941 cobalt Substances 0.000 description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
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- 229920001684 low density polyethylene Polymers 0.000 description 5
- 239000004702 low-density polyethylene Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 4
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- LNGAGQAGYITKCW-UHFFFAOYSA-N dimethyl cyclohexane-1,4-dicarboxylate Chemical compound COC(=O)C1CCC(C(=O)OC)CC1 LNGAGQAGYITKCW-UHFFFAOYSA-N 0.000 description 2
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N ethyl trimethyl methane Natural products CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 description 2
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- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 235000015113 tomato pastes and purées Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 241001148471 unidentified anaerobic bacterium Species 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
- B65D81/26—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
- B65D81/266—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/672—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/025—Polyesters derived from dicarboxylic acids and dihydroxy compounds containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
- C08L2203/162—Applications used for films sealable films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Mechanical Engineering (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Wrappers (AREA)
- Polyethers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP17156041.0 | 2017-02-14 | ||
| EP17156041.0A EP3360911A1 (en) | 2017-02-14 | 2017-02-14 | Oxygen scavenging plastic material |
| PCT/EP2018/053399 WO2018149778A1 (en) | 2017-02-14 | 2018-02-12 | Oxygen scavenging plastic material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110291131A CN110291131A (zh) | 2019-09-27 |
| CN110291131B true CN110291131B (zh) | 2022-09-16 |
Family
ID=58054013
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201880011550.XA Active CN110291131B (zh) | 2017-02-14 | 2018-02-12 | 氧清除塑性材料 |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US11447627B2 (es) |
| EP (2) | EP3360911A1 (es) |
| JP (1) | JP7127045B2 (es) |
| KR (1) | KR102548545B1 (es) |
| CN (1) | CN110291131B (es) |
| AR (1) | AR111152A1 (es) |
| AU (1) | AU2018222474B2 (es) |
| CA (1) | CA3050058A1 (es) |
| EA (1) | EA201991903A1 (es) |
| ES (1) | ES2868096T3 (es) |
| MX (1) | MX2019009391A (es) |
| MY (1) | MY192428A (es) |
| SA (1) | SA519402349B1 (es) |
| SG (1) | SG11201906649VA (es) |
| TW (1) | TWI756351B (es) |
| UA (1) | UA124040C2 (es) |
| WO (1) | WO2018149778A1 (es) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3360911A1 (en) | 2017-02-14 | 2018-08-15 | Clariant Plastics & Coatings Ltd | Oxygen scavenging plastic material |
| US20200223569A1 (en) * | 2017-10-02 | 2020-07-16 | Basf Se | Container made from polybutylene terephthalate having a low oxygen permeability |
| WO2019096942A1 (en) * | 2017-11-17 | 2019-05-23 | Unilever Plc | Soil release polymers and laundry detergent compositions containing them |
| EP3489340A1 (en) * | 2017-11-28 | 2019-05-29 | Clariant International Ltd | Renewably sourced soil release polyesters |
| US12030984B2 (en) | 2018-05-24 | 2024-07-09 | Clariant International Ltd | Soil release polyesters for use in detergent compositions |
| EP3594260A1 (en) * | 2018-07-13 | 2020-01-15 | Clariant Plastics & Coatings Ltd | Composition comprising a polyester-polyether polymer, a transition metal catalyst, and an active material |
| CN113825567B (zh) | 2019-05-14 | 2024-07-26 | 艾尔诺沃股份有限公司 | 用于保存活性物质的器皿以及相应的盖和容器 |
| WO2020229601A1 (en) | 2019-05-14 | 2020-11-19 | Airnov, Inc. | Receptacle for holding an active substance and corresponding closure and container with such a receptacle |
| TWI712646B (zh) * | 2019-06-27 | 2020-12-11 | 遠東新世紀股份有限公司 | 聚酯組成物 |
| US20230013817A1 (en) | 2020-01-03 | 2023-01-19 | Airnov, Inc. | Assembly defining a chamber for an active material |
| EP4084893A1 (en) | 2020-01-03 | 2022-11-09 | Airnov, Inc. | Gas-permeable element for a receptacle |
| WO2021219850A1 (en) | 2020-04-30 | 2021-11-04 | Airnov, Inc. | Marking method and marked receptacle |
| CN116615380A (zh) | 2020-12-18 | 2023-08-18 | 艾尔诺沃股份有限公司 | 防盗用封闭件 |
| US20240017906A1 (en) | 2020-12-29 | 2024-01-18 | Airnov, Inc. | A gas-permeable element and a method of manufacturing the same |
| CN113956451A (zh) * | 2021-12-07 | 2022-01-21 | 中国科学院宁波材料技术与工程研究所 | 可降解高气体阻隔性聚酯-聚碳酸酯共聚物、制法及应用 |
| CN114044888B (zh) * | 2021-12-07 | 2024-02-13 | 中国科学院宁波材料技术与工程研究所 | 可水解降解的聚合物、其制备方法及应用 |
| CA3240294A1 (en) * | 2021-12-24 | 2023-06-29 | Bing Wang | Process for the production of polyester (co)polymers |
| EP4206089B1 (en) | 2021-12-30 | 2024-08-28 | Airnov, Inc. | Blister pack |
| EP4209429A1 (en) | 2021-12-30 | 2023-07-12 | Airnov, Inc. | Dispensing device |
| TW202327952A (zh) | 2021-12-31 | 2023-07-16 | 美商艾爾諾沃股份有限公司 | 為活性材料定義腔室的總成和製造該總成的方法 |
| GB202215453D0 (en) | 2022-10-19 | 2022-11-30 | Colormatrix Holdings Inc | Scavenging oxygen |
| EP4393837A1 (en) | 2022-12-30 | 2024-07-03 | Airnov, Inc. | Tamper-evident closure |
| WO2024156740A1 (en) | 2023-01-24 | 2024-08-02 | Airnov, Inc. | Sealing cap and closure comprising the same |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5137993A (ja) * | 1974-09-27 | 1976-03-30 | Teijin Ltd | Seidenseihoriesuteruno seizoho |
| JPS59135222A (ja) * | 1983-01-25 | 1984-08-03 | Teijin Ltd | ポリエステル共重合体 |
| JPH03229724A (ja) * | 1990-02-02 | 1991-10-11 | Du Pont Toray Co Ltd | ポリエステルエラストマ共重合体の製造方法 |
| US6083585A (en) | 1996-09-23 | 2000-07-04 | Bp Amoco Corporation | Oxygen scavenging condensation copolymers for bottles and packaging articles |
| DE69701814T2 (de) | 1996-09-23 | 2000-10-12 | Bp Amoco Corp., Chicago | Nicht sauerstoffdurchlässige kunstoffflasche für bier und andere anwendungen |
| US6455620B1 (en) | 1999-08-10 | 2002-09-24 | Eastman Chemical Company | Polyether containing polymers for oxygen scavenging |
| JP4651146B2 (ja) * | 2000-02-24 | 2011-03-16 | 三菱エンジニアリングプラスチックス株式会社 | 共重合ポリエステルエーテル及びそれからなるフィルム |
| EP1701998B1 (en) | 2003-12-17 | 2011-02-09 | DSM IP Assets B.V. | Oxygen scavenging composition |
| DE602004019688D1 (de) | 2003-12-17 | 2009-04-09 | Dsm Ip Assets Bv | Sauerstoffabfangzusammensetzung |
| US20110008554A1 (en) * | 2007-08-31 | 2011-01-13 | Invista North America S.A.R.I. | Oxygen scavenging plastic compositions |
| KR101742831B1 (ko) * | 2009-02-20 | 2017-06-15 | 인비스타 테크놀러지스 에스.에이 알.엘. | 짧은 유도 기간을 갖는 산소 제거 수지 |
| EP2886601A1 (en) * | 2013-12-20 | 2015-06-24 | Invista Technologies S.A R.L. | Improved polyester-ether resin blends |
| US9447321B2 (en) | 2014-01-16 | 2016-09-20 | Graham Packaging Company, L.P. | Oxygen scavenging compositions for plastic containers |
| US20160130433A1 (en) * | 2014-11-07 | 2016-05-12 | Graham Packaging Company, L.P. | Oxygen scavenging compositions requiring no induction period |
| EP3250640B1 (en) * | 2015-01-30 | 2019-03-13 | Graham Packaging Company, L.P. | Durable oxygen scavenging plastic containers |
| EP3360911A1 (en) | 2017-02-14 | 2018-08-15 | Clariant Plastics & Coatings Ltd | Oxygen scavenging plastic material |
-
2017
- 2017-02-14 EP EP17156041.0A patent/EP3360911A1/en not_active Withdrawn
-
2018
- 2018-01-30 TW TW107103239A patent/TWI756351B/zh active
- 2018-02-12 WO PCT/EP2018/053399 patent/WO2018149778A1/en unknown
- 2018-02-12 US US16/485,565 patent/US11447627B2/en active Active
- 2018-02-12 EA EA201991903A patent/EA201991903A1/ru unknown
- 2018-02-12 EP EP18708911.5A patent/EP3583152B8/en active Active
- 2018-02-12 AU AU2018222474A patent/AU2018222474B2/en active Active
- 2018-02-12 MX MX2019009391A patent/MX2019009391A/es unknown
- 2018-02-12 CN CN201880011550.XA patent/CN110291131B/zh active Active
- 2018-02-12 SG SG11201906649VA patent/SG11201906649VA/en unknown
- 2018-02-12 UA UAA201909811A patent/UA124040C2/uk unknown
- 2018-02-12 ES ES18708911T patent/ES2868096T3/es active Active
- 2018-02-12 CA CA3050058A patent/CA3050058A1/en active Pending
- 2018-02-12 JP JP2019543077A patent/JP7127045B2/ja active Active
- 2018-02-12 MY MYPI2019004094A patent/MY192428A/en unknown
- 2018-02-12 KR KR1020197026728A patent/KR102548545B1/ko active IP Right Grant
- 2018-02-14 AR ARP180100348A patent/AR111152A1/es active IP Right Grant
-
2019
- 2019-07-30 SA SA519402349A patent/SA519402349B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| SA519402349B1 (ar) | 2022-08-01 |
| EA201991903A1 (ru) | 2020-01-20 |
| MY192428A (en) | 2022-08-19 |
| JP7127045B2 (ja) | 2022-08-29 |
| AU2018222474A1 (en) | 2019-08-01 |
| US20200017679A1 (en) | 2020-01-16 |
| ES2868096T3 (es) | 2021-10-21 |
| BR112019015421A2 (pt) | 2020-03-31 |
| CA3050058A1 (en) | 2018-08-23 |
| AU2018222474B2 (en) | 2022-12-15 |
| KR20190112325A (ko) | 2019-10-04 |
| WO2018149778A1 (en) | 2018-08-23 |
| KR102548545B1 (ko) | 2023-06-29 |
| AR111152A1 (es) | 2019-06-12 |
| EP3583152B8 (en) | 2021-05-05 |
| CN110291131A (zh) | 2019-09-27 |
| EP3360911A1 (en) | 2018-08-15 |
| UA124040C2 (uk) | 2021-07-07 |
| MX2019009391A (es) | 2019-10-15 |
| JP2020507654A (ja) | 2020-03-12 |
| EP3583152A1 (en) | 2019-12-25 |
| TW201841975A (zh) | 2018-12-01 |
| TWI756351B (zh) | 2022-03-01 |
| EP3583152B1 (en) | 2021-03-24 |
| US11447627B2 (en) | 2022-09-20 |
| SG11201906649VA (en) | 2019-08-27 |
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